Browse Topic: Nitrogen oxides

Items (5,077)
Find
Effects of Equivalence Ratio on Hydrogen Combustion Flow and NOX Emission Characteristics in a Jet-Trapped Vortex Combustor2026-99-08067/30/2026
The jet-trapped vortex combustor presented in this study was designed based on the trapped vortex combustor with good flame stability by introducing a jet flame-stabilization method. Leveraging the superior air-fuel mixing efficiency and enhanced heat and mass transfer of the jet stabilization method, this configuration addresses the inherent limitations of heat and mass transfer between the mainstream flow and the cavity in a conventional trapped vortex combustor. To investigate the influence of different hydrogen-air equivalence ratios on the flow dynamics, combustion performance, and emission within the jet-trapped vortex combustor, numerical simulations were conducted in this study. The results show that under different equivalence ratios, a vortex pair structure can be formed in the mixing zone between the hydrogen jet and the air jet. Complete combustion can be achieved at all equivalence ratios except for Φ = 1.56. When Φ is below 0.86, the axial distance required to achieve complete combustion progressively decreases as the equivalence ratio is reduced. The temperature distribution in the combustor is more uniform with minimal variation, and the concentration of NO emissions decreases progressively. Among these cases, the combustion efficiency, temperature distribution, and NO emission characteristic of the combustor are relatively better at Φ = 0.34.
Yan, Pinghua, Hou, Xinglong, Ren, Guanlong, Sun, Haijun, Luo, Kun, Yang, Shucheng
NOx Tracking Parameter AccuracyJ3349_202607 (Current)7/23/2026
This SAE Information Report provides SAE’s recommendations for meeting the requirements for Real Emissions Assessment Logging (REAL) oxides of nitrogen (NOx) accuracy demonstration and for the implementation of REAL NOx binning requirements as defined in onboard diagnostics (OBD) regulations 13 CCR 1971.1 and 13 CCR 1968.2.
Vehicle E E System Diagnostic Standards Committee
Study on Diesel-Methanol Non-Premixed Combustion Characteristics of a Marine Dual-Fuel Engine at Different Methanol Substitution Rate2026-99-05177/10/2026
Methanol use in marine engines has the potential to reduce nitrogen oxide emissions, particulates, and greenhouse gas emissions. A turbocharged four-stroke marine diesel powerplant was converted to run as a double-DI (direct injection) diesel-methanol hybrid engine. Experimental studies using a non-premixed combustion scheme showed that higher methanol substitution ratios (MSR) led to increased peak heat release rates. The combustion process displayed distinctive two-phase behaviors. Increasing MSR caused retarded ignition timing, shortened combustion duration, and improved thermal efficiency. Combustion stability was significantly improved at higher MSR. Emissions results showed NOX and HC were increased in proportion to MSR, whilst particulate emissions and CO concentrations were inversely reduced. Methanol enrichment was found to enhance NOX and HC formation processes but also accelerate soot particulate decomposition and CO oxidation mechanisms.
Li, Xiao, Jiang, Yuqi, Yan, Ping, Zheng, Liang, Li, Hongmei, Zhang, Wenzheng, Chen, Chao, Man, Zhongguo
NO x Formation Characteristics of Lean Hydrogen Combustion: From 0D Analysis to Comprehensive 3D-CFD Engine Investigations2026-01-07327/1/2026
The transition toward climate-neutral transportation requires powertrain concepts that combine high efficiency with low pollutant emissions. In this context, hydrogen-fueled internal combustion engines represent a promising solution when hydrogen is produced from renewable energy sources. Owing to its specific molecular properties, hydrogen offers new possibilities for influencing and optimizing the combustion process and reducing the emission formation. This paper presents a numerical approach for characterizing the NOx formation in a single-cylinder research engine equipped with port fuel injection and a passive pre-chamber ignition system. The single-cylinder is operated over a wide range of engine loads and speeds, covering air-to-fuel ratios from λ=1.5 to 2.5 and achieving up to 23 bar indicated mean effective pressure. The study focuses on the influence of engine load and mixture composition on NOx emissions. A dedicated look-up table approach in combination with several reaction parameters based on the extended Zeldovich mechanism are evaluated through comparison with experimental data. Furthermore, multiple sampling positions within the CFD mesh are examined. The simulations reproduce measured trends across variations in load and air-to-fuel ratio with good accuracy. At high load and λ=1.5, NOx emissions of up to 6000 ppm are produced, decreasing exponentially with increasing excess air. Finally, potential NOx reduction strategies for the single-cylinder are examined. While influencing the mixture homogenization shows limited effectiveness, temperature-based actions prove to be more effective. Among the investigated approaches, a Miller intake valve strategy yields the largest benefit, achieving approximately 10% NOx reduction by lowering end-of-compression temperatures and increasing residual gas dilution under otherwise identical operating conditions.
Gal, Thomas, Vacca, Antonino, Chiodi, Marco, Schmelcher, Robin, Kulzer, Andre Casal
A Modeling and Experimental Study of the Argon Power Cycle Using Mixing-Controlled Combustion2026-01-50436/19/2026
The closed-cycle hydrogen-fueled argon power cycle is a zero emissions concept that combines a carbon-free fuel with argon as a diluent replacement for nitrogen. The lack of nitrogen in the argon power cycle results in zero NOx emissions on an internal combustion engine platform. There is also massive efficiency improvement because argon is monatomic and has a very high ratio of specific heats. However, this will also result in combustion temperatures and pressures exceeding those normally achieved on an air-standard engine platform. The literature shows conflict between modeling, which promises incredibly high efficiency gains, and experiment, which show more modest efficiency gains. This work combined thermodynamic modeling, literature analysis, and experiments to understand this discrepancy and ultimately understand what level of efficiency gain can be expected for the argon power cycle. It was found that while low compression ratio engines stand to see the largest relative efficiency improvement, high compression ratio engines are the ones that can ultimately achieve ~60%+ efficiency, corresponding to a 15–20% relative improvement in efficiency over an air-standard engine platform operating at or above 50% efficiency. The elevated temperatures and pressures of the cycle result in knock in spark ignition, so either a high compression ratio knock mitigation strategy or mixing-controlled operation is required. Experiments conducted using a diesel-fueled compression ignition engine showed that a 30% argon replacement resulted in ~6% and full nitrogen replacement with argon resulted in ~14% relative efficiency improvement at 8 bar gross indicated mean effective pressure (IMEPg) without intake boosting on a heavy-duty engine with a compression ratio of 20.0 and late intake valve closing, agreeing with modeling results. The key takeaway to match modeling and experimental trends is to accurately model heat transfer, which increases significantly for the argon power cycle.
Gainey, Brian, Ahrling, Christoffer, Tunestal, Per, Tuner, Martin
Accelerated Computational Fluid Dynamics (CFD)-Based Quantitative Prediction of Urea Deposition in Selective Catalytic Reduction (SCR) Systems2026-01-50416/12/2026
Mitigation of harmful emissions from oil-based engines is essential to avoid environmental pollution and comply with various NOx regulations across the globe. This can be partially achieved by injecting urea to produce ammonia (NH3), which reacts with NOx in a catalyst to produce harmless nitrogen (N2) and water vapor (H2O). However, urea deposition in a selective catalytic reduction (SCR) system poses a significant threat to the NOx removal process by not only reducing the urea conversion rate but also blocking the incoming flow and causing an additional pressure drop. Numerical modeling of this urea deposit formation involves multiphase flow physics coupled with accurate heat transfer calculations. Additionally, since urea decomposes into various by-products like biuret, cyanuric acid (CYA), and ammelide, detailed chemical kinetics modeling is equally important. Accurate and fast computational fluid dynamics (CFD) simulations can help accelerate SCR system design cycles, leading to a reduction in experimental cost. In this study, we employ CONVERGE CFD to model the whole process from urea–water solution (UWS) injection to droplet evaporation and decomposition (using 12-step detailed-chemistry), film formation, and final deposition as a solid. A new spray-wall interaction model is introduced based on published experimental observations. The efficacy of the numerical model is demonstrated using an S-bend tube, where the UWS is injected just at the end of the S-bend. The predicted deposit mass and patterns are compared with the experiments, and good agreement is observed for three different operating conditions. A novel boundary morphing feature is activated to model the deformation of the tube walls because of urea deposition. Finally, to accelerate the simulations, a spray database approach is introduced. Coupled with the fixed-flow feature, this results in around 58% reduction in computational time without compromising accuracy. The present work thus provides a numerical framework to accurately capture urea deposition with a fast turnaround time.
Morab, Sumant R., Khalate, Suraj, Ansari, Shoaib, Yang, Pengze
SAE Truck & Off-Highway Engineering: June 202626TOFHP066/11/2026
Hitting the road in the all-new VNR Volvo Trucks' revised VNR brings updated safety tech, improved fuel economy and driver comfort features to the regional haul segment. In fuel control How to ensure off-highway combustion systems operate with sufficient control to meet tightening emissions standards and evolving fuel landscapes without sacrificing reliability. Keeping industrial vehicles secure in a digital landscape OEMs, integrators and suppliers must continuously process, assess and identify platform vulnerabilities to prioritize and implement updates that protect systems from cyberattacks and data breaches. Editorial Diversification key for sustainable fleets ACT 2026: Uncertainty still exists over EPA 2027 NOx limit ZF bets big on hybrid transmissions Moog simplifies off-highway electrification Bosch shows off its first U.S. electrolyzer Microvision fast-tracks adoption of Luminar tech; eyes defense, industrial sectors Future-ready, customizable connectivity powers precision agriculture Kenworth's new C580 clocks in for work Harbinger extends its range of medium-duty EVs Kubota's SVL110-3 brings new tech and service features to CTL segment Product Briefs SPOTLIGHTS: Diesel Engines & Subsystems; Manufacturing Tools & Materials; Motors, Inverters & Gearboxes Q&A Volvo turns attention to vocational trucks
Investigating the Potential of Two Individually Controlled Injectors per Rotor for a Direct Injection Hydrogen Wankel Engine2026-37-00086/9/2026
Hydrogen-fueled rotary engines offer a promising zero-emission solution for compact commercial powertrains. This study reports experimental results from the further development of a naturally aspirated, direct-injection hydrogen rotary engine by HTM. Initial applications, such as an airport baggage tractor, demonstrated technical feasibility but revealed pre-ignition that limited maximum torque. To address this, mixture formation was investigated using an experimental setup with two independently controlled injectors feeding a single rotor injection channel. The effects on operating behavior, efficiency, and NOx emissions were evaluated. The dual-injector configuration significantly shortens injection duration and improves spatial distribution of hydrogen within the combustion chamber. Enhanced mixture control suppresses pre-ignition and enables higher mean effective pressure. Systematic variation of injection timing under representative steady-state conditions also shows potential for NOx reduction through differentiated injector operation. In-cylinder pressure analysis and exhaust gas measurements provide detailed insight into combustion characteristics and abnormal events. The dual-injector setup increases torque capability and operational robustness without additional mechanical complexity, supporting the use of hydrogen rotary engines in compact hybrid systems and stationary power applications.
