Browse Topic: Emissions control
The ongoing efforts for reduction of the traffic-related greenhouse gas emissions and, at the same time, the mitigation of harmful pollutant emissions from vehicle exhaust emissions are important development tasks for the entire automotive industry worldwide according to demand to provide clean and efficient products. Further tightened fleet average FE standards and ultra-low limits for exhaust emissions require the continuous development of new propulsion system types. Due to the given reluctance of the end customer and corresponding low acceptance of fully electrified vehicles, especially in the commercial vehicle segment, new and innovative topologies are needed to meet regulatory requirements and maintain the high versatility of today’s dominating solutions. For further optimization of operating conditions with enhanced fuel efficiency, the technical strategy is also determined by uplifting the attractiveness of electric driving incl. the avoidance of areas with poor ICE efficiency and as well as the coverage of emission-critical operations by electric propulsion. In this context, the support provided by an electric drive on board the vehicle in a combined drive system is becoming increasingly important. This article discusses accordingly various platform strategies for hybridized Diesel powertrains in different sectors of commercial vehicle applications and delivers a comprehensive comparative analysis of different hybrid drive concepts. Specifically, several hybrid powertrain configurations that extend an electric drive platform (hybridized BEVs), such as series and parallel-series topologies, are compared with traditional parallel hybrid powertrain topologies based on internal combustion engines (ICE). The study focuses mainly on two different cornerstone applications: a large light commercial vehicle, ranging from 3,5 to 6,5 to. and a heavy-duty long-haul truck with 40…44 to. gross vehicle weight. It evaluates the advantages in terms of CO2 emissions and Diesel fuel savings and investigates the effects on emission controls aspects. In addition to technical comparisons, the paper addresses also regulatory demands and end customer merits, assessing the integrational effort and commonalities in components with pure ICE and battery electric topologies. Furthermore, it explores the additional impact of advanced operational strategies for Hybrid Diesel powertrains, incorporating insights from innovative observations from executed hybrid technology demonstrator vehicles.
QuesTek is advancing a suite of emerging alloy technologies to address modern rotorcraft engineering challenges. Current initiatives prioritize the optimization of "print-to-use" materials, such as 17-4PH and other specialized steels designed to minimize or eliminate post-processing requirements in additive manufacturing. These innovations represent a strategic shift toward materials that are not only high-performing but are also specifically tailored for next-generation manufacturing workflows. The catalyst for these advancements is QuesTek’s mastery of Integrated Computational Materials Engineering (ICME). These core capabilities are now deployed through QuesTek's ICMD® software platform, which empowers engineering teams with predictive simulation tools that eliminate the bottlenecks of traditional trial-and-error methodologies. By integrating these physics-based models into a centralized digital environment, QuesTek enables the rotorcraft industry to design, test, and implement advanced materials with unprecedented speed, reduced costs, and increased technical confidence.
With the growth of energy demand, fuel cells as efficient and clean energy devices, have attracted increasing attention. However, the high cost of membrane electrode assembly (MEA) restricts their large-scale application. Therefore, reducing the platinum usage and improving performance have become key research point. In this work, MEA was prepared and excellent performance of 1.52 W·cm-2 was achieved at a low platinum loading. The influence of different ionomer/carbon (I/C) ratio on the performance of fuel cells was systematically investigated. It was found that the performance of the MEA was the highest when the I/C ratio is 0.6. Quantifying hydrophilic and hydrophobic characteristics of catalyst layers with varying ionomer contents revealed that the proton conduction efficiency is optimal when the I/C ratio is 0.6. This balance established efficient proton conduction pathways, from the results of proton conduction impedance testing. SEM analysis demonstrated that pore structure integrity was compromised at non-optimal I/C ratios, exhibiting pore blockage or cracking. The CV test results confirmed that the electrochemical active surface area (ECSA) reaches a maximum of 40 m2gPt-1 when the I/C ratio is controlled at 0.6. And the EIS tests indicated that the lowest charge transfer impedance. Combined the physical and electrochemical characterization results with I-V curves, it was clear that the proper ratio of the low I/C region benefits the mass transfer and proton conductions. This study provides theoretical and technical support for performance enhancement and has the potential for the large-scale application of low-platinum MEA in fuel cells in the future.
