Browse Topic: Biofuels

Items (4,256)
Paper considers the effects of fluid properties from liquified gases during high pressure pumping, at ranges from 200 to 1500 bar, and at speeds of 500 to 1500 rpm. Tests represent highest to date pressure ranges attained with liquified fluids such as DME. The paper examines the effects of compressibility on the pumping and resulting loading torque characteristics described over the pumping cycle as resolved by a high-fidelity sensor. Experimental tests and simulated performance based on a 1-D model are compared for Diesel and DME for a high-pressure fuel pump, piston style, featuring two plunger-barrels. Each of the pump’s plunger-barrel is inlet metered electronically, allowing the pump to run at a variable displacement and with the flexibility to deactivate one or both plungers fully. The model captures the response of the inlet metering valve and output valve lifts across speed and loads. The output check valve is subject to pressure pulsations and shows the importance to optimize
de Ojeda, WilliamWu, Simon (Haibao)
Blending natural gas (NG) with hydrogen (H₂) can improve combustion and engine performance while potentially facilitating the catalytic conversion of methane and other pollutants, resulting in cleaner tailpipe emissions. This study evaluates the impact of H2 on the conversion of methane, CO, and NOx emissions on a commercial three-way catalyst (TWC) in a flow reactor using synthetic gas mixtures that simulate stoichiometric engine exhausts with NG or NG+H₂ combustion. The work examines whether, and how, the additional amount of H₂ in the exhaust stream affects the conversion efficiency of methane and other pollutants. Experiments were conducted with both degreened and aged catalysts under controlled conditions, systematically varying temperature, the air-to-fuel equivalence ratio (λ), and λ modulation. Test conditions covered λ values from 0.996 to 1.000 to represent nominally stoichiometric engine operation with different λ modulation amplitudes, as well as a range of temperatures to
Prikhodko, VitalyWang, MinPark, YeonshilChen, Hai-YingPihl, Josh
Methanol is one of the most readily produced e-fuels and remains in liquid form at ambient conditions, making storage and transportation relatively simple. In the marine sector, methanol has already been actively adopted as a pathway toward carbon neutrality. For automotive sectors, methanol offers significant potential for carbon emission reduction owing to its higher octane number and lower carbon content compared with gasoline. However, its high latent heat of vaporization and low vapor pressure suppress evaporation at low ambient temperatures, leading to increased emissions during cold-start operation. To address this issue, previous studies have explored heating the injector tip or fuel rail to enhance evaporation and atomization. The present study focuses on visualizing and quantifying the improvement in methanol evaporation characteristics under cold-start conditions by applying controlled heating to the injector tip. Experiments were conducted in a constant-volume chamber where
Lee, SeungwonKim, HyunsooBae, SuminHwang, JoonsikBae, Choongsik
Rail transportation in North America consumes over 4 billion gallons of diesel fuel [1]. This is raising energy security and supply chain resilience concerns. Adopting renewable or alternative fuels is a practical approach to reduce petroleum dependence and improve supply security. The objective of this paper is to investigate the combustion and emission characteristics of biodiesel and renewable diesel as drop-in fuels without engine modification. In this study, a single-cylinder, four-stroke locomotive engine was employed to investigate the combustion and emissions characteristics of four fuels: conventional diesel No. 2, plant-based biodiesel, animal-based biodiesel, and renewable diesel. The experimental campaign was carried out under both part-load and full-load operating conditions, with injection duration adjusted to achieve the targeted engine load and speed. Results indicate that both biodiesel fuels and renewable diesel deliver comparable peak in-cylinder pressure and brake
Ewphun, Pop-PaulBiruduganti, MunidharEl-Hannouny, EssamLongman, DouglasFu, XiaoSubramanya, Raghavendra
To mitigate global warming, many countries are working toward carbon neutrality. Reducing CO₂ emissions from vehicles requires electrification technologies in hybrid and plug-in hybrid electric vehicles (HEVs, PHEVs) and improving thermal efficiency of internal combustion engines (ICEs). Lean-burn combustion is one approach to improving ICE thermal efficiency. Biofuels and synthetic fuels can also reduce CO₂ emissions in existing vehicles. Ethanol, a bio-derived fuel, is widely used in varying contents worldwide, and its further utilization is anticipated. This study examines the effects of ethanol blending on emissions, thermal efficiency, knocking, and combustion speed in a super-lean-burn engine. Gasoline surrogates with varying ethanol contents were tested at an excess air ratio (λ) of 2.5. Higher ethanol content reduced nitrogen oxides (NOx) emissions due to lower adiabatic flame temperature. Total hydrocarbon (THC) emissions measured by a Flame Ionization Detector (FID) showed a
Sugata, KenjiMatsubara, NaoyoshiYamada, RyotaKitano, Koji
Stochastic Preignition (SPI) is an abnormal combustion phenomenon that can occur in spark-ignition engines particularly under high-load operation. SPI is characterized by uncontrolled initiation of combustion prior to spark discharge, an abnormal combustion process that can lead to severe knock events and significant engine damage. SPI has been associated with fuel properties, lubricant composition, and engine design and operation. In this work, a single-cylinder test engine with a dry-sump oil system was utilized to study the SPI response of E10 and E25 fuels with a range of Reid Vapor Pressure (RVP). An automated test procedure was employed, consisting of ten square-waved load profile segments, with each segment composed of 5 min of low-load operation followed by 25 min of sustained high-load operation. These tests were replicated across multiple days of testing including a lubricant triple flush between tests, and an online Fuel in Oil diagnostic measurement. Exhaust particulate
