Browse Topic: Selective catalytic reduction (SCR)

Items (1,086)
As vehicle emission standards are becoming stringent worldwide because of the looming climate crisis, it is important to control the pollutants that vehicles emit. To achieve the stringent emission target, it has become a priority to enhance the capability of Emission Control System (ECS) which consist of Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR) sub-systems. One of the bottlenecks is the limited operating temperature range of the after-treatment system. In modern emission control systems, the temperature characteristics should always be optimized to have the best efficiency involving chemical conversions. To achieve this optimal operating temperature, different thermal control strategies are followed in the Engine and emission control unit. Temperature sensor values are one of the primary inputs for thermal management strategies. In the event of temperature sensor malfunction, the ECS performance is affected due to
Kumar, AmitV H, YashwanthKumar, RamanHegde, KarthikManojdharan, Arjungopal
The present study aims to meet the Euro-VII compliance applicable for internal combustion engines (diesel and hydrogen) by improving the performance of selective catalytic reduction (SCR) system using a novel urea water solution (UWS) mist injection technique. In SCR system, the interaction of exhaust gas and UWS resulted into ammonia (NH3) species, which is mixed with harmful NOx emission and converted into harmless by-products. Despite the proven technology, there are several challenges presented in the existing system which restricts the ideal performance of SCR system especially during cold starting condition: (i) incomplete droplet evaporation (ii) solid deposit formation (iii) non uniformity of NH3 distribution at the catalyst entrance. The past studies shows that the droplet size plays a major role in this context. Further, it is noted that the smaller size droplets are desirable to overcome the impediments and enhance the efficiency of SCR application. Therefore, it is decided
Venkatachalam, PalaniappanShiva, ShashidharGovindarajan, VaishaliSoni, PrernaPatidar, Sachin
Selective catalytic reduction (SCR) technology is currently one of the most effective methods to reduce NOx emissions for engine. NH3-SCR technology is also considered to be the most promising hydrogen engine after-treatment device. This paper used Cu-SSZ-13, which is widely commercially available, as the research object, and explored the relationship between micron and nanoscale grain sizes through experimental methods such as BET, XRD, NH3-TPD, UV-vis-DRS and activity testing, the influence mechanism of micron-scale and nano-scale grain size on the morphology and properties of Cu/SSZ-13 catalyst was explored. The results show that the fresh nanoscale 900F sample has higher low-temperature NOx conversion efficiency, while the micron-scale 1800F sample has poor low-temperature activity and better high-temperature activity. This is closely related to its morphological characteristics, adsorption and desorption characteristics and dual-site properties. The specific surface area and total
Chen, YajuanLou, DimingZhang, YunhuaTan, PiqiangFang, LiangHu, Zhiyuan
A major challenge for auto industries is reducing NOx and other exhaust gas emissions to meet stringent Euro 7 emission regulations. A urea Selective Catalyst Reduction (SCR) after-treatment system (ATS) commonly uses upstream urea water injection to reduce NOx from the engine exhaust gas. The NOx emission conversion rate in ATSs is high for high exhaust gas temperatures but substantially low for temperatures below 200°C. This study aims to improve the NOx conversion rate using urea pulse injection in a mass-production 2.2 L diesel engine equipped with an SCR ATS operated under low exhaust gas temperature. The engine experimental results show that, under 200°C exhaust temperature and 3.73x104 h-1 gross hourly space velocity (SV), the NOx conversion rate can be improved by 5% using 5-sec ON and 12-sec OFF (denoted as 5/12 s) urea pulse supply compared to the constant supply under time-averaged 1.0 urea equivalence ratio. It is experimentally observed that the urea pulse supply’s
Yoshida, FukaTakahashi, HideakiKotani, YuyaZu, QiuyueSok, RatnakKusaka, Jin
Engine and aftertreatment solutions have been identified to meet the upcoming ultra-low NOx regulations on heavy duty vehicles in the United States. These standards will require changes to current conventional aftertreatment systems for dealing with low exhaust temperature scenarios while increasing the useful life of the engine and aftertreatment system. Previous studies have shown feasibility of meeting the US EPA and California Air Resource Board (CARB) requirements. This work includes a 15L diesel engine equipped with cylinder deactivation (CDA) and an aftertreatment system that was fully DAAAC aged to 800,000 miles. The aftertreatment system includes an e-heater (electric heater), light-off Selective Catalytic Reduction (LO-SCR) followed by a primary aftertreatment system containing a DPF and SCR. The e-heater was capable of providing up to 10 kW, however for the purpose of this project, lower power settings of 2.5 kW and 5 kW were studied in combination with CDA for lowest
Kramer, JanRice, MichaelZavala, BryanSharp, ChristopherMcCarthy, JamesKarrer, Ben
