There is a need to reduce both the greenhouse gas emissions of internal combustion engines, and the reliance on traditional fossil fuels like Ultra Low Sulphur Diesel (ULSD). In this research, a synthetic aviation fuel created from natural gas feedstocks using the Fischer-Tropsch process was investigated to determine its autoignition and combustion characteristics, emissions, and tribological properties. This fuel, S8, has a Derived Cetane Number (DCN) of 62, which reflects a short Ignition Delay (ID) and Combustion Delay (CD) compared to ULSD, which has a DCN of 48. However, due to the chemical properties of S8, it lacks sufficient lubrication qualities in comparison to ULSD, so addition of 3% methyl oleate by mass was used to improve lubricity. The shorter ignition delay of S8, initially observed in a Constant Volume Combustion Chamber (CVCC), was also observed in the instrumented Common Rail Direct Injection (CRDI) engine. Investigations with an He-Ne laser apparatus with Mie