Fe/zeolite selective catalytic reduction (SCR) catalysts are commercially used for NOx emissions reduction from diesel engines. In comparison to Cu/zeolite, these catalysts are widely reported to form less N2O as a byproduct of the SCR reactions. However, Fe/zeolite SCR is less active than Cu/zeolite for low temperature NOx conversion under standard SCR conditions. In this study, a state-of-the-art Fe/zeolite SCR catalyst is probed with a combination of N2 physisorption, SEM/EDX, reactor-based performance and active site quantification. Measurements investigate the impact of degreening, mild and extreme hydrothermal aging. In a degreened condition, the impact of water vapor on standard and fast SCR and isothermal desorption of NH3 is assessed. The Fe/zeolite catalyst’s hydrothermal durability is studied following hydrothermal aging at temperatures from 550°C up to 950°C. NH3 adsorption and temperature programmed desorption (TPD) and NO2 adsorption and TPD experiments are used to quantify the surface acidity and active Fe sites of the catalysts, respectively. Kinetic analysis of the standard SCR data is conducted to elucidate the mechanisms responsible for SCR activity loss upon hydrothermal aging. The authors believe the results presented herein can support the industry wide efforts to continue to improve diesel emissions control.
Drop-in synthetic gasoline fuels are an attractive alternative to traditional fossil fuels for transportation due to their high energy density, compatibility with the existing fleet and potential to decrease carbon intensity. Despite of meeting gasoline standards, the composition of these fuels can vary depending on the feedstock used for production and the production process, which has been shown to affect engine performance and emissions. This study investigated the effects of synthetic fuel composition on combustion in a direct-injection spark-ignition engine. Spark timing sweeps from the stability limit to the knock limit were performed with three different bio-fuels, methanol-to-gasoline, ethanol-to-gasoline and hydrotreated-biomass gasoline, at different exhaust gas recirculation (EGR) rates, and results were compared against a research-grade E10 (10%vol ethanol) regular gasoline representative of petroleum gasoline available in the US. Octane index analyses showed that knock resistance differences between fuels cannot be explained by their octane rating when EGR is added. Results demonstrated that adding EGR at medium loads is a very effective approach to increase efficiency despite of increasing burn duration because higher EGR rates led to lower pumping loses and lower heat transfer, while keeping combustion efficiency constant. The impact of EGR on combustion has shown to be very sensitive to fuel composition, and the knock resistance of fuels with strong low-temperature chemistry increased more with EGR addition that that of fuels with mild low-temperature chemistry. Similarly, the early flame propagation of fuels with strong low-temperature chemistry is more affected by EGR, limiting retardability and EGR tolerance. Results from this study indicated that, despite being considered drop-in, composition variability of synthetic fuels can be leveraged to improve engine performance.
Green hydrogen, produced through water electrolysis, is a next-generation eco-friendly energy source as it does not generate pollutants like carbon dioxide during production. Catalysts play a crucial role in the water electrolysis process, splitting water into hydrogen and oxygen. The efficiency of green hydrogen production largely depends on the performance of these catalysts. Therefore, the commercialization of green hydrogen hinges on the development of cost-effective catalysts capable of maintaining high performance over extended periods.
