Browse Topic: Biofuels

Items (4,271)
Fuel adulteration increases operating costs, reduces vehicle efficiency, and contributes to air pollution. Fuel-quality verification typically requires laboratory infrastructure or dedicated sensors that are not available to most end users. In our previous work, we demonstrated that a software-only approach based on standard on-board diagnostics (OBD) signals and supervised machine learning can detect water adulteration in hydrated ethanol under real-world driving conditions with high accuracy. However, supervised classifiers remain challenging because fuel-trim dynamics vary across vehicles due to powertrain calibration, component aging, and operating environments, which can limit model generalization. This work addresses this limitation by introducing a detection framework that learns a vehicle-specific baseline of normal operation using gradient boosting regression (GBR) and flags anomalous events through residual-based cumulative sum (CUSUM) monitoring. The baseline model is trained using compliant-fuel data, and the CUSUM decision threshold is calibrated from temporally ordered normal-operation data using an expanding-window procedure with an initial warm-up segment. Across two vehicles, the proposed framework achieved recall values of 99.77% and 84.38%, with F1 scores of 99.88% and 91.53%, respectively, while maintaining zero false positives under compliant-fuel operation.
Marchezan, André Ricardo, Giesbrecht, Mateus
As a part of the project, the homogeneous reactivity-controlled compression ignition (hRCCI) concept is being investigated along with the development of 0D/1D combustion simulation models. The proposed concept employs early direct injection of octanol as the high-reactivity fuel in combination with port fuel injection of ethanol as the low-reactivity fuel. In the previous parts of the publication, testing results and the in-cylinder fuel and temperature distribution predictions were studied. Low-temperature combustion (LTC) concepts such as hRCCI are strongly governed by autoignition chemistry of the fuels and oxidizer, making the explicit consideration of chemical kinetics essential for predictive simulations. In addition, the hRCCI combustion process exhibits high sensitivity to a wide range of control parameters, including intake temperature, intake pressure, excess air ratio, premixed fuel ratio, and direct injection parameters, posing further challenges to model robustness. To address these challenges, a predictive and robust quasi-dimensional multi-zone combustion model for LTC engines is developed. The model couples a 0D/1D flow framework implemented in GT-POWER with detailed chemical kinetics solved using a Python–Cantera interface for user-defined combustion modeling. The combustion framework incorporates dedicated sub-models to account for fuel evaporation, interzonal heat transfer, wall heat transfer, spatial distribution of directly injected octanol, and temperature stratification across the zones. The model’s predictive capability is validated against experimental data from a single-cylinder research engine under variations in intake pressure, intake temperature, premixed ratio, and the start of direct octanol injection. The simulation results show strong agreement with experimental measurements, demonstrating the robustness and predictive accuracy of the developed modeling approach. The proposed simulation framework provides a valuable tool for the future development and optimization of low-temperature combustion engine concepts aimed at improving efficiency and reducing emissions.
Sundaram, Pravin Kumar, Grundl, Larissa Michaela, Trapp, Christian Thorsten, Tinschmann, Georg
As part of the dtec.bw MORE project, serial hybrid powertrains featuring alternative combustion regimes, specifically homogeneous reactivity-controlled compression ignition (hRCCI), are under investigation to maximize thermal efficiency while minimizing NOx and soot emissions. The proposed hRCCI concept utilizes dual-fuel stratification, employing early direct injection (DI) of octanol (high-reactivity fuel) alongside port fuel injection (PFI) of ethanol (low-reactivity fuel). While 0D/1D engine modeling is essential for developing predictive powertrain simulation frameworks, conventional models often lack the robustness required to capture the complexities of low-temperature combustion (LTC). This study addresses this limitation by developing a multi-zone “onion skin” quasi-dimensional model. Since for LTC, ignition and heat release rates are highly sensitive to thermal and chemical stratification, capturing these gradients is critical. 3D computational fluid dynamics (CFD) simulations are capable of capturing thermal and chemical stratifications to a high degree of accuracy, whereas 0D simulation models, in general, do not consider them. The primary contribution of this work is the translation of high-fidelity 3D CFD data into a computationally efficient quasi-dimensional environment. A simplified 3D CFD architecture was utilized to map the effects of various operating parameters on mixture distribution. Using these results, a regression learning model was trained to predict octanol and temperature stratification within the combustion chamber. Validation against simulation data demonstrates that this coupled machine learning and multi-zone approach provides a robust, predictive tool for evaluating advanced LTC concepts within larger system-level simulations.
Sundaram, Pravin Kumar, Grundl, Larissa Michaela, Trapp, Christian Thorsten, Tinschmann, Georg
With the rising pressure of a global energy transition to cleaner energy systems, the transportation sector faces a challenge in maintaining its current structure and adapting to all the required changes. Dual-fuel technology emerges as a promising alternative to keep the viability of the sector while utilizing environmentally friendly fuels alongside traditional hydrocarbons, without deep structural changes in the current framework. This work investigates the impact of the use of methane gas coupled with diesel fuel, specifically focusing on its influence on the ignition delay time (IDT) in a dual-fuel combustion setting. The investigation employed the Advanced Fuel Ignition Delay Analyzer (AFIDA), a constant-volume combustion chamber capable of automatically measuring multiple samples in a single run. Methane gas was introduced into the chamber at molar concentrations of 1%, 2%, and 3% and at initial pressures of 5 and 10 bar, with temperature values ranging from 653 to 723 K. With the same amount of diesel being injected for all experiments, it was possible to replace up to 40% of the total energy release with methane during the combustion process. Compared to pure diesel, the IDT values of the methane–diesel mixtures were only affected in low-temperature settings. At higher temperatures, the IDT values remained largely consistent with those of pure diesel, suggesting that higher substitution ratios of methane are feasible without compromising the ignition delay. This work also uncovered that the percentage of energy replaced by methane does not have a direct correlation with IDT or peak pressure values.
Pacheco Virginio, Thiago, Eraqi, Basem, Sakleshpur Nagaraja, Shashank, Sarathy, S. Mani
Compression-ignition engines operating with biodiesel blends often exhibit variability in fuel properties, such as density, viscosity, and cetane number, which can lead to systematic deviations in injected fuel mass when using conventional physics-based models. These deviations can reduce combustion efficiency and increase brake-specific fuel consumption (BSFC). This study proposes a lightweight neural network–based approach to compensate for structural errors in baseline injection models, using a single-layer perceptron trained on the relative error (delta) between actual and modeled injected mass. By normalizing engine and fuel parameters and introducing a small amount of measurement noise, the network learns to predict a corrective factor that adapts the injected mass to match the desired target under varying fuel conditions. Simulation results demonstrate that the neural correction significantly reduces systematic bias: in test cases with intentionally introduced structural error, the average injection deviation of −1.7% in the baseline model is reduced to approximately 0.002% after correction. Root-mean-square (RMS) error over training and validation datasets remains below 0.16%, indicating robust generalization. The proposed method offers a computationally efficient solution suitable for embedded engine control units, requiring minimal additional complexity while ensuring precise fuel delivery. By eliminating bias caused by fuel property variability, the approach has the potential to improve fuel economy, reduce emissions, and maintain consistent engine performance under a wide range of operating conditions. This framework provides a practical path for integrating adaptive, data-driven correction mechanisms in diesel engines operating with heterogeneous or variable biofuels.
Gutierrez, Marcos, Taco, Diana
The entire mobility industry currently faces enormous regulatory demands due to the Paris agreement and its corresponding initiatives to eliminate the business sector-related greenhouse gas emissions (GHG) emissions. A major focus is hereby set on wide-spread electrification of all kinds of applications, but from current perspective it is obvious that a quick and complete shift is highly unlikely, especially with view on heavy and challenging industrial and commercial applications. In line with this, it’s apparent that internal combustion engines (ICEs) maintain to play an important role in the overall propulsion system line-up. For compliance with the engaged CO2 reduction policies and efficiency improvement demands, a fast and broad replacement of fossil fuels needs to be realized. Due to the specific properties of carbon-neutral fuels and as well the variety of the range of industrial applications, different types of alternative fuels are considered. These novel fuels can be subdivided into preferred solutions for smaller or on-highway applications vs heavy off-highway and marine applications, or simply according to local or national preferences or policies. As of now, Hydrogen as well as Methanol/Ethanol is highly attractive for on-highway applications as well as construction/agricultural applications, the heavier and larger applications tend to more energy-dense energy carriers like NH3 and partially Methanol/Ethanol. In addition, to support a smooth transition to fully carbon-neutral operation, intermediate dual-fuel layouts are requested, partially requiring a full redundancy between classical Diesel operation and powering with new fuels. This complexity and variety in customer demands provide a major challenge for globally operating OEMs as future engines designs and definitions need to be developed under extreme cost pressure. The paper at hand delivers an interesting approach to design and develop modern ICE platforms for the anticipated multi-fuel case, aiming at superior key performance indicators concerning power output and efficiency, while maximizing the degree of commonality between the individual engine versions and variants. This flexibility and modularity needs to be incorporated in the base engine design, especially in the top end of the assembly, as it implicates different demands in air delivery and as well the transition from a diffusive combustion system to a pre-mixed combustion principle. This affects on one hand the installation of key sub-systems like fuel injection and ignition, but as well also the decision about an appropriate compression ratio and the definition of an adjusted in-cylinder charge motion. The article closes with recommendations for a future multi-fuel engine definition and an assessment concerning the major design changes in contrast to a refined and optimized Diesel engine layout.
