Browse Topic: Emissions

Items (24,077)
Increasing global pressure to reduce anthropogenic carbon emissions has inspired a transition from conventional petroleum-fueled internal combustion engines to alternative powertrains, including battery electric vehicles (EVs) and hybrids. Hybrids offer a promising solution for emissions reduction by addressing the limitations of pure EVs such as slow recharge and range anxiety. In a previous research endeavor, a prototype high-power density generator was meticulously designed, fabricated, and subjected to testing. This generator incorporated a compact permanent magnet brushless dynamo and a diminutive single-cylinder two-stroke engine with low-technology constructions. This prototype generated 8.5 kW of electrical power while maintaining a lightweight profile at 21 kg. This study investigates the performance and emissions reduction potential by adapting the prototype to operate on methanol fuel. Performance and emissions were experimentally evaluated under varying operating conditions
Gore, MattNonavinakere Vinod, KaushikFang, Tiegang
Diesel aftertreatment (AT) systems are critical for controlling emissions of CO, HC, NOX, and PM in the on-road transportation sector. Ensuring compliance with regulatory standards throughout the AT system's lifespan requires precise prediction of various degradation mechanisms under real-world operating conditions and mitigating their impact through proper catalyst sizing and advanced controls. In the SwRI A2CAT-II consortium, a medium-duty diesel engine production aftertreatment system was subjected to full useful life aging, involving chemical poisoning with phosphorus (P) and sulfur (S) species, along with hydrothermal aging following the DAAAC protocol. This study was aimed to model and predict the aging trajectory of this production AT system thereby capturing changes in system dynamics under both steady-state and transient conditions. The system, designed to meet the 0.2 g/bhp-hr standard, comprised a Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), Selective
Balakrishnan, ArunChundru, Venkata RajeshEakle, ScottSharp, Christopher
A diesel engine was run on off-highway cycle sequence on nine (9) fuels and blends. Number-weighted solid particle size distribution (PSD) in the size range from 5.6 nm to 560 nm was measured at inlet and outlet of a diesel particulate filter (DPF) on a sequence of five (5) non-road transient cycles (NRTCs) and five (5) non-road steady-state cycles (NRSCs). The measurements were used to correlate the fuel properties to the DPF-In concentrations and filtration of different size particles in the DPFs. The data showed an expected trend with the DPF-In emissions. Ultra-low sulfur diesel (ULSD) had the highest solid particle number (SPN) concentrations and biodiesels (soy-based biodiesel (B100) and rapeseed-based biodiesel (RME)) had the lowest concentrations. The geometric number mean diameter (GNMD) of DPF-In PSD correlates with the concentrations. The calculated GNMD was the highest for ULSD and lowest for B100/RME. An opposite trend for the GNMD was observed at the DPF-Out where the
Lakkireddy, VenkataKhalek, ImadBuffaloe, Gina
Minimizing the time needed to achieve light-off temperatures in diesel engine aftertreatment devices is key to mitigate pollutant emissions during the first minutes of operation. Catalyst heating operation typically includes one or multiple post-injections late during the expansion stroke aimed to increase the enthalpy of the exhaust gases. However, post-injection retardability is constrained by low combustion efficiency and the formation of CO and unburned hydrocarbons that cannot be oxidized by a still-inactive oxidation catalyst. In this study, the effects of post-injection strategy on the performance and emissions of a medium duty diesel engine have been investigated experimentally, focusing on the impacts on post-injection retardability. A five injection strategy (two pilot, one main, two post) was implemented in the engine, and the injection duration ratio between the two post-injections has been varied systematically while performing post-injection timing sweeps to identify the
Lopez Pintor, DarioLee, SangukCho, SeokwonBusch, StephenWu, AngelaNarayanan, AbhinandhanAbboud, Rami
Simulated distillation (SimDis) uses wide bore capillary gas chromatography (GC) to provide a detailed volatility profile of blended gasoline. The boiling point distribution from SimDis analysis is correlated to the hydrocarbon contents of spark ignition fuels and provide the resolution necessary to characterize the compositions of the fuel. Recent publications on simulated distillation applied to spark ignition fuel reveal the merits of indexing a gasoline fuel so that it can be correlated to the tendency of particulate emissions from vehicles. With this in mind, SimDis can be a useful and quick tool in assessing the PM-formation potential of market gasolines. Heavy aromatic compounds are compounds identified as having at least 10 Carbons and 1 aromatic ring. These compounds that are present in spark ignition fuels are major contributors to vehicle particulate emissions. These compounds can be found in the higher boiling portion (T70+) of the distillation profiles. As demonstrated in
Goralski, SarahGeng, PatDozier, JonButler, Aron
Track testing methods are utilized in the automotive industry for emissions and fuel economy certification. These track tests are performed on smooth road surfaces which deteriorate over time due to wear and weather effects, hence warranting regular track repaves. The study focuses on the impact of repaving on track quality and surface degradation due to weather effects. 1D surface profiles and 2D surface images at different spatial frequencies were measured at different times over a span of two years using various devices to study the repave and degradation effects. Data from coastdown tests was also collected over a span of two years and is used to demonstrate the impact of track degradation and repaving on road load characterization parameters that are used for vehicle certification tests. Kernel density estimation and non-parametric spectral estimation methods are used to visualize the characteristic features of the track at different times. In the pre-processing stage, outliers
Singh, YuvrajJayakumar, AdithyaRizzoni, Giorgio