Endres, Jonas, Beidl, Christian, Herold, Tim, Lavall, Philipp, Schmidt, Marvin, Hofmann, Silas, Kahl, Jonas
An Open-Source Framework to Automate Virtual Optimization of Internal Combustion Engine Calibration Maps through Shape-Based Strategy2026-37-00016/9/2026
The automotive industry is facing increasingly stringent regulatory constraints, driving the need for faster and more efficient powertrain development. This results in higher systems complexity, making internal combustion engine calibration progressively more challenging to meet performance and emissions targets. This, combined with the manual nature of traditional calibration workflows, leads to a time-consuming process that heavily relies on human expertise. Although virtualization can reduce development time and costs, the overall workflow remains largely dependent on manual decision-making and iterative refinement. In this context, this work presents a virtual calibration framework based on a genetic algorithm, aimed at the automated optimization of engine calibration maps to satisfy performance and emissions constraints, while reducing manual effort. Each calibration map is represented through a polynomial parameterization. Specifically, a generic three-dimensional polynomial with map-specific order encodes the shape of each map, ensuring smoothness which directly impact on drivability. Accordingly, the calibration problem is reformulated as the optimization of a compact set of polynomial parameters that uniquely define the full set of calibration maps, rather than individual set-point. Each candidate solution is assessed by generating the corresponding calibration maps and simulating the engine behavior through a neural-network-based digital twin, providing predictions of operating conditions, hardware limits, performance metrics, and emissions. The proposed framework was validated on a passenger-car diesel engine, considering a reduced yet representative set of calibration maps, including main injection start of injection, air mass, boost pressure, and injection rail pressure. The objective of optimization was the minimization of brake mean fuel consumption, subject to an upper bound constraint on nitrogen oxides emissions. The global optimization process explored approximately 106 different calibration candidates within about 36 hours, leveraging parallel computation on a standard laptop. The results indicate that the procedure can deliver multiple near-optimal preliminary calibration solutions, providing an effective starting point for subsequent manual finetuning.
Romano, Gianvito, Aglietti, Filippo, Spedicato, Tonio, Cozza, Ivan Flaminio, Capra, Andrea
Combined EGR-Air Dilution Effects on Performance, Combustion and Emissions of a Single-Cylinder Spark-Ignition Direct-Injection Hydrogen Engine2026-37-00096/9/2026
Hydrogen internal combustion engines (H2ICE) have emerged as a promising solution for decarbonisation of the transport sector, due to low cost and potential for rapid deployment. However, abnormal combustion and high nitrogen oxide (NOx) emissions limit stoichiometric operation, making dilution strategies essential. While lean combustion has been widely studied, combined dilution strategies of air and exhaust gas recirculation (EGR) require further investigation. This work presents experimental results from a boosted 0.5-litre spark-ignition direct-injection single-cylinder research engine equipped with high-tumble ports and cooled high-pressure EGR. Relative air–fuel ratios (lambda) of 1 to 3 and EGR rates of 0 to 40% are evaluated at 5, 10, and 15 bar of indicated mean effective pressure (IMEP) at 2000 rpm to assess effects on net indicated thermal efficiency (nITE), combustion, and emissions. A peak nITE of 43.5% is achieved at 10 bar IMEP, λ = 2.5, and 30% EGR, which can be primarily attributed to low heat losses while maintaining lower combustion losses than at higher dilution levels. NOx emissions are effectively mitigated with increasing EGR and are largely independent of lambda at 5 bar IMEP under EGR dilution. At high load, EGR is shown to be beneficial to achieve high efficiency and lower NOx at lower dilution rates, thereby reducing boosting requirements. Equivalent dilution parameters are used to investigate combined effects of EGR and air dilution, from a mass dilution perspective with the mass dilution rate (MDR) and equivalent thermal reduction with the thermal dilution parameter (TDP). Indicated efficiency and unburned hydrogen emissions correlated strongly with MDR, while temperature-dependent parameters showed a high correlation with TDP. At constant engine speed, burn durations are shown to depend mainly on degree of thermal dilution, with no effect of load observed. At high dilution rates, combustion became increasingly insensitive to further dilution, indicating the presence of thermodiffusive instabilities under high levels of both EGR and air dilution.
King, Aidan, Islam, Reza, Pickering, Simon, Yuan, Hao, Mudge, Henry, Giles, Karl, Goyal, Harsh, Jones, Peter, Akehurst, Sam, Esposito, Stefania
Nitrogen-Based Emissions from Ammonia Combustion in a Heavy-Duty Spark Ignition Engine2026-37-00326/9/2026
Ammonia (NH3) is a carbon-free fuel with strong potential for spark-ignition (SI) engine applications. However, the engine can produce complex nitrogen-based emissions not adequately captured by conventional engine models. This study consolidated the results of experimental and numerical studies on the use of neat NH3 combustion in a heavy-duty compression-ignition engine converted to spark-ignition operation, first for a sweep of equivalence ratios (ϕ) from 0.7 to 1.0, and another from varying the energy substitution ratio of methane (CH4)– NH3 blends from neat CH4 to neat NH3 at constant ϕ = 0.8. Two 0-D two-zone SI engine models with detailed chemistry (called “original” and “extended”) predicted engine thermodynamics and emissions. While the original model reproduced in-cylinder pressure and combustion phasing, it failed to capture the effect of fuel composition or operating condition on NO trends, both under- and over-predicting them for neat NH3 and CH4-rich operations. An extension of the model incorporating a burned-zone batch reactor and two more reactors simulating the post-combustion oxidation of the mixture exiting crevices and the DeNOx processes during exhaust blowdown were implemented to address these limitations. Analysis of NO formation pathways highlighted the differences between modeling approaches. The equilibrium assumptions in the original model restricted NO formation primarily to thermal (Zeldovich) mechanisms. In contrast, the kinetics-driven model showed that non-thermal pathways dominate NO formation for all NH3-containing cases, which shows the limitations of conventional SI models developed for hydrocarbons when applied to nitrogen-containing fuels. Post-combustion homogeneous reactors for crevice-based oxidation and exhaust blowdown revealed significant NO and N2O formation after the end of combustion at moderate temperatures (850–1200 K), suggesting that N2O formation was dominated by secondary thermal processes. Therefore, the inclusion of post-combustion chemistry and more consistent models are essential for accurate emission prediction in NH3-fueled SI engines.
Trujillo Grisales, Juan, Saenz Prado, Stefany, Alvarez, Luis F., Akkerman, Vyacheslav, Dumitrescu, Cosmin E.
ACT 2026: Uncertainty still exists over EPA 2027 NOx limit26TOFHP06_056/1/2026
Though the U.S. EPA has rolled back many emissions regulations surrounding the mobility industry, its HD rules remain intact, meaning manufacturers must hit the world's most stringent NOx requirement. It was clear at a panel of industry experts that the new rule was still causing confusion among operators and fleet owners. The EPA's new limits are set at 0.035 grams per horsepower-hour during normal operation, 0.050 grams at low load and 10.0 grams at idle. A panel immediately following revealed how companies have hit the tough target, which goes into effect in January of 2027.
Clonts, Chris
Conceptual Design of Hydrogen Fuel-Cell-Based Utility Aircraft2026-26-07836/1/2026
The aviation industry contributes to around 2% of global carbon dioxide emissions. As various sectors of the economy look to reduce their global carbon footprint, the aviation industry is positively acknowledging alternatives to jet fuel. Hydrogen proves to be one such alternative having a high energy density and producing zero carbon emissions on combustion. Hydrogen when used in a jet engine produces water vapour and NOx emissions. In order to reduce the effect of GHGs, the current study aims to develop aircraft concepts suitable with hydrogen propulsion through fuel cells for a short-haul commercial mission profile. Aircrafts such as Metro-23 and Dornier 228-212 were referenced for the requirements of a utility turboprop aircraft. The weight estimation was done to obtain the take-off weight of 10,863 kg following the optimization of thrust to weight ratio and wing loading to calculate the initial dimensions. OpenVSP was used to model the initial structure of the aircraft. For the propulsion system, the PEM fuel cell was sized for the aircraft to achieve a range of 2,065 km and endurance of 6 hours in two configurations. Also, various configurations of fuel tanks and their positions were analyzed. The design was able to achieve a reduction of up to 18% in the propulsion system weight through fuel stack configuration. Iterations were performed to achieve static stability and CG was estimated to be 31% of root chord. The final configuration layout with cabin seats, propellers, fuel tank and fuel cells were analysed for static stability. The flight performance of the aircraft is comparable to the reference aircrafts. The proposed design leads towards the path of sustainable aviation.
