Browse Topic: Ethanol

Items (1,551)
Fuel adulteration affects operating costs, vehicle efficiency, and air pollution. Published estimates suggest it accounts for at least 10% of global sales. The Brazilian National Petroleum Agency (ANP) reported noncompliance in about 23% of inspections in 2023, including 4.3% confirmed adulteration. Quality verification requires laboratory equipment, and sensor-based approaches are often inaccessible to end consumers. This article proposes a sensorless (software-only) method that detects water adulteration in hydrated ethanol from standard Onboard Diagnostics (OBD) data using supervised machine learning, enabling on-vehicle fuel quality monitoring without additional hardware. The proposed approach is evaluated on real-world driving data from two production vehicles with three water adulteration levels in hydrated ethanol (0.0%, 2.5%, and 5.0%), achieving 84.85%–95.85% multiclass classification accuracy. These results indicate that software-only, OBD-based monitoring can provide a
Marchezan, Andre RicardoGiesbrecht, Mateus
The integration of ethanol into gasoline presents compatibility challenges for automotive fuel-system materials. In this study, the degradation of NBR-PVC fuel hoses exposed to ethanol-gasoline blends (E30, E50, E70, and E100) was investigated under dynamic flow conditions. A custom-designed test rig simulates real-time fuel circulation for 1,200 h. FESEM, ATR-FTIR, and elemental mapping analyses revealed ethanol-induced degradation, including dehydrochlorination, plasticizer leaching, and filler detachment. Among the blends, E30 exhibited the least material degradation, whereas E100 showed significant surface damage and chemical alteration. This study recommends multilayered fuel hose structures with ethanol-resistant inner linings for enhanced durability.
PC, MuruganL S, AdhityaG, Arun PrasadW, Beno WincyT, Karthi
In alignment with its carbon reduction commitments, India is transitioning towards higher ethanol-blended fuels, with E20 set for nationwide implementation by 2025. Ethanol is a renewable, domestically produced biofuel produced through fermentation of biomass such as sugarcane, corn. It possesses a higher octane rating and oxygen content compared to conventional gasoline, making it a favorable additive for improving engine performance and reducing emissions. This study investigates the impact of E20 fuel on performance parameters of a 694 cc MPFI , water-cooled, twin-cylinder gasoline engine. For deriving maximum benefits of increased Octane rating of E20, compression ratio was increased to 12.5:1. Experimental analysis was conducted to assess the changes in combustion behavior, brake specific fuel consumption (BSFC), torque output, engine out emissions and thermal efficiency when operating on E20 compared to baseline gasoline (E10). Base results indicate that E20 promotes more
Kulkarni, DeepakMalekar, Hemant AThonge, RavindraKanchan, Shubham
The adoption of flex-fuel vehicles (FFVs) in India presents a significant opportunity to reduce dependence on fossil fuels, lower greenhouse gas emissions, and ensure compliance with the country’s evolving emission norms. This paper explores the key aspects of flex-fuel technology in the context of Indian four-wheeler regulations, particularly Bharat Stage VI and potential future emission norms. The study begins with an overview of flex-fuel technology, detailing its advantages and associated challenges. A critical focus is placed on blend identification techniques, which play a vital role in optimizing combustion efficiency and ensuring seamless transitions between different ethanol-gasoline blends. Furthermore, the impact of ethanol blending on various fuel properties is examined, including changes in energy content, latent heat of vaporization, octane number rating, and stoichiometric air-fuel ratio. These factors significantly influence engine performance and emission
Balasubramanian, KarthickKR, PrabhakarKallahallii Somu, Santhosh Kumar
Increasing ethanol blending in gasoline is significant from both financial (reducing dependency on crude oil) and sustainability (overall CO2 reduction) points of view. Flex Fuel is an ethanol-gasoline blend containing ethanol ranging from 20% to 85%. Flex Fuel emerges as an exceptionally advantageous solution, adeptly addressing the shortcomings associated with both gasoline and ethanol. Performance optimization of Flex Fuel is a major challenge as fuel properties like knocking tendency, calorific value, vapour pressure, latent heat, and stoichiometric air-fuel ratio change with varying ethanol content. This paper elaborates on the experimental results of trials conducted for optimizing engine performance with Flex Fuel for a 2-cylinder engine used in a small commercial vehicle. To derive maximum benefit from the higher octane rating of E85, the compression ratio is increased, while ignition timing is optimized to avoid knocking with E20 fuel. For intermediate blends, ignition timing
Kulkarni, DeepakMalekar, Hemant AUpadhyay, RajdipKatkar, SantoshUndre, Shrikant
On the way to net zero emissions and to cut the oil import bills, NITI Aayog, Government of India and Ministry of Petroleum & Natural Gas (MoP&NG) has rolled out roadmap for ethanol blending in India during 2020-2025. Also, National Policy on Biofuels – 2018, provides an indicative target of 20% ethanol blending under the Ethanol Blended Petrol (EBP) Programme by 2030. Considering these Government’s initiatives current studies were performed on BSVI compliant gasoline direct injection vehicle on RDE compliant route (Route formulated by Indian Oil R&D Centre) with different ethanol blended gasoline fuel formulations i.e., E0 (Neat Gasoline), E10 (10% Ethanol in gasoline) & E20 (20% Ethanol in gasoline). The study aims to determine the compliance of Conformity Factor (C.F.) for ethanol blended gasoline fuel on Direct Injection gasoline engine. The conformity factors were calculated in each case for CO, NOx & PN using moving window average evaluation method. For reference CO2
Kant, ChanderArora, AjaySaroj, ShyamsherKumar, PrashantSithananthan, MChakradhar, Dr MayaKalita, Mrinmoy
