Browse Topic: Chromium

Items (2,004)
This study investigates the characterization and dry machining performance of advanced physical vapor deposition (PVD) aluminum titanium nitride (AlTiN) and aluminum chromium titanium nitride (AlCrTiN) coatings deposited using three techniques: cathodic arc evaporation (CAE), high-power impulse magnetron sputtering (HiPIMS), and scalable pulse power plasma (S3p). The coatings were evaluated for thickness, microstructure, surface roughness, coefficient of friction (CoF), adhesion strength, and microhardness. Among the tested coatings, the S3p-deposited AlCrTiN showed the best performance, exhibiting the highest microhardness (40 GPa), the strongest adhesion (108 N), and the lowest CoF (0.25), along with a defect-free microstructure. Under the selected dry turning condition of 150 m/min cutting speed, 0.15 mm/rev feed rate, and 0.7 mm depth of cut, the S3p-deposited AlCrTiN coating achieved a maximum tool life of 10,800 mm, nearly three times higher than the CAE-deposited AlTiN coating. In contrast, CAE coatings showed comparatively lower hardness and weaker adhesion, with minimum values of 25 GPa and 68 N for C1, along with higher CoF values of 0.58–0.60. Furthermore, AlCrTiN coatings produced by HiPIMS and S3p provided 20–30% longer tool life than AlTiN coatings under identical cutting conditions, highlighting the importance of deposition technique.
Dinkar Sonawane, Gaurav
This specification covers a blend of chromium carbide and a nickel-chromium alloy in the form of powder.
AMS F Corrosion and Heat Resistant Alloys Committee
In the category of cast stainless steels, there are several variants per different level of addition of chromium, vanadium along with some minor elements, such as molybdenum, niobium, tungsten to meet the requirement of corrosion and oxidation resistance. However, the influence of chemical composition variations on the mechanical properties of cast SS continues to lack a clear understanding. In the present study, via machine learning, the effects of each element on the tensile properties of the selected cast stainless steel are studied. The machine learning model is then used to predict how variations in elements affect tensile behavior, with the predictions validated through physical testing.
Mishra, NeelamBiswas, SurjayanV S, RajamanickamAluru, PhaniLiu, YiAkbari, MeysamCoryell, Jason
This specification covers the requirements for electrodeposited hard chromium plate.
AMS B Finishes Processes and Fluids Committee
A new material might contribute to a reduction of the fossil fuels consumed by aircraft engines and gas turbines in the future. A research team from Karlsruhe Institute of Technology (KIT) has developed a refractory metal-based alloy with properties unparalleled to date. The novel combination of chromium, molybdenum, and silicon is ductile at ambient temperature. With its melting temperature of about 2,000 degrees Celsius, it remains stable even at high temperatures and is at the same time oxidation resistant. The results are published in the journal Nature.
A new high-temperature resistant material exhibits great potential for applications such as energy-efficient aircraft turbines. Karlsruhe Institute of Technology, Karlsruhe, Germany A new material might contribute to a reduction of the fossil fuels consumed by aircraft engines and gas turbines in the future. A research team from Karlsruhe Institute of Technology (KIT) has developed a refractory metal-based alloy with properties unparalleled to date. The novel combination of chromium, molybdenum, and silicon is ductile at ambient temperature. With its melting temperature of about 2,000 degrees Celsius, it remains stable even at high temperatures and is at the same time oxidation resistant. The results are published in the journal Nature. High-temperature-resistant metallic materials are required for aircraft engines, gas turbines, X-ray units, and many other technical applications. Refractory metals such as tungsten, molybdenum, and chromium, whose melting points are around or higher than 2,000 degrees Celsius, can be most resistant to high temperatures. Their practical application, however, has limitations: They are brittle at room temperature and, in contact with oxygen, they start to oxidize causing failure within short time already at temperatures of 600 to 700 degrees Celsius. Therefore, they can only be used under technically complex vacuum conditions - for example as X-ray rotating anodes.