Splitter, DerekJatana, GurneeshDelVescovo, DanDouvry-Rabjeau, JulienFioroni, GinaChapman, ElanaSalyers, John
The increasing need to decarbonize the transport sector is accelerating the adoption of renewable and low-carbon fuels such as Hydrotreated Vegetable Oil (HVO) and biodiesel as sustainable substitutes for fossil diesel. These fuels are evaluated as drop-in solutions requiring no engine recalibration, enabling immediate GHG emission reduction in existing diesel fleets. This study experimentally investigates the combustion, performance, and emission characteristics of a turbocharged common-rail two-cylinder diesel engine (Kohler LWD 442 CRS) operated with conventional fossil Diesel, pure HVO (Hydrotreated Vegetable Oil), and an HVOB20 blend (80% HVO and 20% biodiesel produced from waste cooking oil and animal fats). Tests were carried out under steady-state conditions at the DIIEM Engine Laboratory of Roma Tre University. The analysis focused on in-cylinder pressure evolution, brake power, brake specific fuel consumption (BSFC), and both regulated and unregulated emissions. Regulated
Zaccai, MartinaChiavola, OrnellaPalmieri, FulvioVerdoliva, Francesco
The market is witnessing an unprecedented proliferation of low-emission fuel components. To effectively evaluate the suitability of these novel fuels for engine applications, fuel blenders and original equipment manufacturers require rapid and reliable assessment methodologies. Traditionally, such evaluations rely on comprehensive engine testing, which, while thorough, is both time-intensive and costly. In response to the growing diversity of emerging fuel options, this work aims to establish a streamlined screening approach capable of effectively replicating the outcomes of full-scale engine testing. We examined the use of a constant volume combustion chamber for the measurement of fuel effects on NOx emissions, with the goal of developing a method to rapidly screen or rank fuels in a small - volume experiment. A small amount of fuel was injected into air at 650°C and 20 bar, where it ignited and burned. The chamber was sampled post-combustion using a chemiluminescence NOx analyzer
Luecke, JonRahimi, MohammadMohamed, SamahNaser, NimalChausalkar, AbhijeetMcCormick, Robert
Port fuel injection (PFI) is an attractive strategy for methanol adoption in both spark-ignition and dual-fuel compression-ignition engines due to its lower cost and simpler hardware compared to direct-injection. However, methanol PFI mixture formation can be challenging due to methanol’s high heat of vaporization, low volatility at cold conditions and high tendency to wall wetting. Understanding and addressing these challenges is critical to ensure robust engine operation. In this study, the effects of injector geometry, coolant temperature, intake temperature and fueling rate on mixture formation of methanol PFI have been investigated for anhydrous methanol and for a blend of 90%vol methanol plus 10%vol water in an optical engine. Mie scattering and infrared imaging were applied to assess the liquid and vapor methanol distribution in the cylinder. For a high-flow injector compatible with methanol, significant amounts of liquid were detected in the cylinder at all conditions tested
Lee, SangukNarayanan, Abhinandhan
E-methanol is increasingly seen as a promising clean fuel because its chemical makeup is close to fossil fuels, making it easier to use in existing engines. It offers a carbon-neutral option to help reduce greenhouse gases in sectors where cutting emissions is especially difficult, such as transportation. However, while e-methanol avoids adding new carbon dioxide, burning it in internal combustion engines still releases harmful gases like oxides of nitrogen (NOx) and other toxic by-products like formaldehyde and formic acid that damage both health and the environment. This report explores a new strategy that combines methanol with hydrogen to run engines under “ultra-lean” conditions and its impact on emissions, performance and efficiency. Experiments were carried out on a single-cylinder spark ignition engine, with directly injected methanol and port fuelled injection of hydrogen. The findings show that adding about 10% hydrogen (energy basis) at low engine loads can extend the lean
Ambalakatte, AjithGeng, SikaiCairns, AlasdairVaraei, AmirataHarrington, AnthonyHall, JonathanBassett, MikeCracknell, Roger
This work demonstrates an initial proof-of-concept approach for operating a compression ignition off-road and marine relevant engine using neat methanol. The approach utilizes mixing controlled compression ignition (MCCI) of methanol that is enabled by a homogeneous charge compression ignition (HCCI) pre-burn of premixed dimethyl ether (DME). Although two fuels are used, this work explores and evaluates the opportunity and performance to generate the premixed fuel via methanol catalytic dehydration over an alumina catalyst at engine relevant temperatures, pressures, and space velocities. Conversion purity and species output results from catalytic dehydration bench flow reactor studies were coupled with single-cylinder experiments of the characterized output species for pre-burn HCCI performance. Subsequently, methanol MCCI performance is also evaluated and compared to conventional diesel combustion. The detailed flow reactor results show that the catalytic dehydration conversion
Jatana, GurneeshSplitter, DerekPark, YeonshilSzybist, JamesSvensson, KenthMontgomery, David