Progressive emission reductions and stricter legislation require a closer look at the emission behaviour of a vehicle, in particular non-exhaust emissions and resuspension. In addition to the analysis of emissions in isolation, it is also necessary to consider the impact of transport routes and dispersion potential. These factors provide insight into the movement of dust particles and, consequently, the identification of particularly vulnerable areas. Measurements using low-cost environmental sensors can increase the level of detail of dispersion analyses and allow a statement on the distribution of emissions in the vehicle's wake, as several measuring points can be covered simultaneously. A newly developed measurement setup allows vehicle emissions to be recorded in a plane behind the vehicle in a measurement area of 2 by 2 metres. The measuring grid consisting of 16 sensors (4x4 grid) can be variably positioned up to 1 metre from the rear of the vehicle. The sensors detect fine dust
Kunze, MilesIvanov, ValentinGramstat, Sebastian
To study the real driving emission characteristics of light-duty vehicles fueled with liquefied petroleum gas (LPG) and gasoline in a high-altitude city, experimental investigations were performed on two LPG taxis and three gasoline passenger cars in Lhasa using a portable emission measurement system (PEMS). The results reveal that the emission factors of CO2, CO, NOx, and HC of LPG taxis are 159.19±11.81, 18.38±9.73, 1.53±0.46, and 1.27±0.99 g/km, and those of gasoline cars are 223.51±23.1, 1.51±0.68, 0.27±0.16, and 0.06±0.04 g/km, respectively. The emissions show strong relationships with driving mode, which is considerably affected by driving behavior. Furthermore, as vehicle speed increases, the emission factors of both LPG taxis and gasoline cars decrease. The emission rates of both types of vehicles are low and change slightly at a vehicle specific power (VSP) of 0 kW/t or below; After that, the rates slowly increase initially and then increase rapidly with increasing VSP. These
Lyu, MengXu, YanHuang, MeihongWang, Yunjing
The integration of low-octane gasoline with a compression ignition combustion system has been proposed as a strategy to reduce Well-to-Wheel CO2 emissions from automobiles using petroleum-based fuel. In the current situation where low-octane gasoline is not widely available in the market, onboard reforming of commercial gasoline to increase the cetane number (lower the octane number) allows for compression ignition combustion even with commercial gasoline. This requires “Cetane on Demand” technology, which enables compression ignition combustion with both commercial gasoline and low-octane gasoline. It is known that the ignition property of fuel is enhanced when the fuel is oxidized to generate hydroperoxides. Moreover, the use of N-hydroxyphthalimide (NHPI) as a catalyst promotes hydroperoxide generation at low temperatures. The objective of this study is to develop a device that enhances the ignition properties of gasoline through onboard fuel reforming. Initially, from the seven
Hashimoto, KohtaroYamada, YoshikazuMatsuura, KatsuyaKudo, TomohideChishima, HiroshiAl-Taher, MaryamKalamaras, ChristosAlbashrawi, Reem
As part of the global effort to combat climate change, electric vehicles (EVs) are gaining popularity, even for long-haul commercial transportation. A battery pack is a critical component of an EV, and it contains several modules with many series- and parallel-connected electrochemical cells. Strict safety and operational limits are enforced on the cell-level to ensure safe operation of the battery pack. However, variations in the electrochemical properties among the cells in the pack causes some cells to reach the safety and operational limits faster than others. This limits the total power, and over time, the energy delivered and the lifetime of the battery pack. Maximizing the energy delivered by the battery pack (potentially also improving the battery pack’s lifetime) can be achieved by increasing cell-level control, and battery-integrated modular multilevel converters (BI-MMC) is presented as a solution. A BI-MMC has several series-connected DC-to-AC converters, commonly called
Balachandran, ArvindJonsson, TomasEriksson, Lars
The adoption of hybrid electric vehicles (HEVs) is becoming more popular during the last few years due to government incentives and favourable legislation both for automotive companies and final users. This type of vehicle claims very low carbon dioxide emissions while eliminating the range anxiety associated with battery electric vehicles thanks to the on-board range extender being able to recharge the battery throughout the journey. Unfortunately, the low emissions values are more representative of the particular mathematical model implemented by the legislation than the measured real driving emissions. Specifically, the legislation does not take into account the CO2 embedded in production of the batteries or of the electrical energy stored in it. This work analyses these aspects by means of a numerical model of the BMW i3 94Ah vehicle. The results obtained are collected from simulations conducted over the Worldwide harmonized Light vehicles Test Cycle (WLTC) by using the commercial
Turner, JamesVorraro, Giovanni
This study evaluates the impacts of the gasoline compression ignition (GCI) engine on heavy duty long-haul trucks in both the Chinese and US markets. The study examines various aspects such as vehicle performance requirements, fuel consumption, emissions, and ownerships costs, and how they influence the implementation and impact of new technologies in these markets. By considering a wide variety of drive cycles, including standard regulatory cycles and real-world cycles, the study aims to identify the impact of varying degrees of powertrain electrification using diesel and GCI engines on fuel consumption and emissions. Additionally, this paper explores the viability of powertrain electrification in long-haul trucks by analyzing factors such as levelized cost of driving (LCOD), manufacturing costs, and energy costs. These considerations play a crucial role in determining the economic feasibility and attractiveness of electrification technologies in various driving scenarios and market
Nieto Prada, DanielaVijayagopal, RamYan, ZimingSari, RafaelHe, Xin