With rising environmental concerns, developing lead-free solders is crucial for sustainable electronics. Traditional lead-based solders, while effective, pose health and environmental risks, prompt a shift to safer alternatives that retain reliability. Sn-9Zn alloys, when alloyed with elements such as cerium (Ce) and chromium (Cr), show enhanced mechanical and thermal properties suited for modern electronics. This study examines the effects of Ce and Cr, and their combination in Sn-9Zn solder alloy, analyzing improvements in microstructure, thermal, wettability, and hardness properties. Microstructural analysis reveals that Ce and Cr additions refine the alloy’s structure, benefiting performance. Wettability testing shows that Sn-9Zn-0.05Ce achieves the lowest wetting angle, while Sn-9Zn-0.05Ce-0.1Cr displays a balanced angle between Sn-9Zn-0.05Ce and Sn-9Zn-0.1Cr. Differential scanning calorimetry (DSC) results indicate that Sn-9Zn-0.05Ce has the lowest melting temperature, while Sn-9Zn-0.1Cr has the highest, with Ce and Cr together reducing the melting temperature by 2.83°C from the peak in Sn-9Zn-0.1Cr. Apart from this, the Vickers microhardness test reveals the highest hardness in Sn-9Zn-0.05Ce-0.1Cr with 19.62 HV, underscoring the strengthening effects of Ce and Cr. The outcomes suggest Ce and Cr alloying as a promising approach to enhance the performance of lead-free solders in eco-friendly electronics.
Kumar, NiranjanMaurya, Ambrish
This specification covers a corrosion-resistant steel in the form of cold-worked bars and wire up to 1.750 inches (44.45 mm), inclusive, in nominal diameter or least distance between parallel sides.
AMS F Corrosion and Heat Resistant Alloys Committee
Electrical discharge machining (EDM) technology is one of the unconventional machining processes with an ability to machine intricate geometrics with micro finishing. Powder-mixed EDM (PMEDM) extends the EDM process by adding conductive powder to the dielectric fluid to improve performance. This set of experiments summarizes the effect of brass and copper electrode on HcHcr D2 tool steel in chromium powder-mixed dielectric fluid. Powder concentration (PC), peak current (I), and pulse on-time (Ton) are considered as variable process parameters. General full factorial design of experiment (DOE) and ANOVA has been used to plan and analyze the experiments where powder concentration is observed as the most significant process parameter. The results also reveal that a brass electrode offers a high material removal rate (MRR). Whereas, the copper electrode has reported noteworthy improvement in surface roughness (Ra). Moreover, teaching–learning-based optimization (TLBO) algorithm has been used to optimize the developed multi-objective function assisted by the regression equations.
Sonawane, Gaurav DinkarSulakhe, VishalDalu, RajendraKaware, KiranMotwani, Amit
Purified nickel and a large number of MgTi2 / NiO2 catalysts with various MgTi2 loadings were produced using the traditional incipient wetness method. X-ray crystallography and Fourier-transform infrared spectroscopy were used to examine the catalysts. To understand the material's microstructure better, the researchers investigated oxygen adsorption at 90K. The amine titration method was used to investigate the acidic characteristics of these catalysts. In a study on cumene cracking, these catalysts were employed. The catalyst was found to be amorphous up to a loading of 12 weight percent MgTi2, but at higher loadings, crystalline MgTi2 phase formed on an amorphous silica substrate. When NiO2 is doped with more MgTi2, there are significant differences in the structure, surface acidity, and catalytic activity of the catalysts. Catalysts with a higher MgTi2 loading are noticeably more acidic than those with a lower MgTi2 loading. A correlation between the amount of cracking activity and the number of acid sites on the catalyst surface has been shown in numerous studies. Cumene cannot be cracked over the investigated catalysts unless the catalyst contains extremely acidic sites. Unmistakably Bronsted acid sites, with the breaking action attributed to a mechanism involving chromium ions. The results were validated by comparing them with relevant studies in the existing literature. These comparisons demonstrate consistency with similar research, confirming the effectiveness of the MgTi2/NiO2 catalysts.
Ashok Kumar, B.Dhiyaneswaran, J.Selvaraj, MalathiPradeepkumar, M.Shajeeth, S.