Bhattacharya, Anisha, Seetha Ramu, Sree Valli, C N, Lakshmi Manasa, Rohit, Benjamin
Experimental Investigation of Diesel, Aqueous Ammonia, and Compressed Natural Gas Mixtures on Performance and Emissions in a Compression Ignition Engine04-19-03-00115/30/2026
Abstract This study investigates and evaluates systematically the combustion, performance, and emissions characteristics of heavy-duty diesel engines fueled by diesel–ammonia–compressed natural gas triple blends. While dual-fuel systems are well-documented, the interactive effects of ammonia and CNG within a single compression ignition (CI) engine remain largely unexplored. Experiments were conducted on a 300 Nm, 660 rpm diesel engine by testing pure diesel, diesel–ammonia blends (10–20 wt.% aqueous ammonia), and triple-fuel mixtures containing 10% of the total energy from compressed natural gas. Pure diesel was first tested to provide baseline data, and subsequently blends were tested for a comparative study. The primary contribution of this work is the identification of a synergistic effect of the fuel triple blends on engine performance and emissions. Results indicate that all fuel blends improve thermal efficiency and reduce fuel consumption compared to conventional diesel. The blend containing 20% aqueous ammonia, 80% diesel, and 10% of the total fuel energy supplied by compressed natural gas achieved the highest thermal efficiency of 39.7% (7% higher than diesel) and the lowest brake specific fuel consumption of 211.22 g/kWh. Furthermore, emissions analysis revealed that carbon dioxide and nitrogen oxide emissions were significantly reduced with this triple blend. The blend decreased carbon dioxide by 26.6% and nitrogen oxide emissions by 32.1%, while hydrocarbon emissions were also lowered by up to 29.2%. Carbon monoxide emissions increased slightly for the triple blends, reaching a maximum value of 3.9028 g/kWh for the A20D80CNG10 mixture, compared to diesel operation. The slight increase in carbon monoxide emissions for triple blends highlights a trade-off in emission behavior. These findings address the combined utilization of diesel–ammonia–compressed natural gas triple-fuel mixtures in heavy-duty engines, demonstrating that strategic blending can simultaneously improve efficiency while mitigating environmental impact. Graphical Abstract
Sinkala, Happy, Sarıtaş, Mehmet, Kül, Volkan Sabri, Akansu, Selahaddin Orhan, Ünalan, Sebahattin
Effect of Burning Biomass Fuel Cyclohexanol on Diesel Engine Performance2026-99-17085/22/2026
Against the backdrop of growing global demands for energy sustainability and stricter emission regulations for diesel engines, this study investigates the performance implications of incorporating cyclohexanol—a renewable oxygenated fuel—into diesel fuel blends. Using a marine medium-speed diesel engine as the experimental platform, the research systematically evaluates engine performance and emission characteristics across a range of cyclohexanol-diesel blend ratios under low, medium, and high load conditions. Experimental findings reveal multifaceted effects of cyclohexanol blending on engine operation. Combustion of the blended fuels enhances the engine’s dynamic performance, particularly under medium and high loads, where the maximum in-cylinder burst pressure exhibits a noticeable increase. This improvement is attributed to cyclohexanol’s oxygen-carrying capacity, which promotes more vigorous and sustained combustion reactions. In terms of emissions, increasing the proportion of cyclohexanol in the fuel blend leads to significant reductions in soot and carbon monoxide (CO) emissions, reflecting the cleaner-burning properties of the oxygenated component. However, this is accompanied by an uptick in nitrogen oxide (NOx) emissions, likely due to the elevated combustion temperatures generated by the more efficient fuel oxidation process. From an economic perspective, cyclohexanol blending at consistent load levels induces a postponement in the crank angle at which peak heat release occurs during combustion. This temporal shift prolongs the effective combustion duration, enabling more complete fuel utilization within the cylinder. Consequently, fuel consumption rates decrease, and overall engine efficiency improves, highlighting the potential of cyclohexanol blends to enhance operational economy in marine propulsion systems. In summary, this study underscores the complex trade-offs associated with cyclohexanol-diesel blends: while they offer tangible benefits in power output, fuel efficiency, and reduced particulate emissions, managing the increase in NOx emissions remains a critical challenge. The results provide a foundational framework for advancing biofuel applications in marine engines, emphasizing the need for integrated emission control strategies to optimize the balance between performance and environmental sustainability.
Chen, Ke, Yang, Chenxi, Wang, Yibin, Fan, Jinyu, Liu, Yuchen, Ye, Zixiao, Huang, Jialiang
Research on the Statistical Method of Real Driving Emission Data of Commercial Vehicle under Low Load2026-99-17215/22/2026
Current emission regulation in China (National VI b) adopts the work-based window (WBW) method to statistically analyze PEMS experimental data. This method cannot fully account for experimental data under low load and cold start conditions. In light of this, this paper proposes a statistical method for low-load condition experimental data. Firstly, the adaptability of the WBW method to low-load condition experimental data is analyzed. Secondly, the representativeness and authenticity of statistical results from different methods are compared. The results indicate that when the power threshold of the WBW method is set at 20%, the effective window qualification rate in six experiments is less than 40%. And as the load decreases, the power threshold required to meet regulatory requirements needs to be further reduced, meaning more low-power data points are discarded. The WBW method eliminates many low output power data points with high CO and NOx emissions from test data on an urban road section with low driving speed, significantly underestimating the CO and NOx emission data under low load conditions, with NOx emissions 56.8% lower than the cumulative averaging (CA) method results. It is recommended to use the CA method for calculating CO and NOx emissions under low load conditions.
Tang, Gangzhi, Liu, Jiajun, Wang, Shuaibin, Du, Baocheng, Deng, Xuefei
Effect of EGR Rate on Cyclohexanol-Diesel Dual-fuel Engines2026-99-17095/22/2026
To reduce high NOx emissions from diesel-cyclohexanol blends, this study employed a marine medium-speed diesel engine as the experimental platform. An in-cylinder combustion model was developed and meshed using AVL - FIRE software, with model validity validated against experimental data. Tests were conducted at four load conditions (25%, 50%, 75%, and 100% load) with a 30% cyclohexanol blend (C30) and four EGR rates (0%, 7.5%, 10%, and 12.5%) to analyze combustion characteristics, emissions, and fuel economy. The results showed that the introduction of EGR had a striking inhibitory effect on NOx emissions. At 100% load with 12.5% EGR rate, NOx emissions were substantially reduced compared to baseline operation without EGR. However, EGR implementation led to delayed ignition timing, reduced in-cylinder pressure, and worsened fuel economy. Therefore, an appropriately calibrated EGR strategy can effectively reduce NOx emissions, though it requires optimization to mitigate adverse effects on combustion performance and efficiency.
Liu, Yuchen, Yang, Chenxi, Fan, Jinyu, Chen, Ke, Ye, Zixiao, Huang, Jialiang
Experimental Study of Hydrogen Combustion in Argon-Oxygen Mixture Using an Optical Engine2026-01-03284/7/2026
The Argon Power Cycle (APC) is an emerging high-efficiency combustion technology for internal combustion engines. In APC, the conventional air-based working fluid is replaced with an inert argon gas. This substitution inherently increases engine efficiency through thermodynamic properties of argon, in particular a high adiabatic factor ?? ~1.67. A hydrogen-fueled APC engine offers the potential for highly efficient zero emission combustion by also eliminating nitrogen oxide (NOx) formation. In the present paper, hydrogen combustion is studied in an optical heavy-duty research engine, with the objective of providing the first visualization of H2 combustion in an argon–oxygen mixture. A comparative analysis of high-speed optical imaging and in-cylinder pressure measurements is conducted for two different modes: 1) conventional air operation and 2) argon-oxygen mixture operation. The high-speed images reveal a distinctly different combustion process between the two operating modes. The main results of the study are as follows: 1) The cylinder peak temperature during compression, estimated from cylinder pressure, increases from approximately 800K (air) to 1200K (argon-oxygen). 2) Abrupt hydrogen pre-ignition was observed for the argon-oxygen mixture, leading to strong pressure oscillations. In contrast, for hydrogen-air combustion, the mixture was ignited by the spark without pre-ignition. 3) The initial heat release was significantly higher in the argon-oxygen mixture yielding a pressure rise in a few crank angle degrees (CAD) in contrast to 5-10 CAD for the air mixtures. 4) Extremely lean hydrogen combustion was observed for the argon-oxygen case.
Kapp, Joakim, Cheng, Qiang, Kaario, Ossi, Vuorinen, Ville
Effect of Exhaust Gas Components on Oxygen Storage Capacity Measurements of Automotive Catalysts2026-01-03604/7/2026
Three-way catalytic converters (TWC) are one of the most popular methods to help reduce harmful tailpipe emissions emitted from internal combustion (IC) vehicles. To help improve conversion efficiency, TWCs can store and release oxygen via an oxygen storage capacity (OSC) mechanism. During engine control unit (ECU) calibration, on board OSC measurements are correlated to TWC and vehicle emissions to monitor emissions performance throughout the full useful life (FUL) of the vehicle. It is known that different test conditions, including temperature, space velocity and background gases in the exhaust stream affect OSC measurement, potentially altering the calculated OSC values and thus the perceived level of OSC and emissions preformance during operation. This study utilises an OMEGA test bench to complete OSC measurements on the full-scale automotive catalyst samples to quantify the effects of different background gases including carbon monoxide, hydrocarbons and nitric oxide on OSC measurements, concluding that all background gases studied affect measured OSC values. The study revealed that hydrocarbons had the largest effect on OSC measurement increasing OSC values by up to 50%. It was concluded that the increase in OSC measurement with injected hydrocarbons was due to the breakdown of hydrocarbons on the catalyst surface during rich periods of operation increasing the amount of oxygen required to fully oxidise the catalyst resulting in a larger perceived OSC measurement. During the initial ECU calibration original equipment manufacturers (OEM) should consider these effects on OSC measurement and understand how this will affect perceived OSC and vehicle emissions performance for FUL and onboard diagnostics (OBD) applications. This will help ensure emissions compliance and guide optimized catalyst and engine calibrations.
Mc Grane, Liam, Douglas, Roy, Irwin, Kurtis, Woods, Andrew, Elliott, Matthew, Istrate, Oana, Nockemann, Peter
On-Road Vehicle Testing and Characterization2026-01-01954/7/2026
Vehicle testing for fuel economy and emissions is typically performed indoors over standard dynamometer drive schedules to minimize variability and maximize repeatability of the results. In contrast, during on-road operation, operational parameters such as vehicle speed and acceleration and environmental factors such as temperature and wind will change unpredictably. These factors influence vehicle fuel economy and emissions, making on-road operation much more variable than dynamometer results. However, even though on-road conditions may be unpredictable, the on-road operational data can still be used to characterize vehicle performance. This paper describes the development of an on-road vehicle test methodology, with a focus on accounting for on-road factors with a high degree of accuracy while requiring only an achievable and reasonable amount of data. To develop this methodology, a 2016 Honda Civic was instrumented and driven multiple times over a route covering urban, rural, and freeway segments. Vehicle operational data, environmental conditions, fuel consumption, and emissions were recorded. The route was divided into segments and drive cycle parameters were calculated for each segment. Simple empirical equations were developed for this vehicle correlating fuel consumption with drive cycle parameters and the environmental conditions. The empirical models were compared to fuel consumption data from dynamometer tests with good results. Criteria pollutants (CO, NOx, and THC) were also measured and compared to dynamometer data. Finally, the amount of testing and data required to adequately characterize vehicle performance is discussed.