Internal combustion engines are expected to continue to play an important on-going role in the future of transportation, particularly in long haul transit and off-road applications. Substantially reducing criteria emissions of heavy-duty (HD) commercial vehicle engines while also reducing fuel consumption is the quickest way to achieve more sustainable transportation. The opposed-piston (OP) engine developed by Achates Power has demonstrated the ability to meet the most stringent ultralow NOx emissions requirements using only a conventional, underfloor aftertreatment system, offering reduced cost, complexity and compliance risk compared to other diesel engines. This paper is focused on the measurement results of Achates Power heavy-duty engine achieving CARB proposed ultralow NOx emission for 2027 and 2031+ full useful life requirements while also meeting the EPA Greenhouse Gas (GHG) Phase 2 limits with a conventional aftertreatment system (ATS), which was aged to 435k, 600k and 800k
Kale, VaibhavBako, Zoltan
The hydrogen internal combustion engine technology, with its potential for almost full carbon emissions reduction and adaptability to a wide range of fossil fuel-based internal combustion engine (ICE) platforms, offers a promising future. However, as with any innovative technology, it also presents challenges, such as abnormal combustion phenomena. These challenges, including intake backfire, which is more common when using port fuel injection (PFI), and pre-ignition in the combustion chamber, which can be experienced with PFI or direct injection (DI), require detailed investigation to understand and optimize the engine’s performance and efficiencies. This study comprehensively investigates the main abnormal combustion events that could happen in a spark ignition (SI) hydrogen engine. It examines both direct and port fuel injection systems and uses high-resolution in-cylinder, intake, and exhaust pressure measurements alongside a suite of fast-response gas analyzers. The study provides
Mohamed, MohamedMirshahi, MiladWang, XinyanZhao, HuaHarrington, AnthonyHall, JonathanPeckham, Mark
Low-carbon alternatives to diesel are needed to reduce the carbon intensity of the transport, agriculture, and off-grid power generation sectors, where compression ignition (CI) engines are commonly used. Acid-catalysed alcoholysis produces a potentially tailorable low-carbon advanced biofuel blend comprised of mixtures of an alkyl levulinate, a dialkyl ether, and the starting alcohol. In this study, model mixtures based on products expected from the use of n-butanol (butyl-based blends) as a starting alcohol, were blended with diesel and tested in a Yanmar L100V single-cylinder CI engine. Blends were formulated to meet the flash point, density, and kinematic viscosity limits of fuel standards for diesel, the 2022 version of BS 2869 (off-road). No changes to the engine set-up were made, hence testing the biofuel blends for their potential as “drop-in” fuels. Changes in engine performance and emissions were determined for a range of diesel/biofuel blends and compared to a pure diesel
Wiseman, ScottLi, HuTomlin, Alison S.
The Environmental Protection Agency’s Advanced Light-Duty Powertrain and Hybrid Analysis (ALPHA) modeling tool was initially created to simulate the Greenhouse Gas emissions from light-duty vehicles. ALPHA is used to predict tailpipe CO2 emissions and energy consumption from advanced automotive technologies. ALPHA is a physics-based, forward-looking vehicle computer simulation tool capable of analyzing various vehicle types with different powertrain technologies while replicating realistic vehicle behavior. ALPHA version 3.0 is the current version of the MATLAB/Simulink based software. Key changes made for ALPHA v3.0 include the addition of new light- and medium-duty vehicle models to support simulation of electrified vehicle architectures (hybrid, plug-in hybrid, and battery electric vehicles) aligning with the automotive industry transition towards electrified fleets. Each electrified vehicle model was tuned to replicate operational behavior of components (such as engine
Kargul, JohnMoskalik, AndrewBarba, DanielButters, Karla
Urea-based selective catalytic reduction (SCR) systems are widely used to meet stringent NOx emission standards in industrial diesel engines. However, suboptimal design of the urea-water solution (UWS) mixing pipes in SCR systems can lead to the formation of urea-derived solid deposits, which may adversely affect the system performance and reliability. Although recent advancements in deposit simulation technology using three-dimensional Computational Fluid Dynamics (3D CFD) have significantly improved the performance and compactness of mixing pipes, assessing deposit formation across all operating and environmental conditions remains challenging due to high simulation costs. This study introduces a novel computational method for predicting the formation and temperature of permanent liquid films from UWS injection which are closely related to deposit formation, along with new deposit evaluation criteria based on them. This proposed method integrates a one-dimensional heat transfer model
Sugimoto, KazumaKawabe, Ken
The pollutant emission regulation for Non-Road Mobile Machinery (NRMM) is currently under consideration, both in the European Union (EU) and the United States (US). In Europe a Stage V review is expected within 2025 and in the US, the California Air Resource Board (CARB) has released their Tier 5 proposal in late 2024. It is expected that there will be further focus on covering a wide variety of operation conditions in actual use cases, including continuous low load scenarios. In addition, CO2-neutral fuels are being investigated to reduce the carbon footprint of NRMM Internal Combustion Engines (ICE), which remains an important powertrain for the sector. The objective of the work presented is to assess the potential for emissions reductions in the future, both NOx and CO2. A simulation study is conducted, modelling a 9l class engine with 8-10 g/kWh engine-out NOx emission level. Three different emission control systems are investigated: an enhanced stage V system with single SCR, a
Demuynck, JoachimBosteels, DirkMichelitsch, PhilippNoll, Hannes
In recent years, the stronger push for reducing GHG and NOx emissions has challenged vehicle manufacturers globally. In USA, Multi-Pollutant Emissions Standards for Model Years 2027 and Later Light Duty and Medium-Duty Vehicles released by EPA in April 2023 aims to reduce the CO2 emissions by 56% and 44%, respectively, for light and medium duty vehicles by 2032 from 2026 levels. It also includes the NMOG+ NOx standards, which require a 60 – 76% reduction by 2032 from 2026 levels for light to medium-duty vehicles. Europe also aims to reduce CO2 emissions by 55% by 2030 from 1990 levels and 100% by 2035. To achieve such low levels of CO2 emissions, especially in the near-term scenario of limited EV sales, hybridization of conventional powertrains has found renewed interest. While hybrid powertrains add complexity, if optimized well for the application, they can offer best tradeoff between upfront cost, range, payload, performance, emissions and off-ambient operation. This study
