Browse Topic: Catalytic converters
Spark ignition engines utilize catalytic converters to reform harmful exhaust gas emissions such as carbon monoxide, unburned hydrocarbons, and oxides of nitrogen into less harmful products. Aftertreatment devices require the use of expensive catalytic metals such as platinum, palladium, and rhodium. Meanwhile, tightening automotive emissions regulations globally necessitate the development of high-performance exhaust gas catalysts. So, automotive manufactures must balance maximizing catalyst performance while minimizing production costs. There are thousands of different recipes for catalytic converters, with each having a different effect on the various catalytic chemical reactions which impact the resultant tailpipe gas composition. In the development of catalytic converters, simulation models are often used to reduce the need for physical parts and testing, thus saving significant time and money. However, calibration of these models can be challenging and requires significant time
The model-based design is very much prominent in the vehicle level control system design and state estimation algorithms. It gives the edge to understand and interpret the dynamic systems. Three-way catalytic converter is a thermo-chemical device to convert the toxic oxides into carbon dioxide and water vapor, during this conversion reactions it generates the heat over the catalyst surface. Detailed chemical and thermal model of the catalyst will be able to predict the conversion efficiency, state of stored oxygen (SoX) and oxygen storage capacity (OSC). As the catalyst get aged, the reaction rates of conversion reactions deteriorate, in results the temperature dynamics also varies which wanes the exothermic heat. In this work, a novel perspective is presented to capture the behavior of SoX and health of the catalytic converter using thermal model analysis of TWC. An equivalent second order multi input single output (MISO) linear sub-space model is identified for the complex detailed
Due to climatic movements and politics, there is no doubt that a stricter emission legislation will soon face the two-wheeler sector and their manufacturers with new challenges. Additional to the already limited pollutants, a limitation of particulate number will probably also be introduced, which means that there is an urgent need for action in exhaust gas after treatment and particulate reduction systems. For natural aspirated, port injected engines, as used in two-wheeler-technologies, conventional systems already established in passenger cars are not necessarily applicable. Moreover, the emission spectrum is fundamentally different from passenger car engines due to the better homogenization of they typically used MPFI engine types. Adapting conventional particulate filter technologies to the finer particles of MPFI engines would result in a disproportionately larger exhaust backpressure. For this reason, we are investigating the effects of 3-way catalytic converters on particulate
The carbon footprint calculation of a catalytic converter coating process at Heraeus Precious Metals is presented in this publication. The emission hot spots are identified and discussed. Heraeus Precious Metals is a German world-wide leading company in the field of precious metal products and Tier-1 Supplier of emission catalytic converter coatings. In the first step of the carbon footprint calculation, all relevant raw materials and production process steps of the coating process are collected and modelled by use of a flowchart. In this case study the manufacturing of the metal honeycomb carrier is not included in the calculation. Transport emissions from the origin of the raw materials to the manufacturing plant of Heraeus Precious Metals in Germany are also considered in the carbon footprint calculation. Included activities for the production of the washcoat dispersion are the mixing of all components by use of an electric agitator and the grinding of the mixture by use of an
Emission Control has always been a major concern in each and every field. An increase in emissions leads to climate change, global warming, and even various diseases. The transportation system is responsible for around 30% of emission production, of which 70% of the total atmospheric burden comes from automobiles. Recently developed emission-free electric vehicles have positively affected the levels of impurity in the environment, yet the remaining Internal Combustion Engine (ICE) vehicles on the road have been left with unchecked emissions. Traditional Catalytic Converters are widely used to reduce the emissions of vehicles. It works on the principle of converting hazardous gases emitted from the engine to less harmful carbon dioxide (CO2), nitrogen (N2), and water (H2O). It is integrated with the exhaust of the engine. High efficiency and better emission control catalytic converters are still major milestones to achieve for automotive industries. For this purpose, a new approach is
Kinetic modelling of exhaust aftertreatment systems is a topic of extensive research in the automobile sector. This study represents the modelling of catalytic reactions on the surface of platinum dispersed diesel oxidation catalysts. In addition to oxidation reactions in the catalytic converter, a model for hydrocarbon adsorption/desorption on zeolite was adopted and validated with experimental results. The model was further used to simulate the experimental results at two different Pt loadings on the catalyst surface. The simulated results were observed to fit reasonably well with the experimental results at each Pt loading on the catalyst. The adsorption/desorption behaviour on the catalyst surface was found to be affected by Pt loading. The simulation results have shown that Pt atoms might have occupied the active site of zeolite which resulted in the reduction of adsorption/desorption rates. Less Pt loading has caused more storage sites on the zeolite surface and hence, higher
