Browse Topic: Emissions control

Items (7,046)
Heavy-duty vehicles emissions are a serious problem, and remote monitoring platforms are a key means of emission control for heavy-duty vehicles. However, the frequent occurrence of anomalies in the remote monitoring data has seriously limited the monitoring efficiency of the remote monitoring platform. Therefore, this paper takes 500 National VI heavy-duty vehicles as the research object, and proposes a whole-process data quality control system of “anomaly identification-dynamic correction-accuracy verification”. First, four types of anomaly patterns, namely, lost, invalid, outlier and mutation, are defined, and polynomial fitting, median filtering and contextual interpolation are adopted to realize differentiated correction. Second, a data accuracy validation framework based on correlation analysis was constructed. The results show that the accuracy of key parameters is significantly improved after correction, and the data fitting degree R2 is greater than 0.97. The research results
Liu, YuZhang, ChengZhang, HaoYu, HanzhengnanLi, JingyuanAn, XiaopanMa, KunqiLiang, YongkaiXu, Hang
On-Board Diagnostic (OBD) strategies utilize a predictive model to estimate engine out NOx levels for a given set of operating conditions to ensure the accuracy of the Nitrogen Oxides (NOx) sensor. Furthermore, this model is also used to determine urea dosing quantities in situations where the NOx sensor is unavailable such as cold starts or as a reaction to a NOx sensor plausibility failure. Physics-based NOx prediction models guarantee high levels of accuracy in real-time but are computationally expensive and require measurements generally not available on commercial powertrains making them difficult to implement on controllers. Consequently, manufacturers tend to adopt a mathematical approach by estimating NOx under standard operating conditions and use a variety of correction factors to account for any changes that can influence NOx production. Such correction factors tend to be outcomes of base engine calibration settings or outputs of models of other related sub systems and may
Sunder, AbinavSuresh, RahulPolisetty, Srinivas
The growing emphasis on environmental protection and sustainability has resulted in increasingly stringent emission regulations for automotive manufacturers, as demonstrated by the upcoming EURO 7 and 2027 EPA standards. Significant advancements in cleaner combustion and effective aftertreatment strategies have been made in recent decades to increase the engine efficiency while abiding by the emission limits. Among the exhaust aftertreatment strategies, three-way catalyst has remained the primary solution for stoichiometric burn engines due to its high conversion efficiency and ability to simultaneously allow both oxidative and reductive reactions in a single stage with spatial separation due to the oxygen storage capabilities of ceria. However, fuel and lubricant-borne sulfur and phosphorus compounds have been shown to have a significant long-term effect on the activity of three-way catalysts, particularly during the lean-rich transitions and oxygen storage processes. In the present
Sandhu, Navjot SinghYu, XiaoJiang, ChuankaiTing, DavidZheng, Ming
The mainstream automotive market is rapidly transitioning to electrified and fully electric powertrains. Where gasoline engines are still employed, they are frequently turbocharged units with relatively low maximum engine speed and modest power density. The hypercar class, in contrast, has recently seen somewhat of a renaissance in high performance, high speed, naturally aspirated gasoline engines, which are prized for their emotional contribution to the vehicle. In order to guarantee high conversion efficiency of a Three Way Catalyst in the exhaust system, an engine must be operated at stoichiometric air-fuel ratio. At high power density, this may result in very high exhaust gas temperature, which poses a risk to engine and vehicle hardware. A number of technological interventions to extend the maximum stoichiometric performance whilst respecting component limitations have already been described in the literature, but many of these are not applicable to specific engine architectures
Corrigan, Dáire JamesVilla, DavidePenazzi, EugenioMeghani, AmitKnop, VincentCaroli, GiacomoFrigeri, DavideRuggiero, FedericoMalaguti, SimonePostrioti, LucioMaka, Cristian
