Browse Topic: Nanomaterials

Items (1,185)
ABSTRACT The purpose of this project was to study the underlying fundamental phenomena associated with the formation of dendrites in Lithium-metal batteries through the use of in-situ optical microscopy, and other techniques, and develop material solutions to suppress dendritic growth, such as carbon (graphene) nanoribbons (CNRs). Throughout the course of this effort, sixteen different slurry compositions were prepared and made into a total of 96 electrodes (six of each composition). These electrodes were built into in-situ optical cells and coin half-cells and then tested using in-situ optical microscopy and cycle testing. The results found that the inclusion of CNRs generally reduced the severity of dendrite formation. Citation: D. Skalny, J. Mainero, E. Joseph, M. Anger, B. Fahlman, “Fundamental Study on the Suppression of Dendrite Growth in Lithium-Metal Batteries via Carbon Nanoribbons Through In-Situ Optical Microscopy”, In Proceedings of the Ground Vehicle Systems Engineering
Skalny, DavidMainero, JamesJoseph, EliseAnger, MichaelFahlman, Bradley
ABSTRACT Additions of both carbon fiber (CF) and carbon nano-tubes (CNTs) as reinforcements to polyurea (PUr) based adhesives are computationally investigated. Both CF and CNTs show an increase in stiffness. The effect of CF reinforcements on the PUr is more pronounced than the CNT’s but this due to CNT loading being dramatically lower. On percent basis the CNT effect on strength was greater than the CF. Increasing hard segment content of PUr also had a positive effect on the joint strength, but a negative effect on the shear joint displacement. Finally the addition of CF reinforcements moved the performance of a PUr formulation from a Group IV adhesive into the Group III category. This paper illustrates the potential for commonly available reinforcements to be used to tailor the strength elongation characteristic of a PUr adhesive system. Citation: Demetrios A. Tzelepis, Robert Hart, “Optimization of Nano-Enhanced Elastomeric Adhesives Through Combined Experimental and Computational
Tzelepis, Demetrios A.Hart, Robert
ABSTRACT Fiber reinforced thermoset composites are well known for delivering 50% or more weight savings when compared with steel components while also providing strength, stiffness, and toughness. Nanoparticle additives have been shown to significantly increase the mechanical properties of thermoplastic and thermoset polymer matrices over the base matrix values. Extensive testing and characterization of composites containing graphene nanoplatelets (GnP) has been conducted and reported by XG Sciences’ (XGS) collaborators at the Michigan State University (MSU) Composite Materials and Structures Center. In a recent program with U.S. Army Tank Automotive Research, Development and Engineering Center (TARDEC), MSU investigated lightweight composites for blast and impact protection. High strain rate test facilities as well as high speed photography and non-destructive interferometry-based evaluation techniques were used to evaluate blast performance. The experimental results are presented
Privette, R.Fukushima, H.Drzal, L.T.Robinson, M.
This paper explores the groundbreaking applications of plasma propulsion engines and advanced nanomaterials in low-altitude aircraft, addressing the challenges and recent technological advancements that make such applications feasible. Traditional space plasma thrusters operate effectively in near-vacuum conditions by taking advantage of the ease of plasma ignition at low pressures. However, these thrusters face significant difficulties when operated at near-atmospheric pressures found in low-altitude environments, where plasma ignition is challenging. This paper highlights recent breakthroughs in high-pressure plasma glow discharge technology and the integration of nanomaterials, which together enable the use of plasma propulsion engines in low-altitude aircraft. These innovations offer substantial advantages over conventional engines, including higher efficiency, reduced emissions, and the potential to fundamentally change the propulsion systems of low-altitude aircraft
Ma, XinDing, ShuitingPan, YilunLiu, JinshuoQiao, HuizheYang, Jincai
A flexible and stretchable cell has been developed for wearable electronic devices that require a reliable and efficient energy source that can easily be integrated into the human body. Conductive material consisting of carbon nanotubes, crosslinked polymers, and enzymes joined by stretchable connectors, are directly printed onto the material through screenprinting
Researchers have shown that twisted carbon nanotubes can store three times more energy per unit mass than advanced lithium-ion batteries. The finding may advance carbon nanotubes as a promising solution for storing energy in devices that need to be lightweight, compact, and safe, such as medical implants and sensors