Fnu, DhanrajCorreia Garcia, BrunoPaul, SumitJoshi, SatyumFranke, Michael
This is a follow-up paper to the two previous reports [1, 2] regarding the development of a zeolite-based, hydrocarbon (HC) trap-type cold-start catalyst (CSC) as a method to meet future vehicle tailpipe emission standards. In this paper, vehicle tests at a low ambient temperature of -7°C have been performed and the CSC has been shown to further decrease the tailpipe cold start non-methane hydrocarbon (NMHC) emissions by 59% when compared to a standard 23°C WLTC test. This work has proven that the increased presence of condensed water at low ambient temperatures within the exhaust system does not affect the ability to provide a NMHC reduction, in fact the lower ambient temperature enables an increase in the reduction capability due to the ability to retain and then release the stored NMHC in a more controlled manner. Additionally, the impact of the zeolite loading level was investigated and the high zeolite loading within a CSC did improve the cold-start NMHC but the benefits did
Xu, LifengZhao, FuchengWei, HongZhao, PengfeiZhao, JiajiaMa, RuiboNewman, PhilipWang, LinQian, WangmuQian, Menghan
The transport sector is responsible for about one third of the global CO2 emissions. To align to the net zero emission scenario, the transportation sector needs the implementation of policies aimed to reduce as much as possible the highly emitting transport options and, at the same time, the use of new technologies to reduce the environmental impact of transport methods whose emissions cannot be entirely eliminated. An exploitable solution for the internal combustion engine (ICE), even in the nearest future, would be to use hydrogen as a fuel in these engines. This is supported by the fact that H2-ICE is the only ICE technology currently capable of meeting the standards imposed by the European Union for 2035. Due to the possibility of different injection strategies as well as the variation of in-cylinder back pressure, the comprehensive knowledge of hydrogen injection jet behavior and characteristics is fundamental for improving the combustion process in direct injection H2-ICE. In
Montanaro, AlessandroMancaruso, EzioMeccariello, GiovanniAllocca, Luigi
The upcoming EURO 7 and EPA Tier 4 regulations and the possible China 7 are expected to tighten the tailpipe particulate emissions limits significantly. High performance Gasoline Particulate Filters (GPFs) with high filtration efficiency and low pressure drop would be mandated for gasoline engines to meet these stringent regulations. Due to packaging constraints, GPFs are often coated with three-way catalyst (TWC) materials to achieve four-way functionality. Ash accumulation in GPFs also has a significant impact on the performance of GPFs. This paper utilizes 3D CFD to predict the transient filtration efficiency and pressure drop of a washcoated GPF with ash accumulation during the soot loading process. Simulation results show a decent match with experimental data. The 3D CFD model also provides detailed information on soot penetration in the GPF wall substrate and soot cake characteristics on the wall. These information can be crucial for GPF wall substrate design and washcoating
Yang, PengzeCheng, Zhen
Three-way catalysts (TWCs) containing significant amounts of precious metals are commonly employed to purify exhaust emissions (CO, NOx, and THC) from gasoline-powered vehicles. A critical factor contributing to TWC degradation is the sintering of these precious metals. Maintaining the appropriate particle size and distribution of the metals is essential for optimal catalyst performance. In this study, palladium (Pd) nanoparticles with a uniform size were synthesized using ethylene glycol as a reductant under ultrasonic conditions, yielding particles in the range of 3 nm to 5 nm. These Pd nanoparticles were subsequently used to prepare three-way catalysts on cordierite substrates supplied by Corning (China) Inc. Chemisorption analysis revealed that the Pd active component in the catalysts prepared via the ultrasonic method exhibited higher dispersion than the state-of-the-art commercial catalysts. The aged catalysts were obtained after 150 hours of aging following the General Motors
Hao, ShijieLv, YananWang, WeidongRao, ChaoWei, WeiMao, BingbinChen, TaoZhao, Huawang
This study evaluates the performance of alternative powertrains for Class 8 heavy-duty trucks under various real-world driving conditions, cargo loads, and operating ranges. Energy consumption, greenhouse gas emissions, and the Levelized Cost of Driving (LCOD) were assessed for different powertrain technologies in 2024, 2035, and 2050, considering anticipated technological advancements. The analysis employed simulation models that accurately reflect vehicle dynamics, powertrain components, and energy storage systems, leveraging real-world driving data. An integrated simulation workflow was implemented using Argonne National Laboratory's POLARIS, SVTrip, Autonomie, and TechScape software. Additionally, a sensitivity analysis was performed to assess how fluctuations in energy and fuel costs impact the cost-effectiveness of various powertrain options. By 2035, battery electric trucks (BEVs) demonstrate strong cost competitiveness in the 0-250 mile and 250-500 mile ranges, especially when
Mansour, CharbelBou Gebrael, JulienKancharla, AmarendraFreyermuth, VincentIslam, Ehsan SabriVijayagopal, RamSahin, OlcayZuniga, NataliaNieto Prada, DanielaAlhajjar, MichelRousseau, AymericBorhan, HoseinaliEl Ganaoui-Mourlan, Ouafae
Marine ports are an important source of emissions in many urban areas, and many ports are implementing plans to reduce emissions and greenhouse gases using zero-emission cargo handling equipment. This paper evaluates the performance and activity profiles for various zero-emission (ZE) cargo transport equipment being demonstrated at different ports in California. This included 23 battery-electric (BE) 8,000 lb. (8K) and 36,000 lb. (36K) forklifts, a BE railcar mover, and an electrified rubber-tired gantry crane (eRTG). The study focused on evaluating the performance of the ZE equipment in terms of activity patterns and the potential emissions reductions. Data loggers were used to collect activity data, including hours of use, energy consumption, and charging information over periods from 6 to 21 months. The results showed that the BE forklifts, BE railcar mover, and the eRTG averaged 2-3 hours, 5 hours, and 14 hours of use per day of operation, respectively. The average energy use for