Super duplex stainless steel (SDSS) is a type of stainless steel made of chromium (Cr), nickel (Ni), and iron (Fe). In the present work, a 1.6 mm wide thin sheet of SDSS is joined using gas tungsten arc welding (GTAW). The ideal parameter for a bead-on-plate trial is found, and 0.216 kJ/mm of heat input is used for welding. As an outcome of the welding heating cycle and subsequent cooling, a microstructural study revealed coarse microstructure in the heat-affected zone and weld zone. The corrosion rate for welded joints is 9.3% higher than the base metal rate. Following the corrosion test, scanning electron microscope (SEM) analysis revealed that the welded joint’s oxide development generated a larger corrosive attack on the weld surface than the base metal surface. The percentages of chromium (12.5%) and molybdenum (24%) in the welded joints are less than those in the base metal of SDSS, as per energy dispersive X-ray (EDX) analysis. Corrosion modeling is done using the COMSOL Multiphysics software. Electrochemical corrosion modeling is used to determine the electrolyte potential (i.e., 0.09 V) and current density (i.e., 0.2 A/m2 to 1.8 A/m2). An entire mesh model contains 6240 elements. The largest and smallest element sizes are 4 mm and 0.1 mm, respectively. The maximum element rate of growth is 1.2.
Kumar, SujeetKumar, YogeshE. K., Vimal K.
High-strength steel has several industrial applications such as automobile, tool and die, construction industries etc. However, it is challenging to achieve it. Various strengthening mechanisms, such as dispersion strengthening, alloying, grain boundary strengthening etc., plays a vital role in deciding the properties of the steel. At the industrial level, high-strength steel is produced by adding alloying elements such as Tungsten, Chromium, and Molybdenum in the steel matrix, increasing the high-strength steel cost. On the other hand, Wire Arc Additive manufacturing (WAAM) can produce dispersion strengthening in steel to mimic the properties of a high-strength steel matrix. The WAAM is a relatively low-cost additive manufacturing technology which uses a welding process to build up layers of material to fabricate the finished product. We have dispersed hard silicon carbide (SiC) particles in the mild steel matrix using the WAAM process in this work. SiC-dispersed steel's hardness is 28% higher than mild steel samples prepared by the WAAM process. The SEM micrograph shows the presence of dispersion of SiC in the steel matrix, which increases hardness compared to mild steel samples.
Natarajan, HarshavardhanaVincent, Akash
This specification covers an aluminum alloy in the form of sheet and plate 0.006 to 3.000 inches (0.15 to 76.20 mm), inclusive, in nominal thickness (see 8.5).
AMS D Nonferrous Alloys Committee
This specification covers the requirements for brush plating of zinc-nickel by electrodeposition.
AMS B Finishes Processes and Fluids Committee
Electroplating is a process whereby an object is coated with one or more relatively thin, tightly adherent layers of one or more metals. It is accomplished by placing the object to be coated on a plating rack or a fixture, or in a basket or in a rotating container in such a manner that a suitable current may flow through it, and then immersing it in a series of solutions and rinses in planned sequence. The advantage to be gained by electroplating may be considerable; broadly speaking, the process is used when it is desired to endow the basis material (selected for cost, material conservation, and physical property reasons) with surface properties it does not possess. It should be noted that although electroplating is the most widely used process for applying metals to a substrate, they may also be applied by spraying, vacuum deposition, cladding, hot dipping, chemical reduction, mechanical plating, etc. The purpose for applying an electroplate and the metals used for various applications follow.
Metals Technical Committee
This specification covers an aircraft-quality, low-alloy steel in the form of bars, forgings, and forging stock.
AMS E Carbon and Low Alloy Steels Committee
This specification covers an aluminum alloy in the form of coiled sheet 0.010 to 0.249 inch (0.25 to 6.32 mm), inclusive, in thickness, supplied in the -T4 temper (see 8.5).
AMS D Nonferrous Alloys Committee
E-25 General Standards for Aerospace and Propulsion Systems
The present work discusses the effects of Electrolytically deposited chromium coating on the Tribological behaviour of piston ring material. The frictional behaviours were evaluated using the linear reciprocating Tribometer under varying conditions of load and temperature. Test temperatures of 25, 50, and 100 degrees Celsius and loads of 20, 30, and 40N were applied during the tests to obtain the wear response of the coating under conditions similar to real piston cylinder/ring friction conditions. Tests were carried out with a constant sliding speed of 0.1 m/s. Optical micrographs and scanning electron microscope were used to analyze the nature of wear. It has been found that for lubricated or non-lubricated and coated or uncoated specimens, on increasing load, wear and surface roughness both increased for pins and plates. For dry conditions and a fixed load of 30N, wear of coated pins is found to be increasing with temperature from 25॰C to 100॰C, but plate wear shows a fully opposite variation in wear with increasing temperature thus wear decreased. Therefore, a substantial resistance to wear has been achieved by the hard chromium coating of pins.