Researchers have discovered that minuscule, self-propelled particles called “nanoswimmers” can escape from mazes as much as 20 times faster than other passive particles. The tiny synthetic nanorobots are incredibly effective at escaping cavities within maze-like environments
When wounds happen, we want them to heal quickly and without complications, but sometimes infections and other complications prevent it. Chronic wounds are a significant health concern affecting tens of millions of Americans
Vehicle light-weighting constitutes a critical component in the automotive sector’s drive to improve fuel economy and reduce greenhouse gas emissions. Among the various options for lightweight materials, thermoplastic foams are distinguished by their durability, low weight, and environmental sustainability. This study explores the manufacturing of novel graphene-filled polypropylene (PP) foam, employing supercritical nitrogen as an eco-friendly substitute instead of conventional chemical foaming agents, and investigated the role of over-molding a solid skin over a foamed core on the flexural strength of the molded component. Our approach is broken down into four distinct investigations—Study I investigated the effect of different graphene content by weight percentage (wt.%), namely 0.1%, 0.5%, and 1%, on flexural properties and foam morphology obtained for 15 wt.% reduction of the PP thermoplastic, thereby helping identify an optimum graphene loading wt.%. Study II broadened the wt
Pradeep, Sai AdityaDeshpande, Amit MakarandShah, BhavikKhan, SaidaFarahani, SaeedSternberg, JamesLi, GangPilla, Srikanth
In this investigation, AA6351 alloy matrix composites with a larger volume proportion of SiC (20 wt%) were fabricated and tested for microstructure and mechanical behavior. Composites were hot extruded from mechanically milled matrix and reinforcements. Hot extrusion uniformly distributed reinforcements in the matrix and strengthened phase interaction. Mechanical ball milling causes AA6351 powder to become more homogeneous, reducing the mean particle size from 38.66 ± 2.31 μm to 23.57 ± 2.31 μm due to particle deformation. The micrograph shows that the SiC particles are equally dispersed in the AA6351 matrix, avoiding densification and reinforcing phase integration issues during hot extrusion. In hot extrusion, SiC particles are evenly distributed in the matrix, free of pores, and have strong metallurgical bonds, resulting in a homogenous composite microstructure. SiC powders and mechanical milling increase microhardness and compressive strength, giving MMC-A 54.9% greater than AA6351
Saiyathibrahim, A.Murali Krishnan, R.Jatti, Vinaykumar S.Jatti, Ashwini V.Jatti, Savita V.Praveenkumar, V.Balaji, K.
Engineers at the University of California San Diego have developed an ultra-sensitive sensor made with graphene that can detect extraordinarily low concentrations of lead ions in water. The device achieves a record limit of detection of lead down to the femtomolar range, which is one million times more sensitive than previous sensing technologies
Borophene is more conductive, thinner, lighter, stronger, and more flexible than graphene, the 2D version of carbon. Now, researchers have made the material potentially more useful by imparting chirality — or handedness — on it, which could make for advanced sensors and implantable medical devices. The chirality, induced via a method never before used on borophene, enables the material to interact in unique ways with different biological units such as cells and protein precursors
Advances in optical sensors and imaging technologies are ever more rapidly assimilated into how humans interact, understand themselves, and explore the world around them. The scope of inquiry for optical devices is broad and they enable technologies within, such as implanted transdermal bioMEMS devices, and beyond, or as space-flight surveyors deployed as near and deep space instruments. Central to the functionality of modern optical devices, ultra-narrow bandpass (UNBP) thin-film optical filters enable discrimination of sub-nanometer bands inside broad spectra. These filters, pioneered as NIR DWDM filters for the telecommunications industry, are now essential in extracting meaningful signal from imaging and sensing devices operating anywhere between the deep ultraviolet and the mid infra-red bands
University of Rochester Medical Center Rochester, NY