With the advent of BS VI regulations, automotive manufacturers are required to innovate the powertrains, fuel systems, exhaust and its after treatment systems to meet the regulatory requirements. The exhaust regulations can be met either by reducing the exhaust gases being generated by the engine (attacking the source) or by treating the exhaust gases in after treatment devices. The choice of the opted system varies with the manufacturer. The after-treatment devices such as catalytic converters are generally mounted in the engine compartment to take advantage of high temperature of exhaust gases to yield the reactions. Such an arrangement imposes a lot of thermal load on the peripheral components such as gearshift cables, bearings, oil seals, driveshafts etc. Thermal shields or thermal sleeve are used to address thermal issue and to protect transmission components. System level validation test requirement of transmission need to be re-visited considering change in environmental
Affordable, efficient and durable catalytic converters for the Commercial Vehicle and Non-Road industry in all countries are required to reduce vehicle emissions under real world driving conditions and fulfill future legal requirements. Specially for India traffic conditions and payload to engine size conditions new cost-effective solutions are needed to participate in a cleaner and healthier environment. Metallic substrates with structured foils like the Transversal StructureTM (TS) or the Longitudinal StructureTM (LS) have been proved to be capable of improving conversion behavior, even with smaller catalyst size. Now Vitesco Technologies is developed a new Substrate for Heavy duty applications that specifically maintains the geometric surface area at a very high level and improves further the mass transport of the pollutants, which potentially leads together to very high pollutant conversion rates. Together with active temperature management this solution will maintain a high
Gasoline engine control strategies ensure a combustion control around stoichiometry. That is because the three-way catalytic converter allows CO and HC oxidation under lean operating conditions while ensuring NOx reduction for rich mixtures. In case of engine malfunction, the controller must adapt to compensate for potential torque loss and other critical attributes, potentially leading to significant deviation of the fuel-air mixture richness from stoichiometry and higher emission levels. Therefore, during development of the engine fault diagnostics, the impact on the pollutant emissions must be considered. In this paper, a model-based development process is proposed. It is based on system simulation modelling techniques, where a complete exhaust line is represented in order to predict tail-pipe emissions under stoichiometric, lean and rich conditions, for engine control design purposes. Two different modelling approaches are applied and evaluated in this paper. First, a physics-based
The present work investigates a means of controlling engine hydrocarbon startup and shutdown emissions in a Wankel engine which uses a novel rotor cooling method. Mechanically the engine employs a self-pressurizing air-cooled rotor system (SPARCS) configured to provide improved cooling versus a simple air-cooled rotor arrangement. The novelty of the SPARCS system is that it uses the fact that blowby past the sealing grid is inevitable in a Wankel engine as a means of increasing the density of the medium used for cooling the rotor. Unfortunately, the design also means that when the engine is shutdown, due to the overpressure within the engine core and the fact that fuel vapour and lubricating oil are to be found within it, unburned hydrocarbons can leak into the combustion chambers, and thence to the atmosphere via either or both of the intake and exhaust ports. As well as shutdown it also affects the startup process, where higher hydrocarbon emissions are caused due to the forced
The three-way catalytic converter (TWC) is a vital component of the S.I. (Spark Ignition) engine to meet the current emission norms. TWC can perform the three conversion processes simultaneously. Hence, health diagnosis and performance monitoring of TWC is a major requirement of the power-train control system. In TWC modeling, the chemical species CO, THC, NOx, O2, and CO2 are the major components of the redox reaction over the wash-coat surface which impacts the overall conversion efficiency of the gases. This research work examines a generalized chemical model for a fresh catalytic converter validated for significant engine operating points in an urban drive cycle. The gas concentration measurements across the catalyst are harvested from an engine dynamo-meter test-bed. This work attempts to find the best method to optimize the chemical kinetic parameter of the Arrhenius equation parameters. An optimization framework is designed and has been tried on two different optimization
Diesel engine exhaust poses an ongoing threat to human health as well as to the environment. Automotive exhaust treatment systems have been developed over the years to reduce the large amount of diesel particulate matter (DPM) released to the atmosphere. Current systems can be categorized as selective catalytic reduction, catalytic converters, and diesel particulate filters. This study presents an emission system that focuses on the removal of exhaust particles using Brownian diffusion of DPM toward fog drops followed by cyclonic separation of DPM rich fog drops. The experimental system consisted of a 13.2 kW diesel engine, heat exchanger to cool the exhaust to saturation temperature, ultrasonic fogger, cyclone separator, and recovery of waste particulate. Representative emission tests have been performed at five different diesel engine speeds and corresponding crankshaft loads. The scavenging coefficient as measured by the particle number concentration is 0.4-0.65 without fog and 0.6