Koerfer, Thomas, Dhongde, Avnish, Yadav, Jaykumar
Increasing concern over climate change on planetary scale and urban pollution on a local spatial dimension are the pressing needs which invite to reduce greenhouse gas emissions in transportation as well as pollutant emissions. Both goals have prompted governments, industry stakeholders, and researchers to pursue innovative pathways toward sustainability in the on-the-road transportation sector trying to interpret this concept on the three requested dimensions, social, economic and environmental. Within this framework, hydrogen–methane mixtures have emerged as a promising alternative fuel solution which in someways match the three expectations. This primary solution matches the needs of urban transportation by buses, representing a further innovation step after the diesel-fuel to methane conversion. Hydrogen is characterized by carbon-free combustion, while methane is a comparatively clean and widely available fossil fuel. When blended, these two fuels can lower overall emissions relative to the use of pure CNG, while still being compatible with existing internal combustion engines if the content of hydrogen in the blend do not exceed 20 % by volume. Greater shares till to 35-40 % are compatible simply re-setting the ignition time according to the engine load. This compatibility makes the adoption of such blends both economically viable and technically achievable in the short to medium term, also increasing the market demand for hydrogen, reducing its cost. The social dimension of this choice is also saved, re-focusing attention on the reciprocating internal combustion engines which represent a great part of the industrial economy. This study describes the methodology adopted to assess the emissions performance of a hydrogen-methane-fueled (HCNG) bus for on-road emission testing. Two experimental campaigns were carried out: the first using conventional CNG, and the second employing an HCNG blend composed of 15% hydrogen and 85% CNG by volume. Tests were conducted along two routes, representing urban and extra-urban driving conditions, with different drivers and traffic conditions. The experimental results enabled a direct comparison between the two fuels. In both driving scenarios, a slight decrease in CO₂ emissions was observed when using the HCNG blend, corresponding to a reduction in fuel consumption. More significant decreases were recorded for pollutants such as CO, HC, and PN, whereas NOx emissions showed a modest increase of only a few percentage points. No modification has been implemented on the aftertreatment devices. The study indicates that the HCNG blend enhances vehicle responsiveness compared to conventional CNG and represents a step ahead in public urban transportation like the one from diesel fuel to methane.
Di Battista, Davide, Di Bartolomeo, Marco, Di Prospero, Federico, Di Diomede, Domenico, Cipollone, Roberto
Cashew nut shell oil–based biodiesel (BD) is an environmentally friendly and sustainable alternative energy source that can help decrease the depletion of fossil fuels and reduce environmental pollution. In this research, the BD extracted from cashew nut shell was enriched with green-synthesized nanoparticles with various blends and evaluated for its performance. The BD20A blend recorded the best thermal efficiency of the brake, 29.5%, which was a boost of about 20.4% over diesel when using a medium load of 2.7 kW. Furthermore, the decrease in brake-specific fuel consumption was 36.2%, and exhaust gas temperature improved by 26.1% due to enhanced combustion, indicating better combustion and utilization of heat. The BD10A and BD20A recorded a considerable decrease in emissions compared to diesel under full-load conditions, with carbon monoxide and hydrocarbons reducing by 35.7% and 33.3%, respectively, and a moderate increase of nitrogen oxides. Among the multi-objective optimization approaches, the Jaya algorithm exhibited the fastest convergence rate and identified the optimum operating condition that achieved the best trade-off between engine performance and exhaust emissions. BD blends, particularly BD20A, provide greater thermal performance and better combustion behavior as well as lower exhaust emissions, making them viable as green alternatives to the traditional diesel fuel.
Victor Soosai Irudayaraj, S., Thanigaivelan, V., Brucely, Y., Lenin, N.
State and federal legislation has helped double the consumption of renewable and biodiesel in North America over the past half decade. But is policy alone enough to make them ready for prime time? As crude oil prices continue to fluctuate globally, creating budgeting and logistical headaches for fleets of all sizes, renewable diesel (RD) fuels have quietly gained ground in North America. According to Chevron, total biomass consumption of renewable fuels in the U.S. has grown exponentially over the past five years, from 2.7 million gallons in 2020 to 5.1 million gallons in 2024. While that represents a fragment of annual diesel consumption in the U.S., the environmental benefits and viability of renewable fuels are growing greater everyday thanks to legislative support and technological investment from various fuel producers.
Wolfe, Matt
For large-bore marine methanol / diesel dual-fuel engines, this study investigates the formation characteristics of unregulated emissions through experimental methods and explores the mechanisms by which engine load and injection timing influence the emissions of unburned methanol and formaldehyde. The study was carried out on a supercharged intercooled inline six-cylinder engine, and Fourier Transform Infrared Spectroscopy (FTIR) was used to monitor the exhaust composition in real time. The study shows that methanol released in the exhaust is due to the incomplete combustion of the methanol fuel. In the combustion process of methanol fuel, formaldehyde mainly arises from two pathways, the first of which is the partial oxidation of methanol inside the cylinder; secondly, the unburned methanol in the exhaust gas oxidizes in the exhaust pipe to generate formaldehyde. As the load increased from 25% to 100%, the unburned methanol emissions decreased by 29%, and formaldehyde emissions decreased by 71%. This is mainly attributed to the enhanced oxidation reaction and reduced wall crevice effect due to the increased combustion temperature. Methanol injection timing optimization was effective in controlling unregulated emissions, with methanol emissions lower at -7° CA ATDC and formaldehyde emissions reaching larger values under this condition. Delaying the diesel injection to -16°CA ATDC led to a 38% increase in unburned methanol emissions, caused by fuel spray interactions and longer stagnation, whereas formaldehyde emissions showed minimal change.
Jiang, Yuqi, Li, Hongmei, Zhang, Wenzheng, Li, Xiao, Zheng, Liang, Meng, Yangqian, Gu, Xianan, Hua, Hanqing
Methanol use in marine engines has the potential to reduce nitrogen oxide emissions, particulates, and greenhouse gas emissions. A turbocharged four-stroke marine diesel powerplant was converted to run as a double-DI (direct injection) diesel-methanol hybrid engine. Experimental studies using a non-premixed combustion scheme showed that higher methanol substitution ratios (MSR) led to increased peak heat release rates. The combustion process displayed distinctive two-phase behaviors. Increasing MSR caused retarded ignition timing, shortened combustion duration, and improved thermal efficiency. Combustion stability was significantly improved at higher MSR. Emissions results showed NOX and HC were increased in proportion to MSR, whilst particulate emissions and CO concentrations were inversely reduced. Methanol enrichment was found to enhance NOX and HC formation processes but also accelerate soot particulate decomposition and CO oxidation mechanisms.
Li, Xiao, Jiang, Yuqi, Yan, Ping, Zheng, Liang, Li, Hongmei, Zhang, Wenzheng, Chen, Chao, Man, Zhongguo
The mitigation of Greenhouse Gas (GHG) emissions poses a major challenge for the transportation sector, driving the need for renewable fuels. Bioethanol represents a promising fuel for Spark-Ignition (SI) engines, combining a reduced life-cycle CO₂ impact with advantageous combustion properties. However, despite its proven performance under steady-state conditions, the widespread of fuels with high ethanol content is still constrained by significant difficulties during engine cold-start operation. This study aims to experimentally assess the effect of ethanol concentration on cold-start performance and warm-up transient behavior of a Naturally Aspirated (NA), Port Fuel Injected (PFI) SI engine. Warm-up tests were conducted at an operating condition of 2000 rpm engine speed and 20 Nm torque using three fuels with increasing ethanol content: commercial gasoline (E5), E30 and E60. In addition, dedicated startability tests were carried out for E60 and neat ethanol (E100) at different initial engine wall temperatures to evaluate fuel sensitivity to thermal conditions during engine start. The experimental results indicate that increasing ethanol concentration has a negligible effect on the overall duration of the warm-up process, while leading to a modest reduction in both engine wall and exhaust gas temperatures. At the same time, E100 displays severe startability limitations at low initial wall temperatures, requiring repeated cranking attempts before stable operation can be achieved. The same startability issues have been observed for E60 but with limited intensity. Two minimum engine wall temperature ranges were identified for reliable cold-start operation at 20-25 °C for E60 and 25-30°C for E100. Overall, these findings experimentally confirm the dominant influence of engine thermal conditions on the reliable startability of ethanol-fueled spark-ignition engines.