Moskalik, Andrew, Barba, Daniel
Model-Based Development of a Heavy-Duty H 2 -ICE and Integrated, Turbogeneration, Electrification, and Supercharging (ITES) System2026-01-04264/7/2026
Changing global economic conditions and efforts to reduce greenhouse gas emissions are driving the need to develop efficient, near-term, alternative propulsion system technologies for heavy-duty vehicles. This study combines a hydrogen internal combustion engine (H2-ICE) with electrically assisted turbocharging, exhaust energy recovery, and mild hybridization to maximize propulsion system efficiency and reduce NOx emissions. To reduce cost and packaging impact of integration of these technologies on an engine, the study presents a model-based development and optimization of an Integrated Turbogeneration, Electrification, and Supercharging (ITES) system that combines the enabling components into a single compact unit. In the first phase of this study, a H2-ICE and aftertreatment concept for a MY2027 7.7L medium heavy-duty on-road engine was developed and evaluated through 1D simulation. The concept was to convert a diesel engine by changing the cylinder head to implement a port fuel injection (PFI) lean H2 SI combustion system with two-stage turbocharging and no external EGR. The concept was optimized for compression ratio, valve lift profiles, turbocharging, aftertreatment size/specification, and calibration using 1D system simulation in GT-SUITE. In the second phase of this study, the H2-ICE concept performance was further improved by integrating the ITES system and evaluated through 1D simulation. The ITES system replaces the conventional low-pressure stage of the boosting system and adds the capability of electrically assisted turbocharging, turbogeneration from exhaust energy, and P1 mild-hybridization. Applying a model-based approach, the H2-ICE & ITES component sizes were optimized for the best performance and emissions benefit. Using 1D simulation of validated models, the efficiency benefit of the ITES system on engine and vehicle level system was predicted. Finally, a vehicle level simulation was conducted comparing the fuel consumption between a conventional advanced boosting system H2-ICE concept and H2-ICE+ITES concept for Class 6-7 medium heavy duty truck application.
Bustamante, Oscar, Correia Garcia, Bruno, Joshi, Satyum, Franke, Michael
Heavy Duty Hydrogen Internal Combustion Engine Emissions Development to Achieve Ultra-low NOx2026-01-03564/7/2026
This paper presents the emissions development of a heavy-duty hydrogen internal-combustion engine (H₂ICE) targeting ultra-low NOx with a design goal of 20 mg/hp-hr. The approach integrates advanced thermal management of the engine and aftertreatment, including engine out NOx management through air-fuel ratio controls and an electric heater to accelerate catalyst light-off and sustain activity at low-load/idle conditions. A diesel-derived aftertreatment system (ATS) is selected to maximize practicality and component commonality, and an integrated controls strategy spanning the engine and ATS is implemented to demonstrate ultra-low NOx capability over EPA certification cycles. The paper concludes with considerations for periodic SCR regeneration to ensure emission compliance.
Shakya, Bijesh, Xu, Hui, Yang, Zhao, Stetter, John
Impact of Hydrogen on Methane and Pollutant Emissions over Three-Way Catalysts with Natural Gas–Hydrogen Blends2026-01-03574/7/2026
Blending natural gas (NG) with hydrogen (H₂) can improve combustion and engine performance while potentially facilitating the catalytic conversion of methane and other pollutants, resulting in cleaner tailpipe emissions. This study evaluates the impact of H2 on the conversion of methane, CO, and NOx emissions on a commercial three-way catalyst (TWC) in a flow reactor using synthetic gas mixtures that simulate stoichiometric engine exhausts with NG or NG+H₂ combustion. The work examines whether, and how, the additional amount of H₂ in the exhaust stream affects the conversion efficiency of methane and other pollutants. Experiments were conducted with both degreened and aged catalysts under controlled conditions, systematically varying temperature, the air-to-fuel equivalence ratio (λ), and λ modulation. Test conditions covered λ values from 0.996 to 1.000 to represent nominally stoichiometric engine operation with different λ modulation amplitudes, as well as a range of temperatures to inform control strategies for effective CH₄, CO, and NOₓ reduction. Overall, the results show that hydrogen addition significantly improves the conversion efficiency of CH₄ and NOₓ, particularly at temperatures below 500 °C. More significantly, this study highlights that exhaust gas composition, operating temperature, λ management, and the oxygen storage capacity of the TWC all play major roles in affecting the tailpipe emissions from NG and NG+H₂ combustion.
Prikhodko, Vitaly, Wang, Min, Park, Yeonshil, Chen, Hai-Ying, Pihl, Josh
Development of a Zeolite-Based (HC/NOx Trap Type) Cold-Start Catalyst (CSC) for Meeting Tier4/LEV IV Tailpipe Emission Standards, Part IV2026-01-03644/7/2026
This paper is a follow-up study to three preceding reports [1,2,3] that focus on the development of a β-zeolite-based hydrocarbon/nitrogen oxide (HC/NOₓ) trap-type cold-start catalyst (CSC) — a cost-efficient technical strategy for meeting the increasingly stringent vehicle tailpipe emission standards for automotive exhaust systems, including Tier 4 and LEV IV, which are to be enforced in the near future. A core challenge in meeting Tier 4 and LEV IV exhaust emission standards lies in the fact that both the SC03 and US06 test cycles commence from ambient (cold) temperatures, as opposed to the elevated (hot) starting temperatures mandated for the preceding Tier 3 and LEV III standards. In the present study, a hybrid electric vehicle (HEV) fitted with two distinct Tier 3-certified exhaust aftertreatment systems—one officially certified to Bin 30 standards and the other a Bin 20-equivalent system (non-officially certified)—was subjected to testing under the cold SC03, cold US06, hot SC03, and hot US06 test cycles for the purpose of comparative analysis. To meet the Tier 4/LEV IV Bin 30 engineering target of 13.13 mg/mile for combined NOₓ+NMHC tailpipe emissions, the HEV with the Tier 3 Bin 30 system required an approximate 64% reduction in tailpipe emissions during cold SC03 tests, while the HEV with the Tier 3 Bin 20 system needed a 52% reduction. For cold US06 tests, these two HEVs required emission reductions of 50% and 38%, respectively, to achieve the same target. The higher tailpipe emissions observed in cold tests (relative to hot tests of the same cycles) are attributed to elevated cold-start emissions. The CSCs developed in this work were applied to modify the Tier 3 Bin 20 aftertreatment system, and vehicle tests were conducted with the CSC-modified systems under both cold SC03 and cold US06 cycles. Notably, the CSCs effectively reduced cold-start tailpipe emissions (NOₓ+NMHC) in both test cycles, enabling the HEV to meet the Tier 4/LEV IV Bin 30 engineering target of 13.13 mg/mile for NOₓ+NMHC tailpipe emissions. Detailed emission results, along with the effects of zeolite loading and Pd loading on CSC performance, were also investigated and are discussed in this manuscript.
Xu, Lifeng, Wei, Hong, Zhao, Pengfei, Ma, Ruibo, Wang, Lin, Qian, Wangmu, Qian, Menghan
Virtual Sensor Development for Real-Time Estimation of Transient NOx Emissions for Internal Combustion Engine2026-01-03704/7/2026
Accurately measuring NOx emissions under transient engine conditions is becoming increasingly important with upcoming Euro 7 and EPA 2027 regulations. Traditional physical sensors often struggle with cost and response time, especially with aging of sensors in dynamic operation. This paper introduces a machine-learning–based virtual NOx sensor that can provide real-time emission estimates while reducing reliance on hardware sensors. The approach uses multiple machine-learning methods (Random Forest, Bootstrap Aggregating, Adaptive Boosting, Gradient Boosting, Extreme Gradient Boosting) and selected best one to establish correlations between engine operating parameters, measured steady-state data, and transient duty cycle NOx emissions. Validation across different duty cycles has shown strong alignment with physical sensor readings, with R2 values above 99.95% for training cycle data sets and above 95.34% for held-out cycles during training. The model needs to be trained with larger training samples to further improve accuracy for unseen data sets. By reducing sensor costs, this solution supports scalable use in production engines. The NOx virtual sensor can also serve as a redundancy measure to back up physical sensors, reducing the risk of compliance failures in case of physical sensor faults. Overall, the proposed method offers a cost-effective pathway to improve compliance monitoring, engine performance optimization, and regulatory readiness for the next generation of efficient powertrains.
Kumar, Chandan, Dahodwala, Mufaddel, Thawrani, Kiran
Experimental and Kinetic Modeling Study of Aged Natural Gas Three-Way Catalyst Performance2026-01-03734/7/2026
The applicability of three-way catalyst (TWC) models for system-level aftertreatment simulations under transient operating conditions of natural gas engines depend on accurate integration of reaction kinetics as a function of the air-fuel equivalence ratio lambda(λ). A comprehensive global kinetic model has been developed for an aged commercial three-way catalyst (TWC), incorporating key reaction pathways including oxidation of CO, CH₄, C₂H₆, and H₂; reforming of CH₄ and C₂H₆; the water-gas shift reaction; and NO reduction via CO and H₂. The model also accounts for oxygen storage capacity (OSC) and its dynamic interaction with CO and H₂. To calibrate kinetic parameters, systematic bench-scale flow reactor experiments were conducted under lean, stoichiometric, and rich conditions. Performance metrics focused on CH₄ and C₂H₆ oxidation and reforming across varying O₂ and CO concentrations, and NO reduction with CO and H₂ under different oxygen levels. Experimental results revealed that CO suppresses the reforming of CH₄ and C₂H₆. NO conversion was observed between 150°C and 600°C, with H₂-driven reduction producing NH₃, N₂, and N₂O depending on lambda (λ). Under rich conditions, complete NO conversion occurred from 150°C, while lean conditions showed reduced NO conversion at elevated temperatures due to H₂ oxidation. NO reduction with CO initiated at 250°C, achieving full conversion under rich conditions. The model accurately captures the influence of λ on NO reduction with both H₂ and CO, predicts NH₃ formation under rich conditions, and simulates H₂ generation via the water-gas shift reaction above 400°C. It successfully reproduces λ sweep data (λ = 0.95–1.02) and demonstrates CO inhibition effects on H₂ oxidation and NO reduction. This global model is validated with dithering reactor data and qualitatively captures key trends in data which aids in catalyst sizing, calibration robustness and the system level modeling of end of useful life parts. Further validation of the current developed model with lean-rich cycle tests confirms the model’s ability to predict NOx slip at the onset of rich cycles impacting the ability to accurately predict NOx emissions during engine braking events in system level models.