With the increasing demand of emission reductions from the automotive industry, advanced after-treatment strategies have been investigated to overcome the challenges associated with meeting increasingly stringent emission regulations. Ongoing investigations on low temperature combustion (LTC) strategies are being researched to meet future emission regulations, however, the lowered exhaust temperature presents an even greater issue for exhaust after-treatment due to the change in combustion modes. Catalyst temperature is critical for the catalytic ability to maintain effective conversion efficiency of regulated emissions. The use of periodic flow reversal has shown benefits of maintaining catalyst temperature by alternating the exhaust flow direction through the catalytic converter, reducing the catalyst sensitivity to inlet gas temperature fluctuations. Cyclically alternating the exhaust flow direction can produce a thermal wave, elevating the central catalyst temperature above the
In this study, a new system of assessment method was developed to evaluate the characteristics of urban buses based on remote online monitoring. Four types of buses, including China V emission standards diesel bus, lean-burn CNG bus, air-fuel equivalence ratio combustion CNG bus and gas-electric hybrid bus, were chosen as samples to analyze the emission characteristics of urban buses with different engine types in urban scenario. Based on the traffic conditions in Beijing, the actual emission characteristics of buses under newly-built driving conditions were analyzed. Moreover, the emission factor database of urban buses in Beijing was established to analyze the characteristics of excess emission. The research results are shown as follows. 1) Compared with other types of buses, NOX emission factor and emission rate of lean-burn CNG bus are much higher. The equivalent air-fuel ratio CNG engine combined with TWC catalytic converter and hybrid power technology can better reduce NOX
The results of this paper will show the reader how to quantify a minimum light-off temperature to meet the required emissions standards with the use of a 3-way catalytic converter. The method can be applied to both motorcycle and larger automotive catalysts to help meet their respective emissions standards (Euro 5/Euro 7). The ability to predict a light-off temperature for any catalyst at the beginning of the project saves both time and resource. With an emphasis on how the shape of the light-off curve affects the cumulative tailpipe emissions and how shape of the light-off curves change with the ageing process. Changes in the light-off curves will be reviewed to understand how the chemical reactions and pore diffusion mechanisms within the catalyst deplete to negatively affect performance over its life time. Using the total cumulative emissions target to achieve the OBD (On Board diagnostic) requirement along with WMTC data, light-off curves were modelled using predicted catalyst
The aim of this paper was to describe a method of accelerated three way catalytic converter (TWC) ageing performed on the engine test bed for European On Board Diagnostics (EOBD) monitoring purposes and screening of different catalysts solutions. To accelerate the catalyst ageing process, the exhaust gas temperature was elevated to a range 1000 - 1200°C, which is typical for an ageing cycle performed using ovens. Catalyst emissions performance was checked at new condition (after degreening) and subsequently at predefined ageing intervals, based on the oxygen storage capacity (OSC) evaluation. The emission tests were performed in the laboratory on the chassis dynamometer using legislative cycles. The accelerated ageing method was found to be of use for verifying the EOBD functionality under vehicle operation with a degraded catalyst substrate. Secondly, the described method allows execution of a time-efficient ageing cycle on a test bed in order to validate catalyst chemistry and
Investigations were performed, in which the emission behavior of renewable and conventional fuels of different composition and renewable fuel components was observed. The influence of the start of injection on the emissions at WOT was investigated. This shows how much wall and valve wetting as well as the available evaporation time affects the mixture formation of the different fuels. Further, the air fuel ratio in an operating point for catalytic converter heating, with medium engine temperatures, was varied. This shows the ability of evaporation of the fuels at engine warm-up conditions and sub-stochiometric λ-values. The studied fuels were four fuel mixtures of significantly different composition of which three were compliant with the European fuel standard EN 228. A RON 98 in-field fuel, a Euro 6 reference fuel, an Anti-Spark-Fouling (ASF) fuel (designed for minimum soot production) and a potentially completely renewable, thus CO2-neural, fuel, which is designed by Dr. Ing. h.c. F
Oxides of Nitrogen (NOx) emissions are considered as among the most harmful emissions globally having a direct influence on human beings and the environment. This work deals with a strategy to arrive at achieving lower NOx values consistently in mass production of single cylinder automotive diesel engines meeting BS IV Emission standards using the DoE technique for dimensional optimization of critical parameters. Catalytic converters and particulate filters are mostly used as after - treatment devices for compression Ignition (CI) engines for bringing down the limits (Values) of the pollutants from the tail pipes. But the real ingenuity lies in achieving the same effect through optimization of in - cylinder combustion. Optimization of the critical factors like Nozzle Tip Protrusion (NTP), Static Injection Timing (SIT), Bumping Clearance (BC) and Swirl Number (SN) are considered as the most important engine design parameters for ensuring the optimum combustion which help release of
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