Browse Topic: Metallurgy
g-C₃N₄, a metal-free semiconductor photocatalyst, demonstrates remarkable potential, but its practical application in pollutant degradation is significantly limited by the rapid recombination of photogenerated electron-hole pairs and low photocatalytic efficiency. To address this, a series of magnetic recyclable g-C₃N₄/CoFe₂O₄ composite photocatalysts with different CoFe₂O₄ doping ratios were innovatively designed and prepared via thermal polymerization, sol- gel, and combined with ultrasonic and heat treatment processes. The novelty of this composite design lies in the effective integration of magnetic CoFe₂O₄ with g-C₃N₄ through a heterojunction structure. It substantially boosts the absorption of visible light. Concurrently, it effectively fosters the separation and mobility of photo-induced charge carriers. The composite materials were systematically characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, photoluminescence spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy. Using tetracycline hydrochloride as the target pollutant, the photocatalytic activity of the composites was evaluated under visible light irradiation, and the effects of initial concentration, catalyst dosage, and the influence of solution pH on degradation efficiency were also examined. The results indicated that the composite with a CoFe₂O₄ to g-C₃N₄ mass ratio of 1:3 (denoted as 3-CN/CFO) exhibited the optimal performance: a TCH degradation rate of 80.29 % within 105 minutes and a total organic carbon removal rate of 61.63 %. After five consecutive cycling experiments, the degradation efficiency remained above 70 %, demonstrating good reusability and stability. The performance improvement is attributed to the formation of heterojunctions in the composite, which effectively facilitates charge separation, inhibits carrier recombination, and enhances visible light absorption. Furthermore, the inherent magnetism of the composite permits efficient recovery, streamlining its integration into practical applications. Toward the purification of antibiotic-contaminated water, this research proposes a viable method for fabricating highly effective and recyclable photocatalysts.
This study carefully designed and successfully developed a mechanical voltage stabilizing control device. The device uses silicone oil as the key component material of the liquid spring and 1Cr13 as the main material of the pressure control unit, enhancing its high-pressure resistance (up to 35 MPa), oxidation resistance, and acid-alkali corrosion resistance. By optimizing the transmission mechanism and simplifying the pressure regulation module, the device achieves a pressure regulation range of 0.1–21 MPa with an accuracy of ±0.01 MPa, significantly broader and more precise than traditional devices. To address manufacturing challenges, advanced CNC machine tools, ceramic cutting tools, and optimized heat treatment processes (e.g., quenching and tempering) were adopted, ensuring component machining accuracy within ±0.02 mm. Field applications in 13 oil wells demonstrated a 15.6% increase in daily oil production (from 25.5 t/d to 29.5 t/d) and a 17.9% increase in daily gas production (from 2800 m^3/d to 3300 m^3/d), with stable casing pressure control at 5.3 MPa. The device has created 1.225 million yuan in economic benefits while eliminating safety hazards, providing critical technical support for efficient and environmentally friendly oil and gas production.
Blended metal powders offer a compelling alternative to pre-alloyed powders in metal additive manufacturing by providing access to a wider range of alloy compositions and avoiding the high costs in producing pre-alloyed powders. In this work, a new and crack-free Ti-5AlMnScZrMgSiFe alloy (in wt.%) was manufactured by laser powder bed fusion (L-PBF) from mixed powders to investigate the microstructures, mechanical performance of printed parts. Ti-5 AlMnScZrMgSiFe alloy contains both alpha (α) and alpha prime (α′) phases. Further microstructural characterizations show that the L-PBF Ti-5 AlMnScZrMgSiFe contain dense dislocations and twins formed in additive manufacturing process. The as-printed Ti-5 AlMnScZrMgSiFe alloy exhibits a tensile fracture strength of ~950 MPa with a fracture elongation of ~12.5%. The eye-catching properties are attributed to the dense dislocations, nano-twins and solid-solution strengthening.