Sharma, Vipin KumarJoshi, SumitMittal, RajatKaushik, IshaanVashisth, GarvitGoel, KunalGupta, Tarun
This paper will illustrate the surface treatment coating that forms a strong metallurgical bond between the titanium alloy matrix regarding the high friction properties and challenging lubricating of titanium alloys. In this research, TC4 has been selected as a base material instead of TiC. Then Ni-composite coating was employed as the surface treatment of TC4 by laser cladding (LC) process. The Ni-based alloy coating material powder is good self-fluxing, has high-temperature resistance, and is analytically pure with 200 mesh. The chemical properties of Ni composite coating include 31.2 % Chromium, 8%Titenium, and 3.6% Carbon. Overall characterization and microstructure analysis of the prepared coating utilizing OM, XRD, SEM, EDS, and EPMA with different laser-specific energies (LSP) performance impact. It is evident that an excellent coating can be employed at the LSP of about 12.5kJ/cm2. The TiC ceramic particle reinforced phase is dispersed into a two-phase solid solution of β-Ti and γ-Ni. The micro-hardness of the employed coating is greater than the base alloy. This research also optimized that laser power is proportional to the coating structure. This research has practical value in the modern aerospace and automobile industry to increase the application of titanium alloy.
Miah, Md HelalChand, Dharmahinder SinghMalhi, Gurmail SinghKhan, Shahrukhal Muin, Abdullah
This specification covers the requirements for electrodeposited chromium plating.
AMS B Finishes Processes and Fluids Committee
This specification defines limits of variation for determining acceptability of the composition of wrought low-alloy and carbon steel parts and material acquired from a producer.
AMS E Carbon and Low Alloy Steels Committee
This specification covers an aircraft-quality, low-alloy steel in the form of bars, forgings, mechanical tubing, and forging stock.
AMS E Carbon and Low Alloy Steels Committee
This specification covers an aircraft-quality, low-alloy steel in the form of sheet, strip, and plate.
AMS E Carbon and Low Alloy Steels Committee
In current scenario, there is trend to use stainless steels in place of carbon steels and aluminized carbon steels for Exhaust application. In response to changing regulatory requirements and durability performance requirements of exhaust systems, the ferritic stainless steels are proven to be best suited for the purpose. There are multiple ferritic stainless steels available as options for exhaust system. The material in an exhaust system is subject to heat, oxidation, corrosion and condensate. These environment condition demands that exhaust material should possess high temperature corrosion and oxidation resistance along with required mechanical performance such as vibration and thermo-mechanical load cycles. This work is an attempt to develop simulated test methods for corrosion and thermal environment and evaluate performance of commonly used ferritic stainless steels. The ferritic stainless steels, in this study, were subjected to corrosive media and synthetic exhaust environment. Specific test conditions with respect to chemical concentration and thermal cycles were used to simulate exhaust conditions. The results showed improvement in performance of ferritic stainless steel grades with increase in chromium content. The study also provided comparative performance of ferritic stainless steel grades at different temperatures. The relative performance derived from the study can be used to select the right exhaust stainless steel material for the exhaust system.
Chauhan, ShivPonkshe, ShripadrajPolisetti, Venkata Sumanth
This specification defines limits of variation for determining acceptability of the composition of cast or wrought nickel, nickel alloy, and cobalt alloy parts and material acquired from a producer.