The internal combustion engine (ICE) is projected to remain the dominant technology in the transport sector over the short to medium term, and there exists significant potential for further improvements in fuel economy and emission reductions. One promising approach to enhancing the efficiency of spark ignition engines is the implementation of passive pre-chamber spark plugs. The primary advantages of pre-chamber-initiated combustion include the mitigation of knocking, an increase in in-cylinder turbulence, and a combustion process that is both faster and more stable compared to that achieved with conventional J-gap spark plugs. Additionally, the higher ignition energy provided by pre-chamber spark plugs enables operation under higher intake pressures, maintains similar exhaust gas recirculation rates, and supports leaner combustion conditions. These benefits are predominantly attributed to volumetric ignition via hot, reactive jets. However, the pre-chamber spark plug also presents
Korkmaz, MetinJuressen, Sven EricRößmann, DominikKapus, Paul E.Pino, Sandro
The widespread adoption of battery electric vehicles (BEVs) is progressing more slowly than anticipated, making hybridization crucial for improving efficiency through load point shifting, running the engine at its most efficient operating points and kinetic energy recovery. As the world continues to use fossil fuels, enhancing powertrain efficiency is critical to reducing CO2 emissions. Improved efficiency will also increase the share of renewable e-fuels in the energy mix, supporting the transition to low-carbon mobility. A significant portion of energy in ICEs is lost through exhaust heat, which is a high-grate energy source that can be converted into electricity in hybrid systems. Conventional turbochargers, widely used to enhance volumetric efficiency and drivability, typically incorporate a wastegate (WG) to regulate boost pressure. However, this results in the intentional dumping of excess valuable exhaust energy leading to energy loss. This paper investigates the replacement of
Kodaboina, Raghu VamsiVorraro, GiovanniTurner, James W. G.
The increasing importance of hydrogen as alternative energy source to reduce CO2 emissions in the transport sector makes its adoption in spark-ignited engines an attractive and cost-efficient alternative to fuel cell-powered vehicles. Lean combustion is the preferred operating strategy for H2-engines in order to achieve performance targets, enhance efficiency and at the same time avoid critical knocking and pre-ignition phenomena. Additionally, an effective approach to lower cylinder temperatures, relevant engine-out NOx emissions and boost pressure requirements at the same time, is an external exhaust gas recirculation (EGR) system. The aim of this work is to analyze and compare the effects of exhaust gas recirculation on the combustion of a lean hydrogen mixture in a turbocharged 4-cylinder H2-ICE with direct injection. For this investigation a load point at 18 bar BMEP and 4000 rpm is selected with and without the utilization of additional external EGR. In this case, a BTE of 38
Schmelcher, RobinKulzer, Andre CasalGal, ThomasVacca, AntoninoChiodi, MarcoGrabner, PeterGschiel, Kevin
The market penetration of Battery Electric Vehicles (BEV) in Europe is not following the foreseen scenario. This is related to several factors, such as uncertainty of the second-hand value of BEV, real driving range under cold conditions and availability of charging stations. Even if the European Community is still planning a full ban of Internal Combustion Engines (ICE) by 2035, in the rest of the world a more technology neutral approach is being pursued. Car manufacturers are developing different powertrain architectures, from mild- to full-hybrid and Range Extenders (REEX). In this context of different emission regulations, and wide range of powertrain architectures, the focus of the development will be the increase of catalyst efficiency without any big impact on exhaust aftertreatment cost. In previous work [1] the authors have used a 1D simulation approach to support the optimization of metallic TWC substrate for the High Power Cold Start use case. Additionally, a 3D CFD was used
Montenegro, GianlucaDella Torre, AugustoMarinoni, AndreaOnorati, AngeloKlövmark, HenrikLaurell, MatsPace, LorenzoKonieczny, Katrin
Premixed Charge Compression Ignition (PCCI) presents a promising alternative to conventional diesel combustion (CDC), offering significant reductions in pollutant emissions by lowering local in-cylinder temperatures and enhancing fuel-air mixing. However, a significant challenge in implementing PCCI is controlling the start of combustion, especially given its narrow operating load range. This is primarily due to early ignition and knocking combustion at higher loads when using high-reactivity diesel fuel, which limits the practical applicability of PCCI mode in diesel engines. In the present study, experimental investigations are carried out on a light-duty diesel engine operating in PCCI mode using two fuel blends: 10% (D90G10) and 20% (D80G20) gasoline mixed with diesel on a volume basis. To facilitate combustion control and emission reduction, exhaust gas recirculation (EGR) and water vapor are used as charge diluents. A common rail direct injection (CRDi) system replaces the