The Government of India has mandated biofuel blending in automotive fuels to reduce crude oil imports and support the national economy. As part of this initiative, Oil Marketing Companies (OMCs) have begun nationwide blending of E20 fuel (20% ethanol in petrol). Ethanol supply is expected to exceed demand by the end of 2025 due to initiatives like the Pradhan Mantri JI-VAN Yojana. Alternative applications for ethanol are being explored; one promising approach is its use as a co-blend with diesel fuel (ED blends). However, ethanol’s low cetane number and poor lubricity pose challenges for direct use in diesel engines without modifications. ED blends demonstrated reduced emissions while maintaining performance comparable to conventional diesel. To further address concerns related to materials compatibility of ED blends with fuel system components, particularly plastomers that may impact engine durability, a detailed study was conducted using elastomers such as FVMQ, FKM, HNBR, and NBR in
Johnpeter, Justin PChakrahari, KiranChakradhar, MayaArora, AjayPrakash, ShantiPokhriyal, Naveen Kumar
This paper presents the methodology and outcomes of modifying a 1.2L naturally aspirated (NA) engine to enable flex-fuel compatibility, targeting optimal performance with ethanol blends ranging from E20 to E100. Ethanol is being increasingly promoted due to its potential to reduce greenhouse gas emissions and to provide an additional source of income for farmers. As per the road map for Ethanol blending released by Govt. of India, there has been continuous increase in blending of ethanol in gasoline. An initial target of 20% ethanol blending in gasoline by April 2025 has already been achieved. This work is in alignment with the broader push for development of flex-fuel vehicles, which necessitates engine adaptations capable of operating on varying ethanol blends. The primary objective was to upgrade the engine, which can give optimum performance with both lower range of ethanol blends starting from E20 as per IS 17021:2018 standard till higher blends of up to E100 as per IS 17821:2022
Tyagarajan, SethuramalingamPise, ChetanKavekar, PratapAgarwal, Nishant Kumar
One alternative to fossil fuels is the use of bioethanol in internal combustion engines. However, the application of this renewable fuel in compression-ignition engines is limited due to its low cetane number. This barrier, however, can be overcome by using additives that enhance this property. Consequently, additized ethanol emerges as a promising option with significant potential for decarbonization and improved combustion efficiency. In this context, the present study numerically investigated, using the CONVERGE CFD software, the use of additized ethanol in a compression-ignition internal combustion engine used in marine transportation. As a comparative baseline for each investigated setup, cases involving conventional diesel fuel were also analyzed numerically. The reaction mechanisms used for modeling the combustion of both additized ethanol and conventional diesel were validated against experimental data available in the literature. Di-tert-butyl peroxide (DTBP) was the studied
Assis, GuilhermeSánchez, Fernando ZegarraPradelle, Renata Nohra ChaarBraga, Sergio LealTicona, Epifanio MamaniSouza Junior, JorgePradelle, Florian
Brazil PL8 regulation has required that manufacturers comply with new emissions levels for all of vehicle life – 0 km up to 160.000 km. On this study, tests found that results between new and used vehicles are remarkably similar except for Aldehydes on Ethanol tests. To better understand this phenomena, two main ideas were considered: first, the engine mileage needed to stabilize aldehydes emissions; and second, the main factors responsible for higher acetaldehyde values on new engines only.
Fernandes, SarahBorsari, MarcioBrondani, Dhouglas
The growing demand for sustainable energy and the need to reduce greenhouse gas emissions have driven interest in low-carbon hydrogen production. Ethanol steam reforming (SR) offers a promising on-board H2 source by exploiting ethanol’s renewability and liquid-fuel convenience. This study presents an integrated energy and exergy analysis of ethanol SR across 573 to 923 K and steam-to-ethanol (S/E) ratios from 1 to 4 using Gibbs free energy minimization in MATLAB to predict equilibrium compositions and thermal duties. Energy analysis shows the heating duty rising from 0.0311 kWh/mol ethanol at 573 K (S/E = 1) to 0.0521 kWh/mol at 923 K (S/E = 4). Reforming duty shifts from -0.0075 to +0.2426 kWh/mol, while cooling duty recovers between -0.0219 and -0.0727 kWh/mol. The net energy balance transitions from strongly endothermic below 650 K to near-neutral at 700 to 750 K for S/E > 2, and becomes exothermic above 800 K, reaching +0.2463 kWh/mol at 923 K. Exergy analysis reveals that heating
Apaza, Jerson Bequer UrdayPradelle, FlorianBraga, Sergio LealSánchez, Fernando ZegarraGuzman, Juan Jose Milon
This study aims to quantify, through Monte Carlo simulation (100,000 iterations), the greenhouse gas (GHG) emissions associated with the complete production cycle of ethanol from sugarcane in Brazil, expressed in kg CO2eq/ha, and to project these emissions over a 20-year horizon. To achieve this, the production cycle was segmented into distinct stages - land use change, soil management and preparation, fertilization, harvesting and straw management, soil carbon sequestration, and industrial processing - and the parameters for each stage were defined based on recent. Three representative scenarios were considered: Worst-case (unsustainable practices involving conversion of native vegetation, high fertilizer dosages, and complete burning of the straw), Typical (conventional practices, with conversion of degraded pastures and sustainable management), and Ideal (best practices, characterized by reduced input dosages, the use of nitrification inhibitors, and high straw retention). The
Assis, Marcelo Suman SilvaPaula Araújo, Gabriel Heleno deBaeta, José Guilherme CoelhoAbreu, Pedro Blaso Barbosa deFilho, Fernando Antonio Rodrigues
The concern about CO2 emissions from commercial vehicles powered with internal combustion engines has been motivating research and development projects to reduce the transportation sector carbon footprint. One of the promising alternatives is the use of biofuels associated with high-efficient internal combustion engines, taking advantage of the current infrastructure of car manufacturers and automotive suppliers, as well as of the potential growth in biofuel production. With the stringent emissions regulations, the use of downsized SI engines for passenger cars has driven the adoption of direct injection technology, enabling the use of different fuel injection strategies such as stratified mixtures and multiple injection events, as well as the increase of the compression ratio as a way to improve engine thermal efficiency. This path also led to a gradual increase in injection pressure, aiming to improve spray formation and reduce the formation of particulate matter. In this sense, the