As part of the dTEC MORE project, sustainable powertrain technologies are being explored, including an alternative combustion concept tailored for engines in serial hybrid powertrains. Among the low-temperature combustion strategies, Reactivity-Controlled Compression Ignition (RCCI) is a prominent approach, offering significant reductions in NOx and soot emissions while enhancing combustion efficiency. The dual-fuel nature of RCCI enables improved control over combustion by utilizing fuels of differing reactivities. In this study, a premixed RCCI strategy was implemented using ethanol as a port-injected low-reactivity fuel and octanol as a directly injected high-reactivity fuel. The experimental work was conducted on a single-cylinder research engine with design features that are found in a gasoline passenger car application. Key combustion parameters such as the start of injection (SOI) of the high-reactivity fuel, injection pressure, intake temperature, lambda, premixed fuel ratio
Sundaram, Pravin KumarGrundl, Larissa MichaelaTrapp, Christian ThorstenTinschmann, Georg
Climate change and the depletion of fossil fuels have increased the need for renewable energy sources such as biodiesel. Biodiesel is an environmentally friendly fuel derived from various vegetable oils through a process known as transesterification. In this study, a new graphite-based heterogeneous catalyst was developed by modifying it Na2CO3, K2CO3, Al2O3 and was used for biodiesel production from linseed, cottonseed, sunflower, olive oils. Catalyst activity gradually decreased from 90.0 to 76.7% for cottonseed oil, from 93.0 to 76.0% for olive oil, from 95.0 to 77.0% for sunflower oil, and from 89.0 to 69.0% for linseed oil after the fourth operation. The fuel properties of the obtained biodiesel samples were investigated and the most favorable characteristics of cottonseed oil–based biodiesel were found to be d 4 20 = 0.8448, ν 40 = 3.3820, flash point of 93°C. Based on the X-ray broad peaks at 22.8° and 26.4°, we can note that after the four-time reaction cycle, the structure of
Mamedov, IbrahimMamedova, GulbenMamedova, Yegana
Fuel adulteration affects operating costs, vehicle efficiency, and air pollution. Published estimates suggest it accounts for at least 10% of global sales. The Brazilian National Petroleum Agency (ANP) reported noncompliance in about 23% of inspections in 2023, including 4.3% confirmed adulteration. Quality verification requires laboratory equipment, and sensor-based approaches are often inaccessible to end consumers. This article proposes a sensorless (software-only) method that detects water adulteration in hydrated ethanol from standard Onboard Diagnostics (OBD) data using supervised machine learning, enabling on-vehicle fuel quality monitoring without additional hardware. The proposed approach is evaluated on real-world driving data from two production vehicles with three water adulteration levels in hydrated ethanol (0.0%, 2.5%, and 5.0%), achieving 84.85%–95.85% multiclass classification accuracy. These results indicate that software-only, OBD-based monitoring can provide a
Marchezan, Andre RicardoGiesbrecht, Mateus
In this study, the combustion and emission characteristics of a single-cylinder direct injection (DI) diesel engine fueled with Spirulina biodiesel along with diesel blends were examined using a combined CFD and thermodynamic simulation framework. Three test fuels, including pure diesel (D100), Spirulina biodiesel blends (B20 and B40), and pure Spirulina biodiesel (B100), were analysed at 1500 rpm under full load. In the first stage, CFD simulations were performed in ANSYS Fluent, where the Discrete Phase Model (DPM) was applied to capture spray atomization and droplet evaporation, while a non-premixed combustion model coupled with the RNG k-ε turbulence model was employed to resolve in-cylinder flow and heat release dynamics. Subsequently, the Diesel-RK software was utilised to predict engine performance and exhaust emissions based on compression ratios (18.5) and injection timings. Results from the CFD analysis revealed faster atomization and reduced ignition delay for biodiesel
Kumar, B Varun
This study investigates the potential of using a dual green alternative fuel combination, the one is hydrogen fuel and another one is biodiesel for enhancing the Performance, combustion and emission profile of a compression ignition engine. The kapok oil biodiesel was blended with Diesel in proportions of 20% (K20) and 40% (K40) by volume. The hydrogen gas was supplied at a constant flow of 4 liter per minute (LPM). The experimental fuels are neat diesel D100, K20 (80% Diesel and 20 % kapok methyl ester), K40 (60% Diesel + 40 % Kapok methyl ester), K20 + H4L (K20 with 4 LPM hydrogen) and K40+H4L (K40 with 4 LPM hydrogen). These test blends are investigated in a single cylinder direct injection CI engine under 0% to 100% load conditions at a fixed speed of 1500 rpm combustion, and emissions characteristic were evaluated and compared with base fuel. The outcomes indicated that the use of B20 and B40 blends without hydrogen led to reduced BTE because of their lower cetane number and
Anbarasan, BM, KumaresanBalamurugan, SRajesh, Munnusamy
The integration of ethanol into gasoline presents compatibility challenges for automotive fuel-system materials. In this study, the degradation of NBR-PVC fuel hoses exposed to ethanol-gasoline blends (E30, E50, E70, and E100) was investigated under dynamic flow conditions. A custom-designed test rig simulates real-time fuel circulation for 1,200 h. FESEM, ATR-FTIR, and elemental mapping analyses revealed ethanol-induced degradation, including dehydrochlorination, plasticizer leaching, and filler detachment. Among the blends, E30 exhibited the least material degradation, whereas E100 showed significant surface damage and chemical alteration. This study recommends multilayered fuel hose structures with ethanol-resistant inner linings for enhanced durability.