Electricity, e-fuel and H2 are considered important recent and future sources of energy for heavy-duty vehicles. Heavy-duty battery electric vehicles (BEV) have many technical challenges. Therefore, internal combustion engines (ICE) powered by e-fuel and hydrogen can be used as an alternative to batteries in heavy-duty trucks. Selective catalytic reduction (SCR) systems are necessary for achieving the goals of zero-emission internal combustion engines that use e-fuel or H2 as a fuel. The Japanese automotive industry mainly utilizes Cu-Zeolite-based SCR catalysts since vanadium-based catalysts have been difficult to be used to prevent the release of vanadium into the atmosphere due to the relatively low evaporation temperature. This study investigated whether improving the conversion rate by pulsing the NH3 supply was possible. Experiments were conducted in a mini-reactor with an inflow of simulated exhaust gas to examine the effect of the pulse amplitude, frequency, and duty ratio on
Morita, DaikiKotani, YuyaZu, QiuyueYoshida, FukaSok, RatnakKusaka, Jin
The proposed Euro 7 regulation aims to substantially reduce the NOx emissions to 0.03 g/km, a trend also seen in upcoming China 6b and US EPA regulations. Meeting these stringent requirements necessitates advancements in Urea/Selective Catalytic Reduction (SCR) aftertreatment systems, with the urea deposit formation being a key challenge to its design. It’s proven that Computational Fluid Dynamics (CFD) can be an effective tool to predict Urea deposits. Transient wall temperature prediction is crucial in Urea deposit modeling. Additionally, fully understanding the kinetics of urea decomposition and by-products solidification are also critical in predicting the deposit amount and its location. In this study, we introduce (i) a novel film boiling model (IFPEN-BRT model) and (ii) a new urea by-product solidification model in the CONVERGE CFD commercial solver, and validate the results against the recent experiments. The IFPEN-BRT model handles the spray-wall heat transfer in various
Bhatt, Mrugank P.Yang, PengzeHabchi, Chaouki
Hydrogen (H2) is commonly considered as one of the most promising carbon-free energy carriers allowing for a decarbonization of combustion applications, for instance by retrofitting of conventional diesel internal combustion engines (ICEs). Although modern H2-ICEs emit only comparably low levels of nitrogen oxides (NOx), efficient catalytic converters are mandatory for exhaust gas after-treatment in order to establish near-zero emission applications. In this context, the present study evaluates the performance of a commercial state-of-the-art oxidation catalyst (OC) and of a catalyst for selective catalytic reduction (SCR) that are typically used for emission reduction from diesel exhausts under conditions representative for H2-fueled ICEs, namely oxygen-rich exhausts with high water vapor levels, comparably low temperatures, and potentially considerable levels of unburnt H2. Herein, the OC is supposed to convert H2 slippage, which can occur due to incomplete combustion, and to oxidize
Lott, PatrickSchäfer, KathrinDeutschmann, OlafWerner, ManuelWeinmann, PhilippZimmermann, LisaToebben, Heike
When used with injecting urea-water solution forming ammonia, Selective Catalytic Reduction (SCR) catalyst is a proven technology for greatly reducing tailpipe emission of nitrogen oxides (NOx) from Diesel engines. However, one major shortcoming of an SCR-based system is forming damaging urea deposits (crystals) in low temperature exhaust operations, especially exacerbated during higher injection rates. Deposits reduce SCR efficiency, damage exhaust components, and induce high concentration ammonia slips. We describe here an Electrically Heated Mixer (EHM™) demonstrated on a Diesel engine markedly inhibiting deposit formation in urea SCR systems, both in low (near 200 °C) and higher exhaust temperature operations and for both low and high urea injection rates in various, realistic engine operations. Engine test runs were conducted in long durations, 10 to 20 hours each, for a total of nearly 100 hours. In nearly all operation modes, EHM maintained deposits below 1% of the total
Vernham, BruceKadam, VaibhavMasoudi, MansourNoorfeshan, SahmPoliakov, Nick
In this study, an integrated emission prediction model was used to predict whether EURO7-compliant commercial internal combustion engine vehicles would be able to meet upcoming regulations. In particular, the optimal value of Adblue injection and EHC (Electrically Heated Catalyst) control strategy for each combination of the specifications of the close-coupled SCR system (volume, substrate spec., EHC, etc.) was derived. Through this, it was intended to derive the best specification combination in terms of control and emission performance, and to use the results as a basis for decision-making in the early stages of product concept selection
Cho, JihoChoi, SungmuLee, Sang MinHwang, Dong Min
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation. System model validation involved comparing the model against real-world data from production diesel engine after-treatment systems for transient cycles, including Federal Test
Chundru, Venkata RajeshSharp, ChristopherRahman, Mohammed MustafizurBalakrishnan, Arun
This paper describes the after-treatment technology that could be used to meet a future BS-VII standard, considering close-coupled SCR (cc-SCR) to help start NOx conversion earlier. Both active (Cu/Fe-SCR based) and passive (V-SCR based) systems have the potential to meet emission limits. V-SCR may be considered in the rear position because V-SCR shows a fast response with very low N2O formation. Next-gen V-SCR technology shows significantly improved performance and durability closer to Cu-SCR. The steady-state NOx conversions over Next-Gen V-SCR were better than BS-VI V-SCR in both fresh and aged-580°C/100h conditions. High durability was also observed after engine aging of 1000h (WHTC + high load). Another big challenge in BS VII could be the PN10 requirement. With enhanced filtration coating (EFC) technology, PN emissions drop drastically in comparison to Euro VI reference without EFC to meet a future BS VII