Frederickson, ChasVu, AlexanderMakki, MaedehJohnson, KentDurbin, ThomasBurnette, AndrewHuang, EddyAlvarado, EricaRao, Leela
The hydrogen internal combustion engine (H2-ICE) is an attractive powertrain solution for decarbonization of heavy equipment. This paper presents the development of a lean burn spark ignited (SI) H2-ICE with Port Fuel Injection (PFI). The targeted application is STAGE V fixed speed power generation realized without the need for NOx aftertreatment. A 13L EURO VI diesel engine is used as a base. The engine conversion process to hydrogen fuel is presented in detail discussing key aspects regarding both hardware and control software adaptations to fulfill the performance, emission, and safety requirements. In the development process, measurements have been performed on a single-cylinder and a multi-cylinder engine setup supported by detailed CFD computations to quantify operational limits and specify development directions. These results are translated into updated hardware and software of the fixed speed SI H2-ICE. The resulting H2-ICE is shown to comply with the requirements for power
Seykens, XanderDoosje, ErikBekdemir, CemilWezenbeek, Peter
As the demand for cleaner and more efficient propulsion systems increases, hydrogen internal combustion engines have emerged as a promising solution due to their high thermal efficiency and zero-carbon emissions potential. Achieving ultra-lean combustion conditions (lambda > 2.8) in hydrogen engines significantly improves thermal efficiency while maintaining combustion stability and reducing knock intensity. However, hydrogen injection timing and pressure are crucial factors influencing the combustion and emission characteristics of hydrogen engines. This study investigates the effects of hydrogen injection timing and pressure on the combustion performance and emission characteristics of a direct injection hydrogen engine under different load conditions. Experimental tests were conducted on a multi-cylinder engine equipped with a hydrogen direct injection system, focusing on part-load operation to explore the interplay between injection parameters and engine performance. Results show
Du, JiakunWu, GuangquanChen, HongSun, FanjiaXie, FangxiLi, YuhuaiSun, YaoQi, HongzhongLi, Yong
In hydrogen-fueled internal combustion engine (H2ICE), there are some ways to reduce nitrogen oxides (NOx) emissions. Using the wide flammability range of hydrogen, such as conducting lean combustion to reduce nitrogen oxides and employing exhaust gas recirculation (EGR), have been adopted. However, challenges exist in terms of load expansion, and due to the absence of high heat capacity of carbon dioxides in the exhaust, EGR also struggles to exhibit significant effects. In such a scenario, there is growing interest in injecting water into the H2ICE as an alternative to augment the EGR effect. In this study, the spark ignition (SI) single-cylinder engine equipped with two direct injectors was used to evaluate the hydrogen and the water dual direct injection combustion system. This system involved the direct injection of hydrogen using a wall-guided gasoline direct injector and the direct injection of water into the combustion chamber using a diesel injector. This approach utilizes the
Kim, KiyeonLee, SeungilKim, SeungjaeLee, SeunghyunMin, KyoungdougOh, SechulSon, JongyoonLee, Jeongwoo
Pre-chamber combustion is an advanced ignition strategy that has been shown to enhance spark ignition (SI) combustion stability in natural gas (NG) engines by providing distributed ignition sites from turbulent jets and enhancing main-chamber turbulence. Pre-chamber combustion has been proven especially advantageous compared to SI in ultra-lean and dilute operating conditions. This work involves experimental investigation of the effects of varying passive pre-chamber nozzle configuration on pre-chamber and main chamber combustion under simulated exhaust gas recirculation (EGR) dilution (0 and 20%) conditions in a heavy-duty, single-cylinder, optically accessible NG engine at stoichiometric fuel-air ratio. Pre-chamber nozzle configurations include four pre-chambers with constant nozzle area to pre-chamber volume ratio (A/V) with different nozzle sizes and orientations and one configuration with larger nozzles. The optical engine is operated in a skip-fire sequence consisting of 18
Dhotre, AkashNyrenstedt, GustavRajasegar, RajavasanthVarma, ArunSingh, SatbirNorthrop, WilliamSrna, Ales
This study numerically investigates ammonia-diesel dual fuel combustion in a heavy-duty engine. Detailed and reduced reaction mechanisms are validated against experimental data to develop injection timing maps aimed at maximizing indicated thermal efficiency (ITE) while mitigating environmental impacts using stochastic reactor model (SRM). The equivalence ratio, ammonia energy share (AES), injection timing, and engine load are varied to optimize combustion efficiency and minimize emissions. The results demonstrate that advancing injection timing reduces ITE due to heightened in-cylinder temperatures, resulting in increased heat losses through walls and exhaust gases. Maximum chemical efficiency is observed at an equivalence ratio near 0.9 but decreases thereafter, influenced by ammonia’s narrow flammability range. Emission analysis highlights significant reductions in Global Warming Potential (GWP) and Eutrophication Potential (EP) with higher AES, driven by decreased CO2 and nitrogen
Karenawar, Shivraj AnandYadav, Neeraj KumarMaurya, Rakesh Kumar
In order to comply with the tightening of global regulations on automobile exhaust gas, further improvements to exhaust gas control catalysts and upgrades to on-board diagnostics (OBD) systems must be made. Currently, oxygen storage capacity (OSC) is monitored by front and rear sensors before and after the catalyst, and deterioration is judged by a decrease in OSC, but it is possible that catalyst deterioration may cause the rear sensor to detect gas that has not been sufficiently purified. It is important to observe the activity changes when the catalyst deteriorates in more detail and to gain a deeper understanding of the catalyst mechanism in order to create guidelines for future catalyst development. In this study, we used a μ-TG (micro thermogravimetric balance) to analyze in detail how differences in design parameters such as the type of precious metal, detection temperature, and mileage (degree of deterioration) affect the OSC rate in addition to the OSC of the ceria-based