Falbo, Luigi, Falbo, Biagio, Perrone, Diego, Castiglione, Teresa
Biodiesel blends (B7, B20, B100) were evaluated in a Stage V-compliant SCR on Filter (SCRoF) system for heavy-duty applications to quantify soot reactivity and filter regeneration capability. Compared to conventional diesel (B7), B20 showed slightly faster regeneration performance under real-driving conditions, while B100 resulted in reduced particulate formation and higher soot reactivity, with more intense exothermic events requiring careful management. These differences are attributed to the distinct physical-chemical properties of the fuels (oxygen content, lower heating value) and their interaction with Diesel Oxidation Catalyst (DOC)/SCRoF. All tests were conducted on an engine dynamometer with a Cursor 9 FPT (Fiat Powertrain). Findings are discussed in the context of EU Stage V limits and practical control strategies for heavy-duty applications.
Costa, Simone
Ethanol requires elevated intake temperatures to initiate autoignition in Homogeneous Charge Compression Ignition (HCCI) as a high-octane single-stage fuel. To leverage the high thermal efficiency, low engine-out NOx, and near-zero soot inherent to HCCI with ethanol, a custom piston design was developed to enable high compression ratios (CR) up to 22.5:1. This study investigates HCCI combustion with ethanol at three CRs of 17.5, 20.0, and 22.5 through equivalence ratio and boost sweeps performed to assess the reduction in the intake temperature requirement at high CRs and the emissions and efficiency trade-offs. Results indicate a clear benefit with reduced intake temperature requirements with increasing CR. However, a combustion efficiency penalty was observed at high CRs. Three-dimensional Computational Fluid Dynamics (CFD) simulations were performed using Large Eddy Simulation (LES) coupled with a detailed chemistry model to investigate the underlying mechanisms of the combustion efficiency penalty. CFD results reveal that the combustion efficiency penalty at high CR is primarily due to increased crevice mass trapping unburned or partially oxidized species and a rapid expansion effect inhibiting complete carbon monoxide (CO) oxidation.
Vedpathak, Kunal, Kumar, Mohit, Motwani, Rahul, Datar, Aditya, Gainey, Brian, Lawler, Benjamin
The ongoing energy transition demands the decarbonization of the transport sector, for which the use of premixed hydrogen in spark-ignition (SI) engines appears very promising. However, modeling the combustion of the lean hydrogen/air mixtures required for safe, efficient, and low-NOx engine operation involves multiple open issues. Correct prediction of flame kernel initiation and growth is a difficulty that hydrogen shares with hydrocarbon fuels, while properly accounting for the instabilities that characterize lean hydrogen flames is an additional demanding task. In this work, a 1D kernel expansion model of general validity recently proposed by the authors is implemented into OpenFOAM, an open-source 3D CFD software package, to enable numerical simulation of expanding spark-ignited flame kernels. Firstly, the OpenFOAM framework is presented focusing on XiFluid, its flame propagation model based on a regress variable whose evolution depends on the laminar flame speed. Then, the authors’ kernel expansion model, based on the transient thermo-diffusive theory, is briefly recalled to highlight its capabilities and outputs. The coupling between OpenFOAM and authors’ model is split into two stages, namely ignition and expansion. During the ignition stage, an artificial profile of the regress variable is temporarily imposed to ensure a stable numerical solution, following which the kernel expansion is simulated by feeding into XiFluid an equivalent flame speed extracted from the 1D model. The coupling is currently formulated for laminar kernels, simulations of which are conducted firstly for conventional fuels (methane and propane) and then for hydrogen. The results are validated against outcomes of experimental tests performed in a constant-volume combustion chamber operated by engine manufacturer Wärtsilä. The validation is satisfactory for all fuels, although minor disagreements appear in case of intense flame stretch. These will be addressed in future developments, which will also extend this approach to unstable turbulent hydrogen flames in SI engines.
Dotteschini, Enrico, Pretto, Marco, Giannattasio, Pietro, Gadalla, Mahmoud
The reduction of Greenhouse Gas (GHG) emissions represents a key challenge for the transportation sector, requiring the adoption of renewable fuels capable of ensuring both environmental benefits and compatibility with existing internal combustion engine technologies. In this context, bioethanol emerges as a viable solution for Spark Ignition (SI) engines, offering a low life-cycle CO₂ footprint and favorable combustion characteristics. Nevertheless, despite its well-known advantages under steady-state operation, the widespread use of high-ethanol-content fuels is still limited by critical issues during engine cold start. The aim of this work is to experimentally investigate the influence of ethanol content on cold-start behavior and idle warm-up transient operation of a Naturally Aspirated (NA), Port Fuel Injected (PFI) SI engine. The experimental campaign was carried out under idle conditions using four fuels with increasing ethanol content, namely commercial gasoline (E5), E30, E60, and neat ethanol (E100). Cold-start and full warm-up tests were performed starting from ambient temperature, while additional dedicated experiments were conducted on E100 to evaluate startability under different initial engine wall temperatures. The results show that increasing ethanol content has a limited impact on the overall warm-up duration, while slightly reducing engine wall and exhaust gas temperatures. Conversely, E100 exhibits pronounced startability issues at low initial wall temperatures, requiring multiple cranking attempts to achieve stable idle operation. A minimum wall temperature threshold in the range of 25-30 °C was identified as necessary to ensure reliable cold start with E100. The outcomes of this study provide experimental evidence of the key role played by engine thermal conditions in enabling stable operation of ethanol fueled SI engines during cold start.
Falbo, Luigi, Falbo, Biagio, Perrone, Diego, Castiglione, Teresa
Regulators and policymakers have introduced increasingly stringent limits on tailpipe CO₂ and pollutant emissions to accelerate the decarbonization of heavy-duty vehicle applications. The development of innovative propulsion technologies — such as advanced combustion systems, low-friction reciprocating components, and improved aftertreatment solutions — combined with hybridization and the adoption of alternative fuels (e.g., biogas, HVO, green hydrogen), is a key pathway for meeting future emission and GHG targets. In this study, advanced combustion systems were developed for a 13-liter diesel engine for heavy-duty truck applications, with the objective of meeting forthcoming Euro VII regulations while maximizing thermal efficiency. The combustion system architecture—including open-bowl geometry with high aspect ratio, injector nozzle with wider spray opening angle, and reduced swirl ratio—was optimized using a Machine Learning–algorithm trained on high-fidelity 3D CFD combustion data. The method enabled the identification of two optimized combustion-system “recipes”, one of which was evaluated through engine tests, which refined nozzle specifications and injection strategies, using a structured Design of Experiments (DoE) approach. Results were benchmarked against a MY24 baseline combustion system, assessing efficiency, NOx–soot trade-offs, and combustion behaviors. Based on 3D-CFD results, the advanced combustion concept achieved an improvement in Brake Thermal Efficiency (BTE) of up to +0.8% points and delivered substantial NOx reductions of up to 45%, while maintaining smoke emissions at or below baseline levels. The experimental results indicate that the advanced combustion system developments designed for next-generation heavy-duty engines can further increase BTE by up to ~1% relative to the baseline combustion system, without deteriorating the soot–NOx trade-off.
Belgiorno, Giacomo, Centini, Maria Pia, Pezza, Vincenzo, Cozza, Ivan F., Pesce, Francesco C., Vassallo, Alberto, Colombo, Giovanni, Gallo, Alessandro, Mirzaeian, Mohsen, Borg, Jonathan
The global transport sector accounts for approximately 30 % of total final energy consumption and 15.9 % of worldwide greenhouse gas (GHG) emissions, with road transport alone accounting for the largest share at 11.8 %. Decarbonizing this sector requires energy sources that combine scalable generation from renewable sources with compatibility with various modes of transportation and existing infrastructure. Methanol and ethanol emerge as promising alternative energy carriers that can leverage existing logistics infrastructure while reducing dependence on fossil fuels. Global methanol production reached 112 million metric tons, and global ethanol production totaled approximately 93.5 million metric tons in 2024, compared to more than 2 billion metric tons of gasoline and diesel produced annually. The review assesses production pathways and cost trajectories for both alcohols, evaluates fuel requirements across multiple transport modes, including passenger vehicles, light- and heavy-duty vehicles, maritime shipping, aviation, and rail, and provides regulatory frameworks governing fuel standards in six major markets, the European Union, the USA, Brazil, China, Japan, and India. From a technical perspective, the internal combustion engine is examined in greater detail as the energy conversion system, synthesizing current combustion research on engine performance, emissions characteristics, and cold-start behavior. Current standards predominantly accommodate ethanol blending for spark-ignition (SI) engines in passenger vehicle applications, with permitted concentration limits ranging from 3 % in Japan to nearly pure ethanol in Brazil. Methanol applications remain more limited in road applications. In the maritime sector, recent ISO 8217:2024 specifications and International Maritime Organization (IMO) interim guidelines have established frameworks for the use of methanol and ethanol as marine fuels. Aviation remains the most restrictive sector, with alcohol fuels explicitly prohibited in certified aviation fuels due to material compatibility and safety concerns. To unlock the decarbonization potential of methanol and ethanol in the transport sector, coordinated policy support and continued technological innovation will be essential. As production scales and regulatory frameworks mature, both alcohol fuels may play an increasingly central role in the transition toward sustainable mobility.