PC, MuruganL S, AdhityaG, Arun PrasadW, Beno WincyT, Karthi
Rolls-Royce has successfully tested the world's first high-speed marine engine powered exclusively by methanol on its test bench in Friedrichshafen, Germany. The company began this engine-development journey six years ago when it gathered experts to determine what the future fuel of the maritime industry should be, according to Denise Kurtulus, senior vice president of global marine at Rolls-Royce. “For us, it's clear. It's methanol,” she said. Rolls-Royce worked with industry partners as part of the joint project meOHmare, which is funded by the German Federal Ministry for Economic Affairs and Energy. Injection system specialist Woodward L'Orange and the WTZ Roßlau technology and research center contributed their expertise. Their goal was to not only develop a comprehensive concept for a CO2-neutral marine engine based on green methanol, but also to run it on the test bench by the end of 2025.
Gehm, Ryan
In alignment with its carbon reduction commitments, India is transitioning towards higher ethanol-blended fuels, with E20 set for nationwide implementation by 2025. Ethanol is a renewable, domestically produced biofuel produced through fermentation of biomass such as sugarcane, corn. It possesses a higher octane rating and oxygen content compared to conventional gasoline, making it a favorable additive for improving engine performance and reducing emissions. This study investigates the impact of E20 fuel on performance parameters of a 694 cc MPFI , water-cooled, twin-cylinder gasoline engine. For deriving maximum benefits of increased Octane rating of E20, compression ratio was increased to 12.5:1. Experimental analysis was conducted to assess the changes in combustion behavior, brake specific fuel consumption (BSFC), torque output, engine out emissions and thermal efficiency when operating on E20 compared to baseline gasoline (E10). Base results indicate that E20 promotes more
Kulkarni, DeepakMalekar, Hemant AThonge, RavindraKanchan, Shubham
Increasing ethanol blending in gasoline is significant from both financial (reducing dependency on crude oil) and sustainability (overall CO2 reduction) points of view. Flex Fuel is an ethanol-gasoline blend containing ethanol ranging from 20% to 85%. Flex Fuel emerges as an exceptionally advantageous solution, adeptly addressing the shortcomings associated with both gasoline and ethanol. Performance optimization of Flex Fuel is a major challenge as fuel properties like knocking tendency, calorific value, vapour pressure, latent heat, and stoichiometric air-fuel ratio change with varying ethanol content. This paper elaborates on the experimental results of trials conducted for optimizing engine performance with Flex Fuel for a 2-cylinder engine used in a small commercial vehicle. To derive maximum benefit from the higher octane rating of E85, the compression ratio is increased, while ignition timing is optimized to avoid knocking with E20 fuel. For intermediate blends, ignition timing
Kulkarni, DeepakMalekar, Hemant AUpadhyay, RajdipKatkar, SantoshUndre, Shrikant
On the way to net zero emissions and to cut the oil import bills, NITI Aayog, Government of India and Ministry of Petroleum & Natural Gas (MoP&NG) has rolled out roadmap for ethanol blending in India during 2020-2025. Also, National Policy on Biofuels – 2018, provides an indicative target of 20% ethanol blending under the Ethanol Blended Petrol (EBP) Programme by 2030. Considering these Government’s initiatives current studies were performed on BSVI compliant gasoline direct injection vehicle on RDE compliant route (Route formulated by Indian Oil R&D Centre) with different ethanol blended gasoline fuel formulations i.e., E0 (Neat Gasoline), E10 (10% Ethanol in gasoline) & E20 (20% Ethanol in gasoline). The study aims to determine the compliance of Conformity Factor (C.F.) for ethanol blended gasoline fuel on Direct Injection gasoline engine. The conformity factors were calculated in each case for CO, NOx & PN using moving window average evaluation method. For reference CO2
Kant, ChanderArora, AjaySaroj, ShyamsherKumar, PrashantSithananthan, MChakradhar, Dr MayaKalita, Mrinmoy
The Government of India has mandated biofuel blending in automotive fuels to reduce crude oil imports and support the national economy. As part of this initiative, Oil Marketing Companies (OMCs) have begun nationwide blending of E20 fuel (20% ethanol in petrol). Ethanol supply is expected to exceed demand by the end of 2025 due to initiatives like the Pradhan Mantri JI-VAN Yojana. Alternative applications for ethanol are being explored; one promising approach is its use as a co-blend with diesel fuel (ED blends). However, ethanol’s low cetane number and poor lubricity pose challenges for direct use in diesel engines without modifications. ED blends demonstrated reduced emissions while maintaining performance comparable to conventional diesel. To further address concerns related to materials compatibility of ED blends with fuel system components, particularly plastomers that may impact engine durability, a detailed study was conducted using elastomers such as FVMQ, FKM, HNBR, and NBR in
Johnpeter, Justin PChakrahari, KiranChakradhar, MayaArora, AjayPrakash, ShantiPokhriyal, Naveen Kumar
Today, passenger car makers around the world are striving to meet the increasing demand for fuel economy, high performance, and silent engines. Corporate Average Fuel Economy (CAFE) regulations implemented in India to improve the fuel efficiency of a manufacturer's fleet of vehicles. CAFE goal is to reduce fuel consumption and, by extension, the emissions that contribute to climate change. CNG (Compressed Natural Gas) engines offer several advantages that help manufacturers meet and exceed these standards. The demand for CNG vehicles has surged exponentially in recent years, CNG engine better Fuel efficiency and advantage in CAFÉ norms make good case for OEM & Customer to use more CNG vehicle. CNG is dry fuel compared to gasoline. These dry fuels lack lubricating properties, unlike conventional fuels like petrol, diesel and biofuels, which are wet and liquid. Consequently, the operations and failures associated with these fuels differ. The materials and designs of engine parts, such as
