To solve the dual environmental issues of plastic pollution and reliance on fossil fuels, this study investigates the pyrolysis of waste polypropylene (PP) plastic into alternative diesel fuel. To improve fuel performance, the refined pyrolytic oil from PP was combined with regular diesel and 5% diethyl ether (DEE). The following three blend ratios were developed and assessed for important fuel characteristics: viscosity, density, flash point, cetane number, and calorific value: B10-DEE5-D85, B20-DEE5-D75, and B30-DEE5-D65. In order to enhance cold-start performance and ignition quality, DEE was used as an oxygenated additive. A four-stroke, single-cylinder diesel engine was used to test these mixes in order to evaluate their emissions and brake thermal efficiency. According to the results, the B10-DEE5-D85 mix had the most balanced performance, reducing CO and CO₂ emissions significantly when compared to pure diesel, especially while operating at full load. However, as the amount of