Antolini, JácsonZabeu, Clayton BarcelosPires, Gustavo CassaresPolizio, Yuri
Ethanol is a hydrogen-rich liquid and has a specific energy of 8.0 kWh/kg. In a vehicle, hydrogen storage is done in high-pressure cylinders. The same fundamental technology is used at other fuel cell systems in vehicles such as Toyota Mirai and Honda Clarity. Hydrogen is also introduced into the cell to generate electricity, which will power an electric motor that drives the vehicle. Excess electricity is stored in batteries. The main characteristic of the system described here is that hydrogen can be generated through an additional process in a reformer, installed at a fixed station. The reformer transforms the ethanol stored in the fuel station tank into hydrogen, which can then fuel a vehicle equipped with high-pressure cylinders and fed into the fuel cell. The system, however, emits water vapor, heat, and CO2. This is because carbon dioxide is a byproduct resulting from the transformation of ethanol into hydrogen. According to studies, despite this the system is carbon neutral
Fontana, Romeu
The increasing demand for reduced emissions in the automotive sector has driven research into alternative fuels, including Diesel, Biodiesel, and ethanol blends. This study aims to optimize mixing rules to predict the physicochemical properties of ternary fuel blends, essential for improving engine performance and minimizing emissions. Seven established mixing rules—Kay’s Equation, Semilogarithmic Equation, Grunberg-Nissan Equation, Modified Lederer Equation, Hu-Burns Equation, Power Law, and Polynomial Equation—were evaluated to estimate key properties such as kinematic viscosity, cetane number, cetane index, flash point, pour point, and cloud point. A comprehensive database, sourced from previous literature, included pure fuel properties and blend data for 33 to 101 cases. MATLAB was used to implement nonlinear optimization, adjusting coefficients to minimize error metrics like Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), and Standard Deviation (SD). The physical
Tirado, Carlos Andrés AbantoLobato, Maria Letícia CostaPassos, Sthefany FaberPradelle, Renata Nohra ChaarPradelle, Florian
The transition to renewable fuels is critical to reduce greenhouse gas emissions and achieve carbon neutrality in the transportation sector. Ethanol has emerged as a promising biofuel for compression ignition (CI) engines due to its renewability and low-carbon profile. However, its low cetane number, high latent heat of vaporization, poor lubricity, and corrosive properties severely limit its auto-ignition capability and durable operation under conventional CI conditions. Building upon previous work using a Rapid Compression Machine (RCM) to assess ignition improvers for ethanol, this study explores a broader range of fuel formulations to enhance ethanol-based combustion. A total of nine blends were prepared, consisting predominantly of hydrated ethanol (50-80% by volume), combined with 5-25% biodiesel and up to 5% of a commercial ignition improvers. The biodiesel component acted both as a co-solvent and as a combustion stabilizer, particularly under cold-start conditions. Tests were
Bacic, Denise AmatoSánchez, Fernando ZegarraTicona, Epifanio MamaniPradelle, Renata Nohra ChaarSantos Coelho, Lucas dosMota, Crislane Almeida Pereira daPradelle, Florian
Flex-fueled vehicles (FFV) dominate the Brazilian market, accounting for over 75% of the national fleet. Ethanol fuel is widely used, primarily in the form of hydrated ethyl alcohol fuel (HEAF). Given the similar physicochemical properties of ethanol and methanol, fuel adulteration is a growing concern, often involving the addition of anhydrous ethanol, methanol, or even water to hydrated ethanol. These adulterants are visually imperceptible and can only be detected through analyses conducted by regulatory agencies using specialized instruments. However, they can significantly affect vehicle performance and accelerate engine component deterioration. The experiment was performed with a small displacement 3-cylinder port fuel injection flex-fuel engine on an engine test bench (dynamometer) and compared when fueled with ethanol and methanol. Data acquisition included combustion pressure, spark plug temperature, torque, air-fuel ratio, fuel flow, spark maps, and the overall effects of
Mascarenhas, Giovana RebellatoGomes, EdersonCruz, DiegoDuque, Edson Luciano
In alignment with the International Maritime Organization’s 2023 GHG Strategy and the Paris Agreement, this study investigates the viability of ternary blends of marine diesel, biodiesel, and ethanol as low-emission marine fuels. While previous studies have established the physicochemical behavior and storage stability of such blends, particularly the co-solvency role of biodiesel to prevent phase separation, limited data exists on their combustion performance under engine-relevant conditions. This work addresses this gap through a series of controlled experiments conducted in a Rapid Compression Machine (RCM), which enables the approximate a single-cycle combustion in a compression ignition engine. The tested blends included varying proportions of ethanol (up to 20% in volume) in a blend of fossil fuel with 25% of biodiesel (25%), and their combustion were evaluated across different injection timings. Key performance metrics such as ignition delay, maximum temperature and pressure
Lobato, Maria Letícia CostaSánchez, Fernando ZegarraTicona, Epifanio MamaniPradelle, Renata Nohra ChaarBraga, Sergio LealCoelho, Lucas Dos SantosPradelle, Florian
Particulate matter (PM), mainly its finer fraction, is among the main atmospheric pollutants present in an urban environment. The relationship between the increase in the concentration of this pollutant and the harm to human health is well established. The main sources of particulate matter in urban areas are mobile sources, which include the exhaust emission from light duty vehicles. This work measured the emission of PM in three light duty passenger vehicles, characterizing it in terms of emitted mass in one “flex” vehicle with port fuel (indirect) injection (PFI), using ethanol and gasohol (mixture of 22% anhydrous ethanol and 78% gasoline, by volume), in another “flex” vehicle with direct fuel injection (GDI), and in a diesel vehicle. In addition to mass measurement, images of the filters used in PM sampling were produced using scanning electron microscopy. The processing of these images made it possible to determine the average PM size, as well as establish a particle size