Singhania, AmitWallin, MikaelaEdvardsson, JonasChatterjee, SougatoVediappan, SudhagarKomori, MitsuruPhillips, Paul
The BS6 norms (phase 1) were implemented in India from April 1, 2020 and replaced the previous BS4 norms. Phase 2 of the BS6 norms, which came into effect on April 1, 2023. In accordance with the regulation requirement, effective performance of after treatment systems like DPF and SCR demands critical hardware implementation and robust monitoring strategies in the extended operating zone. Effective OBD monitoring of DPF, which is common to all BSVI certified vehicles, such that the defined strategy detects the presence or absence of the component is imperative. A robust monitoring strategy is developed to detect the presence of the DPF in the real world incorporating the worst possible driving conditions including idling, and irrespective of other environmental factors subject to a location or terrain. The differential pressure sensor across the DPF is used to study the actual pressure drop across the DPF. Additional for BS 6 (phase 2) PM sensor becomes an important part to keep the
Sharma, PrashantHareesh, SangarajuV, SuryanarayananPalanisamy, KrishnarajP, JagdesanRathiya, Akash
Selective Catalytic Reduction (SCR) is an optimized technology developed to encounter current BS6 Emission Regulations. AdBlue is the reductant used in the SCR Dosing system to eliminate NOx in the Exhaust gas. In order to ensure engine emissions compliance, insufficient or improper reductant in tank required to be detected. The right AdBlue concentration of 32.5% is highly necessary to attain the higher NOX conversion efficiency. Low concentration of the reductant will drastically reduce the NOx conversion in the system. Hence monitoring the AdBlue concentration in the tank itself is more important as per the OBD legislation. This implies on a physical quality sensor in the tank for detecting the reductant concentration. The functionalities of the quality sensor can also be instituted via a virtual software modelling called Improper Reductant Detection (IRD). IRD logic is highly robust and work competently to meet the BS6 stage 2 legislation’s NOx target. The reductant is suspected
M, JayashreeK, SabareeswaranYS, Ananth Kumar
BS6.1 emission standards were implemented in India in 2020 followed by BS6.2 which added more controls on emission limits. For BS6.2 OBD (On Board Diagnostics) and RDE (Real Driving Emission) were added on to the existing BS6.1 emissions. Emission control changes usually need addition of new parts, calibration changes and durability requirements. For the current 1.5L, 3-cylinder diesel engine an pSCR (Passive Selective Catalytic Reduction) brick was added for control of NOx for meeting RDE. For meeting OBD requirements PM (Particulate Matter) and NOx sensors were added in the cold end pipe along with calibration changes to meet the BS6.2 norms. In this paper we will discuss on the design aspects of sensors and pSCR only. The sensor and pSCR positioning plays vital role in meeting the legislative requirements and to ensure the ease of assembly and durability of the parts. We discuss on the various options explored for positioning, the constraints of sensor application and the importance
Vinaya Murthy, VijayendraRengaraj, ChandrasekaranDharan R, BharaniSasikumar, M
The major objective of this paper is to develop thermal management strategy targeting optimum performance of Selective Catalytic Reduction (SCR) catalyst in a Medium Duty Diesel Engine performing in BS6 emission cycles. In the current scenario, the Emissions Norms are becoming more stringent and with the introduction of Real Drive Emission Test (RDE) and WHTC test comprising of both cold and hot phase, there is a need to develop techniques and strategies which are quick to respond in real time to cope with emission limit especially NOx. SCR seems to be suitable solution in reducing NOx in real time. However, there are limitations to SCR operating conditions, the major being the dosing release conditions which defines the gas temperature at which DEF (Diesel Exhaust Fluid) can be injected as DEF injection at lower gas temperatures than dosing release will lead to Urea deposit formation and will significantly hamper the SCR performance. The second factor for optimum SCR operation is to
Sharma, Ajeet KumarKreuzig, GerhardGupta, AyushGoyal, DineshGarg, Varun
Urea-NH3 dosed Selective Catalytic Reduction is a powerful reaction system to ensure NOx reduction in the exhaust gases by minimizing ammonia slip. When the dosed ammonia exceeds the actual request than the required, NH3 to NOx ratio is potentially high, the unused ammonia is limited to 10ppm corresponding to experimental result of every World Harmonic Transient Cycle. The dosage estimation depends on the NOx sensors which has this drawback of high cross-sensitivity to ammonia that can affect the measurement of NOx and compromise the SCR-ASC closed loop strategies. This paper aims to resolve the complexity in prediction of ammonia slip to resolve the cross-sensitivity of tailpipe NOx sensor in the SCR system by a closed loop estimation of NOx and ammonia slip to ensure high NOx conversion efficiency. The focus is to develop a simplified model-based solution for estimating ammonia slip, because of the limitations in the real drive conditions in SCR system. This model approach is
