Browse Topic: Metals
A machine-learning strategy has generated a new class of ultra-high strength and ductility steel for 3D printing that costs less, resists rust, and requires only a fraction of the usual processing time.
Led by Dr. Marina Freitag, a research group from the School of Natural and Environmental Sciences created dye-sensitized photovoltaic cells based on a copper (II/I) electrolyte, achieving an unprecedented power conversion efficiency of 38 percent and 1.0V open-circuit voltage at 1,000 lux (fluorescent lamp). The cells are non-toxic and environmentally friendly — setting a new standard for sustainable energy sources in ambient environments.
Additive manufacturing (AM) processes facilitate the production of components with high geometrical complexity, presenting substantial opportunities for innovation in demanding sectors such as aerospace and biomedical engineering. A significant challenge impeding their broader application is the characteristic surface roughness of as-fabricated parts, which results from the layer-wise construction and the presence of partially melted powder particles. While electrochemical polishing (EP) represents a viable post-processing technique for achieving a smooth surface finish, a comprehensive understanding of how the non-equilibrium microstructures characteristic of AM materials interact with the EP process remains incomplete. This investigation centers on the electrochemical polishing behavior of Ti-6Al-4V alloy fabricated by direct energy deposition (DED), utilizing a sodium chloride-ethylene glycol electrolyte. The findings reveal that the material's distinct engenders anisotropic anodic dissolution. This behavior is attributed to the differential electrochemical potentials among the constituent phases and their crystallographic orientations, which consequently narrows the operational process window for effective, uniform polishing. This preferential dissolution of certain phases results in the formation of a subtle, micro-scale topographical variation that mirrors the orientation of the original columnar grain structure. Notwithstanding this microstructural influence, the EP treatment proved highly successful in refining the surface finish, substantially decreasing the average surface roughness from 0.350 μm to 0.042 μm. Concurrently, the treatment led to a significant enhancement in the alloy's corrosion resistance, attributed to an oxide layer. These findings underscore the critical necessity of accounting for microstructural characteristics when developing optimized electrochemical polishing protocols for additively manufactured components.
To facilitate the development and application of bulb-flat titanium alloys in aerospace and automotive industries, this study selects TC4 as the research material and employs finite element simulation software to simulate the hot rolling process of TC4 bulb flat titanium. The temperature field, strain field, and metal flow velocity in each rolling pass are analyzed, and rolling experiments are conducted after optimizing the roll pass system. The results indicate that during the rolling process of TC4 bulb flat titanium, the head undergoes relatively smaller deformation, resulting in a slower temperature decrease, whereas the waist experiences greater deformation and a faster temperature drop. A significant temperature difference exists between the core and surface, which can be mitigated by appropriately increasing the roll temperature to reduce heat transfer. Prior to the K4 pass, the billet temperature drops to a level that may affect rolling performance, necessitating furnace reheating. Strain increases progressively with each rolling pass, with higher values observed at the waist compared to the head. A gradual strain transition occurs at the interface between the head and waist. Furthermore, the irregular design of the roll pass leads to a considerable difference in metal flow velocity between the upper and lower surfaces. During the K1 pass rolling, this imbalance can cause the guide guard to be displaced upward and result in roll wrapping. Without altering the roll diameter, shifting the entire roll pass system toward the side with higher metal flow velocity effectively reduces the linear velocity and prevents these issues, ensuring stable billet rolling. Rolling experiments successfully produced the final TC4 bulb flat titanium, thereby validating the feasibility of the optimized roll pass system and the rationality of the selected rolling parameters. It provides the possibility for its development and application in fields such as aircraft and automobiles.
Blended metal powders offer a compelling alternative to pre-alloyed powders in metal additive manufacturing by providing access to a wider range of alloy compositions and avoiding the high costs in producing pre-alloyed powders. In this work, a new and crack-free Ti-5AlMnScZrMgSiFe alloy (in wt.%) was manufactured by laser powder bed fusion (L-PBF) from mixed powders to investigate the microstructures, mechanical performance of printed parts. Ti-5 AlMnScZrMgSiFe alloy contains both alpha (α) and alpha prime (α′) phases. Further microstructural characterizations show that the L-PBF Ti-5 AlMnScZrMgSiFe contain dense dislocations and twins formed in additive manufacturing process. The as-printed Ti-5 AlMnScZrMgSiFe alloy exhibits a tensile fracture strength of ~950 MPa with a fracture elongation of ~12.5%. The eye-catching properties are attributed to the dense dislocations, nano-twins and solid-solution strengthening.
This research demonstrates a facile method for fabricating an anti-icing coating through spray deposition on a metallic substrate. A dual-layer structure was designed to enhance icephobic properties: a primer layer incorporating fluorocarbon resin, butyl acetate, and rod-shaped micrometer-sized metal oxides to establish a secondary roughness morphology, followed by a topcoat composed of butyl acetate and nano-scaled superhydrophobic particles. Evaluation of the coating performance revealed a maximum water contact angle of 171.9°, indicating exceptional hydrophobicity. Furthermore, the coating exhibited notable abrasion resistance and anti-icing capabilities against overlaying ice.
The malfunction of the aircraft windshield electric heating system, particularly arc discharge, poses a serious threat to flight safety by causing glass breakage. A systematic study was conducted on the causes and effects of arc faults on windshield structural integrity, employing macroscopic observation, microscopic analysis, and energy dispersive spectroscopy (EDS) following a windshield fracture incident. The results indicate that arc discharge typically occurs at the interface between the heating film busbar and adjacent structures. Localized high temperatures cause the outer glass to fracture, generating radial cracks. The ablation of the busbar silver coating and the carbonization of the PVB interlayer are direct evidence of arc action, whereas the heating wire remains a passive component affected by the high-temperature environment. The fault is primarily attributed to local disbonding at the busbar interface and moisture ingress. Based on the findings, recommendations are proposed for process optimization and inspection method improvement, providing a basis for the safe design and maintenance of windshield structures.
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