Borsari, VanderleiNeto, Edson Elpídiode Abrantes, Rui
Achieving compression ignition (CI) with ethanol, a renewable fuel, comes with challenges because of its much lower cetane number compared to diesel. Additionally, ethanol’s high cooling potential and high volatility compared to diesel also offer challenges and opportunities to achieving robust, high-efficiency CI. Increasing the compression ratio (CR) and expanding the injection strategy beyond a conventional close-coupled pilot-main diesel injection strategy can help overcome these challenges. This work experimentally tested ethanol CI with several different injection strategies with CRs ranging from 16.3 to 22.3. The results showed that in homogeneous charge CI (HCCI), increasing the CR improved thermal efficiency but incurred a combustion efficiency penalty. In any CI concept, increasing the CR lowered the required intake temperature to achieve ignition. Using close-coupled pilot injections is an effective way to achieve ethanol CI, but it was also shown that HCCI-like intake
Gainey, BrianVedpathak, KunalKumar, MohitLawler, Benjamin
As global energy demands continue to grow and environmental challenges intensify, Biodiesel stands out as an environmentally sound and technically feasible alternative to curb fossil fuel use and emissions. This study provides an in-depth analysis of the performance and emissions profile of a compression ignition (CI) engine running on a renewable diesel fuel blend made from ethanol and cottonseed (Cs) combinations enhanced with aluminium oxide (Al2O3) nanoparticles. The experimental fuel blends, consisting of 10%, 20%, and 30% cottonseed biodiesel with 5% ethanol and remaining with conventional diesel, were analyzed under varying engine load conditions. The inclusion of ethanol improved fuel atomization due to its lower viscosity and higher volatility, while Al2O3 nanoparticles acted as advanced combustion catalysts, promoting enhanced oxidation rates and thermal efficiency. Among the blends, B10 (10% cottonseed biodiesel) exhibited superior performance metrics, achieving a brake
T, KarthiG, ManikandanSaminathan, SathiskumarM E, ChandhuruS, BavanyaS, Arunkumar
Alcohol is being considered as an alternative to traditional fuels for compression ignition engines due to their oxygen content and biomass origin. Although alcohol generally has lower cetane numbers, which makes them more favorable for premixed combustion, they also offer potential for lowering emissions in internal combustion engines, particularly when combined with strategies such as exhaust gas recirculation (EGR). This research focuses on enhancing the performance of a single-cylinder, four- stroke diesel engine by introducing ethanol into the intake port during the intake phase. Diesel and rubber seed biodiesel were used as primary fuels and were directly injected into the combustion chamber. The findings indicated that adding ethanol to rubber seed biodiesel, along with 10% EGR, led to improved brake thermal efficiency and a reduction in NOX emissions. The ethanol injection timing and duration were optimized for effective dual-fuel operation. At full engine load, the highest
Saminathan, SathiskumarG, ManikandanBungag, Joel QuendanganT, Karthi
Alcohol fuels are regarded as a feasible approach to address rising energy demands and reduce the dependency on fossil fuels, with ethanol and methanol emerging as a promising renewable fuel for spark-ignition engines. In this research work, tests were performed on a spark ignition engine altered from a diesel engine that employs ethanol/methanol-gasoline blend as fuel operating under lean conditions. The experiments were conducted at 10.5:1 compression ratio and 1500 rpm under full throttle condition with three fuel blends namely M10 (10% of methanol+ 90% gasoline), E10 (10% of ethanol+ 90% gasoline), E5M5 (5% of each ethanol and methanol+ 90% gasoline). Investigational results reveals that alcohol-gasoline blends displayed low COV of IMEP. Furthermore, the alcohol-gasoline mixtures enhanced the peak in-cylinder pressure owing to improved flame speed and flammability limits. Adopting lean-burn operation and high compression ratio can efficiently improve combustion attributes in an
Devunuri, SureshPorpatham, Dr. E
Alcohol fuels, produced from renewable energy sources, are considered a crucial solution for achieving life-cycle carbon neutrality in internal combustion engines. The Boosted Uniflow Scavenged Direct-Injection Combustion Engine (BUSDICE) exhibits significant potential for high thermal efficiency with an aggressive downsizing design. In this study, a computational investigation was carried out to assess the spray mixing and combustion characteristics of BUSDICE fuelled with methanol and ethanol, compared with gasoline, under a high-load condition. The injection duration of methanol and ethanol is significantly longer than that of iso-octane, leading to incomplete evaporation. The mixture exhibits an “outer-rich, central-lean” stratification pattern due to the short mixing time and swirl flow transportation for all three fuels. However, the prolonged injection of methanol induces stronger turbulence, which can enhance the local mixing. The spatial mixture stratification, particularly
Feng, YizhuoLu, EnshenDong, ShuoKeshtkar, HosseinWang, XinyanZhao, Hua
Various fuels are being considered as the next generation of carbon neutral fuels, including methanol, ethanol, and SAF. These have widely different ignition properties. Methanol and ethanol are high-octane fuels, so there are no major problems with their use in gasoline engines. However, SAF is a hydrocarbon with a large molecular weight, so it has a fundamentally low octane rating and is not easy to use in SI engines. In order to put carbon-neutral fuels of various properties into practical use, it is effective to develop a technology that allows fuels with low octane to be operated in SI engines. Therefore, in this study, basic research was conducted on the combustion of fuels with low octane using PRF fuel in opposed-piston engines. Opposed piston engines are characterized by their light weight due to the absence of a cylinder head, low S/V ratio due to the ultra-long stroke, reduced cooling loss due to the long stroke, and reduced vibration due to the offsetting of the