K, SabareeswaranM, JayashreeYS, Ananthkumar
In the Journey towards Zero Emission and decarbonization, with emerging advancement in technology form current BS6 to near future EURO7 standards of emission, these emission norms are achievable when we amalgamate with an assistive technology of Electrically Heated System for thermal management in Diesel emission control i.e., called CatVap®. With the increasingly stringent limits on vehicle pollutants- including NOx emission levels are fulfilled with Twin Urea Dosing mechanism. These comprehensive lists of advanced technology to converge lowest NOx emissions without increasing CO2 emissions. The Major effort in the existing structure is to accelerate the SCR temperature and enhance the conversion efficiency of NOx in Real Drive Emission during cold start and low load duty cycle. CatVap®system provides sufficient thermal energy to facilitate rapid heating in the course of low load cycles and cold city rides for efficient gas conversion. As they are used to accelerate the light-off
YS, AnanthkumarK, SabareeswaranM, Jayashree
A urea-selective catalytic reduction (SCR) system is used for the reduction of NOx emitted from diesel engines. Although this SCR catalyst can reduce NOx over a wide temperature range, improvements in NOx conversion at relatively low temperatures, such as under cold-start or low-load engine conditions, are necessary. A close-coupled SCR (cc-SCR), which was set just after the engine exhaust manifold, was developed to address this issue. The temperature of the SCR catalyst increases rapidly owing to the higher exhaust temperatures, and NOx conversion is then enhanced under cold-start conditions. However, since the diesel oxidation catalyst is not installed before the SCR catalyst, hydrocarbon (HC) emissions pass directly through the SCR catalyst and poison it, leading to lower NOx conversion. Therefore, the mechanism of NOx conversion reduction on HC-poisoned SCR catalysts are required to be studied. In this study, the effects of HC poisoning on the NOx conversion of Cu-CHA catalysts
Tanaka, KotaroDobashi, IbukiSakaida, SatoshiKonno, Mitsuru
Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance. Sulfur was deposited uniformly on the aftertreatment components while the oil derived
Seuser, GrantEakle, ScottRahman, Mohammed MustafizurSharp, ChristopherZavala, Bryan
This study was visualized by experimental and numerical analysis for the unknown injected droplet phenomena with the multi-phase flow in the Urea-SCR dosing system. Visualization experiments were conducted on the droplet behavior inside the pipe with simulated urea SCR injection system. Although the total number of droplets decreases at gas temperatures of 150°C and 200°C, a significant number of injected droplets remained at the position corresponding to the SCR catalyst. That is physical kinetic energy was found to dominate over thermal evaporation. However, the impingement of droplets into the pipe wall had occurred complex behavior by physical/thermal evaporation, and these droplets weren't on gas airflow at the lower part of the pipe. Furthermore, these actual phenomena were reflected in experimental coefficients for new reduction model analysis instead of CFD
NOHARA, TetsuoSUGIYAMA, NaokiNARA, ShotaroONO, JyoONOUE, HirokiOSADA, RinaKAWAMOTO, YukiOCHIAI, MasayukiTAKAHASHI, ShunOOSUMI, KazuoISHIKAWA, Naoya
This study presents the development of newly proposed SCR mixer for diesel engine that improves vehicle NOx emission without rebound of the exhaust pressure loss. Unique SCR mixer structure which produces multiple vortices can realize lower NOx emission due to the highly uniform mixing of NH3 generated from the SCR spray and the exhaust gas, compared to the conventional mixer which produce a single vortex. Through its unique mixer structure constructed with some blades that generate multiple vortices. In order to study the mixer structure in a short period of time, 2 steps design process have been studied by separating parametric study in flow analysis and performance confirmation in the dual-phase flow analysis. Consequently, this newly proposed SCR mixer realize excellent mixing performance without increasing the exhaust pressure loss
Ashida, MasaakiShiga, YoshihiroOyanagi, Susumu
This study shows the newest results of a near-series pre-turbo-catalyst (PTC) system reaching lowest emissions for electrified diesel passenger cars to address future emission legislation. The PTC system is developed using a state-of-the-art tool chain containing 1D & 3D simulation approaches and testing near-series exhaust gas aftertreatment systems under real-driving boundary conditions. The innovative concept of a selective catalytic reduction (SCR) PTC and a PTC bypass path solve the challenge of a thermal handshake between PTC and underfloor SCR System as well as the challenge of a particular filter regeneration. The development of adaptive PTC bypass path operation strategies based on exhaust gas and catalyst conditions enables lowest NOx and NH3. Using this concept, zero-impact NOx emissions, that don’t impact cities air quality, can be reached in a wide range of operating scenarios while sustaining full drivability and highest efficiency. Advanced catalyst technologies enable a
Conin, MichaelKnaf, DanielFiore, LuisKeck, MathiasBeidl, ChristianKreuz, JoachimHohenberg, Günter