Fitz, Patrick, Fellner, Felix, Rößlhuemer, Raphael, Härtl, Martin, Jaensch, Malte
Low-load natural gas–diesel reactivity controlled compression ignition (RCCI) in medium-speed marine engines is constrained by an insufficient charge thermal state. This limitation leads to partial fuel oxidation, producing high methane emissions. This work evaluates the use of negative valve overlap (NVO) combined with NVO diesel injection as an in-cylinder reactivity enhancement strategy. The simulation study was performed using the University of Vaasa’s advanced thermo-kinetic multi-zone model (UVATZ), extended for reactive simulations during NVO. The extended framework was validated against test-bench data from a prototype Wärtsilä 6L20 dual-fuel engine operating in RCCI mode. The baseline low-load operating point for reforming simulations was defined by reducing the intake manifold temperature to replicate conditions close to partial misfire with 52% combustion efficiency. The parametric sweeps of NVO injection timing and ratio showed that the strategy can be used for in-cycle fast thermal management, effectively restoring complete combustion on an individual cycle basis. In simulated conditions, the best performance was obtained with an NVO injection ratio of 0.3, with the injection scheduled before top dead center. In contrast, increasing the NVO fraction beyond ~0.3 provided no benefit and led to complete misfire due to excessive reduction of main-event high-reactivity fuel. The simulations revealed a coupled thermal–chemical control mechanism. Early NVO injections stabilize combustion through recompression heat release and an increased next-cycle intake valve closing temperature. Sufficiently late injections stabilize combustion by carrying unreacted diesel into the subsequent cycle. Injections near NVO TDC primarily undergo fuel conversion to CO, H2O, and unsaturated light/mid-range hydrocarbons with negligible thermal boost, yielding an overall reactivity deficit.
Soleimani, Amir, Nurmi, Mikael, Hunicz, Jacek, Kim, Jeyoung, Hyvonen, Jari, Mikulski, Maciej
How to ensure off-highway combustion systems operate with sufficient control to meet tightening emissions standards and evolving fuel landscapes without sacrificing reliability. Off-highway equipment is being asked to do more with less. Less margin for emissions, less tolerance for downtime and less room for inefficiency, while operating under some of the most demanding duty cycles in the transport sector. Tier 4 and Tier 5 emissions standards have reshaped engine calibration strategies. Renewable diesel and biodiesel blends are entering worksites and farms at scale. At the same time, construction, mining and agricultural machines are expected to run for 20-25 years, often at sustained high load and far from service infrastructure. In this environment, combustion systems are far from being phased out.
Anderson, Todd
We hear it often at industry events, in keynote speeches and during expert panel discussions: There is no silver bullet. Peter Voorhoeve, president of Volvo Trucks North America, says as much in this issue's Q&A (page 44). “Electric is one solution, but biodiesel is another solution, and hydrogen is, too. So we have these different fuel solutions to get to better sustainability.”
Gehm, Ryan
Against the backdrop of growing global demands for energy sustainability and stricter emission regulations for diesel engines, this study investigates the performance implications of incorporating cyclohexanol—a renewable oxygenated fuel—into diesel fuel blends. Using a marine medium-speed diesel engine as the experimental platform, the research systematically evaluates engine performance and emission characteristics across a range of cyclohexanol-diesel blend ratios under low, medium, and high load conditions. Experimental findings reveal multifaceted effects of cyclohexanol blending on engine operation. Combustion of the blended fuels enhances the engine’s dynamic performance, particularly under medium and high loads, where the maximum in-cylinder burst pressure exhibits a noticeable increase. This improvement is attributed to cyclohexanol’s oxygen-carrying capacity, which promotes more vigorous and sustained combustion reactions. In terms of emissions, increasing the proportion of cyclohexanol in the fuel blend leads to significant reductions in soot and carbon monoxide (CO) emissions, reflecting the cleaner-burning properties of the oxygenated component. However, this is accompanied by an uptick in nitrogen oxide (NOx) emissions, likely due to the elevated combustion temperatures generated by the more efficient fuel oxidation process. From an economic perspective, cyclohexanol blending at consistent load levels induces a postponement in the crank angle at which peak heat release occurs during combustion. This temporal shift prolongs the effective combustion duration, enabling more complete fuel utilization within the cylinder. Consequently, fuel consumption rates decrease, and overall engine efficiency improves, highlighting the potential of cyclohexanol blends to enhance operational economy in marine propulsion systems. In summary, this study underscores the complex trade-offs associated with cyclohexanol-diesel blends: while they offer tangible benefits in power output, fuel efficiency, and reduced particulate emissions, managing the increase in NOx emissions remains a critical challenge. The results provide a foundational framework for advancing biofuel applications in marine engines, emphasizing the need for integrated emission control strategies to optimize the balance between performance and environmental sustainability.
Chen, Ke, Yang, Chenxi, Wang, Yibin, Fan, Jinyu, Liu, Yuchen, Ye, Zixiao, Huang, Jialiang
Port fuel injection (PFI) is an attractive strategy for methanol adoption in both spark-ignition and dual-fuel compression-ignition engines due to its lower cost and simpler hardware compared to direct-injection. However, methanol PFI mixture formation can be challenging due to methanol’s high heat of vaporization, low volatility at cold conditions and high tendency to wall wetting. Understanding and addressing these challenges is critical to ensure robust engine operation. In this study, the effects of injector geometry, coolant temperature, intake temperature and fueling rate on mixture formation of methanol PFI have been investigated for anhydrous methanol and for a blend of 90%vol methanol plus 10%vol water in an optical engine. Mie scattering and infrared imaging were applied to assess the liquid and vapor methanol distribution in the cylinder. For a high-flow injector compatible with methanol, significant amounts of liquid were detected in the cylinder at all conditions tested, leading to poor mixing and high fuel stratification during the compression stroke. This effect was mitigated by using a multi-hole injector that promoted better atomization, indicating that high atomization is preferred over high flow for methanol PFI. The probability of detecting liquid in the cylinder decreased as the coolant temperature or the intake temperature increased or if the fueling rate decreased, with coolant temperature being the dominant parameter to control methanol vaporization. Liquid probability increased with water addition mainly because of the high heat capacity of water. Liquid methanol accumulated in the intake port, decreasing the effective engine intake temperature and limiting fuel vaporization. This accumulation led to a delay of the system response to changes in the PFI settings, with injected fuel requiring one cycle to reach the cylinder and additional 50 cycles required to completely flush the fuel accumulated in the port. Finally, the operating envelope for liquid-free operation was defined.
Lee, Sanguk, Narayanan, Abhinandhan
Paper considers the effects of fluid properties from liquified gases during high pressure pumping, at ranges from 200 to 1500 bar, and at speeds of 500 to 1500 rpm. Tests represent highest to date pressure ranges attained with liquified fluids such as DME. The paper examines the effects of compressibility on the pumping and resulting loading torque characteristics described over the pumping cycle as resolved by a high-fidelity sensor. Experimental tests and simulated performance based on a 1-D model are compared for Diesel and DME for a high-pressure fuel pump, piston style, featuring two plunger-barrels. Each of the pump’s plunger-barrel is inlet metered electronically, allowing the pump to run at a variable displacement and with the flexibility to deactivate one or both plungers fully. The model captures the response of the inlet metering valve and output valve lifts across speed and loads. The output check valve is subject to pressure pulsations and shows the importance to optimize its time response to stabilize it and thus provide optimal pumping. The model also captures the torque response, with contributions arising from the pressure loading, spring return force, and acceleration. Torque depends on the volume pumped, which conversely is dependent on pressure and compressibility. The volumetric efficiency is reduced as pressure increases, but the mechanical efficiency of output pressure-work over input torque remains high, between 80-90% in most of the pump operating conditions. Experimental torque measurements show close alignment with the simulations at elevated pump speeds and pressures but differences are noted at lower speeds. The deviations appear to arise from the outlet check valve stability and from the flow dynamics experienced at the pump inlet. These inlet dynamics were not properly captured in the model, but they are notable in the experimental results. Tests show significant variability in the pump pressure feed owing to the flow dynamics. Test results show this variability is reduced when the pump operates with two plunger-barrels rather than one. With one plunger-barrel the torque profile is notably cyclical, a high torque from one plunger is succeeded by a lower toque on the following plunger, while with the two plunger-barrels configuration the torque profile becomes more uniform from one plunger to the next.
de Ojeda, William, Wu, Simon (Haibao)
To mitigate global warming, many countries are working toward carbon neutrality. Reducing CO₂ emissions from vehicles requires electrification technologies in hybrid and plug-in hybrid electric vehicles (HEVs, PHEVs) and improving thermal efficiency of internal combustion engines (ICEs). Lean-burn combustion is one approach to improving ICE thermal efficiency. Biofuels and synthetic fuels can also reduce CO₂ emissions in existing vehicles. Ethanol, a bio-derived fuel, is widely used in varying contents worldwide, and its further utilization is anticipated. This study examines the effects of ethanol blending on emissions, thermal efficiency, knocking, and combustion speed in a super-lean-burn engine. Gasoline surrogates with varying ethanol contents were tested at an excess air ratio (λ) of 2.5. Higher ethanol content reduced nitrogen oxides (NOx) emissions due to lower adiabatic flame temperature. Total hydrocarbon (THC) emissions measured by a Flame Ionization Detector (FID) showed a decreasing trend; however, after correction for low sensitivity to ethanol and aldehydes, no significant differences were observed. Thermal efficiency increased with ethanol content, due to reduced cooling losses. Knocking was mitigated by the higher Research Octane Number (RON) from ethanol blending; however, the extent was smaller than in the production engine operating at λ = 1. This mechanism was examined through ignition delay calculations. At λ = 2.5 and in-cylinder pressures above 9 MPa, the 50–90% combustion duration was prolonged, attributable to suppressed ethyl radical formation under lean conditions and a greater influence of the reaction in which methyl radicals consume hydrogen atoms to produce methane under high-pressure conditions.