This specification, in conjunction with the general requirements for steel heat treatment covered in AMS2759, establishes the requirements for heat treatment of precipitation-hardening corrosion-resistant, maraging, and secondary hardening steel parts. Parts are defined in AMS2759. Parts made from steels other than those specified in this specification may be heat treated in accordance with the applicable requirements herein using processing temperatures, times, and other parameters recommended by the material producer unless otherwise specified by the cognizant engineering organization. General ordering instructions are specified in AMS2759.
Current lithium-ion batteries should generally only be charged above 0 °C, as charging below this temperature can promote lithium plating and irreversible degradation. However, conventional pack-level heating elements increase system mass and design complexity. In addition, heat is transferred from outside into the cell, causing the temperature inside the cell to rise slowly. This study evaluates internal Joule heating of cylindrical Li-ion cells using a zero-mean square-wave current excitation and quantifies the associated aging impact. LG INR21700-M50L cells were tested at 0 °C, −10 °C, and −20 °C with three excitation frequencies (50 Hz, 1 Hz, 10 mHz) at 5 A amplitude. Each cycle consisted of 30 min heating followed by 60 min cooling; reference capacity-based state of health (SOH) was assessed every 50 cycles up to 400 cycles. A maximum surface temperature rise of 14.3 K was achieved, with larger temperature rise at lower ambient temperature and lower excitation frequency. Capacity fade remained below approximately 1% for most conditions; however, at −20 °C and 10 mHz a pronounced SOH decrease to 87% was observed, indicating a critical operating regime. The results provide practical guidance for pulse-heating parameter selection and highlight the need for safeguards and further diagnostics in extreme low-frequency excitation at very low temperatures. This heating approach is particularly suitable for simpler battery-electric applications without thermal management, such as e-bikes or power tools. However, it may also be relevant for applications with existing thermal management systems, as it simplifies battery pack design.
This specification, in conjunction with the general requirements for steel heat treatment covered in AMS2759, establishes the requirements and procedures for three classes of gas, vacuum, liquid, and low-pressure carburizing (LPC) and related heat treatment of parts fabricated from carburizing-grade steels. Parts made from steels other than those specified in the detail specifications may be heat treated in accordance with the applicable requirements using processing temperatures, times, and other parameters recommended by the material producer. This specification does not cover pack carburizing.
For brake and clutch components of aircraft vehicles which require higher mechanical strength and wear resilient, light-weight aluminium composites were developed infusing solid lubricant. In this study, hybrid composites were developed using powder metallurgy route with aluminum alloy AA356 and various amounts of zirconium oxide (ZrO2) (0, 5, 10, 15, and 20 wt.%) as reinforcements. A solid lubricant hexagonal boron nitride (hBN) at a fixed 5 wt.% is considered. Following the appropriate ASTM guidelines, the specimens were mechanically characterized by measuring their density, porosity, micro-hardness, compression strength, impact strength, and flexural strength, among other properties. The findings showed that the composites' mechanical and physical behaviour were greatly affected by the inclusion of ZrO2. Porosity increased as a result of particle clustering and interfacial voids, while density increased gradually as ceramic content increased. Consistently increasing ZrO2 addition led to micro-hardness improvements; at 20 wt.% reinforcement, values reached their maximum, indicating that the hard ceramic phase contributed to better surface resistance. The best balance between particle reinforcement and matrix continuity was suggested by the compression and flexural strengths peaking at 15 wt.% ZrO2. However, when the addition was raised to 20 wt.%, brittleness and porosity began to marginally deteriorate. Unreinforced and lower ZrO2 composites had superior toughness in impact, whereas materials with a higher content had a poorer energy absorption capacity. The 5 wt.% hBN improved fracture arresting capabilities and helped load transmission over the interface. Inclusion of hBN provides solid-lubricating tribofilm formation that enhances the tribological performance. This study reveals that AA356/ZrO2-hBN hybrid composites have good hardness and compressive strength improvements, with 15 wt.% ZrO2 being the best composition with good strength, toughness, and wear resistance.