AMS F Corrosion and Heat Resistant Alloys Committee
"Physical Characterization of Niobium-Added Gray Irons for Brake Disc Applications "132969/14/2022
"High carbon equivalent (CE) gray iron brake rotors exhibit desirable thermal diffusivity and dampening properties. High CE rotors suffer, however, from reduced mechanical and wear properties in comparison to low CE rotors. Niobium (Nb) is shown to increase the strength and wear resistance of gray iron, but the interaction of niobium with other common alloying elements, namely chromium (Cr) and molybdenum (Mo), is not well understood. Thirteen gray cast iron alloys were produced with varying levels of CE, Cr, Mo, and Nb. Bars with four different diameters (8, 14, 22, and 30 mm) were cast from each alloy and microstructural and physical properties such as graphite flake morphology, pearlite spacing, electrical resistivity, and thermal diffusivity were measured. Mechanical characterization, including tensile testing from ambient temperature to 680?C, ambient temperature pearlite microhardness, macro Brinell hardness, and ASTM G65 sand abrasion wear testing, was conducted. Fluidity during casting was measured using a purpose-built finger mold. It was found that niobium refined the graphite morphology, reduced pearlite spacing, and precipitated eutectic NbC. When compared to Mo, Nb was found to be 2-3 times more potent at increasing strength and wear resistance while minimally reducing thermal diffusivity. One of the Nb containing alloys (0.22 wt% Nb) is compared to test data from a modern Chevy Silverado 1500 rotor (similar alloy chemistry excluding Nb addition) and exhibited a 7.8% increase in thermal diffusivity, a 5.8% increase in tensile strength, and a 8.4% increase in hardness while exhibiting similar wear resistance. "
Hasbrouck, Matthew
This specification covers an aluminum alloy in the form of sheet and plate 0.020 to 4.00 inches (0.51 to 101.60 mm), inclusive, in nominal thickness (see 8.5).
AMS D Nonferrous Alloys Committee
This specification covers an aluminum alloy in the form of sheet and plate 0.008 to 1.000 inch (0.20 to 25.40 mm), inclusive, in thickness, clad on two sides, supplied in the annealed (O) condition. When specified, product shall be supplied in the “as fabricated” (F) temper (see 8.6).
AMS D Nonferrous Alloys Committee
This specification covers an aluminum alloy in the form of sheet and plate with thickness from 0.008 to 4.000 inches (0.20 to 101.6 mm), inclusive, clad on two sides (see 8.6).
AMS D Nonferrous Alloys Committee
This specification covers an aluminum alloy in the form of sheet and plate 0.008 to 4.000 inches (0.20 to 101.6 mm), inclusive, in thickness (see 8.6).
AMS D Nonferrous Alloys Committee
This specification covers an aluminum alloy in the form of sheet clad on both sides with a different alloy for sheet thicknesses of 0.020 to 0.128 inches (0.51 to 3.25 mm), inclusive, in nominal thickness (see 8.5).
AMS D Nonferrous Alloys Committee
This specification covers a corrosion-resistant steel in the form of flat wire 0.005 to 0.095 inch (0.13 to 2.41 mm) thick, inclusive.
AMS F Corrosion and Heat Resistant Alloys Committee
This specification covers an aircraft-quality, low-alloy steel in the form of bars, forgings, flash welded rings, and stock for forging or flash welded rings.
AMS E Carbon and Low Alloy Steels Committee
This specification covers an aircraft-quality, low-alloy steel in the form of bars, forgings, mechanical tubing, and forging stock.
AMS E Carbon and Low Alloy Steels Committee
Hexavalent chromium is not a term frequently associated with engineers. Residents of Hinkley, California, however, know all about it. So do workers tasked with the labor-intensive process of depainting aircraft.
This specification covers an aluminum alloy in the form of sheet and plate from 0.006 to 6.000 inches (0.15 to 152.40 mm), inclusive, in nominal thickness (see 8.6).
AMS D Nonferrous Alloys Committee
This specification covers an aluminum alloy in the form of wire (see 8.7).
AMS D Nonferrous Alloys Committee
This specification covers an aircraft-quality, low-alloy steel in the form of sheet, strip, and plate.