Sugata, Kenji, Matsubara, Naoyoshi, Yamada, Ryota, Kitano, Koji
This work demonstrates an initial proof-of-concept approach for operating a compression ignition off-road and marine relevant engine using neat methanol. The approach utilizes mixing controlled compression ignition (MCCI) of methanol that is enabled by a homogeneous charge compression ignition (HCCI) pre-burn of premixed dimethyl ether (DME). Although two fuels are used, this work explores and evaluates the opportunity and performance to generate the premixed fuel via methanol catalytic dehydration over an alumina catalyst at engine relevant temperatures, pressures, and space velocities. Conversion purity and species output results from catalytic dehydration bench flow reactor studies were coupled with single-cylinder experiments of the characterized output species for pre-burn HCCI performance. Subsequently, methanol MCCI performance is also evaluated and compared to conventional diesel combustion. The detailed flow reactor results show that the catalytic dehydration conversion efficiency of methanol to DME is a function of system pressure, temperature, and space velocity. The engine results demonstrate that a 100% conversion of methanol to DME is not required for successful pre-burn HCCI, and the water formed during the dehydration process does not need to be removed to achieve the desired HCCI event from this pre-burn mixture. Subsequent methanol MCCI combustion results show that the level of methanol slip in the dehydration process affects the pre-burn HCCI phasing, low temperature heat release process, and magnitude of energy release, all of which can dictate the available window for direct-injection of methanol for MCCI combustion. 1
Jatana, Gurneesh, Splitter, Derek, Park, Yeonshil, Szybist, James, Svensson, Kenth, Montgomery, David
Blending natural gas (NG) with hydrogen (H₂) can improve combustion and engine performance while potentially facilitating the catalytic conversion of methane and other pollutants, resulting in cleaner tailpipe emissions. This study evaluates the impact of H2 on the conversion of methane, CO, and NOx emissions on a commercial three-way catalyst (TWC) in a flow reactor using synthetic gas mixtures that simulate stoichiometric engine exhausts with NG or NG+H₂ combustion. The work examines whether, and how, the additional amount of H₂ in the exhaust stream affects the conversion efficiency of methane and other pollutants. Experiments were conducted with both degreened and aged catalysts under controlled conditions, systematically varying temperature, the air-to-fuel equivalence ratio (λ), and λ modulation. Test conditions covered λ values from 0.996 to 1.000 to represent nominally stoichiometric engine operation with different λ modulation amplitudes, as well as a range of temperatures to inform control strategies for effective CH₄, CO, and NOₓ reduction. Overall, the results show that hydrogen addition significantly improves the conversion efficiency of CH₄ and NOₓ, particularly at temperatures below 500 °C. More significantly, this study highlights that exhaust gas composition, operating temperature, λ management, and the oxygen storage capacity of the TWC all play major roles in affecting the tailpipe emissions from NG and NG+H₂ combustion.
Prikhodko, Vitaly, Wang, Min, Park, Yeonshil, Chen, Hai-Ying, Pihl, Josh
Methanol is one of the most readily produced e-fuels and remains in liquid form at ambient conditions, making storage and transportation relatively simple. In the marine sector, methanol has already been actively adopted as a pathway toward carbon neutrality. For automotive sectors, methanol offers significant potential for carbon emission reduction owing to its higher octane number and lower carbon content compared with gasoline. However, its high latent heat of vaporization and low vapor pressure suppress evaporation at low ambient temperatures, leading to increased emissions during cold-start operation. To address this issue, previous studies have explored heating the injector tip or fuel rail to enhance evaporation and atomization. The present study focuses on visualizing and quantifying the improvement in methanol evaporation characteristics under cold-start conditions by applying controlled heating to the injector tip. Experiments were conducted in a constant-volume chamber where the ambient temperature was carefully regulated, while a laterally mounted injector tip was subjected to different heating levels. Extinction images were acquired to determine spatial and temporal liquid volume fraction and to visualize spray morphology and penetration behavior for both methanol and gasoline surrogate fuel E00. Moreover, three-dimensional tomography reconstructed from extinction images taken at multiple viewing angles provided an in-depth assessment of methanol spray structure, droplet distribution, and evaporation behavior with varying injector tip temperatures under simulated cold-start conditions. These findings highlight the crucial role of injector thermal management in improving methanol-fueled engine performance during low-temperature operation.
Lee, Seungwon, Kim, Hyunsoo, Bae, Sumin, Hwang, Joonsik, Bae, Choongsik
E-methanol is increasingly seen as a promising clean fuel because its chemical makeup is close to fossil fuels, making it easier to use in existing engines. It offers a carbon-neutral option to help reduce greenhouse gases in sectors where cutting emissions is especially difficult, such as transportation. However, while e-methanol avoids adding new carbon dioxide, burning it in internal combustion engines still releases harmful gases like oxides of nitrogen (NOx) and other toxic by-products like formaldehyde and formic acid that damage both health and the environment. This report explores a new strategy that combines methanol with hydrogen to run engines under “ultra-lean” conditions and its impact on emissions, performance and efficiency. Experiments were carried out on a single-cylinder spark ignition engine, with directly injected methanol and port fuelled injection of hydrogen. The findings show that adding about 10% hydrogen (energy basis) at low engine loads can extend the lean limit from air-fuel equivalence ratio (λ) of 1.7 to 2. This change cut NOx emissions by 99% and reduced formaldehyde emissions by 18% compared to pure methanol operation at stoichiometric. Furthermore, the NOx emissions were reduced sufficiently that engine could operate within Euro 7 World Harmonic Stationary Cycle (WHSC) limits.
Ambalakatte, Ajith, Geng, Sikai, Cairns, Alasdair, Varaei, Amirata, Harrington, Anthony, Hall, Jonathan, Bassett, Mike, Cracknell, Roger
The market is witnessing an unprecedented proliferation of low-emission fuel components. To effectively evaluate the suitability of these novel fuels for engine applications, fuel blenders and original equipment manufacturers require rapid and reliable assessment methodologies. Traditionally, such evaluations rely on comprehensive engine testing, which, while thorough, is both time-intensive and costly. In response to the growing diversity of emerging fuel options, this work aims to establish a streamlined screening approach capable of effectively replicating the outcomes of full-scale engine testing. We examined the use of a constant volume combustion chamber for the measurement of fuel effects on NOx emissions, with the goal of developing a method to rapidly screen or rank fuels in a small - volume experiment. A small amount of fuel was injected into air at 650°C and 20 bar, where it ignited and burned. The chamber was sampled post-combustion using a chemiluminescence NOx analyzer. Extensive sampling method development was required to obtain repeatable results. Seven hydrocarbon fuels and two biodiesel fuels were tested, all of which have shown difference in NOx emissions in past engine studies. When using a single injection event to deliver the same amount of fuel energy, the test method could not clearly demonstrate the difference in NOx emissions between the hydrocarbon fuels as reported in engine combustion studies. Heat release rate analysis suggested this was caused by large differences in ignition delay and premixed burn fraction for the fuels tested. To improve this, a dual-injection strategy was used. It included a small “pilot” injection followed by a main injection, timed based on each fuel’s ignition delay to coincide with the pilot heat release. This strategy helped reduce differences in heat release caused by how quickly each fuel ignites. For hydrocarbon fuels, this approach revealed the expected relationship between NOx emissions and fuel type. Two soy biodiesel samples did not show higher NOx as observed in engine studies. This suggests that the current test method may not fully reflect engine conditions where biodiesel tends to produce more NOx. Further improvements in test method and setup are recommended to better align constant volume chamber conditions with engine conditions under which biodiesel shows increased NOx emissions.