With the introduction of the emission legislation Euro VI for commercial vehicles (CVs), selective catalytic reduction (SCR) with urea water solution (UWS) as the reducing agent has become a standard to minimize the nitrogen oxides (NOx) emissions from internal combustion engines. The urea processing and mixing unit has been developed and optimized in order to avoid deposit formation and ensure a high level of urea processing over the whole operation range, especially at lower temperatures. However, there are physical limits to the conversion of urea in conventional processing units during very low engine operating conditions. With the EHC Fractal Heater, Purem by Eberspächer has developed a heating measure that, in addition to its main function of accelerating the light-off of catalytic converters, also comes with the possibility of improving the UWS processing, especially under these low-load conditions
Többen, HeikeWeinmann, Philipp
Selective Catalytic Reduction (SCR) operation depends strongly on both heat and ammonia availability (stored or incoming). These requirements make high efficiency SCR challenging in lower temperature cycles where SCR is relatively cold, and Diesel Exhaust Fluid (DEF) injection is largely absent due to deposit risks. Examples include low temperature cycles such as low-idling, stop-and-go or low-load cycles such as city driving or local delivery cycles. An Electrically Heated Mixer/ EHM™ is utilized to address these challenges in a single component. EHM simultaneously provides heat for rapid SCR heat-up during the cold phase or in other low-temperature operations, steady or transient. Second, its heating mechanism makes deposit risks nearly non-existent. Third, EHM enables DEF injection at 130 °C, markedly enhancing the low temperature SCR impact. It is shown that these capabilities collectively make EHM a promising pathway for meeting ultra-stringent NOx targets including California
Masoudi, MansourPoliakov, NickNoorfeshan, Sahm
Increasing concerns due to global warming have led to stringent regulation of greenhouse gas (GHG) emissions from diesel engines. Specifically, for GHG phase-2 regulation (2027), more than 4% improvement is needed when compared to phase-1 regulation (2017) in the light heavy-duty (LHD) diesel engine category. At the same time, California Air Resources Board (CARB) and Environmental Protection Agency (EPA) have proposed the new Low NOx standards that require up to 90% reduction in tailpipe (TP) NOx emissions in comparison to the current TP NOx standards that were implemented in 2010. In addition, CARB and EPA have proposed new certification requirements – Low Load Cycle (LLC) and revised heavy-duty in-use testing (HDIUT) based on the moving average window (MAW) method that would require rigorous thermal management. Hence, strategies for simultaneous reduction in GHG and TP NOx emissions are required to meet future regulations. This paper presents potential pathways to achieve the GHG
Kadam, VaibhavMayilvaganan, ArvindDesai, ChintanVernham, Bruce
This program involved the detailed evaluation of a novel laser-based in-exhaust ammonia sensor using a diesel fuel-based burner platform integrated with an ammonia injection system. Test matrix included both steady-state modes and transient operation of the burner platform. Steady-state performance evaluation included tests that examined impact of exhaust gas temperature, gas velocity and ammonia levels on sensor response. Furthermore, cross sensitivity of the sensor was examined at different levels of NOX and water vapor. Transient tests included simulation of the FTP test cycles at different ammonia and NOX levels. A Fourier transform infrared (FTIR) spectrometer as well as NIST traceable ammonia gas bottles (introduced into the exhaust stream via a calibrated flow controller) served as references for ammonia measurement. Results suggested that Indrio’s sensor exhibits a strong linear relationship with reference ammonia measurement across the tested range of 0 ppm to 200 ppm with a
Premnath, VinayBalakrishnan, ArunSur, RitobrataKhalek, ImadEakle, Scott
Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature. Depending on the types of HC used, the presence of NOx can also influence HC
Xi, YuanzhouOttinger, NathanKiani, DaniyalLiu, Z. Gerald
With the continuous upgrading of emission regulations, NOx emission limit is becoming more and more strict, especially in the cold start phase. Passive NOx absorber (PNA) can adsorb NOx at a relatively low exhaust temperature, electrically heated catalyst (EHC) has great potential to improve exhaust gas temperature and reduce pollutant emissions of diesel engines at cold start conditions, while experimental research on the combined use of these two kinds of catalysts and the coupling mode of the electrically heated catalyst and the aftertreatment system under the cold start condition are lacking. In this paper, under a certain cold start and medium-high temperature phase, the exhaust gas temperature and emission characteristics of PNA, EHC and aftertreatment system under different coupling modes were studied. Results showed that the average inlet temperature of diesel oxidation catalyst (DOC) and selective catalytic reduction catalyst (SCR) integrated into diesel particulate filter
Kang, LuluFang, LiangZhao, YunkunLou, DimingZhang, YunhuaLuo, Chagen