The present work deals with the effects of nano-additives on ternary blend biodiesel fuel added in diesel engine. The ternary blend comprises of mustard oil biodiesel and rice bran oil biodiesel, synthesized by means of transesterification and diesel. Nano-additives used in the current study include carbon nanotubes (CNT) and MgO/MgAl2O4 spinel, which were added in a suitable concentration to the biodiesel. CNTs were procured from the market and MgO/MgAl2O4 spinel was prepared by co-precipitation via ball milling process. The nano-additives were characterized by means of FTIR (Fourier transform infrared spectroscopy), AFM (atomic force microscopy), and DSC (differential scanning calorimetry) analysis. Biodiesel blend samples were prepared such as B20 (20% biodiesel + 80% diesel), B20 + CNT (1000 PPM), B20+MgO/MgAl2O4 spinel (1000 PPM), and B20+CNT+MgO/MgAl2O4 spinel (1000 PPM) were tested against diesel fuel. The maximum increase in brake thermal efficiency (BTE), oxides of nitrogen
Jeyakumar, NagarajanDhinesh, BalasubramanianPapla Venugopal, Inbanaathan
This research explores the experimental analysis of titanium alloy using an innovative approach involving a 2–7% carbon nanotube (CNT)-infused cubic boron nitride (CBN) grinding wheel. Employing a full-factorial design, the study systematically investigates the interactions among varied wheel speed, workpiece feed rate, and depth of cut, revealing compelling insights. The integration of CNTs in the CBN grinding wheel enhances the machining performance of titanium alloy, known for its high strength and challenging machinability. The experiment varies CNT infusion levels to assess their impact on material removal rate (MRR) and surface finish. Significantly, MRR is influenced by CNT content, with 5% and above demonstrating optimal performance. The 7% CNT-CBN wheel exhibits a remarkable 61% improvement in MRR over the conventional CBN wheel. Interaction studies highlight the pivotal role of depth of cut, indicating that slower speeds and feeds, combined with increased depth of cut
Stephen, Deborah SerenadeSethuramalingam, Prabhu
The demand for enhanced safety and extended lifespan of brake systems prompts the investigation to increase the static mechanical properties and fatigue resistance of commercial vehicle brake spiders through the incorporation of niobium nanoparticles into a cast iron alloy. This study aims to improve the material structure as well as the static and dynamic mechanical properties of the component. Chemical, microscopic, and mechanical analyses were conducted in samples of the nanostructured alloy and in the spider. A durability test was performed using a structural bench called “Chuker” to assess the potential increase in fatigue life. The Chuker is capable of simulating a real-world brake system condition, including torque magnitudes up to 17.5 kNm, which are the highest to be withstand by the designed brake power. This torque replicates the brake system activation during a vehicle emergency braking. The spiders manufactured with the nanostructured alloy exhibited most uniform
Titton, Angelo PradellaTuzzin, MatheusLopes, Carlos H. R.Marcon, LucasBoaretto, JoelKlein, Aloísio N.Cruz, Robinson C. D.
Graphene has been called “the wonder material of the 21st century.” But graphene has a dirty little secret: it’s dirty. Now, engineers at Columbia University and colleagues at the University of Montreal and the National Institute of Standards and Technology are poised to clean things up with an oxygen-free chemical vapor deposition (OF-CVD) method that can create high-quality graphene samples at scale. Their work, published in Nature, directly demonstrates how trace oxygen affects the growth rate of graphene and identifies the link between oxygen and graphene quality for the first time
Membranes of vertically aligned carbon nanotubes (VaCNT) can be used to clean or desalinate water at high flow rate and low pressure. Recently, researchers of Karlsruhe Institute of Technology (KIT) and partners carried out steroid hormone adsorption experiments to study the interplay of forces in the small pores. They found that VaCNT of specific pore geometry and pore surface structure are suited for use as highly selective membranes. The research was published in Nature Communications
Innovators at NASA’s Glenn Research Center have made several breakthroughs in treating hexagonal boron nitride (hBN) nanomaterials, improving their properties to supplant carbon nanotubes in many applications. These inventors have greatly enhanced the processes of intercalation and exfoliation. Both processes are crucial in creating usable nanomaterials and tailoring them for specific engineered applications