Yamazaki, YoshiakiOkawara, IkumiLiu, JinruIijima, Akira
Recent studies highlight the urgent need to reduce greenhouse gas (GHG) emissions to mitigate the impacts of global warming and climate change. As a major contributor, the transport sector plays a vital role in these efforts. Ethanol emerges as a promising fuel for decarbonising hard-to-electrify propulsion sectors, thanks to its sustainable production pathways and favourable physical and combustion properties, such as energy density, rapid burning velocity, and high knock resistance. This work proposes a methodology to enable the possibility of replicating the combustion behaviour of ethanol in a 1D CFD simulation environment representative of a single-cylinder research engine. Spark-ignition combustion is simulated through the Eddy Burn-Up combustion model previously calibrated for standard fossil gasoline. The combustion model features a laminar flame speed neural network, trained and tested through reference chemical kinetics simulations. The combustion model showed great accuracy
Ferrari, LorenzoSammito, GiuseppeFischer, MarcusCavina, Nicolò
Low carbon, though poorly igniting (i.e., low cetane) fuels, such as methanol, ethanol, and ammonia, are gaining momentum in the maritime fuel market. The most adopted strategy to address the fact that these fuels will not, under typical two-stroke marine engine conditions, auto-ignite, is to co-inject a pilot fuel, such as (very) low sulfur marine fuel oil, which does auto-ignite and furthermore doubles as a spark of sorts for the poorly igniting base fuel. This so-called dual-fuel approach is costly and cumbersome. Cetane boosters are known to improve ignitability of alcohol fuels to the point that a pilot fuel is no longer required. In our earlier research, we found some indication that lignin model compounds could likewise improve the ignitability of alcohols. This paper builds further on this hypothesis, now using commercially available lignin rather than model compounds. Auto-ignition behavior of methanol and ethanol was investigated with up to 10 wt% of therein solubilized
Sementa, PaoloTornatore, CinziaCatapano, FrancescoLazzaro, MaurizioIannuzzi, StefanoKouris, PanosBoot, Michael
Alcohol-to-jet (ATJ) upcycling of ethanol to sustainable aviation fuel (SAF) is an attractive emerging pathway for SAF production, especially in the US Midwest with large-scale corn ethanol production. Only 39% of the corn carbon is converted to ethanol, 20% is emitted as CO2. Capturing the CO2 to produce additional ethanol or SAF directly can increase the carbon yield. To guide technology selection, this work used life cycle assessment for several CO2-to-SAF production pathways. Additionally, improvements for corn ethanol production were explored by replacing natural gas burners with heat pumps for corn drying, which reduced the carbon intensity of corn ethanol by nearly 16%. But subsequent upgrading of the ethanol to SAF is only 4.5–20% better than conventional aviation fuel. By contrast, CO2-based alternative routes to SAF fared better, reducing carbon intensities between 83% and 90%. Gas fermentation of CO2 to ethanol with subsequent ATJ upcycling to SAF was contrasted to Fischer
McCord, StephenTalsma, SamBouchard, JesseyZavaleta, Victor GordilloHe, XinSick, Volker
Global climate initiatives and government regulations are driving the demand for zero-carbon tailpipe emission vehicles. To ensure a sustainable transition, rapid action strategies are essential. In this context, renewable fuels can reduce lifecycle CO2 emissions and enable low-soot and NOx emissions. This study examines the effects of renewable ethanol in dual-fuel (DF) and blend fueling modes in a compression ignition (CI) engine. The novelty of this research lies in comparing different combustion modes using the same engine test rig. The methodology was designed to evaluate the characteristics of various injection modes and identify the inherent features that define their application ranges. The investigation was conducted on a single-cylinder engine equipped with state-of-the-art combustion technology. The results indicate that the maximum allowable ethanol concentration is 30% in blend mode, due to blend stability and regulatory standards, and 70% in DF mode, due to combustion
Belgiorno, GiacomoIanniello, RobertoDi Blasio, Gabriele
Alcohol fuels have inherent properties that make them suitable candidates to replace conventional fossil fuels in internal combustion engines by reducing the formation of harmful emissions such as lifecycle carbon dioxide (CO2), nitrogen oxides (NOX), and particulate matter (PM). There is an increasing amount of work to use fuels such as ethanol or methanol in mixing-controlled compression ignition (MCCI) as a replacement for diesel fuel. However, employing these fuels in a strictly MCCI strategy results in an evaporative cooling penalty that lowers indicated fuel efficiency. This work proposes the use of an advanced compression ignition (ACI) strategy with a high autoignition resistant fuel, where a fraction of the fuel is premixed and autoignited in conjunction with a fraction of fuel that is burned in a mixing-controlled manner to achieve diesel-like efficiencies with significant emission reductions. A computational model for MCCI with diesel and wet ethanol in an opposed piston two
O’Donnell, Patrick ChristopherGainey, BrianBhatt, AnkurHuo, MingLawler, Benjamin
India aims to achieve 20% ethanol blending (E20) in petrol by 2025 under its National Biofuels Policy to reduce carbon emissions, enhance energy security, and support the agricultural economy. Building on this, E27 (27% ethanol in gasoline) is being evaluated as an advanced mid-level blend to further lower greenhouse gas emissions and reduce reliance on fossil fuels. This study investigates the performance, emissions, and combustion characteristics of a turbocharged gasoline direct injection (TGDI) engine using E27 fuel over 20,000 km in real-world driving conditions, as part of a broader research program accumulating over 100,000 km across multiple vehicle categories. Key findings indicate that E27 achieves an optimal balance of emissions reduction and performance, with NOx and THC emissions decreasing by 12% and 5%, respectively, compared to E10, while CO and CO₂ levels remained stable, reflecting ethanol’s oxygenation effect and lower carbon intensity. Power output and acceleration
D R, VigneshwarBhakthavachalu, VijayabaskarMuralidharan, M.