This work is a part of medium-duty Low NOx technology development project with a focus on evaluating a combination of engine and advanced aftertreatment for 0.02 g/bhp-hr NOx regulation proposed by CARB (California air resource board). In this project, a control oriented chemical kinetics model of SCR (Selective catalytic reduction) was used in the aftertreatment controller that is susceptible to performance degradation due to hydrothermal and chemical aging. This paper focuses on modeling the NOx conversion and NH3 storage characteristics using a controls oriented SCR plant model which is further used for a model-based urea dosing scheme. A set of steady state reactor tests were used to calibrate the SCR performance at degreened, hydrothermal only and hydrothermal + chemical aging conditions and also to determine inhibition factors related to aging. The resultant model is capable of simulating SCR performance deterioration such as a reduction in NOx conversion and NH3 storage. A non
Chundru, Venkata RajeshDesai, ChintanKadam, VaibhavRengarajan, SankarRao, SandeshSharp, ChristopherVernham, BruceSarlashkar, Jayant
Typical two-site storage-based SCR plant models in literature consider NH3 stored in the first site to participate in NH3 storage, NOx conversion and second site to only participate in NH3 storage passively. This paper focuses on quantifying the impact of stored NH3 in the second site on the overall NOx conversion for an ultra-low NOx system due to intra site NH3 mass transfer. Accounting for this intra site mass transfer leads to better prediction of SCR out NH3 thus ensuring compliance with NH3 coverage targets and improved dosing characteristics of the controller that is critical to achieving ultra-low NOx standard. The stored NH3 in the second site undergoes mass transfer to the first site during temperature ramps encountered in a transient cycle that leads to increased NOx conversion in conditions where the dosing is switched off. The resultant NH3 coverage fraction prediction is critical in dosing control of SCR. This phenomenon is evaluated and quantified with different aging
Chundru, Venkata RajeshDesai, ChintanKadam, VaibhavVernham, BruceSharp, ChristopherRengarajan, SankarRao, SandeshSarlashkar, Jayant
Commercial vehicles require advanced engine and aftertreatment (AT) systems to meet upcoming nitrogen oxides (NOx) and carbon dioxide (CO2) regulations. This article focuses on the development and calibration of a model-based controller (MBC) for an advanced diesel AT system. The MBC was first applied to a standard AT system including a diesel particulate filter (DPF) and selective catalytic reduction (SCR) catalyst. Next, a light-off SCR (LO-SCR) was added upstream of the standard AT system. The MBC was optimized for both catalysts for a production engine where the diesel exhaust fluid (DEF) was unheated for both SCRs. This research shows that the tailpipe (TP) NOx could be reduced by using MBC on both catalysts. The net result was increased NOx conversion efficiency by one percentage point on both the LO-SCR and the primary SCR. The CO2 emissions were slightly reduced, but this effect was not significant. Finally, the MBC was used with a final setup representative of future AT
Meruva, PrathikMatheaus, AndrewZavala, BryanSharp, Christopher A.McCarthy Jr., James E.
Rail-wheel interaction plays a key role in determining the life of railway tracks. An increase in the speed and axle load leads to significant wear and fatigue damage on materials resulting in a safety concern for the Indian Railway network. In response to the above context, rail grinding technology is introduced to maintain the stability and safety of the railway system. In the present work, three (3) Zones named South-Central Railway (SCR), North Central Railway (NCR) and Northern Railway (NR) of Indian Railways (IR) were prone to severe problems pertaining to wear and fatigue damage were selected for the rail grinding performance studies. From the collected data, the performance features in terms of rail wear, width and position of contact band, length and pitch of crack, attainment of target profile, defect generation rate and rail/weld fracture analysis were evaluated. Average wear rates per 100 Gross Million Tonnes (GMT) at SCR, NCR and NR for the tangent track were found to be
Verma, SachinJoseph Selvi, BinojYogesh Shah, Vijesh
Achieving higher emission norms involves various techniques and it has always been a challenging task on meeting the same. Improving the exhaust temperature is indispensable in order to enhance better conversion efficiency on the after-treatment systems. This paper clearly investigates on the various strategies involved to improve the exhaust temperatures of selective catalytic reduction and post injection strategies to meet the emission norms. On the basis of MIDC operation, key load points were selected and split injections with three pulses were implemented. The variation of both the post injection timing and quantity were performed in this paper in order to evaluate the optimum output. The effect of post injection timing and quantity variation on hydrocarbon emissions, carbon monoxide, diesel oxidation catalyst temperatures was observed on all load points. The above strategy was also evaluated on generating the pressure crank angle data. SCR efficiency improvement was investigated
Anbarasu, MuthusamyShangar Ramani, Vagesh
Emissions development work for gasoline aftertreatment systems is often conducted in a laboratory on a chassis dynamometer. In this situation, extractive sample lines are frequently connected to the aftertreatment system before and after various components, such as a three-way catalyst, selective catalytic reduction substrate, and the like. This is done to measure the conversion efficiency of the aftertreatment system components as a function of time. The time series exhaust component concentration data, also referred to as continuous data, are combined with a measure of exhaust volumetric flowrate and used to calculate mass-based emissions. As gasoline powertrains become cleaner and produce lower levels of criteria emissions, the proximity (i.e., colocated or not colocated) of the volumetric flowrate and concentration measurements may affect the accuracy of the overall mass emission calculation. In this work, we investigate the effect of water condensation and evaporation on