Poonia, SanjayKumar, ChandanSharma, ShailenderKhan, PrasenjitBhat, AnoopP, PrasathNeb, Ashish
This paper presents the methodology and outcomes of modifying a 1.2L naturally aspirated (NA) engine to enable flex-fuel compatibility, targeting optimal performance with ethanol blends ranging from E20 to E100. Ethanol is being increasingly promoted due to its potential to reduce greenhouse gas emissions and to provide an additional source of income for farmers. As per the road map for Ethanol blending released by Govt. of India, there has been continuous increase in blending of ethanol in gasoline. An initial target of 20% ethanol blending in gasoline by April 2025 has already been achieved. This work is in alignment with the broader push for development of flex-fuel vehicles, which necessitates engine adaptations capable of operating on varying ethanol blends. The primary objective was to upgrade the engine, which can give optimum performance with both lower range of ethanol blends starting from E20 as per IS 17021:2018 standard till higher blends of up to E100 as per IS 17821:2022
Tyagarajan, SethuramalingamPise, ChetanKavekar, PratapAgarwal, Nishant Kumar
India being highly populated and developing country, the demand for various alternative fuel is increasing drastically. It is driven by the need to reduce dependency on traditional fossil fuels & reduce impact on environmental issues like Greenhouse gas, emissions & pollution. The potential options, CNG (Compressed Natural Gas) & Biodiesel, are becoming increasingly popular and important. Biodiesel, a renewable fuel which is produced from waste materials & crops which grown repeatedly & easily available while CNG is more sustainable than diesel as natural gas is a cleaner-burning fossil fuel in comparison to coal or oil. This paper will focus on comparison between basic properties of Diesel, CNG & Biodiesel. In this study will also focus on survey of various Government initiatives, policies & infrastructural development which are evolving to encourage the usage of CNG & Biodiesel. These fuels are emerging as promising alternative contenders to traditional diesel. It has the potential
Bondada, NanditaBaruah, LabanyaMokhadkar, Rahul
The adoption of flex-fuel vehicles (FFVs) in India presents a significant opportunity to reduce dependence on fossil fuels, lower greenhouse gas emissions, and ensure compliance with the country’s evolving emission norms. This paper explores the key aspects of flex-fuel technology in the context of Indian four-wheeler regulations, particularly Bharat Stage VI and potential future emission norms. The study begins with an overview of flex-fuel technology, detailing its advantages and associated challenges. A critical focus is placed on blend identification techniques, which play a vital role in optimizing combustion efficiency and ensuring seamless transitions between different ethanol-gasoline blends. Furthermore, the impact of ethanol blending on various fuel properties is examined, including changes in energy content, latent heat of vaporization, octane number rating, and stoichiometric air-fuel ratio. These factors significantly influence engine performance and emission
Balasubramanian, KarthickKR, PrabhakarKallahallii Somu, Santhosh Kumar
In this study, a novel dual-fuel combustion strategy is investigated, employing late pilot injection in diesel–methane engines to improve performance and reduce emissions. The engine was first tested with conventional diesel and methane, exploring a wide range of pilot injection timings, injection pressures, and intake boost pressures. Subsequently, experiments were repeated using a methane/hydrogen blend to assess the influence of hydrogen addition. Results show that, when using only methane, delayed pilot injections have minimal effects on engine performance. In naturally aspirated operation, unburned hydrocarbons and carbon monoxide are reduced, while in supercharged conditions, emissions increase; however, they remain within acceptable limits. Nitrogen oxides and particulate matter reach their lowest levels with delayed injection. Introducing hydrogen reduces engine performance and hydrocarbons and carbon monoxide emissions; notably, it suppresses the typical nitrogen oxides
Carlucci, Antonio PaoloStrafella, LucianoFicarella, Antonio
Biodiesel, a renewable biofuel obtained from vegetable oils or animal fats, has emerged as a sustainable alternative to fossil fuels. This fuel has stood out for its ability to reduce greenhouse gas emissions, helping to mitigate environmental impacts. Biodiesel is produced by reacting oil with an alcohol in the presence of a catalyst, which can be homogeneous or heterogeneous. Heterogeneous catalysis has advantages such as ease of separation, greater tolerance to oils with a high fatty acid content and the possibility of reusing the catalyst, which reduces costs and minimizes waste generation. Among the various heterogeneous catalysts available, niobium-based compounds stand out. The use of niobium-based catalysts is advantageous due to the vast reserves of this element in Brazil, guaranteeing autonomy in production and strengthening the national biofuels industry. This work investigated the production of biodiesel from soybean oil using the homogeneous and heterogeneous
Coelho, Gabriella VilelaAlvarez, Carlos Eduardo CastillaRibeiro, Jessica Oliveira Notório