This study presents a comprehensive techno-economic assessment (TEA) of an integrated e-methanol production system building upon previously published foundational research utilizing Aspen Plus modeling for e-methanol production from sugar cane and sugar beet biomass. The established integrated system converts biomass into ethanol through fermentation and synthesizes e-methanol using both captured CO2 and syngas derived from biomass residue gasification. This approach maximizes CO2 and biomass utilization, promoting a circular carbon economy. The TEA quantifies capital expenditures (CAPEX), operational expenditures (OPEX), and levelized costs of Methanol (LCOM), providing a detailed economic analysis of the potential for commercializing e-methanol. A sensitivity analysis evaluates the impact of feedstock prices and Technology Readiness Levels (TRL), identifying key leverage points affecting financial viability. The study aims to explore the potential of utilizing existing agricultural
Fernandes, Renston JakeShakeel, Mohammad RaghibNguyen, DucduyIm, Hong G.Turner, James W.G.
Flash boiling atomization is considered a promising atomization technique for combustion applications in automotive powertrains. It can potentially address the deteriorated atomization issue for alternative fuels (such as methanol) in internal combustion engines. However, it has been observed that flash boiling spray atomization for methanol fuels is not as effective as that for traditional alkane-based fuels. This work aims to explain such phenomena using transparent nozzles to reveal the impact of internal vaporization on external spray breakups. Three different working fluids, including methanol, ethanol, and pentane, are tested with elevated temperatures. The flow patterns and external liquid breakup are shown with the high-speed imaging technique. It is found that the internal phase change of the base working fluid is suppressed when ethanol or methanol is used instead of pentane. Consequently, the external liquid breakup is also hindered due to insufficient vapor phase inside the
Zhang, YijiaLi, YilongWang, ShangningZeng, TingxiXu, MinHung, DavidLi, Xuesong
In this study, a strategy for MCCI combustion of a novel alcohol fuel is demonstrated. The novel fuel, “GrenOl”, is the result of the catalytic upgrade of sustainable ethanol into alcohols of higher molecular weight. The composition of GrenOl includes approximately 70% 1-butanol, 15% 1-hexanol, and 5% 1-octanol by mass, resulting in a cetane number around 18. In order to achieve mixing-controlled compression ignition with GrenOl, an exhaust rebreathing strategy is employed. In this strategy, the exhaust valve reopens for a part of the intake stroke, inducting hot exhaust into the cylinder and preheating the fresh air. This study investigates the feasibility of operating with such a valve strategy from idle to peak torque. At idle, the primary challenge is ensuring stable combustion by inducting adequate exhaust to achieve ignition. Under load, when cylinder temperatures are higher, the primary challenge is ensuring sufficient air is inducted to achieve the target torque. It was found
Trzaska, JosephXu, ZhihaoBoehman, André L.
Exhaust gas recirculation (EGR) is widely used in spark ignition engines to reduce throttling losses, decrease exhaust gas temperatures, increase efficiency, and suppress knock. However, the effectiveness of EGR as a knock suppressor is dependent on the fuel type and operating condition. In this study, the effectiveness of EGR to suppress knock was tested with E10, E30, E50, E75, and E100 at a moderately boosted condition. It was found that EGR was effective at suppressing knock with E10, but high EGR rates were required to achieve a knock suppression effect with E30 and E50. No knock suppression effect was observed with E75 and E100 across all tested EGR rates. With E30 and E50, EGR that was passed through a three-way catalyst was more effective at suppressing knock at all EGR rates. Chemkin modeling with neat ethanol revealed that nitric oxide enhanced ignition by increasing the hydroxyl radical concentration in the end gas, resulting in earlier auto-ignition. Directly seeding nitric
Gandolfo, JohnGainey, BrianLawler, Benjamin
Flex fuel vehicles (FFV) can operate effectively from E5 (Gasoline 95%, ethanol 5%) fuel to E100 (Gasoline 0%, ethanol 100%) fuel. It is necessary to meet the performance, drivability, emission targets and regulatory requirements irrespective of fuel mixture combination. This research work focuses on optimizing the combustion efficiency and conversion efficiency of catalytic converter of a spark-ignited less than 200 cc engine for FFV using Taguchi methods robust optimization technique. The study employs an eight-step robust optimization approach to simultaneously minimize engine out emissions and maximize catalytic converter efficiency. Six control factors including type of fuel, catalyst heating rpm, lambda (excess-air ratio), injection end angle, lambda controller delay, and ignition timing are optimized. Four noise factors like compression ratio, clearance volume, catalyst noble metal loading, and catalyst aging are also considered. Through approximately 100 physical experiments on
Vaidyanathan, BalajiArunkumar, PraveenkumarShunmugasundaram, PalaniMurugesan, ManickamJayajothijohnson, Vedhanayagam
Reducing CO2 emissions is now a major focus in India heading towards net zero emissions by 2070. India is the 3rd largest automobile market in the world and the transportation sector is the 3rd largest CO2 emitter. In this direction, it is necessary to reduce the carbon footprint from the automobile sector to combat climate change. The adoption of sustainable biofuels such as ethanol will enable us to reduce emissions, as ethanol is carbon neutral fuel. However, vehicle manufacturers are facing challenges in manufacturing flex fuel compatible parts in the vehicle mainly fuel systems. Ethanol has both nonpolar and polar bonds, making it miscible to both gasoline and water, thereby water contamination is inevitable in ethanol blend fuels. In addition, control of ethanol contamination by sulfates and chlorides during ethanol production is challenging. Thus, ethanol blend fuels are considered more corrosive and tendency towards deposit formation than normal gasoline fuels. Design and
Pandi, Dinesh BabuShanmugam, Gomathy PriyaNagarkatti, ArunGopal, ManishAnbalagan, Prathap