Hamada, ShotaUegaki, ShinyaTanabe, HidetakaNakayama, TomohitoJinjo, ItsukiKurono, SeitaOishi, ShunsukeNarita, KeiichiOnishi, TetsuroYasuda, KazuyaMatsumura, DaijuTanaka, Hirohisa
This paper presents recent developments of the Euler/Lagrange wall film model which allow the efficient simulation of complete Selective Catalytic Reduction (SCR) systems, used for exhaust gas aftertreatment in diesel and newly designed H2 engines. Since release 2024R2, ANSYS Fluent is equipped with a chemistry model from recent literature to predict homogeneous chemical reactions in the film and heterogeneous reactions between gas and film occurring in SCR systems operating with aqueous urea solutions. The implementation of the chemistry model is first validated against results from Thermo–Gravimetric Analysis (TGA) measurements. The SCR–specific chemistry, combined with the Lagrangian Wall Film (LWF) model employing an improved wall–film convective heat transfer model, is then compared favorably with experimental SCR test rig measurements of urea deposits for fifty injection cycles, followed by a relaxation period. The full simulation completes significantly faster due to a new
Sofialidis, DimitriosMutyal, JayeshFaltsi, RanaBraun, MarkusBörnhorst, MarionEsch, Thomas
Mobile Air-Conditioning (MAC) systems are a substantial source of energy consumption and CO₂ emissions in passenger vehicles, particularly for electrified vehicles under real-world operating conditions. Enhancing the efficiency of such systems is imperative to achieving greater energy efficiency and maintaining occupants’ comfort. In recognition of their significance, MAC systems can be classified as eco-innovative technologies under EU Regulation 2019/631, effective from 2025. This study lays the groundwork for a methodology to calculate CO₂ savings from eco-innovative MAC systems in passenger cars. The approach compares CO₂ emissions between baseline and eco-innovative vehicles under active and inactive MAC systems. Literature-derived indicative ambient conditions are applied to reflect realistic MAC usage scenarios in Europe. The testing protocol follows the WLTP procedure under controlled ambient conditions, including temperature, humidity, and solar irradiation, which can either
Di Pierro, GiuseppeCurrò, DavideGil-Sayas, SusanaFontaras, Georgios
This SAE Aerospace Information Report (AIR) describes a method for assessing size dependent particle losses in a sampling and measurement system of specified geometry utilizing the non-volatile Particulate Matter (nvPM) mass and number concentrations measured at the end of the sampling system.1 The penetration functions of the sampling and measurement system may be determined either by measurement or by analytic computational methods. Loss mechanisms including thermophoretic (which has a very weak size dependence) and size dependent losses are considered in this method2 along with the uncertainties due to both measurement error and the assumptions of the method. The results of this system loss assessment allow development of estimated correction factors for nvPM mass and number concentrations to account for the system losses facilitating estimation of the nvPM mass and number at the engine exhaust nozzle exit plane. As the particle losses are size dependent, the magnitude of correction
E-31P Particulate Matter Committee
The automotive industry faces ongoing challenges in reducing vehicle mass and carbon emissions while ensuring structural integrity. Traditional design approaches often fail to address these issues comprehensively. This paper explores the application of generative design (GD) to optimize critical automotive components, specifically focusing on reducing mass and in turn carbon emissions. GD builds upon traditional topology optimization by employing iterative method using MELS approach to refine designs providing multiple alternative designs to choose from. MELS (Modified Extensible Lattice Sequence) specifically is used to equally spread-out points (designs) in a space by minimizing clumps and empty spaces. This property of MELS makes lattice sequences an excellent space filling DOE scheme. GD leverages the design of experiments (DOE) to vary key design variables systematically to generate and consider many potential design concepts for a given problem. It also uses artificial
Hosmath, AnjaneyBarai, JayDhangar, Vinaykumar
On-board diagnosis (OBD) of gasoline vehicle emissions is detected by measuring the fluctuations of the rear oxygen sensor due to the time-dependent deterioration of the oxygen storage capacity (OSC) contained in the automotive catalyst materials. To detect OBD in various driving modes of automobiles with an order of magnitude higher accuracy than before, it is essential to understand the OSC mechanism based on fundamental science. In this study, time-resolved dispersive X-ray absorption fine structure (DXAFS) using synchrotron radiation was used to carry out a detailed analysis not only of the OSC of ceria-based complex oxides, which had previously been roughly understood, but also of how differences in design parameters such as the type of precious metals, reducing gases (CO and H2), detection temperatures, and mileages (degree of deteriorations) affect the OSC rate in a fluctuating redox atmosphere. A fundamental characteristic was clearly demonstrated in ceria-based complex oxides
Tanaka, HirohisaMatsumura, DaijuUegaki, ShinyaHamada, ShotaAotani, TakuroKamezawa, SaekaNakamoto, MasamiAsai, ShingoMizuno, TomohisaTakamura, RikuGoto, Takashi
The Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry, also known as ASTM D5769, identifies aromatic compounds ranging from carbon groups six to twelve (C6-C12). This method provides determination in less than 15 minutes of twenty-three target aromatics, quantification of uncalibrated Indans, as well as C10, C11, and C12 aromatics using extracted ions. In contrast, the Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 100-MetreCapillary (with Precolumn) High-Resolution Gas Chromatography (ASTM D6730) offers a more comprehensive identification of compounds of multiple classes in gasoline samples also using a mass spectrometer (MS), focusing on aromatics from C6 to C14 for this research. This method uses a standard template of identified fuel components and corrects responses based on theoretical Flame Ionized Detector (FID) hydrocarbon responses