Luecke, Jon, Rahimi, Mohammad, Mohamed, Samah, Naser, Nimal, Chausalkar, Abhijeet, McCormick, Robert
The increasing need to decarbonize the transport sector is accelerating the adoption of renewable and low-carbon fuels such as Hydrotreated Vegetable Oil (HVO) and biodiesel as sustainable substitutes for fossil diesel. These fuels are evaluated as drop-in solutions requiring no engine recalibration, enabling immediate GHG emission reduction in existing diesel fleets. This study experimentally investigates the combustion, performance, and emission characteristics of a turbocharged common-rail two-cylinder diesel engine (Kohler LWD 442 CRS) operated with conventional fossil Diesel, pure HVO (Hydrotreated Vegetable Oil), and an HVOB20 blend (80% HVO and 20% biodiesel produced from waste cooking oil and animal fats). Tests were carried out under steady-state conditions at the DIIEM Engine Laboratory of Roma Tre University. The analysis focused on in-cylinder pressure evolution, brake power, brake specific fuel consumption (BSFC), and both regulated and unregulated emissions. Regulated species include carbon monoxide (CO), nitrogen oxides (NOₓ) and particulate number concentration (PNC > 23 nm, PMP-compliant), while unregulated emissions cover non-methane hydrocarbons (NMHC), formaldehyde (HCHO), nitrous oxide (N₂O). CO and NMHC are key indicators of incomplete combustion: CO results from partial oxidation of carbon during fuel burning, and NMHC represents the fraction of unburned hydrocarbons excluding methane. Both pollutants decreased markedly with renewable fuels, indicating a more complete oxidation process promoted by HVO’s paraffinic composition and FAME’s oxygenated nature. Experimental results show that HVO and HVOB20 slightly increase brake torque and reduce BSFC compared with fossil diesel, despite their lower density and heating value. Combustion remained stable across all operating conditions, with negligible variations in ignition delay and pressure rise rate. NOₓ emissions were comparable or marginally higher at medium engine speeds, likely due to faster ignition and elevated combustion temperatures. Unregulated species such as HCHO and N₂O decreased or remained negligible with increasing renewable content, while PNC and count mean diameter (CMD) were significantly reduced, confirming cleaner combustion and reduced soot formation. Overall, both HVO and HVOB20 demonstrated improved combustion efficiency and emission performance while ensuring full engine operability without calibration adjustments. These findings confirm the technical viability of renewable diesel fuels as immediate, drop-in solutions for reducing GHG emissions.
Zaccai, Martina, Chiavola, Ornella, Palmieri, Fulvio, Verdoliva, Francesco
Stochastic Preignition (SPI) is an abnormal combustion phenomenon that can occur in spark-ignition engines particularly under high-load operation. SPI is characterized by uncontrolled initiation of combustion prior to spark discharge, an abnormal combustion process that can lead to severe knock events and significant engine damage. SPI has been associated with fuel properties, lubricant composition, and engine design and operation. In this work, a single-cylinder test engine with a dry-sump oil system was utilized to study the SPI response of E10 and E25 fuels with a range of Reid Vapor Pressure (RVP). An automated test procedure was employed, consisting of ten square-waved load profile segments, with each segment composed of 5 min of low-load operation followed by 25 min of sustained high-load operation. These tests were replicated across multiple days of testing including a lubricant triple flush between tests, and an online Fuel in Oil diagnostic measurement. Exhaust particulate emissions were continuously measured by an AVL microsoot sensor (MSS). Elevated particulate matter emissions were observed to occur concurrently with SPI events as blooms of soot. Particularly after clustered events (i.e., multiple SPI cycles occurring within 10 consecutive engine cycles), high soot emissions were observed to persist over several days of sequential operation despite daily lubricant changes, a complete warm-up procedure, and sustained low-load operation between test segments. This result implies that the particulate emissions trends may be dominated by deposit-based effects, where higher load operation is needed to alter deposition and formation processes. The observed soot blooms were also found to correspond to a reduction in the engine fueling and the fuel engine oil dilution rate despite the engine exhaust remaining at stoichiometric exhaust operation. These observations suggest that post-SPI events, pathways for lubricant migration and consumption into the combustion chamber may occur until these pathways are closed from deposit formation or ring dynamics during extended operation. These observed sooting propensity persisted with all fuels tests, but a linear correlation was observed between the summation of soot and particulate matter index (PMI) value for each fuel as well as SPI events, proving that PMI is a crucial fuel property for reducing SPI.1
Splitter, Derek, Jatana, Gurneesh, DelVescovo, Dan, Douvry-Rabjeau, Julien, Fioroni, Gina, Chapman, Elana, Salyers, John
Rail transportation in North America consumes over 4 billion gallons of diesel fuel [1]. This is raising energy security and supply chain resilience concerns. Adopting renewable or alternative fuels is a practical approach to reduce petroleum dependence and improve supply security. The objective of this paper is to investigate the combustion and emission characteristics of biodiesel and renewable diesel as drop-in fuels without engine modification. In this study, a single-cylinder, four-stroke locomotive engine was employed to investigate the combustion and emissions characteristics of four fuels: conventional diesel No. 2, plant-based biodiesel, animal-based biodiesel, and renewable diesel. The experimental campaign was carried out under both part-load and full-load operating conditions, with injection duration adjusted to achieve the targeted engine load and speed. Results indicate that both biodiesel fuels and renewable diesel deliver comparable peak in-cylinder pressure and brake thermal. efficiency relative to No. 2 diesel, demonstrating their possible use as drop-in fuels. Reductions in smoke emissions were observed for both biodiesels and renewable diesel fuels. However, plant-based and animal-based biodiesels both showed increases in NOx emissions under part-load conditions. At full load, elevated exhaust gas recirculation (EGR) ratios suppressed NOx formation across fuels, limiting assessment of biodiesel-specific NOx effects. Among the fuels tested, renewable diesel provided an additional advantage: reduced CO₂ emissions compared to both biodiesels. This study suggests that renewable diesel is a promising option for rail applications, combining operational performance comparable to petroleum diesel with reduced smoke and CO₂ emissions. Biodiesel, while effective at reducing smoke, may require further strategies to control NOx emissions.
Ewphun, Pop-Paul, Biruduganti, Munidhar, El-Hannouny, Essam, Longman, Douglas, Fu, Xiao, Subramanya, Raghavendra
Vehicle pollutant emissions are a major challenge in the development of internal combustion engines. To meet increasingly strict regulations, the automotive sector is exploring alternative fuels and lean-burn strategies. Methanol is gaining importance as a carbon-neutral fuel due to advances in green production technologies. Methanol, despite its potential for renewable production, faces severe limitations due to its inherent poor cold-start performance with conventional ignition systems. In this context, the present study aims to investigate the influence of pre-chamber ignition on cold-start combustion by using high-speed optical diagnostics to visualize flame propagation while simultaneously measuring in-cylinder pressure and engine performance. A major result concerns the significant cyclic variability of conventional spark ignition (SI) under cold-start conditions, which exhibits significant cyclic variability. Instead, passive pre-chamber ignition significantly enhances cold-start combustion stability, lowering CoV IMEP to below 3% at λ = 1.0 and sustaining stability under 5% even in ultra-lean conditions (λ = 1.6), where conventional SI operation fails. Flame visualization quantitatively confirms that this stability stems from distributed, multi-point ignition, which accelerates initial flame propagation by 3-4x compared to SI. These findings demonstrate that pre-chamber ignition can effectively overcome the traditional "cold-start" problem for methanol, enabling stable combustion from the first cycles. This provides an invaluable dataset for CFD model validation, as it captures a highly stable combustion process largely independent of the adverse thermal boundary conditions typical of cold start, thereby simplifying the modeling challenge.
Sementa, Paolo, Altieri, Nunzio, Tornatore, Cinzia
As part of the dTEC MORE project, sustainable powertrain technologies are being explored, including an alternative combustion concept tailored for engines in serial hybrid powertrains. Among the low-temperature combustion strategies, Reactivity-Controlled Compression Ignition (RCCI) is a prominent approach, offering significant reductions in NOx and soot emissions while enhancing combustion efficiency. The dual-fuel nature of RCCI enables improved control over combustion by utilizing fuels of differing reactivities. In this study, a premixed RCCI strategy was implemented using ethanol as a port-injected low-reactivity fuel and octanol as a directly injected high-reactivity fuel. The experimental work was conducted on a single-cylinder research engine with design features that are found in a gasoline passenger car application. Key combustion parameters such as the start of injection (SOI) of the high-reactivity fuel, injection pressure, intake temperature, lambda, premixed fuel ratio, and valve overlap were varied and evaluated on the engine test bench. The impact of these parameters on performance, combustion stability, and emissions was systematically analyzed. The results were benchmarked against a baseline direct-injected gasoline combustion cycle with a higher compression ratio. The comparison highlights the advantages of the premixed RCCI strategy, particularly in reducing NOx and soot emissions. Additionally, the test results also support in the future steps to model and validate the simulation models, to achieve higher efficiency and lower emissions.