AMS E Carbon and Low Alloy Steels Committee
SS304 (Stainless Steel 304) is a nickel- chromium based alloy, that is extensively used for the applications like cryogenic vessels, valves, refrigerator equipment and evaporators because of its high corrosion resistance, ductility and ability to remain as solid up to a temperature of 14000 C. SS304 is one of the tough to machine materials by conventional methods of machining. Wire Electrical Discharge Machining (WEDM) facilitates the ease of machining complicated cuts with hard to machine, conductive materials where high surface finish is required. In this investigation, a study has been done on WEDM of SS304 and mainly to optimize the process parameters during the machining of SS304 by using Taguchi’s analysis. Taguchi’s DoE approach is used to plan the experimental runs and by considering the process parameters such as pulse on time, pulse off time and peak current at three different levels the experiments were conducted. The performance measures considered in present analysis are material removal rate, surface roughness and overcut. Contour plot analysis has been prepared for revealing the overall influence of process variables on desired performance measures. Analysis of Variance (ANOVA) has been used to establish the significance of independent variables on the desired dependent variables. Through this overall investigational analysis, the effect of individual process parameters on the response parameters have been studied. Stainless steel alloys are primarily applied for high temperature applications. SS304 can maintain its mechanical and chemical characteristics stable in all kinds of working environments. These materials are considered as harder materials due to these extraordinary properties. Stainless Steel 304 is most widely used nickel and chromium based alloy for number of engineering applications such as refrigerator equipments, valves, evaporator coils and cryogenic applications. SS 304 shows high ductility, corrosion resistance and excellent tribological and abrasive behaviour at higher temperatures (Ramesh Raju et al. 2019; Ramesh Raju et al. 2018; Palanisamy et al. 2021; Bagci and Seref, 2006; Kumar et al. 2009). Wire Electrical Discharge Machining (WEDM) is a superior method of modern machining processes which is also familiar as spark erosion machining process. In WEDM, the spark generation is due to the gap voltage developed that is sufficiently higher to develop the required high power spark that rises the temperature to more than 10000 degree Celsius that eventually removes the metal from the work piece as shown in the figure 1. The material removal in this WEDM process is irrespective of the hardness of the material to be machined. (Palanisamy et al. 2020; Davim, 2008; Manikandan et al. 2020; Ugrase et al. 2015; Manikandan et al. 2020; El-Hofy 2005). Taguchi’s concept is a significant one for planning the experimental trials and also adopted for single response optimization. Optimization of process parameters plays a vital role in reducing the overall cost with an improved quality. An appropriate approach also has been adopted for deriving the multi performance called GRG, which is attained by a Multi Criteria Decision Making Method called Grey Relational Approach. The method of GRA is much helpful for deriving the various combinations for attaining better multiple performance machining characteristics (Welling, 2014; Leone et al. 2011; Yang et al. 2017; Durairaj et al. 2013; Raj and Radhika, 2017; Palanisamy and Senthil, 2016; Manikandan et al. 2018). It is surmised from the available research article, that there is a demand of attention on machinability analysis of Wire Electrical Discharge Machining of harder materials. In this present explorative study, an endeavour has been considered for investigating the significance of process variables by Taguchi-Grey approach and to analyze the importance of variables using ANOVA analysis. Contour plots also developed for disclosing the prominence of input variables on desired performance measures.
Thejasree, P.N, ManikandanKrishnamachary, PCVaraprasad, K CJoseph Selvi, Binoj
This specification covers tungsten carbide-cobalt chrome in the form of powder.
AMS F Corrosion and Heat Resistant Alloys Committee
This specification covers a low-alloy steel in the form of sheet, strip, and plate 4.00 inches (101.6 mm) and under in thickness.
AMS E Carbon and Low Alloy Steels Committee
Foundry industries are very much familiar and rich experience of producing ferrous castings mainly Flake Graphite (FG) and Spheroidal Graphite (SG) cast iron. Grey cast iron material is mainly used for dampening applications and spheroidal graphite cast iron is used in structural applications wherein high strength and moderate ductility is necessary to meet the functional requirements. However, both types of cast iron grades are very much suitable in terms of manufacturing in an economical way. Those grades are commercially available and being consumed in various industries like automotive, agriculture etc, High strength SG Iron grades also being manufactured by modifying the alloying elements with copper, chromium, manganese andcobalt. but it has its own limitation of reduction in elongation when moving from low to high strength SG iron material. To overcome this limitation a new cast iron developed by modifying the chemical composition. Additionally, strengthening mechanism were studied to have a linear relationship of strength and elongation even in higher strength. As an outcome, solid solution ferritic strengthened ductile SG iron developed to meet light weight design requirements. In this paper, the effect of alloying elements, strengthening mechanism, chemical, mechanical, microstructural properties, weight optimization, manufacturing challenges and validation etc, are discussed in detail.
Gunalan, MagendranAnandeswaran, V.A
This specification covers the procurement of granular heat-treating salts suitable for use in the molten state.
AMS B Finishes Processes and Fluids Committee
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