Since the beginning of time, people have desired the best materials for production. Metals are often too heavy to be used in manufacturing. Polymer matrix composites (PMC) can be considered more dependable than metals in practical applications because of their high strength-to-weight ratio so it is a good alternative of metals. The article’s objective is to investigate the various PMC properties that are reinforced with carbon fiber. CFRP (Carbon fiber-reinforced polymer) was first made using the hand layup method with carbon fiber as a reinforcement and epoxy resin as a matrix after a thorough literature review. As CFRP have higher stiffness and superior “strength-to-weight ratio,” fiber-reinforced polymer (FRP) composites perform notably better than various conventional metallic materials. The qualities of the matrix can be changed to enhance the characterization of FRP composites. The mechanical qualities of FRP composites have risen as a result of significant advancements in the
Haider, RehanSingh, Pradeep KumarSharma, Kamal
The present work highlights the significance of nanocomposite coatings for their ease of processing and applicability in combating corrosion. Ongoing research is dedicated to the development of an effective nanocomposite hydrophobic coating. A hydrophobic nanocomposite coating was deposited on galvanized iron (GI) using a sol-gel route with polymethylsiloxane (PDMS) reinforced with nano-SiO2. Surface morphology and chemical composition analysis, conducted with scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDAX) and Fourier transform infrared spectroscopy (FTIR), revealed the coating’s structural and compositional attributes. The resulting hydrophobic coating exhibits a water contact angle (WCA) of 104.1°, indicating a 30.45% increase compared to bare GI. Subsequent to these characterizations, the adhesion of the coated GI, rated as 4B per ASTM D3359, is followed by commendable resistance to corrosion, as evidenced by electrochemical tests. The corrosion rate
Kumar, PrakashRamesh, M.R.Doddamani, Mrityunjay
Drug-delivery researchers have developed a device with the potential to improve gene therapy for patients with inherited lung diseases such as cystic fibrosis. In cell culture and mouse models, scientists demonstrated a novel technique for the aerosolization of inhalable nanoparticles that can be used to carry messenger RNA, the technology underpinning COVID-19 vaccines, to patients’ lungs
Researchers have created a flexible paper-based sensor that operates like the human brain. They fabricated a photo-electronic artificial synapse device composed of gold electrodes on top of a 10 μm transparent film consisting of zinc oxide (ZnO) nanoparticles and cellulose nanofibers (CNFs
In a study published in Advanced Materials, researchers Pietro Veglianese, Valeria Veneruso and Emilia Petillo from Istituto di Ricerche Farmacologiche Mario Negri IRCCS in collaboration with Filippo Rossi of the Politecnico di Milano have demonstrated that an innovative nanovector (nanogel), which they developed, is able to deliver anti-inflammatory drugs in a targeted manner into glial cells actively involved in the evolution of spinal cord injury, a condition that leads to paraplegia or quadriplegia
In research that may lead to advancements in the design of next-generation airplane and spacecraft, MIT engineers used carbon nanotubes to prevent cracking in multilayered composites. Massachusetts Institute of Technology, Cambridge, MA To save on fuel and reduce aircraft emissions, engineers are looking to build lighter, stronger airplanes out of advanced composites. These engineered materials are made from high-performance fibers that are embedded in polymer sheets. The sheets can be stacked and pressed into one multilayered material and made into extremely lightweight and durable structures. But composite materials have one main vulnerability: the space between layers, which is typically filled with polymer “glue” to bond the layers together. In the event of an impact or strike, cracks can easily spread between layers and weaken the material, even though there may be no visible damage to the layers themselves. Over time, as these hidden cracks spread between layers, the composite
Advanced two-dimensional (2D) materials discovered in the last two decades are now being produced at scale and contribute to a wide range of performance enhancements in engineering applications. The most well known of these novel materials is graphene, a nearly transparent nanomaterial comprised of a single layer of bonded carbon atoms. In relative terms, it has the highest level of heat and electrical conductivity, protects against ultraviolet rays, and is the strongest material ever measured. These properties have made graphene an attractive potential material for a variety of applications, particularly for transportation-related uses, and especially for automotive engineering. The goal of drastically reducing greenhouse gas emissions has prioritized the electrification of transportation, the decarbonization of industry, and the development of products that require less energy to make, last longer, and are fully recyclable. While this chapter reviews the current state of graphene
Barkan, TerranceCoyner, KelleyBittner, JasonKolodziejczyk, BartJiang, Yuxiang