Sundaram, Pravin Kumar, Grundl, Larissa Michaela, Trapp, Christian Thorsten, Tinschmann, Georg
Climate change and the depletion of fossil fuels have increased the need for renewable energy sources such as biodiesel. Biodiesel is an environmentally friendly fuel derived from various vegetable oils through a process known as transesterification. In this study, a new graphite-based heterogeneous catalyst was developed by modifying it Na2CO3, K2CO3, Al2O3 and was used for biodiesel production from linseed, cottonseed, sunflower, olive oils. Catalyst activity gradually decreased from 90.0 to 76.7% for cottonseed oil, from 93.0 to 76.0% for olive oil, from 95.0 to 77.0% for sunflower oil, and from 89.0 to 69.0% for linseed oil after the fourth operation. The fuel properties of the obtained biodiesel samples were investigated and the most favorable characteristics of cottonseed oil–based biodiesel were found to be d 4 20 = 0.8448, ν 40 = 3.3820, flash point of 93°C. Based on the X-ray broad peaks at 22.8° and 26.4°, we can note that after the four-time reaction cycle, the structure of the catalyst was destroyed to expanded and pure graphite with the loss of catalytic activity. Additionally, the influence of the amount of oleic, linoleic, linolenic, and saturated acyl groups in oil samples on exploitation properties was investigated by NMR spectroscopy.
Mamedov, Ibrahim, Mamedova, Gulben, Mamedova, Yegana
Sodium-ion batteries (SIBs) are becoming a strong candidate for large-scale energy storage applications due to their cost-effectiveness and abundant sodium resource reserves. Ether solvents have advantages such as excellent low-temperature performance and good reduction stability. However, poor oxidation stability limits the use of ether-based electrolytes, which need to be addressed urgently. In this study, 1 M sodium tetrafluoroborate (NaBF4) and 0.05 M sodium difluoro(oxalato)borate (NaDFOB) were added in tetraethylene glycol dimethyl ether (G4), which is named “BDG4”. BDG4 electrolyte can promote the formation of cathode electrolyte interface (CEI) layers containing NaF and B─O/B─Na inorganic components on the surface of the cathode. The dense CEI layers can prevent the solvent from undergoing oxidation reactions. Therefore, thanks to the lower highest occupied molecular orbital (HOMO) energy level of G4 and its close coordination structure with Na+, the electrolyte has a high-voltage stability exceeding 4.5 V versus Na+/Na. Therefore, BDG4 electrolyte can be stably cycled on Na3(VO)2(PO4)2F (NVOPF) and NaNi1/3Fe1/3Mn1/3O2 (NFM) cathode for over 250 cycles at room temperature, exhibiting a high Coulombic Efficiency (CE) exceeding 99.8%. Furthermore, BDG4 demonstrated excellent rate performance of NFM cathode, maintaining 75% capacity retention even at 4 C. Due to the stable solid electrolyte interface (SEI) layers formed by the mixture of inorganic and organic components, BDG4 electrolyte can also cycle stably on the Hard Carbon (HC) anode. Therefore, the commercial NFM||HC pouch full cell can cycle stably with 88.3% capacity retention after 80 cycles. This work reveals the role of NaDFOB and provides a feasible approach for the design of high-voltage ether electrolytes of SIBs.
Bai, Zheng, Mai, Xinyu, Dou, Xin, Chen, Zixin, Song, Zhen, Chen, Long, Li, Chunzhong
Fuel adulteration affects operating costs, vehicle efficiency, and air pollution. Published estimates suggest it accounts for at least 10% of global sales. The Brazilian National Petroleum Agency (ANP) reported noncompliance in about 23% of inspections in 2023, including 4.3% confirmed adulteration. Quality verification requires laboratory equipment, and sensor-based approaches are often inaccessible to end consumers. This article proposes a sensorless (software-only) method that detects water adulteration in hydrated ethanol from standard Onboard Diagnostics (OBD) data using supervised machine learning, enabling on-vehicle fuel quality monitoring without additional hardware. The proposed approach is evaluated on real-world driving data from two production vehicles with three water adulteration levels in hydrated ethanol (0.0%, 2.5%, and 5.0%), achieving 84.85%–95.85% multiclass classification accuracy. These results indicate that software-only, OBD-based monitoring can provide a practical solution for in-use fuel quality control.
Marchezan, Andre Ricardo, Giesbrecht, Mateus
In this study, the combustion and emission characteristics of a single-cylinder direct injection (DI) diesel engine fueled with Spirulina biodiesel along with diesel blends were examined using a combined CFD and thermodynamic simulation framework. Three test fuels, including pure diesel (D100), Spirulina biodiesel blends (B20 and B40), and pure Spirulina biodiesel (B100), were analysed at 1500 rpm under full load. In the first stage, CFD simulations were performed in ANSYS Fluent, where the Discrete Phase Model (DPM) was applied to capture spray atomization and droplet evaporation, while a non-premixed combustion model coupled with the RNG k-ε turbulence model was employed to resolve in-cylinder flow and heat release dynamics. Subsequently, the Diesel-RK software was utilised to predict engine performance and exhaust emissions based on compression ratios (18.5) and injection timings. Results from the CFD analysis revealed faster atomization and reduced ignition delay for biodiesel blends compared with pure diesel, supported by enhanced cylinder pressure development. Diesel-RK simulations indicated that Spirulina biodiesel blends (B20) generally improved brake thermal efficiency at higher compression ratios while increasing brake specific fuel consumption due to their lower calorific value. Emission analysis showed consistent reductions in CO, HC, and smoke capacity with higher biodiesel content, while NOx emissions exhibited a rising trend. The findings confirm Spirulina biodiesel (B20) as a viable renewable fuel and highlight simulation-driven strategies for optimising compression ratio and injection timing in CI engines..
Kumar, B Varun
This study investigates the potential of using a dual green alternative fuel combination, the one is hydrogen fuel and another one is biodiesel for enhancing the Performance, combustion and emission profile of a compression ignition engine. The kapok oil biodiesel was blended with Diesel in proportions of 20% (K20) and 40% (K40) by volume. The hydrogen gas was supplied at a constant flow of 4 liter per minute (LPM). The experimental fuels are neat diesel D100, K20 (80% Diesel and 20 % kapok methyl ester), K40 (60% Diesel + 40 % Kapok methyl ester), K20 + H4L (K20 with 4 LPM hydrogen) and K40+H4L (K40 with 4 LPM hydrogen). These test blends are investigated in a single cylinder direct injection CI engine under 0% to 100% load conditions at a fixed speed of 1500 rpm combustion, and emissions characteristic were evaluated and compared with base fuel. The outcomes indicated that the use of B20 and B40 blends without hydrogen led to reduced BTE because of their lower cetane number and calorific value. Additionally, higher viscosity of the blends resulted in increased BFSC. However, the introduction of hydrogen and the K20H fuel blend demonstrated notable emission improvements compared to conventional diesel, achieving reductions of 9–11% in unburned hydrocarbons, 5.3% in carbon monoxide, and approximately 8% in nitrogen oxides (NOₓ). These findings highlight the potential of K20H as a cleaner alternative fuel.
Anbarasan, B, M, Kumaresan, Balamurugan, S, Rajesh, Munnusamy
The integration of ethanol into gasoline presents compatibility challenges for automotive fuel-system materials. In this study, the degradation of NBR-PVC fuel hoses exposed to ethanol-gasoline blends (E30, E50, E70, and E100) was investigated under dynamic flow conditions. A custom-designed test rig simulates real-time fuel circulation for 1,200 h. FESEM, ATR-FTIR, and elemental mapping analyses revealed ethanol-induced degradation, including dehydrochlorination, plasticizer leaching, and filler detachment. Among the blends, E30 exhibited the least material degradation, whereas E100 showed significant surface damage and chemical alteration. This study recommends multilayered fuel hose structures with ethanol-resistant inner linings for enhanced durability.
PC, Murugan, L S, Adhitya, G, Arun Prasad, W, Beno Wincy, T, Karthi
Rolls-Royce has successfully tested the world's first high-speed marine engine powered exclusively by methanol on its test bench in Friedrichshafen, Germany. The company began this engine-development journey six years ago when it gathered experts to determine what the future fuel of the maritime industry should be, according to Denise Kurtulus, senior vice president of global marine at Rolls-Royce. “For us, it's clear. It's methanol,” she said. Rolls-Royce worked with industry partners as part of the joint project meOHmare, which is funded by the German Federal Ministry for Economic Affairs and Energy. Injection system specialist Woodward L'Orange and the WTZ Roßlau technology and research center contributed their expertise. Their goal was to not only develop a comprehensive concept for a CO2-neutral marine engine based on green methanol, but also to run it on the test bench by the end of 2025.
Gehm, Ryan
Increasing ethanol blending in gasoline is significant from both financial (reducing dependency on crude oil) and sustainability (overall CO2 reduction) points of view. Flex Fuel is an ethanol-gasoline blend containing ethanol ranging from 20% to 85%. Flex Fuel emerges as an exceptionally advantageous solution, adeptly addressing the shortcomings associated with both gasoline and ethanol. Performance optimization of Flex Fuel is a major challenge as fuel properties like knocking tendency, calorific value, vapour pressure, latent heat, and stoichiometric air-fuel ratio change with varying ethanol content. This paper elaborates on the experimental results of trials conducted for optimizing engine performance with Flex Fuel for a 2-cylinder engine used in a small commercial vehicle. To derive maximum benefit from the higher octane rating of E85, the compression ratio is increased, while ignition timing is optimized to avoid knocking with E20 fuel. For intermediate blends, ignition timing is suitably interpolated. Fuel injection pressure is increased to address the higher fuel flow requirement, and a fuel heater is added to address cold starts with E85 fuel. Ethanol content detection is done through software, and by suitable interpolation, fuelling and ignition timing are optimized for the entire range of Flex Fuel in a single calibration file. Engine performance with E20 & E93 fuel is optimized considering all mechanical and thermal limits of the engine through various iterations. The experimental results are analysed using the first principle method.