Dozier, JonathanGoralski, SarahGeng, PatReilly, Veronica
The sustainable and healthy development of the new energy vehicle industry relies on supportive and guiding policies. However, China's auto industry currently faces challenges such as the gradual reduction of subsidies and the overaccumulation of credit points. To more effectively promote the high-quality development of new energy vehicles and support the achievement of carbon peaking and carbon neutrality goals, it is essential to seek innovative solutions to further refine the existing policy framework. Carbon quota policy is considered to be an effective measure to realize the dual-carbon goal and guide the high-quality development of China's new energy vehicle industry. Against this background, this study discusses the incentive mechanism of carbon quota policy on technological innovation of new energy vehicles and makes suggestions for policy implementation. First, this study forecasts China's annual automobile sales based on a multiple regression model using indicators such as
Zhao, Jiaqi
The low emission of carbon and minimum level of soot formation in combustion engines and turbines strategy is adopted by many countries to counteract global warming and climate change. The use of ammonia with hydrocarbon fuels can limit the formation of soot and carbon emissions due to non-carbon atoms. The current study explores the use of ammonia with air at coflow flame conditions, which was not tested before. It may give the choice for diesel cycle engines to use the ammonia either with air or fuel. The combustion and emission characteristics of methane coflow flame were studied at low pressure and air polluted by ammonia conditions. The results showed that a significant decline in carbon formation was observed when ammonia was boosted, 5-10%. The impact of sub-atmospheric pressure, 90-70 KPa, on COx development was higher than that of NH3 addition, 0-5%, thanks to the lower formation of hydroxymethylium, formaldehyde, and aldehyde radical. In the environment of lower pressure, the
Hina, AnamAkram, M ZuhaibShafa, AmnaAkram, M Waqar
Exhaust gas regulations, such as Tier4, Euro7, and China7, are being strengthened. In addition to the regulated values during specified driving patterns, emissions must be minimized under various usage scenarios. Since vehicle catalysts have been using higher amounts of precious metals to satisfy these requirements, there is increasing demand to decrease the usage of these metals from the perspective of environmental protection. The exhaust gas emission is divided into cold emission and hot emission. Recently, improvements of cold emission have become a focus. This research focused on improving catalyst warm-up activity by positioning the palladium (Pd) layer above the rhodium (Rh) layer. At the same time, to resolve the decrease in gas utilization in the Rh layer, connectivity was enhanced, and the influence of sulfur components was suppressed through the optimization of the Pd support. As a result, the usage of precious metals has successfully lowered.
Nishio, TakahiroTakagi, NobuyukiTojo, TakumiFujita, NaotoMori, MizuhoToda, Yosuke
Many countries around the world are currently working toward carbon neutrality, which would reduce greenhouse gas emissions to net zero by 2050. To achieve carbon neutrality, the search for new fuels to replace gasoline has been active. This study focuses on hydrogen and methanol fuels and examines their effects on plain bearings when these fuels are used in internal combustion engines. Compared to gasoline, these fuels differ significantly in the composition of gases produced after combustion. It is assumed that nitric acid, etc. will be mixed in the engine oil when hydrogen is combusted whilst formic acid, etc. will be mixed in the engine oil when methanol fuel is combusted. For this reason, corrosion tests were conducted by adding nitric acid or formic acid solution to the engine oil then placing plain bearings in the deteriorated oil. The results confirmed that significant corrosion of the bismuth overlay coating occurred and subsequently the performance of plain bearings may
Kondo, MakotoKawaura, HirokiShiroya, TomoyasuWatanabe, Airi
Dimethyl ether (DME) is widely regarded as a suitable energy source for compression ignition power systems because of its high reactivity. It has been widely reported that DME possesses a significantly low propensity to form soot, hindering the innate NOx-soot trade-off encountered with diesel fuel operation. Beyond the fuel-borne oxygen content of DME, its unique physical properties present a contrasting combustion behavior which may be advantageous to direct injection systems, especially concerning the mixing-controlled combustion mode. This work aims to detail the energy conversion efficacy of DME through heat release characterization and exhaust emission speciation. The tests were controlled within a single-cylinder research engine with an off-board high-pressure injection system to handle liquified DME up to 1000bar. To mitigate interference in fuel additives over the combustion behavior, the high-pressure fuel system specifically managed neat DME. The in-cylinder pressure was the
Leblanc, SimonCong, BinghaoLeach, JaceYu, XiaoReader, GrahamZheng, Ming
Renewable and alternative liquid fuels are being evaluated for their equivalence with ultra-low sulfur diesel (ULSD) in terms of engine and emission control system performance. Our previous research showed an elevated lightoff temperature for diesel oxidation catalyst (DOC) and lower DOC thermal efficiency for biodiesel blends into ULSD with more than 20% biodiesel. Here we report a similar DOC performance study to gage the performance of blends of biodiesel and hydrocarbon renewable diesel (RD) also made from fats and oils feedstocks. The same DOC used previously was used to evaluate RD blends with biodiesel up to 60 vol% (B60R40) in decrements of 10%. The performance of the DOC was evaluated on a steady-state performance cycle and a transient lightoff curve. Similar to previous results, the performance of the DOC is significantly affected by even low blend levels of biodiesel. At low flow rates 50% (B50R50) and higher biodiesel blends have a poor performance defined as the lightoff