Kempema, Nathan J.Lown, AnneKralik, LoraLoos, Mike
Aftertreatment system meeting BS-VI emission regulations for diesel engines led to a decrease in NOx emissions to a low level. Selective catalyst reduction (SCR) is the most prominent and mature technology used to reduce NOx emissions. Initially, the UWS injection layout was designed without any mixer which resulted in low NH3 uniformity on SCR monolith with reduced UWS conversion efficiency, leading to concentrated wall spray loads. A dual-stage static mixer was designed and introduced to enhance the proper mixing of UWS droplets with exhaust gas upstream, to accelerate UWS breakup and evaporation of droplets. The mixer blades enhance the local turbulence, which resulted in a high mixing degree of droplets with the exhaust gas stream, thus reducing the crystallization risk at the mixer and the surrounding area. Mixers also extend the evaporation path, residence time, and thermal decomposition for droplets. Mixer shape was optimized with various design parameters with good structural
Benny, BineeshBala, HarinivasS, Veera VishnuM, DayanandaB, Sriram
Low temperature Diesel exhaust operations such as during low-load cycles are some of the most difficult conditions for SCR of NOx. This, along with newer regulations targeting substantial reduction of the tailpipe NOx such as California-2024/2027 NOx regulations, adds to challenges of high efficiency SCR of NOx in low temperature operations. A novel design, low-cost, low-energy Electrically Heated Mixer (EHM™), energized via the 12, 24 or 48 V vehicle electrical system, is used to accelerate formation of reductants (ammonia, isocyanic acid) in low temperature exhaust (low load cycles), so to enable high efficiency SCR of NOx in most challenging SCR conditions, while also mitigating urea deposit formation. EHM™ is also used to heat the cooler exhaust flow during engine cold-start. It easily fits common exhaust configurations and can be utilized on light, medium or heavy duty Diesel aftertreatment systems, on- or non-road or in stationary systems
Masoudi, MansourPoliakov, NickNoorfeshan, Sahm
To reach close to zero tailpipe NOx emissions, a double-SCR (selective catalytic reduction) system is proposed. In that, the first SCR unit would be placed upstream of the diesel particulate filter (DPF) and the second SCR unit downstream of DPF. This study focused on the experiments of the first SCR unit. The experiments were conducted utilizing a new, 4.4-liter heavy duty diesel engine that was connected to a research facility for studying after-treatment systems in controlled environment. Three different SCR’s: a vanadium-based SCR (V-SCR), a copper-based SCR (Cu-SCR) and a vanadium-based SCR including an ammonia slip catalyst (V-SCR+ASC) were studied. Studies were done at different exhaust temperatures from 215°C to 350°C. Emissions of NO, NO2, NH3, N2O, CO, CO2 and hydrocarbons were measured by FTIR. Particulate emissions (PM, PN) were studied as a part of the experiments. The results showed that the three SCR units performed differently. The performance of the V-SCR catalyst was
Lehtoranta, KatiVesala, HannuKoponen, PaiviMaunula, TeuvoHapponen, Matti
This SAE Information Report provides SAE’s recommendations for meeting the requirements for REAL NOx accuracy demonstration and for the implementation of REAL NOx binning requirements as defined in OBD regulations 13 CCR 1971.1 and 13 CCR 1968.2
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The design of modern aftertreatment systems to meet Real Driving Emissions (RDE) regulations is a significant challenge faced by manufacturers today. This is because testing vehicles under RDE conditions is both time consuming and expensive. In this study, we quantify the effect of real driving conditions on vehicle performance (efficiency and emissions) using a system model comprised of vehicle and aftertreatment subsystems, built using the commercial simulation software GT-SUITE. The developed system model will allow manufacturers to predict vehicle performance and prospective emissions under real driving conditions early in the development cycle and to ensure compliance with current and future regulations. The engine used in this study is a 2.0 L turbocharged diesel engine, while the aftertreatment system consists of a diesel oxidation catalyst (DOC), a diesel particulate filter (DPF), and a selective catalytic reduction (SCR). The simulated real driving route was generated by using
Mireault, PhilArtuković, DominikGayatri, MohitBender, AchimWahiduzzaman, Syed
Engines have improved a lot and reached a new state of the art in terms of combustion technology, but they alone still fall short in achieving emission limitations without any trade-off on performance. Selective Catalytic Reduction (SCR) is the key technology used to meet the increasingly strict Nitrogen Oxides (NOx) emission regulations. The injection of Urea Water Solution (UWS—32.5% urea solution) upstream the catalyst is currently the leading technique for reducing the emission of NOx from the exhaust (DeNOx). A uniform distribution of the spray droplets is very crucial to achieve a good conversion efficiency. Therefore, the size and velocity distribution of the droplets are of high importance in deciding the fate of the DeNOx process. This article describes an approach of modelling the UWS spray and its validation against experimental data collected under realistic exhaust-like conditions. Droplet size distributions and velocities were recorded using Phase Doppler Anemometry (PDA