Kulkarni, Deepak, Malekar, Hemant A, Upadhyay, Rajdip, Katkar, Santosh, Undre, Shrikant
India being highly populated and developing country, the demand for various alternative fuel is increasing drastically. It is driven by the need to reduce dependency on traditional fossil fuels & reduce impact on environmental issues like Greenhouse gas, emissions & pollution. The potential options, CNG (Compressed Natural Gas) & Biodiesel, are becoming increasingly popular and important. Biodiesel, a renewable fuel which is produced from waste materials & crops which grown repeatedly & easily available while CNG is more sustainable than diesel as natural gas is a cleaner-burning fossil fuel in comparison to coal or oil. This paper will focus on comparison between basic properties of Diesel, CNG & Biodiesel. In this study will also focus on survey of various Government initiatives, policies & infrastructural development which are evolving to encourage the usage of CNG & Biodiesel. These fuels are emerging as promising alternative contenders to traditional diesel. It has the potential to reduce carbon footprints, making them environment friendly & more sustainable energy options. This survey also summaries the industry motivation from govt initiatives to promote the aim of cleaner transportation & its transition towards future sustainable energy. This study presents a comparative journey of CNG & Biodiesel in India. Key parameters like fuel properties, feedstocks and its availability, storage and handling, product integration, emissions and endurance performance assessments, customer acceptability etc. are considered for understanding these fuels in a better way. Also, it will highlight the key bottlenecks, technical challenges & the obstacles hindering the widespread adoption of Biodiesel as compared to CNG. The paper also elaborates the challenges on sustainability of biodiesel and CNG fuels and the futuristic opportunities in carbon neutral fuels like H2. The paper concludes with the comparative study of CNG & Biodiesel on various aspects from ideation to execution.
Bondada, Nandita, Baruah, Labanya, Mokhadkar, Rahul
The Government of India has mandated biofuel blending in automotive fuels to reduce crude oil imports and support the national economy. As part of this initiative, Oil Marketing Companies (OMCs) have begun nationwide blending of E20 fuel (20% ethanol in petrol). Ethanol supply is expected to exceed demand by the end of 2025 due to initiatives like the Pradhan Mantri JI-VAN Yojana. Alternative applications for ethanol are being explored; one promising approach is its use as a co-blend with diesel fuel (ED blends). However, ethanol’s low cetane number and poor lubricity pose challenges for direct use in diesel engines without modifications. ED blends demonstrated reduced emissions while maintaining performance comparable to conventional diesel. To further address concerns related to materials compatibility of ED blends with fuel system components, particularly plastomers that may impact engine durability, a detailed study was conducted using elastomers such as FVMQ, FKM, HNBR, and NBR in accordance with the SAE J1748. Test specimens were immersed in ED blends and conventional diesel at 55°C for 1008 hours. Key physical and mechanical properties were measured before and after the immersion tests. The results revealed that FVMQ, FKM and HNBR demonstrated comparable durability when exposed to ED blends vis-à-vis diesel, whereas NBR performed better only in conventional diesel. SEM analysis of the specimens showed significate surface degradation in NBR, supporting the mechanical test results. Although ED blends exhibited changes in fuel properties such as flash point and water content, the blends remained stable under ambient storage conditions.
Johnpeter, Justin P, Chakrahari, Kiran, Chakradhar, Maya, Arora, Ajay, Prakash, Shanti, Pokhriyal, Naveen Kumar
Today, passenger car makers around the world are striving to meet the increasing demand for fuel economy, high performance, and silent engines. Corporate Average Fuel Economy (CAFE) regulations implemented in India to improve the fuel efficiency of a manufacturer's fleet of vehicles. CAFE goal is to reduce fuel consumption and, by extension, the emissions that contribute to climate change. CNG (Compressed Natural Gas) engines offer several advantages that help manufacturers meet and exceed these standards. The demand for CNG vehicles has surged exponentially in recent years, CNG engine better Fuel efficiency and advantage in CAFÉ norms make good case for OEM & Customer to use more CNG vehicle. CNG is dry fuel compared to gasoline. These dry fuels lack lubricating properties, unlike conventional fuels like petrol, diesel and biofuels, which are wet and liquid. Consequently, the operations and failures associated with these fuels differ. The materials and designs of engine parts, such as fuel lines, ECU, exhaust valves, and cylinder heads, vary depending on the fuel used. In CNG engine most challenging issue is leakage at Valve seat and Valve face interface causing unstable combustion and power drop. This study discusses the countermeasures adopted to address the high valve face, Valve guide and valve seat wear in cylinder heads and engine valves. The investigation focuses on material, design, and manufacturing process improvements specially for Exhaust valve, supported by part-level and vehicle-level validation and testing for CNG exhaust valves and cylinder heads.
Poonia, Sanjay, Kumar, Chandan, Sharma, Shailender, Khan, Prasenjit, Bhat, Anoop, P, Prasath, Neb, Ashish
On the way to net zero emissions and to cut the oil import bills, NITI Aayog, Government of India and Ministry of Petroleum & Natural Gas (MoP&NG) has rolled out roadmap for ethanol blending in India during 2020-2025. Also, National Policy on Biofuels – 2018, provides an indicative target of 20% ethanol blending under the Ethanol Blended Petrol (EBP) Programme by 2030. Considering these Government’s initiatives current studies were performed on BSVI compliant gasoline direct injection vehicle on RDE compliant route (Route formulated by Indian Oil R&D Centre) with different ethanol blended gasoline fuel formulations i.e., E0 (Neat Gasoline), E10 (10% Ethanol in gasoline) & E20 (20% Ethanol in gasoline). The study aims to determine the compliance of Conformity Factor (C.F.) for ethanol blended gasoline fuel on Direct Injection gasoline engine. The conformity factors were calculated in each case for CO, NOx & PN using moving window average evaluation method. For reference CO2 characteristics curve, CO2 values were measured over Modified Indian Driving Cycle (MIDC) on chassis dynamometer. The study suggests that the use of oxygenated fuel formulations (E10 & E20) impacts tail pipe emissions in a greater way and without any change in the hardware of after treatment devices of the vehicle tail pipe emissions can be reduced. Paper presents RDE as well laboratory mass emissions data collected. However, all the emission values are well below the typical BSVI/Euro6d limits and the C.F for NOx is also below than stated limit of BS_2.0 IRDE (Indian Real Driving Emissions).
Kant, Chander, Arora, Ajay, Saroj, Shyamsher, Kumar, Prashant, Sithananthan, M, Chakradhar, Dr Maya, Kalita, Mrinmoy
In alignment with its carbon reduction commitments, India is transitioning towards higher ethanol-blended fuels, with E20 set for nationwide implementation by 2025. Ethanol is a renewable, domestically produced biofuel produced through fermentation of biomass such as sugarcane, corn. It possesses a higher octane rating and oxygen content compared to conventional gasoline, making it a favorable additive for improving engine performance and reducing emissions. This study investigates the impact of E20 fuel on performance parameters of a 694 cc MPFI , water-cooled, twin-cylinder gasoline engine. For deriving maximum benefits of increased Octane rating of E20, compression ratio was increased to 12.5:1. Experimental analysis was conducted to assess the changes in combustion behavior, brake specific fuel consumption (BSFC), torque output, engine out emissions and thermal efficiency when operating on E20 compared to baseline gasoline (E10). Base results indicate that E20 promotes more efficient combustion, owing to its higher laminar flame speed and elevated oxygen content, leading to a 3–4% improvement in low-end torque across real-world operating speed ranges. Conversely, on-road evaluations reveal a 3–4% fuel economy penalty with E20 relative to E10. Recovering E10-comparable fuel efficiency with E20 necessitates comprehensive engine calibration optimization, supported by targeted hardware modifications. Additionally, the high octane rating of ethanol reduces knock propensity, enabling the adoption of more aggressive ignition timing and higher compression ratios without compromising engine durability. Thermal benefits are also taken into consideration, with a reduction in peak mid-catalyst temperatures by approximately 30–40°C, this enables stoichiometric operation throughout operating range without any enrichment. These improvements suggest that engines calibrated specifically for E20 can be benefited through fuel’s inherent properties to achieve higher thermal efficiency and lower tailpipe emissions. In conclusion, the incorporation of E20 fuel in internal combustion engines shows notable advancements in engine performance and efficiency.
Kulkarni, Deepak, Malekar, Hemant A, Thonge, Ravindra, Kanchan, Shubham
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