Browse Topic: Nitrogen oxides
Amidst escalating climate change, the sustainability of internal combustion engine (ICE) vehicles, particularly in heavy transport, remains a critical challenge. Despite emission reductions from 1990 to 2020, ICEs, particularly diesel engines in Europe, continue to pose environmental challenges, notably in nitrogen oxide (NOx) emissions. This study proposes a novel solution to address the problem of NOx emissions by incorporating Air Cycle Technology’s (ACT) turboexpander into diesel engines. Acting as a second-stage compressor, intercooler, and expander, the turboexpander aims to lower intake air temperature, thereby mitigating NOx formation. The study utilizes a 4.4-l JCB-TCA-74 turbocharged diesel engine retrofitted with the ACT turboexpander as the experimental platform. The methodology involves using empirical formulae to calculate the key parameters of engine airflow for a standard turbocharged diesel engine followed by repeating the calculations for the same engine fitted with a
Lean NOx trap is a dedicated DeNOx catalyst for lean hybrid gasoline engines. Noble metals (usually platinum group metals) play the role of catalytic sites for NOx oxidation and reduction, which have significant impact of the performance of LNT. This work focuses on the influence of noble metal catalysts on self-inhibition effect from the view of competitive adsorption between NO and CO, and investigates the influence of CO self-inhibition effect on the main by-product of LNT: N2O formation. Adsorption configurations for NO, CO and N2O on noble metal clusters supported by γ-Al2O3(100) are confirmed. For detailed investigation, electron structures are analyzed by investigating Bader charge, DOS (density of state), charge density differences and COHP (crystal orbital Hamilton population) of selected configurations.The results show that CO self-inhibition effect is caused by competitive adsorption between CO and NO. The essence of competitive adsorption between CO and NO is that
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