Emissions regulations, such as Euro VI, drives the Automotive industry to innovate continuously in Engine development. One significant challenge is the engine oil pumping from the crankcase into the combustion chamber, where it participates in combustion, which contributes to increased Particulate Numbers and fails to meet Euro VI emission compliance. This issue is most noticeable during engine idling and motoring conditions. During this time, a higher negative pressure difference develops between the intake manifold, which is acting above the combustion chamber and the engine crankcase. This pressure difference drives oil-laden blow-by aerosols past piston rings during the intake stroke and through the valve stem seals, allowing oil into the combustion chamber. The impact of the pressure difference between the intake manifold and crankcase was studied by varying the crankcase pressure through crankcase ventilation system. The results confirm that oil entry into the combustion chamber, contributing to combustion, occurs primarily through the piston rings, contributing to increase in Particulate Number (PN). To address this issue, it becomes necessary to introduce a mechanism that optimizes negative crankcase pressure across varying engine operating conditions. By reducing the pressure difference between the intake manifold and crankcase, this mechanism prevents oil entering the combustion chamber, thereby minimizing Particulate Number emissions and ensuring Euro VI compliance. This study focuses on the development and implementation of a negative crankcase pressure control system via the crankcase ventilation system. Through targeted optimization, it provides an effective way to control oil pumping into the combustion chamber, thereby enhancing emission control and advancing the development of cleaner Naturally Aspirated Gas engines.
Environmental pollution is one of the growing concerns of our society. As vehicle emissions are a major contributor to air pollution, emission control is a primary goal of the Automotive industry. Vehicle emissions are higher due to improper combustion, which leads to toxic gases being generated from the exhaust system. Unburnt fuel is one of the leading causes of toxic pollutants such as Carbon Monoxide, Nitric Oxides (NOx) and Hydrocarbons. The catalytic converter converts these gases into less toxic substances such as Carbon Dioxide, Nitrogen, and water vapor. The catalytic converter performs efficiently after reaching its “Light Off” temperature, after which the catalyst becomes active. Hence, elevated temperature of the exhaust gases aids in efficient conversion. Presently, the gases from the exhaust system are approximately at a temperature of 300°C-600°C. This paper outlines the concept of a Peltier (Thermoelectric) Module - based system, which helps maintain the high temperature of the exhaust gases prior to entering the catalytic converter. Peltier Modules are thermoelectric devices well-known for their usage in heating/cooling applications. The proposed system includes a chamber in which the Peltier Module is embedded. As the gases flow through the chamber, the embedded Peltier Module, which is powered by the battery, increases the temperature inside the chamber. Therefore, with this concept, the components required to heat the catalytic converter could be potentially reduced, since the exhaust gases will be maintained at the targeted temperature required for better emission control. Moreover, the Peltier Module is also known to be used for electricity generation. Consequently, by generating electricity through heat utilization on the surface of the chamber, we provide an added benefit of this proposed concept. This can be achieved by mounting the Peltier Module on the hot surface of the chamber. The other side of the Peltier Module is exposed to ambient air and thereby a potential difference is created through the Seebeck Effect.
This paper is to introduce a new catalyst family in gasoline aftertreatment. The very well-known three-way catalysts effectively reduce the main emission components resulting from the combustion process in the engine, namely THC, CO, and NOx. The reduction of these harmful emissions is the main goal of emission legislation such as Bharat VI to increase air quality significantly, especially in urban areas. Indeed, it has been shown that under certain operating conditions, three-way catalysts may produce toxic NH3 and the greenhouse gas N2O, which are both very unwanted emissions. In a self-committed approach, OEMs could want to minimize these noxious pollutants, especially if this can be done with no architecture change, namely without additional underfloor catalyst. In most Bharat VI gasoline aftertreatment system architectures, significant amounts of NH3 occur in two phases of vehicle driving: situations with the catalyst temperature below light-off, which appear after cold start or at low-speed urban driving and hot, high mass flow phases. In this paper, we will compare several approaches to reduce NH3 starting with an existing gasoline technology, diesel technologies modified to gasoline conditions and the especially developed novel gasoline Secondary Emission Treatment (SET) catalyst, providing both ammonia abatement and underfloor three-way functionality. SET is the combination addressing both the cold start phase and hot driving conditions. In addition, it fulfills the role of an underfloor three-way catalyst, responsible for CO and NOx hot phase treatment.
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