The concern about CO2 emissions from commercial vehicles powered with internal combustion engines has been motivating research and development projects to reduce the transportation sector carbon footprint. One of the promising alternatives is the use of biofuels associated with high-efficient internal combustion engines, taking advantage of the current infrastructure of car manufacturers and automotive suppliers, as well as of the potential growth in biofuel production. With the stringent emissions regulations, the use of downsized SI engines for passenger cars has driven the adoption of direct injection technology, enabling the use of different fuel injection strategies such as stratified mixtures and multiple injection events, as well as the increase of the compression ratio as a way to improve engine thermal efficiency. This path also led to a gradual increase in injection pressure, aiming to improve spray formation and reduce the formation of particulate matter. In this sense, the
Antolini, JácsonZabeu, Clayton BarcelosPires, Gustavo CassaresPolizio, Yuri
In alignment with the International Maritime Organization’s 2023 GHG Strategy and the Paris Agreement, this study investigates the viability of ternary blends of marine diesel, biodiesel, and ethanol as low-emission marine fuels. While previous studies have established the physicochemical behavior and storage stability of such blends, particularly the co-solvency role of biodiesel to prevent phase separation, limited data exists on their combustion performance under engine-relevant conditions. This work addresses this gap through a series of controlled experiments conducted in a Rapid Compression Machine (RCM), which enables the approximate a single-cycle combustion in a compression ignition engine. The tested blends included varying proportions of ethanol (up to 20% in volume) in a blend of fossil fuel with 25% of biodiesel (25%), and their combustion were evaluated across different injection timings. Key performance metrics such as ignition delay, maximum temperature and pressure
Lobato, Maria Letícia CostaSánchez, Fernando ZegarraTicona, Epifanio MamaniPradelle, Renata Nohra ChaarBraga, Sergio LealCoelho, Lucas Dos SantosPradelle, Florian
Particulate matter (PM), mainly its finer fraction, is among the main atmospheric pollutants present in an urban environment. The relationship between the increase in the concentration of this pollutant and the harm to human health is well established. The main sources of particulate matter in urban areas are mobile sources, which include the exhaust emission from light duty vehicles. This work measured the emission of PM in three light duty passenger vehicles, characterizing it in terms of emitted mass in one “flex” vehicle with port fuel (indirect) injection (PFI), using ethanol and gasohol (mixture of 22% anhydrous ethanol and 78% gasoline, by volume), in another “flex” vehicle with direct fuel injection (GDI), and in a diesel vehicle. In addition to mass measurement, images of the filters used in PM sampling were produced using scanning electron microscopy. The processing of these images made it possible to determine the average PM size, as well as establish a particle size
Borsari, VanderleiNeto, Edson Elpídiode Abrantes, Rui
This study aims to quantify, through Monte Carlo simulation (100,000 iterations), the greenhouse gas (GHG) emissions associated with the complete production cycle of ethanol from sugarcane in Brazil, expressed in kg CO2eq/ha, and to project these emissions over a 20-year horizon. To achieve this, the production cycle was segmented into distinct stages - land use change, soil management and preparation, fertilization, harvesting and straw management, soil carbon sequestration, and industrial processing - and the parameters for each stage were defined based on recent. Three representative scenarios were considered: Worst-case (unsustainable practices involving conversion of native vegetation, high fertilizer dosages, and complete burning of the straw), Typical (conventional practices, with conversion of degraded pastures and sustainable management), and Ideal (best practices, characterized by reduced input dosages, the use of nitrification inhibitors, and high straw retention). The
Assis, Marcelo Suman SilvaPaula Araújo, Gabriel Heleno deBaeta, José Guilherme CoelhoAbreu, Pedro Blaso Barbosa deFilho, Fernando Antonio Rodrigues
The diversification of the energy matrix, combined with the use of renewable and less polluting fuels in internal combustion engines, has encouraged numerous research efforts both nationally and internationally. In this context, the utilization of waste for biofuel production stands out as a promising alternative, offering a clean and economically viable energy source. Biogas is one of the most sustainable options and has been widely used in the industry. However, it presents low lower heating values (LHV) and difficulties in burning stoichiometric mixtures, which compromise engine performance, resulting in higher specific fuel consumption and lower power output compared to fossil fuels. To address this challenge, this study aimed to improve biogas combustion in internal combustion engines by investigating the application of a new pre-chamber ignition system in the combustion process and engine performance parameters. For this, experimental tests were conducted with two biofuel
Siqueira, Caio Henrique MoreiraÁzara, Luiz Eduardo MartinsRibeiro, José Vitor PuttiniSoares, Gabriel FariaSilva, Fábio MoreiraAlvarez, Carlos Eduardo Castilla
The increasing demand for reduced emissions in the automotive sector has driven research into alternative fuels, including Diesel, Biodiesel, and ethanol blends. This study aims to optimize mixing rules to predict the physicochemical properties of ternary fuel blends, essential for improving engine performance and minimizing emissions. Seven established mixing rules—Kay’s Equation, Semilogarithmic Equation, Grunberg-Nissan Equation, Modified Lederer Equation, Hu-Burns Equation, Power Law, and Polynomial Equation—were evaluated to estimate key properties such as kinematic viscosity, cetane number, cetane index, flash point, pour point, and cloud point. A comprehensive database, sourced from previous literature, included pure fuel properties and blend data for 33 to 101 cases. MATLAB was used to implement nonlinear optimization, adjusting coefficients to minimize error metrics like Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), and Standard Deviation (SD). The physical