This study aims to investigate the effect of ethanol blends on flame propagation and auto-ignition under high pressure and high temperature conditions. Experimental investigations are conducted using n-C7H16 / ethanol blends at various blending ratios (0, 5, 10, 20, 40, 70, and 100 vol%). The blends are premixed with air at stoichiometric ratios and ignited centrally in a cylindrical constant-volume combustion chamber (20-mm inner diameter, 80-mm long) under elevated temperature (500 K) and pressure (1.0 MPa) conditions. The results show that auto-ignition occurs at an ethanol blend ratio of 10% or less and ceases above 20%. Increasing the ethanol blend to 70% results in a slight change in flame propagation speed, with a noticeable delay at 100%. The pressure measurements show a peak of about 5.6 MPa at a blend ratio of 5%, which gradually decreases with increasing ratios. High-pass filtering reveals the maximum pressure fluctuation amplitude at the 5% blend ratio, indicating increased
Tateishi, TokuaYamaguchi, RikiShimokuri, DaisukeTerashima, HiroshiHara, TakayaHonda, YuyaKawano, Michiharu
Drop-in gasoline fuels that originate from renewable, low-net-carbon sources, such as methanol-to-gasoline (MTG), are an important bridge in the transition between traditional fossil fuels and electrification of the transportation sector. The composition of these fuels can be tuned by adjusting the settings of the chemical processes used to create them, which can be leveraged to formulate optimized fuels for higher knock resistance or higher flame speed. This study investigated how the distribution of hydrocarbon classes and molecular structure of a renewable MTG gasoline surrogate affected knock and flame speed using chemical kinetic modeling. The original MTG surrogate was modified by increasing the relative amount of a certain hydrocarbon class while the concentration of other hydrocarbon classes is reduced equally. Increasing normal- and iso-alkanes increased reactivity and penalized octane sensitivity, olefins increased octane sensitivity while keeping the research octane number
MacDonald, JamesLopez Pintor, DarioMatsubara, NaoyoshiKitano, KojiYamada, Ryota
The transition to fully sustainable fuels, like ethanol, for Formula 1 power units in 2026 introduces challenges related to engine performance and emissions. The lower energy content of these fuels can have a negative impact on power output, while the increased levels of formaldehyde produced during combustion pose an environmental concern. This study aims to evaluate engine performance while meeting the FIA’s 2026 regulations using numerical simulations and to develop a method for estimating formaldehyde emissions produced during combustion. An F1 power unit model was developed in GT-Suite, incorporating all relevant regulations for 2026. The model was validated against literature data for combustion characteristics, such as laminar and turbulent flame speeds, and friction losses. Additionally, compliance with operational limits, such as energy flow restrictions, was confirmed. Suitable elementary and global reaction mechanisms for formation and destruction of formaldehyde were
Fuss, NadineSamuel, Stephen
Achieving stable HCCI combustion requires specific in-cylinder boundary conditions. Trace residual species, such as nitric oxide (NO), can have an impact on the reactivity, and thus the combustion stability, of different fuels in HCCI. This study investigates the effects of nitric oxide (NO) on the reactivity and combustion stability of ethanol and gasoline in a single-cylinder HCCI engine. The promoting and inhibiting impact of NO on iso-octane’s ignition delay time are available in the literature; nevertheless, as a baseline study, these effects on the autoignition of gasoline were documented in this work. For ethanol, the NOx concentration seeded in the intake air varied from 0-1000 ppm while maintaining a constant combustion phasing (CA50 at 7.5 CAD) and a global equivalence ratio of 0.34. Ethanol exhibited a linear reduction in intake temperature, decreasing by 47 K with 927 ppm NO. For gasoline, a 225-ppm increase in NO reduced the intake temperature required for HCCI by 40 K
Bhatt, AnkurGandolfo, JohnVedpathak, KunalLawler, BenjaminGainey, Brian
This experimental study presents preliminary investigations of prechamber-enabled mixing-controlled combustion (PC-MCC) at −2 bar brake mean effective pressure (BMEP) and 2200 rpm with fuel-grade ethanol (E98). Experimental results are conducted on a prechamber retrofitted single-cylinder Caterpillar C9.3B test engine. First, a series of prechamber-only experiments were conducted with a motored engine to evaluate the salient combustion trends in response to relevant prechamber operating parameters. Under firing conditions, the prechamber operating strategy was assessed with respect to the impact on ignition assistance of direct-injected E98 and overall engine performance. The preliminary results indicate the jet-induced ignition process is robust and prompts diffusion combustion of E98 at diesel-like boundary conditions. The effect of external exhaust gas recirculation (EGR) on the residual tolerance of the prechamber combustion process was also investigated and showed stable
Zeman, JaredDempsey, Adam
The application of short burn durations at lean engine operation has the potential to increase the efficiency of spark-ignition engines. To achieve short burn durations, spark-assisted compression ignition (SACI) as well as active pre-chamber (PC) combustion systems are suitable technologies. Since a combination of these two combustion concepts has the potential to achieve shorter burn durations than the application of only one of these concepts, the concept of jet-induced compression ignition (JICI) was investigated in this study. With the JICI, the fuel is ignited in the PC, and the combustion products igniting the charge in the main combustion chamber (MC) triggered the autoignition of the MC charge. A conventional gasoline fuel (RON 95 E10) and a Porsche synthetic fuel (POSYN) were investigated to assess the fuel influence on the JICI. Variations of the relative air/fuel ratio in the exhaust gas (λex) were performed to evaluate both the occurrence of the JICI and the dilution
Burkardt, PatrickGünther, MarcoVillforth, JonasPischinger, Stefan
In recent years, the use of ethanol fuel in internal combustion engines has gained importance due to environmental and commercial factors, since ethanol produces lower emission rates at similar performance parameters compared to gasoline fuel. The objective of this study is to evaluate and compare the effects of engine performance parameters on the vibration level of the engine block operated with gasoline and ethanol fuel. The experimental tests consisted of operating an Otto cycle engine on a bench dynamometer under full load conditions varying rotation and correlating the vertical, longitudinal and transverse vibration levels of the block engine with the engine performance parameters. The results showed that the engine vibration level was influenced by engine speed, load, type of fuel and performance parameters of the engine. The combustion process is primarily responsible for the highest level of vibration reached when using ethanol as a fuel. Under all operating conditions, the