Researchers at Columbia Engineering have developed a new gel electrolyte that both improves the lifetime and safety of anode-free lithium batteries, an emerging battery architecture that could dramatically boost energy density while simplifying manufacturing. Although such design promises higher energy density and lower cost, the approach has long been plagued by short battery life and safety concerns caused by unstable lithium plating and parasitic reactions at the electrode-electrolyte interface.
Machina Labs recently closed its latest round of financing with $124 million, enough to develop a facility featuring up to 50 of its RoboCraftsman cells capable of producing thousands of complex structural assemblies for aerospace and defense customers - a list that already includes Lockheed Martin and the U.S. Air Force, among others. Founded in 2019, Machina Labs is a California-based company that seeks to reinvent metal manufacturing with a robot that uses artificial intelligence (AI) to rapidly form and assemble complex military grade structures directly from digital design files. RoboCraftsman is the company's manufacturing robot that leverages its proprietary “RoboForming” process to integrate multiple manufacturing processes - including metal forming, trimming, scanning, and heat treating - into a single containerized machine.
This research demonstrates a new way to make carbon-based battery materials much safer, longer lasting, and more powerful by fundamentally redesigning how fullerene molecules are connected. Today’s lithium-ion batteries rely mainly on graphite, which limits fastcharging speed and poses safety risks due to lithium plating. These research findings mean progress toward safer electric vehicles, longer-lasting consumer electronics, and more reliable renewable-energy storage.
With the growing global demand for sustainable energy and high-performance mobile devices, lithium metal solid-state batteries (LMBs) have emerged as a research hotspot in the field of energy storage due to their exceptional high energy density and significant safety advantages. However, the growth of lithium dendrites and their penetration through the solid electrolyte remain key issues leading to battery short-circuiting and failure. To date, there has been a lack of effective in situ research methods to reveal the failure mechanisms, which has severely restricted the commercialization of LMBs. This study innovatively employs in situ electrochemical impedance spectroscopy (EIS) to investigate lithium plating behavior in symmetric cells during critical current density (CCD) tests under room temperature and elevated temperature conditions. By analyzing characteristic signals at 1 MHz, this study presents the in situ impedance changes at the grain boundaries and interfaces of the battery, revealing that lithium plating is a dynamic reduction-oxidation process. We summarize two modes of lithium plating: one involves lithium metal deposition at the interface due to local current density inhomogeneity; the other involves lithium metal deposition at grain boundaries far from the electrode due to concentration gradient differences. The study further reveals that lithium plating at grain boundaries is the primary cause of battery failure. This research highlights the unique advantages of in situ EIS in the field of solid-state battery research and its applicability to various material systems. Moreover, the proposed lithium plating mechanism provides a theoretical basis for optimizing battery design and enhancing battery safety, thereby facilitating the realization of high-energy-density solid-state batteries.
Composite materials have become widely adopted in commercial aviation, as aerospace manufacturers look to use them to drive weight reduction and improved fuel efficiency in new aircraft designs. In the case of aircraft rotary blades, the poor wear properties of these materials have necessitated the development of metal leading edge guards that can provide critical protection against erosion and impact damage during flight. Electroforming has been a leading process for the manufacture of these protective guards, with nickel parts providing excellent wear resistance that significantly extends the service life of the rotary blade assembly. Currently there has not been a focus on utilizing direct electrodeposition of metal on to carbon filled epoxy composite structures, as traditional plating-on-plastics approaches require considerable effort in surface preparation and normally do not provide adequate adhesion to the underlying structure. Alpha Metalcraft Group has been working in cooperation with aerospace suppliers in the design of an electroplating ready composite structure that would allow for direct nickel deposition, provide excellent adhesion, and significantly reduce both the time and cost for the manufacture of ready-to-assembly rotary blade structures. Test panels were constructed of commercially available prepreg materials or by resin infusion of dry fabrics that incorporated different metal containing conductive layers to allow for the direct deposition through a nickel sulfamate electrodeposition process. Different surface modification strategies were investigated to expose the metal conducting layer and thereby provide the metal-to-metal bonding surfaces required for successful electrodeposition.
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