Raj, Richa, Kim, Mi-Young, Aigbiremolen, Grace, Srinivasan, Anand
Advanced Multifunctional Catalysts for Emission Control in Hydrogen and Diesel Engines2026-01-03674/7/2026
As hydrogen internal combustion engines (H2-ICE) gain traction, optimizing exhaust aftertreatment technologies for nitrogen oxide (NOx) control has become increasingly critical. While selective catalytic reduction (SCR) systems remain the primary approach for NOx mitigation, oxidation catalysts are also being explored to facilitate hydrogen oxidation and improve overall exhaust treatment efficiency. This work presents a multifunctional catalyst (MFC) concept that combines supported Pd and Cu-zeolite to enable simultaneous NOx reduction and hydrogen oxidation within a single catalytic unit. Preliminary results show that hydrogen oxidation on supported Pd occurs above 300 °C, while Cu-zeolite achieves nearly complete NOx conversion. Experiments on individual components indicate that supported Pd initiates ammonia oxidation only after hydrogen is depleted. In the presence of hydrogen, ammonia conversion remains below 20%, indicating that hydrogen availability suppresses ammonia oxidation, which is favorable for SCR operation. The MFC can be configured either on a substrate or as an on-filter catalyst (MFCoF), providing simultaneous chemical conversion and urea-derived particulate filtration. In addition to hydrogen engines, the MFCoF concept can be applied to diesel and biodiesel engines, enabling effective filtration of soot particles while maintaining NOx reduction performance along with hydrocarbon oxidation capability. By combining NOx reduction, hydrogen/hydrocarbon oxidation, and particulate filtration in one unit, the MFCoF approach provides a promising pathway for next-generation exhaust systems across diverse engine platforms.
Danghyan, Vardan, Becker, Jan Martin, Hünnekes, Edgar, Patchett, Joseph
CuSCR Catalysts Under H 2 -ICE Exhaust Gas Conditions2026-01-03614/7/2026
In the near to mid-term, hydrogen internal combustion engines (H2-ICE) can be a bridge technology for reducing carbon emissions. A few challenges anticipated under lean-burn H2-ICE operation are the significant drop in turbo-out temperatures, combined with higher water content, and the possible presence of unburned hydrogen in the exhaust, which could have a potential impact on performance and durability of the downstream exhaust aftertreatment system, particularly oxidation and SCR catalysts, as these conditions can suppress low-temperature oxidation activity, perturb Cu-site speciation and redox cycling in SCR catalysts, and exacerbate hydrothermal aging under sustained wet operation. This study examines the impact of excess water and residual hydrogen on Cu-SCR durability, active site chemistry, and stability for the case with and without an upstream oxidation catalyst, through aging tests at 450 °C and 550 °C. Changes in Cu redox cycles were assessed through site quantification using multiple titration techniques to determine the influence of excess H2O and H2 on catalyst performance and aging.
Kim, Mi-Young, Daya, Rohil, Kamasamudram, Krishna
Compact, Low-Cost Ultra-Low NOx Solution for 2027 US EPA, Euro VII, China VII and Off-Road2026-01-03634/7/2026
Achieving ultra-low NOx emissions remains a major challenge in diesel emission control industry worldwide, especially as increasingly stringent regulations are introduced globally. Selective Catalytic Reduction (SCR), the leading NOx reduction technology in diesel systems, performs best when “sufficient” heat and ammonia are made available to it. At the same time, any proposed solution must be both low-cost and functionally robust in an industry seeking near 100% NOx removal at the lowest feasible cost. This work presents a low-cost architecture, utilizing a small, highly compact, single heater-mixer unit along with a light-off (close-coupled) SCR for meeting most stringent NOx emission regulations worldwide. It also hinders deposit formation lowering warranty costs and mitigating failure modes. Engine studies using a fully-aged aftertreatment system demonstrate that the proposed solution enables compliance with newer heavy-duty regulations including 2027 US, Euro-VII, China-VII, and likely the upcoming Bharat-VII while also rendering a large ‘compliance margin’, providing significant margin for meeting in-use compliance.
Masoudi, Mansour, Poliakov, Nick
Simultaneous Reduction of NOx and Fuel Consumption for Off-Road Powertrains2026-01-02964/7/2026
Simultaneously reducing criteria pollutants and fuel consumption is important for clean air and improving vehicle total cost of ownership. The goal of this effort was focused on a 90% NOx reduction and 10% fuel savings for an off-road 407 kW diesel engine. The baseline was a production Fiat Powertrain 13L engine and aftertreatment system meeting 0.4 g/kW-hr NOx. The baseline system was quantified over the NRTC, RMC, new low load cycle and five field cycles. A next generation engine was built incorporating several fuel-efficient design features, including a higher compression ratio, increased fuel-rail pressure, low-friction piston rings, and a high-efficiency variable-geometry turbocharger. Cylinder deactivation and EGR pump technologies were added to this engine as well. The combination was optimized prior to adding advanced aftertreatment systems, showing the trade-off of engine out NOx and exhaust temperature. Two next-generation catalyst technologies were employed into a LO-SCR plus main SCR system, both with and without an electric heater upstream of the LO-SCR. These catalysts were hydrothermally aged to simulate significant field use. Dual SCR dosing with newly developed controls played a critical role in achieving the proper split between the upstream LO-SCR and the downstream main SCR. Adding a next generation mixer for the downstream SCR proved essential in obtaining the final results. The optimal configuration required adding an electric heater to elevate the exhaust temperature at the LO-SCR for early cycle NOx reduction. The final results showed a 94.8% NOx reduction and 15.7% fuel savings on the composite NRTC.
McCarthy, Jr.,, James, Wine, Jonathan, Bradley, Ryan, Hasseman, Andy, Prikhodko, Vitaly, Howell, Thomas
Combustion and Emission Characteristics of Biodiesel and Renewable Diesel in a 4-Stroke Locomotive Engine2026-01-03154/7/2026
Rail transportation in North America consumes over 4 billion gallons of diesel fuel [1]. This is raising energy security and supply chain resilience concerns. Adopting renewable or alternative fuels is a practical approach to reduce petroleum dependence and improve supply security. The objective of this paper is to investigate the combustion and emission characteristics of biodiesel and renewable diesel as drop-in fuels without engine modification. In this study, a single-cylinder, four-stroke locomotive engine was employed to investigate the combustion and emissions characteristics of four fuels: conventional diesel No. 2, plant-based biodiesel, animal-based biodiesel, and renewable diesel. The experimental campaign was carried out under both part-load and full-load operating conditions, with injection duration adjusted to achieve the targeted engine load and speed. Results indicate that both biodiesel fuels and renewable diesel deliver comparable peak in-cylinder pressure and brake thermal. efficiency relative to No. 2 diesel, demonstrating their possible use as drop-in fuels. Reductions in smoke emissions were observed for both biodiesels and renewable diesel fuels. However, plant-based and animal-based biodiesels both showed increases in NOx emissions under part-load conditions. At full load, elevated exhaust gas recirculation (EGR) ratios suppressed NOx formation across fuels, limiting assessment of biodiesel-specific NOx effects. Among the fuels tested, renewable diesel provided an additional advantage: reduced CO₂ emissions compared to both biodiesels. This study suggests that renewable diesel is a promising option for rail applications, combining operational performance comparable to petroleum diesel with reduced smoke and CO₂ emissions. Biodiesel, while effective at reducing smoke, may require further strategies to control NOx emissions.
Ewphun, Pop-Paul, Biruduganti, Munidhar, El-Hannouny, Essam, Longman, Douglas, Fu, Xiao, Subramanya, Raghavendra
The Effects of Ethanol on Combustion in a Super-Lean-Burn Engine2026-01-03034/7/2026
To mitigate global warming, many countries are working toward carbon neutrality. Reducing CO₂ emissions from vehicles requires electrification technologies in hybrid and plug-in hybrid electric vehicles (HEVs, PHEVs) and improving thermal efficiency of internal combustion engines (ICEs). Lean-burn combustion is one approach to improving ICE thermal efficiency. Biofuels and synthetic fuels can also reduce CO₂ emissions in existing vehicles. Ethanol, a bio-derived fuel, is widely used in varying contents worldwide, and its further utilization is anticipated. This study examines the effects of ethanol blending on emissions, thermal efficiency, knocking, and combustion speed in a super-lean-burn engine. Gasoline surrogates with varying ethanol contents were tested at an excess air ratio (λ) of 2.5. Higher ethanol content reduced nitrogen oxides (NOx) emissions due to lower adiabatic flame temperature. Total hydrocarbon (THC) emissions measured by a Flame Ionization Detector (FID) showed a decreasing trend; however, after correction for low sensitivity to ethanol and aldehydes, no significant differences were observed. Thermal efficiency increased with ethanol content, due to reduced cooling losses. Knocking was mitigated by the higher Research Octane Number (RON) from ethanol blending; however, the extent was smaller than in the production engine operating at λ = 1. This mechanism was examined through ignition delay calculations. At λ = 2.5 and in-cylinder pressures above 9 MPa, the 50–90% combustion duration was prolonged, attributable to suppressed ethyl radical formation under lean conditions and a greater influence of the reaction in which methyl radicals consume hydrogen atoms to produce methane under high-pressure conditions.
Sugata, Kenji, Matsubara, Naoyoshi, Yamada, Ryota, Kitano, Koji
The Impact of Various Renewable Hydrocarbons on Performance and Emissions in a Super Lean Burn Engine2026-01-03064/7/2026
Compared to regular fuels, biofuels can play a key role as low-carbon transitional energy sources for ICE vehicles as the fleet moves towards increasing electrification. Blending of ethanol plays a key role in enhancing the anti-knock properties of the fuel and also allows renewable hydrocarbons (such as bio-naphtha) to be incorporated into the blend whilst maintaining an acceptable overall fuel quality. Super lean burn ICE technology with λ between 2 and 3 can lead to enhanced fuel economy and reduced NOx emissions. The Toyota prototype engine used to generate data for this project injects most of the fuel in PFI mode to generate a homogeneous super-lean charge in the cylinder, but just before spark ignition the DI injector sprays a small amount of fuel towards the spark plug to create a richer charge near the spark plug to promote flame kernel development. Various fuel formulations with high biofuel content were tested in both conventional and super lean burn engines. Certain fuel compositions were formulated with faster burning components such as ethyl benzene. The super lean burn engine showed a clear link between faster combustion and minimization of unburned fuel losses, thereby resulting in a further efficiency benefit. The effect of fuel composition on particulate emissions was more complex: although the conventional engine emitted higher particulate numbers (PN) when operating on fuels with a higher content of heavier aromatics (as might be predicted from standard particulate index approaches), the super lean burn engine suggests that additional factors are at play which are discussed in the paper.