Advanced two-dimensional materials discovered in the last two decades are now being produced at scale and are contributing to a wide range of performance enhancements in engineering applications. The most well known of these novel materials is graphene, a nearly transparent nanomaterial comprising a single layer of bonded carbon atoms. In relative terms, it has the highest level of heat and electrical conductivity, protects against ultraviolet rays, and is the strongest material ever measured. These properties have made graphene an attractive potential material for a variety of applications, particularly for transportation-related uses, and especially for aerospace engineering. The goals of reducing greenhouse gas emissions and creating a world that achieves net-zero emissions have prioritized the electrification of transportation, the decarbonization of industry, and the development of products that require less energy to make, last longer, and are fully recyclable. These aspects have
Barkan, TerranceWalthall, RhondaDixit, SunilDavid, AharonWebb, PhilipFletcher, Sarah
Light is used in many ways in sensor technology for high precision applications. For example, white light technology can be used for confocal chromatic sensors and interferometers that can make extremely precise and accurate measurements of distance and thickness down to the sub-nanometer range. This makes them suitable for production monitoring in different industries, including semiconductor fabrication. However, even though both sensor types work with white light technology, the two measurement methods differ significantly, although they complement each other
This study focused on the synthesis and characterization of monodisperse spherical TiO2 nanoparticles doped on the surface with Se (IV) in order to increase the mechanical properties of the bonded joint reinforcing. Work will begin with the synthesis of monodisperse quasi-spherical TiO2 nanoparticles with a modal diameter of less than 20 nm, using the sol-gel technique. Se (IV) selenium surface doping changed the specimen’s chemistry and physics. Different initial concentrations of the doping element will be tested. Next, a physicochemical characterization of the different solid systems will be carried out in order to determine the effect of the doping element on the properties of titanium dioxide. Their morphology and size will be studied through transmission electron microscope observations; volume chemical composition by X-ray diffraction analysis, EDX (energy-dispersive X-ray), and XRF (X-ray fluorescence). The careful selection of 4% and 6% concentrations produced the optimum
Hadjez, FayssalMaouche, HichemBoumediri, HaithemChorfi, SofianeBoukelia, Taqiy Eddine
In recent years, the use of cutting fluids has become crucial in hard metal machining. Traditional non-biodegradable cutting fluids have long dominated various industries for machining. This research presents an innovative approach by suggesting a sustainable alternative: a cutting fluid made from a blend of glycerol (GOL) and distilled water (DW). We conducted a thorough investigation, creating 11 different GOL and DW mixtures in 10% weight increments. These mixtures were rigorously tested through 176 experiments with varying loads and rotational speeds. Using Design-Expert software (DES), we identified the optimal composition to be 70% GOL and 30% DW, with the lowest coefficient of friction (CFN). Building on this promising fluid, we explored further improvements by adding three nanoscale additives: Nano-graphite (GHT), zinc oxide (ZnO), and reduced graphene oxide (RGRO) at different weight percentages (0.06%, 0.08%, 0.1%, and 0.3%). Comparative tests using a four-ball wear tester
Ganesh, S.Sethuramalingam, Prabhu
This study investigates the effects on combustion characteristics of aluminum oxide (Al2O3) nanoparticles as additives for diesel in a constant volume chamber. Depending on the amount of aluminum oxide nanoparticles added, the test fuels are labeled as DA25, DA50, and DA100, which represent 25, 50, and 100 mg of aluminum oxide nanoparticles into 1 L of pure diesel, respectively. The ambient temperature for this experiment ranged from 800 to 1200 K to cover conventional and low-temperature combustion regimes. The oxygen concentration ranged from 21% to 13% to simulate different levels of exhaust gas recirculation (EGR). Based on in-cylinder pressure traces and results of apparent heat release rates, there was an improvement in combustion characteristics with the addition of aluminum oxide nanoparticles. The best combustion characteristics improvement was obtained under 800K/13% oxygen concentration case, where peak combustion pressure and heat release rate increased by 1.84% and 5.42
Ji, HuangchangLee, TimothyZhao, ZhiyuChen, Shengwei
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