Ranjan, Ashish PratapKrishnasamy, Anand
The dual-fuel combustion process, which is offered as a retrofit solution for conventional diesel engines by various manufacturers, represents an option for reducing emissions from internal combustion engines and is already available today. Current dual-fuel engines run on liquefied natural gas (LNG), which is usually of fossil origin. Due to the existing infrastructure and the possibility of producing LNG by means of electrolysis and methanation, LNG can already be produced in a 100% climate-neutral way and thus make a contribution to climate neutrality in the shipping industry. The adoption of exhaust gas recirculation (EGR) systems in the maritime sector became more significant in 2020 following the enforcement of the sulphur emission cap. By lowering the sulphur content in the fuel, technologies in the exhaust tract are also conceivable without the use of expensive scrubber systems. Dual-fuel LNG/diesel engines are typically operated in lean-burn mode to reduce the risk of knocking
Seipel, PascalGlauner, ManuelDinwoodie, JulesBuchholz, Bert
Decarbonizing the transport sector requires solutions that reduce CO₂ emissions while improving the efficiency of existing engine platforms. This study explores a retrofit strategy in which a heavy-duty diesel engine is converted to Otto-cycle operation and equipped with a passive pre-chamber combustion (PPCC) system. Methanol was used as the fuel due to its high octane number, low carbon intensity, and favourable combustion properties. The performance of the PPCC system is experimentally compared to conventional spark ignition (SI) across varying engine speeds, loads, and exhaust gas recirculation (EGR) levels. A dual-dilution strategy, combining lean operation (λ = 1.6) with EGR, was applied to extend dilution tolerance and assess the feasibility of operating near stoichiometry. All tests were conducted under steady-state conditions with fixed spark timing. Results show that PPCC consistently delivers faster combustion than SI across all conditions, with greater stability and reduced
Fong Cisneros, Eric J.Hlaing, PonnyaCenker, EmreAlRamadan, AbdullahTurner, James WG
The paper reports an investigation into employing a “lambda leap” (λ leap) strategy for hydrogen internal combustion engines (H₂ICEs), wherein inherently low emissions of oxides of nitrogen (NOx) are afforded at light load via operation at lambda 2.5, and at higher load by operation at stoichiometry utilizing a three-way catalyst (TWC) for NOx control. This approach means it is necessary under transient operation to “leap” between high values of lambda and stoichiometry from one cycle to the next, in order to avoid completely the λ ≈ 1.3 area where high combustion NOx is generated away from lambda equal to 1; this is because lean catalysis of NOx will be extremely challenging at the rate that it is generated there. To achieve this, a short cam profile was introduced to reduce air mass flow by 57.5%, enabling this leap without changing the fuel injection amount, while preserving favorable combustion characteristics via an early Miller cycle. The study models a 2.0 L inline four-cylinder
Fong Cisneros, Eric J.Kodaboina, Raghu VamsiVorraro, GiovanniTurner, James W. G.
Reactivity-controlled compression ignition (RCCI), a low-temperature combustion strategy, reduces oxides of nitrogen (NOx) and soot simultaneously; however, high concentrations of carbon monoxide (CO) and total hydrocarbons (THC) and low exhaust gas temperatures pose a significant challenge for the catalytic control of tailpipe CO and THC. Diesel oxidation catalyst (DOC) is generally used in compression ignition (CI) engines for CO, THC, and nitric oxide (NO) oxidation. This work provides a new understanding of the performance characteristics of a DOC in the RCCI combustion strategy with various gasoline–diesel fuel premix ratios ranging from ~46% to ~70% at steady-state operating conditions. Experimental insights from the RCCI strategy prompt considerations of both CO and THC oxidations and THC trap functionalities in the 1D transient model of the DOC. It is observed that an increase in the fuel premix ratio from 50% to 70% in RCCI shifts the CO and THC oxidation characteristics
Suman, AbhishekSarangi, Asish KumarHerreros, Jose Martin