Lakkireddy, VenkataWeber, PhillipMcCormick, RobertHowell, Steve
India, with its low per capita income vast population and growing middle class, represents a significant market for low-cost, fuel-efficient automobiles. As the largest two-wheeler market globally, a transition to four-wheelers is underway, further driving the demand for affordable vehicles. This necessitates the design and development of low-priced vehicles equipped with efficient and economical powertrains. Globally, stringent regulations like Corporate Average Fuel Economy (CAFE), Worldwide Harmonized Light Vehicles Test Cycles (WLTC), and Real Driving Emissions (RDE) are pushing manufacturers to develop fuel-efficient vehicles. India has also adopted similar regulations, including CAFE2 and Bharat Stage 6-Phase 2 (BS6-2), to improve fuel economy and reduce emissions. These regulations, coupled with the growing demand for affordable vehicles, have spurred innovation in engine technology. In response to these challenges, Maruti Suzuki India Limited (MSIL) has consistently focused on
Singh, AmandeepSingh, JaspreetJalan, AnkitKumar, Narinder
With the tightening of emission regulations, Electrically Heated Catalyst (EHC) are an important technical solution for diesel vehicles to address the emission challenges of cold start and Real Driving Emission (RDE). This paper investigates the impact of EHC coupled exhaust aftertreatment system (Diesel Oxidation Catalyst (DOC) + Selective Catalytic Reduction Integrated into Diesel Particulate Filter (SDPF) + Selective Catalytic Reduction (SCR) - Ammonia Slip Catalyst (ASC)) on the energy consumption and emission characteristics of light-duty diesel vehicles based on the World Light Vehicle Test Cycle (WLTC) and RDE. The research results show that under WLTC conditions, compared to EHC off, the time for the SDPF inlet temperature to reach 180 °C when EHC on is 44 seconds earlier. The Carbon Monoxide (CO) emission of diesel vehicles is 63.5 mg/km, the Total Hydrocarbon (THC) emission value is 44.9 mg/km, the Non-Methane Hydrocarbon (NMHC) emission value is 39.5 mg/km, and the Nitrogen
Kang, LuluZhao, ZhiguoLou, Diming
Cu/zeolite selective catalytic reduction (SCR) catalysts are used globally to reduce NOx emissions from diesel engines. These catalysts can achieve high NOx conversion efficiency, and they are hydrothermally durable under real world diesel exhaust environments. However, Cu/zeolite catalysts are susceptible to sulfur poisoning and require some type of sulfur management even when used with ultra-low sulfur diesel (ULSD). In the present study, the authors seek to better illuminate the chemical processes responsible for ammonium sulfate formation and decomposition occurring in Cu/zeolite SCR catalysts. Reactor-based experiments are first conducted with a real-world concentration of SO2 (0.5 ppmv) and a typical diesel exhaust water vapor concentration (7 vol.%) to quantify progressive effects of ammonium sulfate formation. A second group of experiments probe the chemical decomposition of ammonium sulfate via NO titration. The “movement” of sulfate species during this process is monitored
Ottinger, NathanXi, YuanzhouLiu, Z. Gerald
Measurements of Hydrogen emissions from vehicle exhaust have been often substituted for prediction models, partly due to the lack of Hydrogen analyzers targeted for combustion gases. A previous study using a Hydrogen mass spectrometer revealed that the ratio of Hydrocarbons entering a Three-Way Catalyst (TWC) and Hydrogen leaving the catalyst was inconstant throughout a standardized driving cycle. Although Hydrogen by itself is not currently a target of emission regulations, its omission during catalyzer optimization may disrupt the intended performance of the integrated aftertreatment system. The highest emissions of unwanted gases are commonly seen during vehicle cold start. Thus, this study focuses on intermittent operation of an engine, such as that of full hybrid vehicles. In particular, this study measures how the gases trapped in the aftertreatment system continue to react over the TWC as it cools down after the engine stops. Hydrocarbons, NOx, NH3 and H2 are measured before and
Lamas, Jorge EduardoLacdan, Ma CamilleHara, KenjiOtsuki, Yoshinori
China 6b regulation was fully implemented since July 2023 with very strict emission standards for HC, NMHC, NOx, and CO. The country is now also in the process of developing China 7 regulation, which will perhaps impose even stricter emission limits and extra criteria pollutants including NH3. Moreover, increasingly strict fuel consumption regulation has been implemented as well and it is highly possible that greenhouse gas emission limits will be included in the China 7 regulation. With the hybrid technology innovation, PHEVs are effective in fuel economy and emission reduction, which are favored by manufacturers and consumers, and leading to a rapid increase in market share. Through the optimization of hybrid architecture and the synergy of electric motors, the operating conditions of the hybrid engine have been optimized, making it more stable and avoiding extreme engine operating conditions compared to traditional ICE, which also provides possibilities for optimizing the after
Wang, JimingLi, ChunboFeng, XiangyuChen, XiaolangBoger, ThorstenTian, LichenHu, XianliZeng, JunTian, TianGao, BojunLi, DachengLiu, ShichengJiang, Fajun
The heavy-duty low NOx program funded by EMA at Southwest Research Institute (SwRI) evaluates a combination of engine and advanced aftertreatment systems to achieve a 0.035 g/bhp-hr tailpipe NOx standard. This work emphasizes improvements to the light-off SCR (LO SCR) model used for low NOx controls. Two key mechanisms drive these improvements: the first is a real-time feedback system that utilizes the LO SCR outlet NOx sensor for short-term corrections to the model state, and the second involves adjustments to the dosing mechanism based on long-term trends in dosing signals compared to predicted NH3 consumption, derived from LO SCR inlet and outlet NOx sensors, referred to as long-term trim. An algorithm is incorporated to differentiate the LO SCR outlet NOx sensor readings into NOx and NH3 components based on cross-correlation between inlet and out NOx sensors termed as speciation. The integration of this speciation algorithm with both short-term and long-term trim mechanisms
Chundru, Venkata RajeshAdsule, KartikSharp, Christopher
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