Tirado, Carlos Andrés AbantoLobato, Maria Letícia CostaPassos, Sthefany FaberPradelle, Renata Nohra ChaarPradelle, Florian
Environmental agreements and the urgent need to mitigate greenhouse gas emissions have positioned biogas as a sustainable alternative for bioenergy production. Biogas is a highly versatile fuel that can be used for heat and electricity generation, as well as a substitute for fossil fuels. However, its contribution to the global energy matrix remains limited. This study presents a literature search aimed at assessing the potential for biogas and bioenergy production in Latin American countries, with an emphasis on agro-industrial, agricultural, and urban waste sources. This source was conducted using articles retrieved from the CAPES Journals Portal. Based on the findings, Brazil stands out due to its extensive agro-industrial sector, while countries such as Argentina, Colombia, and Mexico also offer substantial opportunities which biogas could meet a significant share of regional energy demand. The review showed that sugarcane residues in Colombia could replace up to 44% of gasoline
Rodrigues, Jônatas SoaresMoreira, Thiago Augusto AraújoSouza Pereira, Felipe Augusto deCastro, Daniel Enrique
Flex-fueled vehicles (FFV) dominate the Brazilian market, accounting for over 75% of the national fleet. Ethanol fuel is widely used, primarily in the form of hydrated ethyl alcohol fuel (HEAF). Given the similar physicochemical properties of ethanol and methanol, fuel adulteration is a growing concern, often involving the addition of anhydrous ethanol, methanol, or even water to hydrated ethanol. These adulterants are visually imperceptible and can only be detected through analyses conducted by regulatory agencies using specialized instruments. However, they can significantly affect vehicle performance and accelerate engine component deterioration. The experiment was performed with a small displacement 3-cylinder port fuel injection flex-fuel engine on an engine test bench (dynamometer) and compared when fueled with ethanol and methanol. Data acquisition included combustion pressure, spark plug temperature, torque, air-fuel ratio, fuel flow, spark maps, and the overall effects of
Mascarenhas, Giovana RebellatoGomes, EdersonCruz, DiegoDuque, Edson Luciano
Brazil PL8 regulation has required that manufacturers comply with new emissions levels for all of vehicle life – 0 km up to 160.000 km. On this study, tests found that results between new and used vehicles are remarkably similar except for Aldehydes on Ethanol tests. To better understand this phenomena, two main ideas were considered: first, the engine mileage needed to stabilize aldehydes emissions; and second, the main factors responsible for higher acetaldehyde values on new engines only.
Fernandes, SarahBorsari, MarcioBrondani, Dhouglas
The transition to renewable fuels is critical to reduce greenhouse gas emissions and achieve carbon neutrality in the transportation sector. Ethanol has emerged as a promising biofuel for compression ignition (CI) engines due to its renewability and low-carbon profile. However, its low cetane number, high latent heat of vaporization, poor lubricity, and corrosive properties severely limit its auto-ignition capability and durable operation under conventional CI conditions. Building upon previous work using a Rapid Compression Machine (RCM) to assess ignition improvers for ethanol, this study explores a broader range of fuel formulations to enhance ethanol-based combustion. A total of nine blends were prepared, consisting predominantly of hydrated ethanol (50-80% by volume), combined with 5-25% biodiesel and up to 5% of a commercial ignition improvers. The biodiesel component acted both as a co-solvent and as a combustion stabilizer, particularly under cold-start conditions. Tests were
Bacic, Denise AmatoSánchez, Fernando ZegarraTicona, Epifanio MamaniPradelle, Renata Nohra ChaarSantos Coelho, Lucas dosMota, Crislane Almeida Pereira daPradelle, Florian
One alternative to fossil fuels is the use of bioethanol in internal combustion engines. However, the application of this renewable fuel in compression-ignition engines is limited due to its low cetane number. This barrier, however, can be overcome by using additives that enhance this property. Consequently, additized ethanol emerges as a promising option with significant potential for decarbonization and improved combustion efficiency. In this context, the present study numerically investigated, using the CONVERGE CFD software, the use of additized ethanol in a compression-ignition internal combustion engine used in marine transportation. As a comparative baseline for each investigated setup, cases involving conventional diesel fuel were also analyzed numerically. The reaction mechanisms used for modeling the combustion of both additized ethanol and conventional diesel were validated against experimental data available in the literature. Di-tert-butyl peroxide (DTBP) was the studied
Assis, GuilhermeSánchez, Fernando ZegarraPradelle, Renata Nohra ChaarBraga, Sergio LealTicona, Epifanio MamaniSouza Junior, JorgePradelle, Florian
This study presents a comparative Life Cycle Assessment (LCA) of urban buses powered by Diesel S10 with three fuel blends: B7 (7% biodiesel), B15 (15% biodiesel), and B100 (100% biodiesel). Employing a well-to-wheel approach, the analysis covers the extraction, production, distribution, and use of the fuels, as well as vehicle manufacturing and maintenance. The environmental impacts were quantified using the CML-IA and ReCiPe 2016 (Midpoint and Endpoint) methods. Results indicate that B100 significantly reduces Global Warming Potential, yet exhibits higher impacts in eutrophication, abiotic depletion, and ecotoxicity. Sensitivity analysis regarding vehicle occupancy revealed greater variability for B100. In conclusion, the optimal fuel choice depends on the prioritization of specific impact categories, providing insights for sustainable transportation policies.