Oxymethylene ethers (OMEs) have been proposed for use in diesel engines as a high-reactivity fuel with reduced soot emission. Historically, the focus on methyl-terminated OMEs has limited drop-in applicability. In this work, a set of extended-alkyl OMEs with methyl, propyl, and butyl terminations are tested in an unmodified 4.5L Deere diesel engine, neat and in various blends with ultra-low-sulfur diesel (ULSD). Engine operability and emissions data are collected for the various fuel blends. External laboratory testing against the ASTM D975 standard demonstrates that a blend of 30% butyl-terminated OMEs with ULSD meets all ASTM standard requirements except lubricity. It is shown that the OMEs and OME–diesel blends demonstrate shorter combustion durations, as defined by the 10%–90% heat release timing, than the ULSD control. Engine brake efficiency is unaffected by OME usage, while specific fuel consumption increases in proportion to the reduced heating values of OMEs. Particulate
Lucas, Stephen P.Zdanowicz, AndrewWolff, Wyatt W.Windom, Bret
Urea–water solution (UWS) is sprayed during selective catalytic reduction (SCR) in the aftertreatment system of a diesel engine. UWS decomposes to ammonia and reacts with harmful nitrogen oxides present in exhaust gas to convert it to harmless nitrogen and water vapor. The interaction of UWS spray droplets with the hot wall of the aftertreatment system plays a crucial role in the performance and life of the aftertreatment system used in modern diesel engines for emission control. We report here a comprehensive experimental investigation on the normal impact of UWS droplets on the heated wall of stainless steel (SS410), mimicking the droplet–wall interaction in an SCR aftertreatment system. We have built a regime map underlying the possible outcomes under operating conditions encountered in an SCR system. The transition zones are identified, and the complex transition dynamics from one regime to another are discussed. Finally, we investigate and discuss the universality of the non
Singh, Kartikeya K.Deka, HiranyaPandey, VinodKhot, AmbarishBasak, NarendranathShastry D. M., Channaveera
Internal combustion engines generate higher exhaust emissions of hazardous gases during the initial minutes after engine start. Experimental data from a state-of-the-art turbo-charged 3-cylinder, 999 cc gasoline engine are used to predict cold start emissions using two Machine Learning (ML) models: a Multilayer Perceptron (MLP) which is a fully connected neural network and an Encoder-Decoder Recurrent Neural Network (ED-RNN). Engine parameters and various temperatures are used as input for the models and NOx (Nitrogen Oxides), CO (Carbon monoxide) and unburned hydrocarbon (UHC) emissions are predicted. The dataset includes time series recordings from the Worldwide harmonized Light-duty vehicles Test Cycle (WLTC) and four Real Diving Emissions (RDE) cycles at ambient and initial engine temperatures ranging from -20 °C to +23 °C. In total, 21 cases are considered, consisting of eight different ambient temperatures and five distinct driving cycles. Each case consists of a sequence of 2500
Mangipudi, ManojDenev, Jordan A.Bockhorn, HenningTrimis, DimosthenisKoch, ThomasDebus, CharlotteGötz, MarkusZirwes, ThorstenHagen, Fabian P.Tofighian, HesamWagner, UweBraun, SamuelLanzer, TheodorKnapp, Sebastian M.
It is becoming increasingly clear that research into alternative fuels, including drop-in fuels, is essential for the continued survival of the internal combustion engine. In this study, the authors have evaluated olefinic and oxygenated fuels as drop-in fuels using a single-cylinder engine and considering fuel characteristic parameters. The authors have assessed thermal efficiency by adding EGR or excess air from zero to the maximum value that allows stable combustion. Next, we attempted to predict fuel efficiency for four types of passenger cars (Japanese small K-car N/A, K-car T/C, Series HV, and Power-split HV) by changing the fuels. We created a model to estimate fuel efficiency during WLTC driving. The results indicated that fuel economy could potentially be improved by adding an olefin fuel that burns stably even with a large amount of EGR or air and an oxygen fuel whose octane number increases. It was observed that the fuel economy improvement rate was particularly notable for
Moriyoshi, YasuoXu, FuguoWang, ZhiyuanTanaka, KotaroKuboyama, Tatsuya
The document provides clarity related to multiple temperature coolant circuits used with on-highway and off-highway, gasoline, and light-duty to heavy-duty diesel engine cooling systems, or hybrid vehicle systems. These multiple temperature systems include engine jacket coolant plus at least one lower temperature system. Out of scope are the low temperature systems used in electric vehicles. This subject is covered in SAE J3073. Note that some content in SAE J3073 is likely to be of interest for hybrid vehicles. Out of scope are the terms and definitions of thermal flow control valves used in either low-temperature or high-temperature coolant circuits. This subject is covered in SAE J3142.