Santana, Claudio MarcioSantana, Linicker Lopes BrunoAlmeida, Helder Giostri Alves
Otto Cycle can operate with both gasoline and ethanol; however, these fuels have different properties that will result in different performance parameters. This work aims to compare the thermal energy balance of an internal combustion engine fueled with gasoline and ethanol. The experimental tests were carried out on a dynamometer bench varying engine speed between 1500 and 6000 rpm and at full load condition. The results showed that the engine’s maximum thermal efficiency ranged from 30.51% with gasoline to 31.72% with ethanol. The percentage of energy dissipated to the cooling system varied from 16.93% with gasoline from 16.12% with ethanol. The percentage of energy dissipated to the exhaust system ranged from 32.82% with gasoline from 34.64% with ethanol. The percentage of energy wasted due to incomplete fuel combustion varied from 3.50% with gasoline from 10.00% with ethanol. The percentage of energy dissipated to the lubrication system ranged from 3.95% with gasoline from 3.76
Santana, Claudio MarcioSantana, Linicker Lopes BrunoAlmeida, Helder Giostri Alves
An inwardly-opening pressure swirl injector for direct injection spark ignition engine applications was used in this work for injecting EXXSOL D60 into laboratory gaseous atmospheric conditions into an open chamber. The EXXSOL D60 fluid was used due to its some similar physical properties to Ethanol fuel. Four injection pressures were used in this work: 50 bar, 60 bar, 70 bar and 80 bar and the simulated engine speed was set up in 2000 rpm in all cases using the injector outside the engine. Shadowgraph technique associated to a filming process with a rate of acquisition of 3300 frames per second was used for acquiring the spray images. The spray images were treated running scripts in Matlab software. The scripts were written for this present analysis. The injector used in this work produced hollow cone sprays. With the image treatment performed in Matlab software, the vertical penetration length and the external cone angle were obtained. The main results showed that penetration length
Guzzo, Márcio ExpeditoFonseca, Lucas GuimarãesBaeta, José Guilherme CoelhoFilho, Fernando Antonio RodriguesPujatti, Fabrício José Pacheco
The aim of this study is to compare possible approaches that support the goal of achieving a carbon-neutral society in the mobility sector, with a specific focus on the two-wheel segment of the mobility sector. One of the key considerations in the mobility sector is the transition from a fossil fuel-based energy mix to a more renewable one. While there are numerous options available for achieving a carbon-neutral society in the four-wheel scenario, the two-wheel sector presents a different challenge due to a smaller number of available options. This study introduces a new comparison between full electric, gasoline, and ethanol-powered two-wheeled vehicles. It suggests that ethanol is a feasible solution for reducing carbon emissions in the two-wheel sector. The study includes an analysis of CO2 emissions for two-wheel vehicles using a life cycle approach, focusing on the technologies of full electric motorcycles, motorcycles with flex-fuel internal combustion engines running on
Pereira, Thaynara K. E.Lima, FlavioUema, Fabio K.Sambuichi, Eduardo M.
The goal of this research is to better understand the methodologies for manufacturing biodiesel worldwide and the main raw materials used in its production. We aim to compare the solutions established by relevant countries with those used in Brazil, identifying their advantages and disadvantages. Our primary areas of interest include the United States, Indonesia, and Europe, where we will analyze the solutions and, whenever possible, understand the commercial and political interests involved. We will highlight aspects related to sustainability in the production, transportation, and use of biodiesel. The methodology is based on research from recent publications and news, organized into graphs to facilitate analysis and comparison. Next, we will also examine the consequences of the solutions adopted in Brazil, envisioning future scenarios and recommended paths. In the short term, biodiesel is expected to be replaced by renewable diesel (also known as green diesel in some regions
Labigalini, Marcio RobertoBarreto, Gilmar
This research paper explores India’s energy landscape, critically analyzing the challenges and potential solutions for sustainable development. With aspirations to become the third largest economy in the world, India faces heightened energy demands fueled by economic growth, population expansion, and urbanisation. The country grapples with a heavy reliance on imported crude oil and a substantial carbon footprint from existing primary energy sources, emphasizing the need for strategic interventions. The research paper advocates a multi-fuel strategy, particularly emphasising the promising role of bioethanol. Key stakeholders in India’s bioethanol ecosystem include farmers, Sugar mills/Grain-based distilleries, Oil Marketing Companies (OMCs), Original Equipment Manufacturers (OEMs) of vehicles, consumers, and the government. The National Policy on Biofuels (NPB) aims to boost bioethanol usage, aligning with national energy security, climate change mitigation, and employment generation
Singh, Rajnesh
Biofuels are gaining significant global attention as renewable and alternative energy sources, produced from various materials through different extraction methods and conversion processes. Food industry generates not only substantial organic waste, presenting economic and ecological challenges but also potential opportunities for valorization. This study focuses on recovering industrial fish waste from the manufacture of canned tuna, specifically targeting non-food and abundant fish co-products such as heads, bones, skin, and viscera, which constitute nearly 50% of the fish body. The process involves several steps: oil extraction using Soxhlet extraction, purification, and conversion into biodiesel via transesterification, followed by physicochemical analysis. The experiments revealed that 32.41% of fish waste was in the liquid phase (a mixture of hexane and oil), and the extracted oil accounted for 26.56% of the total fish waste weight (from 1.012 kg of waste, approximately 268.78 g
Bousbaa, HamzaNAIMA, KhatirLamia, MedjahedBenramdane, MohammedBalasubramanian, DhineshJohnson, Anish Jafrin Thilak
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