Khan, DaniyalBjernemose, Jesper HolmLund, Ivar
Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks. Since the SCR catalyst generally being used in the market today is
Ido, YuyaKinoshita, KojiSaito, ChikaHirose, ShogoToyoshima, HideyukiOhara, EtsujiHonda, TakahiroKaneda, AtsushiWells, AlexanderVogt, Claus Dieter
The implementation of stringent BSVI norms from April 2020 has greatly revolutionized the automobile industry. With the plan for implementation of more stringent BSVI OBD-II norms from April 2023, in place, meeting legislative limits, particularly with CI engines, will be a challenge. The major challenge is the reduction in nitrogen oxides (NOx) which necessitates a selective catalytic reduction (SCR), together with effective calibration, to maintain the conversion efficiencies at the highest possible levels. The conversion efficiency is majorly dictated by temperature and exhaust mass flow. Hence, optimization of thermal management modes are very important. This is achieved by a close-coupled diesel oxidation catalyst (DOC). This paper describes the stepwise effectiveness of model based development for model in the loop simulation on virtual test bed (VTB), along with, experimental testing that goes hand in hand for development of a close-coupled DOC for a light & medium duty (LMD
R, Nishant SharmaChaurasia, VikasLakhlani, HardikMeghwal, FataRathi, HemantkumarShukla, AkhileshAgrawal, Sachin
A physics-based model for SCR (Selective Catalytic Reduction) was developed based on five independent SGB (Synthetic Gas Bench) tests. There are NH3 adsorption & desorption test, NO oxidation test, NH3 oxidation test, SCR reaction (NOx & NH3) test and SV (Space Velocity) test. To validate the accuracy of SCR model’s prediction, transient reactor tests were conducted at four different input conditions. A newly developed SCR model showed more than 90% prediction accuracy in transient test conditions in view of cumulative NOx. Validation of SCR model was conducted on 1.6L light duty diesel vehicle in the WLTC (Worldwide Harmonized Light vehicles Test Cycle). Based upon this SCR model, vehicle level SCR calibrations used for urea dosing control were made and validated in the emission test cycles like WLTC. NOx and NH3 slip from calibration data (map data for dosing control of urea solution) DCU calculated by SCR model were comparable with those from calibration data measured on engine
Choi, SungmuKim, ChangCho, Jiho
This paper analyzes the use of an ammonia sensor for feedback control in diesel exhaust systems. We build our case around the specific example of the heavy duty transient cycle, and an exhaust system with an SCR catalyst, a single urea injector and an upstream and downstream NOx sensor. A key component in our analysis is the inclusion of the tolerance of the ammonia sensor. We show that with the current understanding of the sensor tolerance, the ammonia sensor has limited benefit for controls
Van Nieuwstadt, Michiel
Selective Catalytic Reduction (SCR) is a process where one injects an aqueous solution of urea into a diesel exhaust system in order to reduce NOx emissions. The urea solution known as AdBlue® or Diesel Exhaust Fluid (DEF) is stored in a DEF Tank that can under cold weather conditions freeze over. Since AdBlue® is unusable while frozen, we use heaters installed in the tanks to melt AdBlue® with government regulations mandating time required to melt AdBlue® in the tank. In this article, we investigate whether a CFD (Computational Fluid Dynamics) based methodology can accurately evaluate time required in melting AdBlue® for a given DEF Tank and heater coil design for a production vehicle as per standard testing procedure. Simulations used a coupled methodology with PowerFLOW® as the flow solver and PowerTHERM® as the thermal solver. The flow simulation did require an accurate modelling of phase change from solid to liquid for AdBlue®. We observe excellent agreement between test data and
Mukutmoni, Devadattakandasamy, SatheeshTabacchi, DilettaScotti, MarcoCrippa, LucaFilippova, OlgaZhou, Chong
During the past decades, the Nitrogen Oxides (NOx) emission limitations have become stricter, promoting the development of after-treatment systems like Selective Catalytic Reduction (SCR) for emission reduction purposes. The Urea-Water Solution (UWS) spray characteristics can directly have an effect on the SCR efficiency. To understand the droplet breakup and mixing of the UWS with the surrounding air under different operating conditions, a computational campaign has been set up. The main objective of the present study is to recreate the spray injection process, as well as the chemical processes that the UWS spray undergoes, and to analyze the optimal injection angle to maximize the amount of ammonia generated during the injection process by means of Computational Fluid Dynamics (CFD). A Eulerian-Lagrangian framework has been employed to track the evolution of the injected droplets within a Reynolds-Averaged Navier-Stokes (RANS) turbulence formulation. Typical injection pressures have
Payri, RaulMarti-Aldaravi, PedroBracho, GabrielaMarco, Javier
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