Cooling Systems Standards Committee
Ammonia (NH3) is an emerging carbon-free fuel with the potential to decarbonize the energy sector. However, its widespread adoption is hindered by challenges like low flame speed, high ignition energy, elevated emissions of nitrogen oxides (NOx), and unburned NH3. These limitations necessitate innovative combustion strategies for efficient and stable engine operation. This study investigates the potential of turbulent jet ignition (TJI) to overcome these challenges through the implementation of a pre-chamber, a small auxiliary chamber equipped with a spark plug to create hot, reactive jets that propagate into the main chamber, promoting rapid combustion from distributed ignition sites. In this work, TJI operation is compared to conventional spark ignition (SI) in a diesel engine platform retrofitted for 100% ammonia operation. Experiments were conducted at 1200 and 1800 RPM across varying loads (25%, 50%, 75%, and 100%) with equivalence ratio and spark timing sweeps. Combustion
Dhotre, AkashVoris, AlexOkey, NathanKane, SeamusNorthrop, William
Internal combustion engines (ICEs) remain widely used in automotive transportation for their high energy storage system efficiency and economic benefits. The 4-stroke engine has dominated all other forms to date, because the Otto cycle is relatively simple to understand. However, the significant benefits such as less pumping work and friction, lighter construction of 2-stroke engine, are attractive for applications that prioritize the simplicity and power density as well as meet the emission regulations. The disadvantages of the 2-stroke engine are mainly caused by the lack of sufficient scavenging process. Also, the overlap of the intake and exhaust phases results in charge short-circuiting, more fuel consumption and high unburned hydrocarbon emissions. For these reasons, it is difficult for 2-stroke engines to achieve stoichiometric combustion, making them incompatible with three-way catalyst to control emissions. The residual exhaust gas in the cylinder makes the spark ignition
Liu, JinruYamazaki, YoshiakiOtaki, YusukeKato, HayatoYokota, TakumiIijima, Akira
The development of lean-burn gasoline engines has continued due to their significant improvements in thermal efficiency. However, challenges associated with NOx emissions have hindered their mainstream adoption. As a result, the development of an effective NOx after-treatment system has become a key focus in lean-burn engine research. Additionally, HC emissions pose another challenge, as they tend to increase under lean combustion conditions while their conversion efficiency simultaneously declines. This study presents a novel after-treatment system incorporating a lean NOx trap(LNT) and a passive SCR(pSCR) system. This configuration enables efficient NOx reduction at a competitive cost while maintaining operational simplicity. Moreover, conventional catalyst technologies, including three-way catalysts (TWCs) and fuel-cut NOx traps (FCNTs), were optimized to maximize conversion performance under lean operating conditions. To further enhance system performance, various control
Oh, HeechangLee, JonghyeokSim, KiseonLim, SeungSooPark, JongilPark, MinkyuKang, HyunjinHan, DongheeLee, KwiyeonSong, Jinwoo
This research investigates the impact of combustion duration on combustion characteristics, emissions, and residual gas in a propane-fueled spark ignition engine under varying engine speeds. Using a two-cylinder V-twin engine and AVL-Boost simulation, experiments were conducted at speeds ranging from 3000 to 8000 rpm with combustion durations between 40° and 80° crank angle. The study integrates simulation and experimental methods to address challenges in measuring residual gas and effective release energy (ERE) under different conditions. Results show that longer combustion durations generally lead to increased residual gas and BSFC, while also influencing peak fire temperature, effective release energy, and emission characteristics. At 3000 rpm, optimal conditions were observed with a peak BMEP of 11.11 bar, torque of 25.01 Nm, power output of 14.87 kW, and a minimum BSFC of 311.43 g/kWh. Longer combustion durations elevated the residual gas, reaching up to 0.946 at 8000 rpm, and
Quach, Nhu YLim, Ocktaeck