Aradi, Allen, Krueger-Venus, Jens, Jain, Sandeep Kumar, Cracknell, Roger, Kolbeck, Andreas, Shibuya, Masahiko, Yamada, Ryota, Matsubara, Naoyoshi, Kitano, Koji
Technical Outlook on the Potential of HVO and Biodiesel Blends for Cleaner Combustion2026-01-03164/7/2026
The increasing need to decarbonize the transport sector is accelerating the adoption of renewable and low-carbon fuels such as Hydrotreated Vegetable Oil (HVO) and biodiesel as sustainable substitutes for fossil diesel. These fuels are evaluated as drop-in solutions requiring no engine recalibration, enabling immediate GHG emission reduction in existing diesel fleets. This study experimentally investigates the combustion, performance, and emission characteristics of a turbocharged common-rail two-cylinder diesel engine (Kohler LWD 442 CRS) operated with conventional fossil Diesel, pure HVO (Hydrotreated Vegetable Oil), and an HVOB20 blend (80% HVO and 20% biodiesel produced from waste cooking oil and animal fats). Tests were carried out under steady-state conditions at the DIIEM Engine Laboratory of Roma Tre University. The analysis focused on in-cylinder pressure evolution, brake power, brake specific fuel consumption (BSFC), and both regulated and unregulated emissions. Regulated species include carbon monoxide (CO), nitrogen oxides (NOₓ) and particulate number concentration (PNC > 23 nm, PMP-compliant), while unregulated emissions cover non-methane hydrocarbons (NMHC), formaldehyde (HCHO), nitrous oxide (N₂O). CO and NMHC are key indicators of incomplete combustion: CO results from partial oxidation of carbon during fuel burning, and NMHC represents the fraction of unburned hydrocarbons excluding methane. Both pollutants decreased markedly with renewable fuels, indicating a more complete oxidation process promoted by HVO’s paraffinic composition and FAME’s oxygenated nature. Experimental results show that HVO and HVOB20 slightly increase brake torque and reduce BSFC compared with fossil diesel, despite their lower density and heating value. Combustion remained stable across all operating conditions, with negligible variations in ignition delay and pressure rise rate. NOₓ emissions were comparable or marginally higher at medium engine speeds, likely due to faster ignition and elevated combustion temperatures. Unregulated species such as HCHO and N₂O decreased or remained negligible with increasing renewable content, while PNC and count mean diameter (CMD) were significantly reduced, confirming cleaner combustion and reduced soot formation. Overall, both HVO and HVOB20 demonstrated improved combustion efficiency and emission performance while ensuring full engine operability without calibration adjustments. These findings confirm the technical viability of renewable diesel fuels as immediate, drop-in solutions for reducing GHG emissions.
Zaccai, Martina, Chiavola, Ornella, Palmieri, Fulvio, Verdoliva, Francesco
A Pathway to Exceed 50% Indicated Thermal Efficiency for Gasoline Engines with Active Pre-Chamber2026-01-03004/7/2026
Research on high efficiency and low emission control strategies are crucial for addressing energy security and pollution challenges for combustion engines of vehicles. This paper investigates the effects of increasing the compression ratio and excess air coefficient (λ) in naturally aspirated engines via active pre-chamber technology, and further enhancing λ through the synergy of active pre-chamber with intake boosting and Miller cycle technology, on combustion efficiency and pollutant emissions. Experiments were conducted on a high-compression-ratio (up to 16.6) single-cylinder gasoline engine. Under natural aspiration, the effective compression ratio was raised via valve timing, while λ was increased using integrated passive and active pre-chamber systems. Under boosted conditions, intake flow was controlled via a flow meter, and λ was controlled via an active pre-chamber to analyze the λ distribution and thermal efficiency at high-efficiency operating points. Results indicate that under natural aspiration, increasing the effective compression ratio to 15.8 and λ to 1.4 improved the indicated thermal efficiency (ITE) to 40.3%. Further deployment of an active pre-chamber enabling ultra-lean combustion (λ=2.0) achieved an ITE of 43.3% while reducing NOx emissions to 53×10-6. Under boosted intake pressure with Miller cycle, elevating intake pressure to 282kPa and achieving ultra-lean combustion (λ=2.0–2.2) resulted in ITE over 50%, with NOx emissions consistently below 50×10-6 (ppm - parts per million).
Deng, Jun, Li, Xiaoliang, Miao, Xinke, Xu, Bingxin, Zhang, JianQi, Li, Liguang
Experimental Study on the Effect of Ignition Strategy on Combustion and Emissions in a Direct Injection Hydrogen Engine2026-01-03304/7/2026
Hydrogen-fueled internal combustion engines (H₂ICEs) are a promising pathway toward carbon-neutral transportation, but their efficiency and emissions performance are highly sensitive to ignition control strategies. This study systematically investigates the combined effects of spark timing (−10 to −26 °CA BTDC) and spark energy (25–40 mJ) on combustion characteristics in a direct injection H₂ICE operating at a constant speed of 1400 r/min under low, medium, and high load conditions. Results show that spark timing advance produces load-dependent effects: at low load, it increases the peak heat release rate while delaying peak pressure and shortening combustion duration; at medium and high loads, it advances both peaks toward TDC with an optimal spark timing shifting closer to −14 °CA. Ignition delay was only slightly reduced at low load but significantly shortened by about 3 °CA at high load. NOx emissions increased nearly linearly with spark advance, while slight retardation effectively halved NOx at low load without compromising torque. Increasing spark energy reduced ignition delay by up to 23% and shortened combustion duration by 2–4 °CA at low load, resulting in a torque increase from 48 to 60 N·m; however, the benefits diminished with increasing load. Additionally, higher spark energy led to a moderate NOₓ rise, particularly under medium load. These findings offer valuable insights into the optimization of ignition strategies for H₂ICEs, providing a foundation for improving combustion efficiency while minimizing emissions in zero-carbon hydrogen-powered engine systems.
Zhao, Keqin, Lou, Diming, Zhang, Yunhua, Fang, Liang, Tan, Piqiang, Hu, Zhiyuan
Emission and Combustion Characteristics of a Hydrogen Direct-Injection Spark Ignition Engine Using EGR2026-01-03254/7/2026
This study experimentally investigates the combined effects of exhaust gas recirculation (EGR) and injection timing on the combustion and emission characteristics of a hydrogen direct injection engine. A single-cylinder 395 cc research engine was used, with injection timing varied from 60° to 180° BTDC and EGR rates from 0% to 30%. In-cylinder pressure, apparent heat release rate (AHRR), NOx, and unburned hydrogen concentrations were measured to analyze the influence of mixture formation and dilution on engine performance. Under non-EGR conditions, retarding the injection timing promoted mixture stratification, resulting in faster flame propagation and shorter combustion duration. However, localized high-temperature regions increased NOx formation, while incomplete combustion in lean or rich zones elevated unburned hydrogen emissions. When EGR was introduced, both ignition delay and combustion duration increased due to reduced oxygen concentration and thermal dilution. Nevertheless, the net indicated mean effective pressure (nIMEP) and indicated thermal efficiency (ITE) decreased by less than 1.6% and 1%, respectively, demonstrating that hydrogen’s fast combustion characteristics compensated for the reactivity loss. As the EGR rate increased, the formation of NOx and the emission of unburned hydrogen showed noticeable changes. At 30% EGR, NOx emissions decreased by up to 76% compared to the non-EGR baseline while maintaining stable combustion. However, excessive EGR resulted in increased unburned hydrogen emissions. These findings confirm that, with a properly optimized EGR rate, EGR is a more effective strategy than injection timing control for NOx reduction, achieving significant reduction with minimal efficiency penalty, and providing design insights for practical hydrogen-fueled engines.
Yang, Heetae, Ki, Youngmin, Kim, Jungho Justin, Kim, Jinsu, Bae, Choongsik, Hwang, Joonsik
Effects of Gasoline Composition and Operating Parameters on the Response of End-Gas Autoignition to Nitric Oxide in a Lean-Burn DI-SI Engine2026-01-03134/7/2026
Lean operation of spark-ignition engines can lead to engine thermal efficiency gains and lower NOx emissions due to reduced combustion temperatures. Yet, lean operation could still face challenges in end-gas autoignition and knock generation due to higher intake pressures and trapped NO in the residual gas. This study evaluates the impact of NO on end-gas autoignition for two gasoline fuels with similar octane rating but different composition: high cycloalkane fuel (HCA) and high olefin fuel (HO). Experiments were performed at stoichiometric and lean (λ = 2) conditions and at two engine speeds of 1400 rpm and 2000 rpm. Accompanying chemical kinetics simulations in CHEMKIN revealed that the mechanisms controlling the effect of NO on autoignition are similar λ = 2 and λ = 1, with NO + HO2 = NO2 + OH being the main pathway for enhancing reactivity by promoting low-temperature heat release (LTHR). The compositionally different fuels reacted differently to NO seeding and engine speed, and differences were augmented at λ = 2 compared to λ = 1 as the end-gas autoignition shifted to the low temperature regime. HO, which has inherent low temperature chemistry, was strongly impacted by engine speed at low NO seeding levels, with no noticeable peak of LTHR detected at 2000 rpm. On the other hand, LTHR of HCA was marginally affected by shortened residence time at higher engine speed as NO + HO2 reaction was not greatly affected by shorter time scales, since HO2 production was sustained even at 2000 rpm to support OH generation from NO + HO2. Contrary to HO, HCA exhibited greater sensitivity to NO seeding, as the increased OH production at higher NO concentrations offset the OH-quenching effect of cyclopentane, which accounts for 28.6% of HCA’s composition. Consequently, a sensitivity analysis revealed that fuels with weak inherent low-temperature chemistry, like HCA, are likely to be more sensitive to variations in NO concentration and charge temperature, whereas fuels with strong low temperature chemistry are more sensitive to variations in end-gas λ and intake pressure.
