Browse Topic: Emissions control
Drop-in synthetic gasoline fuels are an attractive alternative to traditional fossil fuels for transportation due to their high energy density, compatibility with the existing fleet and potential to decrease carbon intensity. Despite of meeting gasoline standards, the composition of these fuels can vary depending on the feedstock used for production and the production process, which has been shown to affect engine performance and emissions. This study investigated the effects of synthetic fuel composition on combustion in a direct-injection spark-ignition engine. Spark timing sweeps from the stability limit to the knock limit were performed with three different bio-fuels, methanol-to-gasoline, ethanol-to-gasoline and hydrotreated-biomass gasoline, at different exhaust gas recirculation (EGR) rates, and results were compared against a research-grade E10 (10%vol ethanol) regular gasoline representative of petroleum gasoline available in the US. Octane index analyses showed that knock
Fe/zeolite selective catalytic reduction (SCR) catalysts are commercially used for NOx emissions reduction from diesel engines. In comparison to Cu/zeolite, these catalysts are widely reported to form less N2O as a byproduct of the SCR reactions. However, Fe/zeolite SCR is less active than Cu/zeolite for low temperature NOx conversion under standard SCR conditions. In this study, a state-of-the-art Fe/zeolite SCR catalyst is probed with a combination of N2 physisorption, SEM/EDX, reactor-based performance and active site quantification. Measurements investigate the impact of degreening, mild and extreme hydrothermal aging. In a degreened condition, the impact of water vapor on standard and fast SCR and isothermal desorption of NH3 is assessed. The Fe/zeolite catalyst’s hydrothermal durability is studied following hydrothermal aging at temperatures from 550°C up to 950°C. NH3 adsorption and temperature programmed desorption (TPD) and NO2 adsorption and TPD experiments are used to
With the growth of energy demand, fuel cells as efficient and clean energy devices, have attracted increasing attention. However, the high cost of membrane electrode assembly (MEA) restricts their large-scale application. Therefore, reducing the platinum usage and improving performance have become key research point. In this work, MEA was prepared and excellent performance of 1.52 W·cm-2 was achieved at a low platinum loading. The influence of different ionomer/carbon (I/C) ratio on the performance of fuel cells was systematically investigated. It was found that the performance of the MEA was the highest when the I/C ratio is 0.6. Quantifying hydrophilic and hydrophobic characteristics of catalyst layers with varying ionomer contents revealed that the proton conduction efficiency is optimal when the I/C ratio is 0.6. This balance established efficient proton conduction pathways, from the results of proton conduction impedance testing. SEM analysis demonstrated that pore structure
Green hydrogen, produced through water electrolysis, is a next-generation eco-friendly energy source as it does not generate pollutants like carbon dioxide during production. Catalysts play a crucial role in the water electrolysis process, splitting water into hydrogen and oxygen. The efficiency of green hydrogen production largely depends on the performance of these catalysts. Therefore, the commercialization of green hydrogen hinges on the development of cost-effective catalysts capable of maintaining high performance over extended periods.
Environmental pollution is one of the growing concerns of our society. As vehicle emissions are a major contributor to air pollution, emission control is a primary goal of the Automotive industry. Vehicle emissions are higher due to improper combustion, which leads to toxic gases being generated from the exhaust system. Unburnt fuel is one of the leading causes of toxic pollutants such as Carbon Monoxide, Nitric Oxides (NOx) and Hydrocarbons. The catalytic converter converts these gases into less toxic substances such as Carbon Dioxide, Nitrogen, and water vapor. The catalytic converter performs efficiently after reaching its “Light Off” temperature, after which the catalyst becomes active. Hence, elevated temperature of the exhaust gases aids in efficient conversion. Presently, the gases from the exhaust system are approximately at a temperature of 300°C-600°C. This paper outlines the concept of a Peltier (Thermoelectric) Module - based system, which helps maintain the high
This paper is to introduce a new catalyst family in gasoline aftertreatment. The very well-known three-way catalysts effectively reduce the main emission components resulting from the combustion process in the engine, namely THC, CO, and NOx. The reduction of these harmful emissions is the main goal of emission legislation such as Bharat VI to increase air quality significantly, especially in urban areas. Indeed, it has been shown that under certain operating conditions, three-way catalysts may produce toxic NH3 and the greenhouse gas N2O, which are both very unwanted emissions. In a self-committed approach, OEMs could want to minimize these noxious pollutants, especially if this can be done with no architecture change, namely without additional underfloor catalyst. In most Bharat VI gasoline aftertreatment system architectures, significant amounts of NH3 occur in two phases of vehicle driving: situations with the catalyst temperature below light-off, which appear after cold start or
Emissions regulations, such as Euro VI, drives the Automotive industry to innovate continuously in Engine development. One significant challenge is the engine oil pumping from the crankcase into the combustion chamber, where it participates in combustion, which contributes to increased Particulate Numbers and fails to meet Euro VI emission compliance. This issue is most noticeable during engine idling and motoring conditions. During this time, a higher negative pressure difference develops between the intake manifold, which is acting above the combustion chamber and the engine crankcase. This pressure difference drives oil-laden blow-by aerosols past piston rings during the intake stroke and through the valve stem seals, allowing oil into the combustion chamber. The impact of the pressure difference between the intake manifold and crankcase was studied by varying the crankcase pressure through crankcase ventilation system. The results confirm that oil entry into the combustion chamber
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