Oxidation catalysts can greatly improve the regeneration efficiency of diesel particulate filters (DPF) by providing sufficient levels of NO2 for low-temperature soot oxidation. As for other automotive catalysts, catalyzed DPFs are subject to aging effects, resulting in decreased performance of the NO oxidation reaction. The life span of DPFs generally only considers the elevated back pressure as a consequence of the accumulation of ash. However, with reduced catalytic activity and impaired functionality of the regeneration process there is a risk of premature replacement of the catalyzed DPF or accumulation of soot above critical levels. In this study, a new exhaust aftertreatment system has been developed to accommodate laboratory-scale catalysts and DPFs for testing with full-size heavy-duty engines. The modified exhaust aftertreatment set-up was used together with a rig for accelerated soot and ash loading to assess the impact of catalyst aging on regeneration performance under
af Ugglas, SamuelFinker, PascalErsson, AndersYao, DaweiPettersson, Lars J.Kusar, Henrik
India aims to achieve 20% ethanol blending (E20) in petrol by 2025 under its National Biofuels Policy to reduce carbon emissions, enhance energy security, and support the agricultural economy. Building on this, E27 (27% ethanol in gasoline) is being evaluated as an advanced mid-level blend to further lower greenhouse gas emissions and reduce reliance on fossil fuels. This study investigates the performance, emissions, and combustion characteristics of a turbocharged gasoline direct injection (TGDI) engine using E27 fuel over 20,000 km in real-world driving conditions, as part of a broader research program accumulating over 100,000 km across multiple vehicle categories. Key findings indicate that E27 achieves an optimal balance of emissions reduction and performance, with NOx and THC emissions decreasing by 12% and 5%, respectively, compared to E10, while CO and CO₂ levels remained stable, reflecting ethanol’s oxygenation effect and lower carbon intensity. Power output and acceleration
D R, VigneshwarBhakthavachalu, VijayabaskarMuralidharan, M.
Aqueous zinc-ion batteries (ZIBs) have attracted extensive attention due to their high safety, abundant reserves, and environmental friendliness. Iodine with high abundance in seawater (55 μg L-1) is highly promising for fabricating zinc-iodine batteries due to its high theoretical capacity (211 mAh g-1) and appropriate redox potential (0.54V). However, the low electrical conductivity of iodine hinders the redox conversion for an efficient energy storage process with zinc. Additionally, the formed soluble polyiodides are prone to migrate to the Zn anode, leading to capacity degradation and Zn corrosion.
The results published in this paper emphasize on the study of three-way catalytic convertor for a 1.2 L turbocharged multi-point fuel injection gasoline engine. This paper takes us through the findings on methodology used for finalizing the brick configuration for catalytic convertor along with downstream oxygen sensor placement for emission control and methods applied for catalytic convertor selection with actual testing. The advantages of dual brick configuration over single brick with downstream sensor placed in between the bricks to enable faster dew point of sensor is explained using water splash test and design confirmation of better exhaust gas flow vortices concentration at the sensor tip for better sensing. Selection of catalytic convertor loading by testing its emission conversion capability and light-off behavior. NOx conversion capability across stoichiometric ratio (14.7:1 for petrol) on selected most operational zone was tested (±5% lambda) for the design-finalized
Arun Selvan, S. A.Paul, Arun AugustineSelvaraj, Manimaran
As the suitable substitutes for diesel in compression-ignition (CI) piston engines, hydrotreated vegetable oil (HVO), polyoxymethylene dimethyl ethers (PODEs), and bio-aviation fuel (BAF), among other oxygenated alternative fuels have been widely recognized due to higher cetane values. To explore the in-cylinder fuel spray dynamics and subsequent fuel–air entrainment of these fuels, experimental studies on near-field and full-field spray characteristics were carried out by the diffuser back-illumination imaging (DBI) method within a constant-volume chamber. The local velocity was inferred by momentum flux conservation and Gaussian radial profile assumption, and the dimensionless Jet number was introduced to qualify the strength of interaction within two-phase flow. It was found that the initial spray transitions from a “needle” to a larger spray head structure as injection pressure rises, especially with PODE3-5 exhibiting a stable “mushroom” structure due to its higher surface tension