Kim, Namho, Abboud, Rami, Sjöberg, Magnus, Lopez Pintor, Dario, Saggese, Chiara, Matsubara, Naoyoshi, Kitano, Koji, Yamada, Ryota, Sugata, Kenji
Development of an ‘Online’ Combustion System Calibration Method using a Non-Dominated Sorting Genetic Algorithm2026-01-02854/7/2026
Calibration is a major resource bottleneck and source of risk in powertrain technology development. A promising alternative to the typical design-of-experiments (DoE) approach is the use of a ‘Non-Dominated Sorting Genetic Algorithm’ (NSGA) calibration method, where an iterative process is used to directly identify the Pareto Fronts between performance metrics, for example, net mean effective pressure (NMEP) and NOx emission. The goal of the present work was to develop and demonstrate a fully ‘online’ combustion system calibration method based on an NSGA, where the algorithm operates directly on experimental data rather than empirical models as is typical in the literature. This was completed by first designing an optimal NSGA for combustion system calibration and then demonstrating its use for an experimental combustion system calibration on a single cylinder gasoline engine at one operating condition. Results from the design process here indicate that ‘online’ NSGAs have a strong potential to outperform traditional DoEs in the development of Pareto-optimal engine calibrations; however, NSGA performance is highly sensitive to the specific parameters used in the algorithm logic. The highest sensitivity was to the mutation logic within the genetic reproduction process, and second was the number of genes (calibrations) included in the overall process. Inclusion of both the Primary and Secondary non-dominated Pareto fronts in the set of Pareto-optimal calibrations was found to be critical to the success of the NSGA. When demonstrated for an experimental combustion system calibration the NSGA operated effectively and as expected, continually providing ‘upward’ pressure to generate calibrations that maximize NMEP but also ensure the breadth of the Pareto front (NOx) is scanned with high fidelity. In comparison to a traditional DoE approach, the NSGA was nearly twice as accurate in identifying calibrations along the Pareto front for the same number of total experiments. The Pareto-optimal calibrations developed by the NSGA are reasonable for these operating conditions and in excellent agreement with the literature. The present work strongly motivates and supports further development of NSGA methods for use in more complex systems and situations including for electrified and hybrid powertrains.
Mansfield, Andrew
Adaptive Economic Model Predictive Control for Engine Emissions Management with Compensation for Performance Drift2026-01-02874/7/2026
This paper addresses the changes in engine emissions due to in-use component changes through the synergistic application of predictive control, machine learning, and onboard adaptation. In particular, we consider an adaptive economic Model Predictive Control (eMPC) strategy to mitigate the effects of performance drift on Nitrogen Oxides (NOx) and Soot emissions from compression ignition (diesel) engines. A performance drift block, which applies a multiplier and offset to nominal emissions, is integrated with a high-fidelity Neural Network (NN) plant model to simulate these characteristic changes. To counteract variability, two online adaptation methods are integrated within the eMPC framework: One is based on Recursive Least Squares (RLS) and another on a continuously updated online NN. The proposed control architecture is validated through simulations over standard transient cycles. Results demonstrate that while the rate-based eMPC possesses inherent robustness to performance drift, in particular, for the formulation of eMPC that involves NOx penalty in the cost function, online adaptation further facilitates satisfying emission constraints. In particular, both adaptive methods improve Soot limit enforcement compared to a non-adaptive controller, with the online NN providing superior performance by capturing the nonlinear dynamics of in-use changes.
Zhang, Jiadi, Li, Xiao, Kolmanovsky, Ilya, Tsutsumi, Munecika, Nakada, Hayato
Achieving Euro 7 WHSC NOx Emission Targets from a Spark Ignited Engine Using Methanol-Hydrogen Co-Fuelling2026-01-03214/7/2026
E-methanol is increasingly seen as a promising clean fuel because its chemical makeup is close to fossil fuels, making it easier to use in existing engines. It offers a carbon-neutral option to help reduce greenhouse gases in sectors where cutting emissions is especially difficult, such as transportation. However, while e-methanol avoids adding new carbon dioxide, burning it in internal combustion engines still releases harmful gases like oxides of nitrogen (NOx) and other toxic by-products like formaldehyde and formic acid that damage both health and the environment. This report explores a new strategy that combines methanol with hydrogen to run engines under “ultra-lean” conditions and its impact on emissions, performance and efficiency. Experiments were carried out on a single-cylinder spark ignition engine, with directly injected methanol and port fuelled injection of hydrogen. The findings show that adding about 10% hydrogen (energy basis) at low engine loads can extend the lean limit from air-fuel equivalence ratio (λ) of 1.7 to 2. This change cut NOx emissions by 99% and reduced formaldehyde emissions by 18% compared to pure methanol operation at stoichiometric. Furthermore, the NOx emissions were reduced sufficiently that engine could operate within Euro 7 World Harmonic Stationary Cycle (WHSC) limits.
Ambalakatte, Ajith, Geng, Sikai, Cairns, Alasdair, Varaei, Amirata, Harrington, Anthony, Hall, Jonathan, Bassett, Mike, Cracknell, Roger
The Influence of Split Injection Ratio on Efficiency and NO x Emissions in a Pilot Diesel-Ignited Hydrogen Direct Injection Engine2026-01-03294/7/2026
This study investigates the impact of the hydrogen split injection ratio on the combustion of pilot diesel-ignited hydrogen direct-injection engines, which is expected to affect hydrogen-air mixture conditions and thus flame propagation and diffusion flame developments. Experiments were conducted on a 1-litre single-cylinder diesel engine equipped with an additional hydrogen injector operating at 35 MPa. Hydrogen accounting for 95% of total input energy was injected at 150 and 60 °CA bTDC for the first and second pulses, which were selected as high-efficiency injection timings from previous equal-split injection tests. The 5% diesel energy was injected near TDC to control CA50 at 10 °CA aTDC. While varying the split ratio between the two hydrogen injections, in-cylinder pressure/aHRR profiles, engine efficiency/power output and engine-out emissions of NOx and CO2 were evaluated. Results showed that the hydrogen split ratio does not significantly affect IMEP/efficiency, which consistently achieved a 17.2% increase over the diesel baseline. While CO2 emissions remained at a very low level due to high substitution of hydrogen energy, they showed no dependency on the split ratio. By contrast, NOx emissions were highly sensitive to the hydrogen injection split ratio. Increasing the first hydrogen injection fraction to 30% reduced NOx, attributed to decreased locally rich mixtures formed by late second hydrogen injection and increased lean mixture homogeneity from early first hydrogen injection, leading to a slower burning effect. However, further increasing the first injection fraction led to higher NOₓ emissions due to increased hydrogen compression, which raised TDC and combustion pressure.
Zhao, Yifan, Chan, Qing Nian, Kook, Sanghoon
Combustion Enhancement via Discharge Current Modulation under Turbulence Conditions2026-01-03364/7/2026
Utilizing low carbon fuel in lean burn combustion presents a compelling strategy for improving thermal efficiency and reducing NOx emissions. Methane, the main content of natural gas, still receives challenge of a rapid and complete combustion process because of its low flame speed. The long combustion duration deteriorates the performance of a spark ignition engine, in terms of poor combustion instability and misfire. Although ignition timing can be utilized to adjust the combustion phasing, the ignition process faces challenges due to reduced background pressure and temperature at advanced spark timings. In this paper, a rapid compression machine equipped with a specially designed flow chamber is utilized to enhance the turbulence flow, and a custom-built ignition module is utilized to provide boosted discharge current to enhance the ignition stability under flow conditions. An effective spark energy required to enhance the combustion process is investigated under both stoichiometric and lean conditions. Further increase of discharge current amplitude beyond this boundary yields minimal impact on the flame propagation process. This study will offer important insights for developing an on-demand ignition energy profiling strategy to reduce sparkplug electrode erosion.
Jin, Long, Cong, Binghao, Yu, Xiao, Kong, Xiangxin, Reader, Graham, Zheng, Ming
Reactivity Controlled Compression Ignition (RCCI) Combustion Engine Characteristics Fuelled with Diesel/Compressed Natural Gas (CNG) and Diesel/Methanol Fuel Pairs2026-01-03194/7/2026
Ultra-low oxides of nitrogen (NOx) and particulate matter (PM) from reactivity-controlled compression ignition (RCCI) combustion have motivated researchers to explore more about low temperature combustion (LTC) engines. In this study, a comparative analysis of combustion, performance, and emission characteristics of RCCI combustion fuelled with diesel/compressed natural gas (CNG) and methanol/diesel fuel pairs has been carried out with respect to baseline compression ignition (CI) combustion. All experiments were performed in a constant speed engine at four different engine loads. For RCCI combustion experiments, a constant premixed ratio (rp= 0.50) and 15% exhaust gas recirculation (EGR) were used. The results exhibited a significant reduction in NOx emissions and relatively smoother RCCI combustion compared to baseline CI combustion. RCCI mode combustion resulted in relatively superior engine performance compared to baseline CI combustion, especially at higher engine loads. A comparison between the RCCI combustion fuelled with gaseous fuel (CNG) as a low reactivity fuel (LRF) and a liquid fuel (methanol) showed a slightly lower brake thermal efficiency (BTE) of CNG/diesel fuelled RCCI combustion compared to methanol/diesel fuelled RCCI combustion at low loads. As the load increased, the trend of BTE was reversed. The combustion characteristics of CNG/diesel fuelled RCCI combustion were found to be more stable compared to methanol/diesel fuelled RCCI combustion. The NOx emissions were lowest in methanol/diesel fuelled RCCI irrespective of engine load. At low load, methanol/diesel fuelled RCCI suffered from higher hydrocarbon (HC) and carbon monoxide (CO) emissions, while CNG/diesel fuelled RCCI maintained relatively lower HC and CO emissions.
Saikia, Bhargav, Kant, Akshay, Gupta, Abhishek, Singh, Akhilendra Pratap
Challenges to Ranking Diesel Fuels for NO x Emissions Using a Constant-Volume Combustion Chamber2026-01-03484/7/2026
The market is witnessing an unprecedented proliferation of low-emission fuel components. To effectively evaluate the suitability of these novel fuels for engine applications, fuel blenders and original equipment manufacturers require rapid and reliable assessment methodologies. Traditionally, such evaluations rely on comprehensive engine testing, which, while thorough, is both time-intensive and costly. In response to the growing diversity of emerging fuel options, this work aims to establish a streamlined screening approach capable of effectively replicating the outcomes of full-scale engine testing. We examined the use of a constant volume combustion chamber for the measurement of fuel effects on NOx emissions, with the goal of developing a method to rapidly screen or rank fuels in a small - volume experiment. A small amount of fuel was injected into air at 650°C and 20 bar, where it ignited and burned. The chamber was sampled post-combustion using a chemiluminescence NOx analyzer. Extensive sampling method development was required to obtain repeatable results. Seven hydrocarbon fuels and two biodiesel fuels were tested, all of which have shown difference in NOx emissions in past engine studies. When using a single injection event to deliver the same amount of fuel energy, the test method could not clearly demonstrate the difference in NOx emissions between the hydrocarbon fuels as reported in engine combustion studies. Heat release rate analysis suggested this was caused by large differences in ignition delay and premixed burn fraction for the fuels tested. To improve this, a dual-injection strategy was used. It included a small “pilot” injection followed by a main injection, timed based on each fuel’s ignition delay to coincide with the pilot heat release. This strategy helped reduce differences in heat release caused by how quickly each fuel ignites. For hydrocarbon fuels, this approach revealed the expected relationship between NOx emissions and fuel type. Two soy biodiesel samples did not show higher NOx as observed in engine studies. This suggests that the current test method may not fully reflect engine conditions where biodiesel tends to produce more NOx. Further improvements in test method and setup are recommended to better align constant volume chamber conditions with engine conditions under which biodiesel shows increased NOx emissions.