Cavaliero, Carla Kazue NakaoBarboza, Franciele AlvesSeabra, Joaquim Eugênio AbelFerreira, Marcela CravoCarpoviki, Renan SiqueiraCruz, Robson Ferreira
The growing demand for sustainable energy and the need to reduce greenhouse gas emissions have driven interest in low-carbon hydrogen production. Ethanol steam reforming (SR) offers a promising on-board H2 source by exploiting ethanol’s renewability and liquid-fuel convenience. This study presents an integrated energy and exergy analysis of ethanol SR across 573 to 923 K and steam-to-ethanol (S/E) ratios from 1 to 4 using Gibbs free energy minimization in MATLAB to predict equilibrium compositions and thermal duties. Energy analysis shows the heating duty rising from 0.0311 kWh/mol ethanol at 573 K (S/E = 1) to 0.0521 kWh/mol at 923 K (S/E = 4). Reforming duty shifts from -0.0075 to +0.2426 kWh/mol, while cooling duty recovers between -0.0219 and -0.0727 kWh/mol. The net energy balance transitions from strongly endothermic below 650 K to near-neutral at 700 to 750 K for S/E > 2, and becomes exothermic above 800 K, reaching +0.2463 kWh/mol at 923 K. Exergy analysis reveals that heating
Apaza, Jerson Bequer UrdayPradelle, FlorianBraga, Sergio LealSánchez, Fernando ZegarraGuzman, Juan Jose Milon
Ethanol is a hydrogen-rich liquid and has a specific energy of 8.0 kWh/kg. In a vehicle, hydrogen storage is done in high-pressure cylinders. The same fundamental technology is used at other fuel cell systems in vehicles such as Toyota Mirai and Honda Clarity. Hydrogen is also introduced into the cell to generate electricity, which will power an electric motor that drives the vehicle. Excess electricity is stored in batteries. The main characteristic of the system described here is that hydrogen can be generated through an additional process in a reformer, installed at a fixed station. The reformer transforms the ethanol stored in the fuel station tank into hydrogen, which can then fuel a vehicle equipped with high-pressure cylinders and fed into the fuel cell. The system, however, emits water vapor, heat, and CO2. This is because carbon dioxide is a byproduct resulting from the transformation of ethanol into hydrogen. According to studies, despite this the system is carbon neutral
Fontana, Romeu
In this study, a Kirloskar TV1 compression ignition engine is put to test using diesel, palm biodiesel (B100), and palm biodiesel–diesel blend (B40D60). Among the tested fuels, engine performance at 75% loading condition with reference fuel diesel showed the highest brake thermal efficiency, brake specific energy consumption, and exhaust gas temperature at 27.78%, 12.96 MJ/kWh, and 335.88°C, respectively. While B100 and B40D60 were observed to give a lower value for the same parameters due to their inferior physiochemical properties. In terms of combustion pressure, mean gas temperature, rate of heat release, and rate of pressure rise, the values observed with B40D60 at 67.39 bar, 1397.76 K, 68.83 J/CAD, and 4.34 bar/CAD, correspondingly are better than B100 due to the presence of diesel. Yet for the same combustion parameters, the values for both the aforementioned fuels are still lower than the results seen with pure diesel fueling. Owing to higher cetane number in comparison to
Balakrishnan, Navaneetha KrishnanChelladorai, PrabhuMuhammad, Syahidah Akmal
Achieving compression ignition (CI) with ethanol, a renewable fuel, comes with challenges because of its much lower cetane number compared to diesel. Additionally, ethanol’s high cooling potential and high volatility compared to diesel also offer challenges and opportunities to achieving robust, high-efficiency CI. Increasing the compression ratio (CR) and expanding the injection strategy beyond a conventional close-coupled pilot-main diesel injection strategy can help overcome these challenges. This work experimentally tested ethanol CI with several different injection strategies with CRs ranging from 16.3 to 22.3. The results showed that in homogeneous charge CI (HCCI), increasing the CR improved thermal efficiency but incurred a combustion efficiency penalty. In any CI concept, increasing the CR lowered the required intake temperature to achieve ignition. Using close-coupled pilot injections is an effective way to achieve ethanol CI, but it was also shown that HCCI-like intake
Gainey, BrianVedpathak, KunalKumar, MohitLawler, Benjamin
Alcohol fuels are regarded as a feasible approach to address rising energy demands and reduce the dependency on fossil fuels, with ethanol and methanol emerging as a promising renewable fuel for spark-ignition engines. In this research work, tests were performed on a spark ignition engine altered from a diesel engine that employs ethanol/methanol-gasoline blend as fuel operating under lean conditions. The experiments were conducted at 10.5:1 compression ratio and 1500 rpm under full throttle condition with three fuel blends namely M10 (10% of methanol+ 90% gasoline), E10 (10% of ethanol+ 90% gasoline), E5M5 (5% of each ethanol and methanol+ 90% gasoline). Investigational results reveals that alcohol-gasoline blends displayed low COV of IMEP. Furthermore, the alcohol-gasoline mixtures enhanced the peak in-cylinder pressure owing to improved flame speed and flammability limits. Adopting lean-burn operation and high compression ratio can efficiently improve combustion attributes in an
Devunuri, SureshPorpatham, Dr. E
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