Chen, HouchangJiang, JunxinHu, YongYu, WenbinZhao, Feiyang
Exhaust gas recirculation (EGR) is widely used in spark ignition engines to reduce throttling losses, decrease exhaust gas temperatures, increase efficiency, and suppress knock. However, the effectiveness of EGR as a knock suppressor is dependent on the fuel type and operating condition. In this study, the effectiveness of EGR to suppress knock was tested with E10, E30, E50, E75, and E100 at a moderately boosted condition. It was found that EGR was effective at suppressing knock with E10, but high EGR rates were required to achieve a knock suppression effect with E30 and E50. No knock suppression effect was observed with E75 and E100 across all tested EGR rates. With E30 and E50, EGR that was passed through a three-way catalyst was more effective at suppressing knock at all EGR rates. Chemkin modeling with neat ethanol revealed that nitric oxide enhanced ignition by increasing the hydroxyl radical concentration in the end gas, resulting in earlier auto-ignition. Directly seeding nitric
Gandolfo, JohnGainey, BrianLawler, Benjamin
The use of hydrogen in port fuel injection (PFI) engines faces challenges related to abnormal combustions that must be addressed, especially in transient operation. The in-cylinder air-to-fuel ratio and the amount of trapped exhaust gas have a significant impact on the probability of abnormal combustion as well as NOx emissions, and should be real-time monitored in hydrogen engines. Thus, the real-time estimation of the composition and thermodynamic state of the trapped gas mixture is crucial during transient operations, although highly challenging. This study proposes an on-line real-time physics-based MIMO (Multi-Input-Multi-Output) model to accurately estimate the amount of trapped air and exhaust gas in the cylinder at the intake valve closing (IVC) event, based on the instantaneous in-cylinder pressure measurement. With proper estimation accuracy, the injector can be controlled to correctly provide the amount of fuel necessary to achieve the target air-to-fuel ratio (AFR) and
Galli, ClaudioCiampolini, MarcoDrovandi, LorenzoRomani, LucaBalduzzi, FrancescoFerrara, GiovanniVichi, GiovanniMinamino, Ryota
Platinum (Pt), palladium (Pd), and rhodium (Rh) are used as active substances in exhaust gas purification catalysts for automobiles. Among these, Rh is an essential element because it efficiently promotes a NOx reduction reaction. On the other hand, the price of Rh has been rising in recent years. From the perspective of the supply risk of rare resources, there is an urgent need to develop technologies to replace or reduce the amount of Rh used in catalysts. We focused on the pseudo-rhodium alloy developed by the ACCEL program of the Japan Science and Technology Agency (JST), and then investigated the application of the pseudo-rhodium alloy on the catalysts of our motorcycles and also the degradation process. A nanosized PdRuIr alloy supported on a ceria-zirconia solid solution (PdRuIr/CZ) was prepared and assembled into a motorcycle for emissions measurement. The PdRuIr/CZ catalyst with an alloy loading of 4.0 g/L had initial properties comparable to the Rh supported on a CZ (Rh/CZ
Motegi, TakuyaTatara, ShunyaTakamoto, ShunpeiDoi, Kosuke
This study proposes a technique to predict the catalytic activity of the CO-NO-O2 reaction using the first principle calculations without experiment. The proposed method consists of four steps. (1) Assuming the detailed chemical reactions based on the Langmuir-Hinshelwood mechanism. (2) Estimating the activation energy (Ea) for each detailed chemical reaction using first principle (e.g. Density Functional Theory: DFT) calculations. (3) Defining frequency factors (A) theoretically. (4) Inputting the estimated Ea and A values into simulation software for chemical-kinetics (e.g. exothermia suite) and running the simulation. The validity of the proposed method was evaluated by experiments. This study predicted the catalytic activities of Pt, Pd or Rh(111) surfaces. The predicted results qualitatively matched the experimental outcomes obtained from the Pt, Pd or Rh thin-film catalyst prepared by the “arc plasma method”.