Luecke, Jon, Rahimi, Mohammad, Mohamed, Samah, Naser, Nimal, Chausalkar, Abhijeet, McCormick, Robert
Experimental Evaluation of After-Treatment Solutions for Heavy-Duty Natural Gas Vehicles to Meet Future CNVII Regulations2026-01-03764/7/2026
The heavy-duty truck market in China has seen a significant increase in the adoption of natural gas-powered engines over the past two years. Simultaneously, the anticipated release of the China VII emissions regulation proposal by the end of 2025 is expected to impose stricter emissions limits on all heavy-duty engines, including new particulate number (PN10) thresholds analogous to those in the Euro 7 regulation. While tailpipe oxides of nitrogen (NOx) and methane (CH4) emissions from natural gas engines can be mitigated through tighter lambda control and adjustments to catalyst volume and precious metal (PGM) loading, addressing NOx and particulate number (PN) emissions necessitate more advanced after-treatment solutions. Although natural gas combustion is virtually soot-free, the entrainment of lubricating oil into the combustion chamber, especially during cold-start conditions, poses a challenge, leading to potential exceedance of the proposed future China VII limits. Additionally, PN emissions from natural gas vehicles are highly dependent on duty-cycles and the state of the actual engine, with applications involving frequent stop/go operation experiencing increased piston ring wear, and thus, higher oil consumption, and elevated PN emissions. This study aimed to evaluate the performance of different after-treatment solutions for natural gas engines in meeting future China VII emissions standards, with a particular focus on the efficacy of particle filters for controlling PN10 emissions. Three different after-treatment configurations, comprising close-coupled and underfloor three-way catalysts, as well as bare and coated filters, were tested on a 15L China VI commercial natural gas engine in a controlled laboratory environment. Emissions and PN10 data were collected over regulatory cold and hot World Harmonized Transient Cycle (WHTC) test cycles, and analyzed for light-off behavior, conversion efficiencies, system pressure drop, and filtration effectiveness for particles as small as 10nm. The relative advantages and challenges of each configuration are discussed. The results indicate that natural gas engines will likely require the integration of particle filter devices to comply with future China VII PN10 limits. The results also show that NOx compliance is challenging and fine-tuning of the lambda calibration is essential for CNVII.
Gao, Jiahui, Besch, Marc, Ding, Ning, He, Suhao, Zhao, Yuxin, Yixiao, Li, Shen, Ye
Characterisation of Particle Number and Size from a DI SI Engine Operating on Hydrogen versus Gasoline: Operating Sensitivities and Filtration Effects2026-01-03784/7/2026
Hydrogen Internal Combustion Engines (H₂ICEs) offer the potential for near-zero carbon emissions. However, while nitrogen oxide (NOₓ) emissions have been extensively studied, particulate emissions, specifically particle number (PN), which are widely attributed to in the literature to lubricant oil pyrolysis and exacerbated by hydrogen’s short quenching distance, remain less well understood. This study investigates exhaust-gas particle emission characteristics from a spark-ignition, single-cylinder research engine based on MAHLE Powertrain’s downsizing engine combustion system. The work was carried out at Brunel University of London and compares gasoline and hydrogen direct-injection strategies (central versus side injection) across a wide range of operating conditions, including variations in engine speed, load, air–fuel ratio (λ), rail pressure, and spark timing. While previous studies have investigated hydrogen particle formation mechanisms under isolated operating conditions, the combined influence of combustion strategy, mechanical engine condition, and exhaust filtration has not been systematically explored within a single experimental framework. This study characterises PN emissions and particle size distributions (PSDs) from a direct-injection spark-ignition research engine operating on hydrogen and gasoline under steady-state conditions. The effects of injection strategy (central versus side), air–fuel ratio (λ), rail pressure, and spark timing are examined, alongside a controlled comparison between a freshly overhauled engine and a mechanically worn configuration to assess sensitivity to oil-control condition. Particle measurements were performed using a fast-response differential mobility spectrometer equipped with a catalytic stripper to isolate solid particles, with results interpreted using SPN₁₀-equivalent metrics for comparative analysis. In addition, a series-production gasoline particulate filter (GPF) was evaluated under hydrogen operation to assess its ability to attenuate the ultrafine particles characteristic of H₂ICE exhaust. The results show that hydrogen combustion produces substantially lower engine-out PN than gasoline under comparable operating points, with particle size distributions strongly biased toward sub-23 nm diameters. PN emissions under hydrogen operation exhibit sensitivity to injection targeting, mixture strength, rail pressure, and engine mechanical condition, consistent with literature linking lubricant oil ingress and near-wall combustion behaviour to hydrogen PN formation. The GPF demonstrated measurable PN reduction under hydrogen operation in the single-cylinder, steady-state configuration examined Overall, this work provides an internally consistent dataset linking hydrogen combustion behaviour, engine mechanical condition, and injection strategy to PN emissions and filtration response under steady-state conditions. The findings are intended to inform calibration development, hardware design, and future certification-grade studies, rather than to demonstrate regulatory compliance.
Harrington, Anthony, Zaman, Zayne, Nickolaus, Chris, Zhao, Hua, Wang, Xinyan, Hall, Jonathan
Impact of Hydrothermal Aging and Chemical Poisoning on NOx Reduction Performance of SCR – A Simulation Study2026-01-03724/7/2026
Diesel aftertreatment systems continue to play a critical role in compliance of tailpipe criteria pollutant compliance for commercial transportation applications. Quantification of performance of the aftertreatment system in particular Selective Catalytic Reduction component as a function of aging is critical in ensuring real world tailpipe NOx standard for aged systems. As part of A2CAT-II consortium at Southwest research Institute this aspect of the production AT system was studied for different aging conditions using a set of DAAAC aged components. The performance of these aged components was quantified through a set of steady state reactor tests and transient ECTO burner lab tests that simulate on engine performance. The data was collected at 0, 33 and 100% equivalent aging conditions and this data was used to develop a GT suite-based model with a set of inhibition factors to simulate the loss of Ammonia Storage Capacity and reduced SCR reaction rates caused by thermal load and chemical poisons. A quantitative and qualitative discussion of the degradation mechanism is presented based on the inhibition factors determined as part of the simulation study. Primary mechanism of performance degradation for fully aged component consisted of a 12% drop in ammonia storage capacity and a 10% and 12% drop in standard and fast SCR reaction rates leading to reduced NOx conversion rate. Due to catalyst degradation up to 11% reduced NH3 oxidation rate was observed which led to increased NOx conversion for temperatures above 350C. These trends can have a significant impact of systems designed for ultra low NOx standards by EPA and CARB which require precise control over NOx conversion of the system.
Chundru, Venkata Rajesh, Sharp, Christopher, Gankov, Stanislav, Eakle, Scott
Effect of Key Operating Parameters on Homogenous Reactivity-Controlled Compression Ignition Concept with Renewable Fuels03-19-02-00094/1/2026
As part of the dTEC MORE project, sustainable powertrain technologies are being explored, including an alternative combustion concept tailored for engines in serial hybrid powertrains. Among the low-temperature combustion strategies, Reactivity-Controlled Compression Ignition (RCCI) is a prominent approach, offering significant reductions in NOx and soot emissions while enhancing combustion efficiency. The dual-fuel nature of RCCI enables improved control over combustion by utilizing fuels of differing reactivities. In this study, a premixed RCCI strategy was implemented using ethanol as a port-injected low-reactivity fuel and octanol as a directly injected high-reactivity fuel. The experimental work was conducted on a single-cylinder research engine with design features that are found in a gasoline passenger car application. Key combustion parameters such as the start of injection (SOI) of the high-reactivity fuel, injection pressure, intake temperature, lambda, premixed fuel ratio, and valve overlap were varied and evaluated on the engine test bench. The impact of these parameters on performance, combustion stability, and emissions was systematically analyzed. The results were benchmarked against a baseline direct-injected gasoline combustion cycle with a higher compression ratio. The comparison highlights the advantages of the premixed RCCI strategy, particularly in reducing NOx and soot emissions. Additionally, the test results also support in the future steps to model and validate the simulation models, to achieve higher efficiency and lower emissions.
Sundaram, Pravin Kumar, Grundl, Larissa Michaela, Trapp, Christian Thorsten, Tinschmann, Georg
CFD Simulation of Combustion and Emission Characteristics of Pure Spirulina Microalgae Biodiesel in a Single-Cylinder DI Diesel Engine2026-28-00432/12/2026
In this study, the combustion and emission characteristics of a single-cylinder direct injection (DI) diesel engine fueled with Spirulina biodiesel along with diesel blends were examined using a combined CFD and thermodynamic simulation framework. Three test fuels, including pure diesel (D100), Spirulina biodiesel blends (B20 and B40), and pure Spirulina biodiesel (B100), were analysed at 1500 rpm under full load. In the first stage, CFD simulations were performed in ANSYS Fluent, where the Discrete Phase Model (DPM) was applied to capture spray atomization and droplet evaporation, while a non-premixed combustion model coupled with the RNG k-ε turbulence model was employed to resolve in-cylinder flow and heat release dynamics. Subsequently, the Diesel-RK software was utilised to predict engine performance and exhaust emissions based on compression ratios (18.5) and injection timings. Results from the CFD analysis revealed faster atomization and reduced ignition delay for biodiesel blends compared with pure diesel, supported by enhanced cylinder pressure development. Diesel-RK simulations indicated that Spirulina biodiesel blends (B20) generally improved brake thermal efficiency at higher compression ratios while increasing brake specific fuel consumption due to their lower calorific value. Emission analysis showed consistent reductions in CO, HC, and smoke capacity with higher biodiesel content, while NOx emissions exhibited a rising trend. The findings confirm Spirulina biodiesel (B20) as a viable renewable fuel and highlight simulation-driven strategies for optimising compression ratio and injection timing in CI engines..
Kumar, B Varun
Items per page:
1 – 50 of 5077