Miura, KazuyaKusaba, HirokiMiyoshi, TomoyaYoshida, HiroshiTsuchizaki, HiroyukiMachida, Masato
In order to rapidly achieve the goal of global net-zero carbon emissions, ammonia (NH3) has been deemed as a potential alternative fuel, and reforming partial ammonia to hydrogen using engine exhaust waste heat is a promising technology which can improve the combustion performance and reduce the emission of ammonia-fueled engines. However, so far, comprehensive research on the correlation between the reforming characteristic for accessible engineering applications of ammonia catalytic decomposition is not abundant. Moreover, relevant experimental studies are far from sufficient. In this paper, we conducted the experiments of catalytic decomposition of ammonia into hydrogen based on a fixed-bed reactor with Ru-Al2O3 catalysts to study the effects of reaction temperature, gas hour space velocity (GHSV) and reaction pressure on the decomposition characteristics. At the same time, energy flow analysis was carried out to explore the effects of various reaction conditions on system
Li, ZeLi, TieChen, RunLi, ShiyanZhou, XinyiWang, Ning
Vehicle emission standards have become more and more stringent and have driven the development of advanced engine design with low-cost emission control technologies. For small diesel engine which is used in three-wheel (3W) passenger and load carrying vehicles, it was major task to improve lower engine rpm torque and performance to comply with stringent exhaust emissions standard as well, especially for Oxides of Nitrogen (NOx) and Particulate Matter (PM) emissions. Bharat Stage (BS) VI emission standards for three-wheel vehicles was implemented from April 2020 onwards in India. Water injection technology has proven advantageous for low-cost solution with Mechanical fuel injection system on small diesel engines, Intake port water injection is the easiest method to introduce water to engine cylinder, which calls for minimal modification of existing engine structure. In the present study 435cc naturally aspirated DI Diesel engine used for three-wheel vehicle was explored by adding water
Syed, KaleemuddinChaudhari, SandipKhairnar, GirishKatariya, RahulJagtap, PranjalBhoite, Vikram
With growing global concern about climate change, the challenge is to achieve carbon neutrality (CN) in motorcycles (MCs) as well, and various approaches are needed to achieve CN. For powertrains using internal combustion engines (ICEs), CN can be achieved by adopting CN fuels such as e-fuel and biofuel, but considering cost and supply, it is important to develop CO2 reduction technologies for ICEs. Compared with 4-wheel vehicles, MCs are required to be powerful, lightweight, compact and capable of travelling long distances, the CO2 reduction technologies that can be adopted tend to be a trade-off between dynamic performance and CO2 reduction, and a challenge is to achieve a high level of both requirements. We decided to focus on middle-class sports MCs, which require particularly high dynamic performance, and to develop CO2 reduction technologies. As a technology development target, CO2 emissions were set at 65 g/km in the worldwide-harmonized motorcycle test cycle (WMTC) class 3-2
Makita, NaokiTorigoshi, MasakiTakahashi, ToshihikoTakase, Hiroki
In response to the evolving landscape of exhaust gas regulations for small powertrains, reducing NOx emission is increasingly important. This study deeply investigated the feasibility of a NOx storage catalyst (NSC) containing cerium oxide (CeO2) and barium oxide (BaO) for reducing NOx emission. The key functions, NOx storage and reduction performances were evaluated, and deterioration mechanisms were explored through performance evaluations and physical property analyses. The findings revealed a strong correlation between the size of CeO2 crystals and NOx storage performance at low temperature, such as those encountered during city driving conditions. Conversely, at high temperature, such as those during highway driving conditions, NOx storage performance correlated well with sulfur deposition, suggesting that the formation of barium sulfate (BaSO4) contributes to the deactivation. This experiment also showed a strong correlation between NOx reduction performance and BaSO4 formation
Nakano, FumiyaKoito, Yusuke
With the increasing clarity of the CNVII emission legislation, it is foreseeable that CNVII will further tighten the emission limits of major pollutants such as Nitrogen Oxide (NOx), Nitrous Oxide (N2O) and Particulate Number (PN). Together with the implementation of stage IV fuel consumption legislation in July 2025, which requires engine fuel consumption reduction or thermal efficiency improvement, it will lead to further deterioration of its pollutant emissions and reduction of exhaust temperature, posing greater challenges to the After-Treatment System (ATS) in terms of NOx removal, particularly during engine cold start and N2O formation suppression. This study is an extension of our earlier investigation [1], and a novel copper-based corrugated SCR (Full Body-CuSCR, FB-CuSCR) technology was successfully applied. The results based on a modified CNVI medium duty engine indicated excellent dynamic response of the FB-CuSCR technology over cordierite which helped to improve the
Wang, YanFu, GuangxiaChen, ShuyueAberg, AndreasJiang, ShuiyanZhang, Jun
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