Browse Topic: Thermal runaway

Items (140)
The danger of lithium-ion batteries in electric vehicles (EVs) is intensified when they are used at inappropriate temperatures, leading to self-heating and eventually contributing to thermal runaway. Nevertheless, there is uncertainty through the safety of reusing batteries after they have been exposed to heat damage and water mist from fire extinguishers. To address these concerns, this study aimed to experimentally investigate the impact of temperature on batteries and introduce a thermal management using a water mist. Subjecting a battery to a temperature of 100°C for a duration of 39 minutes can immediately detect inoperability from a sudden drop in voltage. The use of water mist was proposed to rapidly mitigate the heat production inside the battery. The state of health (SOH) and the impedance were employed to confirm the battery’s functionality after exposure to thermal abuse and water spraying. The SOH of fresh cells was measured as a reference line for comparison to tested
Trinuruk, PiyatidaPatthathum, PathompornJumnongjit, Apiwit
Electric vehicles (EVs) are gaining popularity due to their zero tailpipe emissions, superior energy efficiency, and sustainable nature. EVs have various limitations, and crucial one is the occurrence of thermal runaway in the battery pack. During charging or discharging condition of battery pack may result in thermal runaway condition. This promotes the requirement of effective cooling arrangement in and around the battery pack to avoid localized peak temperature. In the present work, thermal management of a 26650 Lithium iron phosphate (LFP) cell using natural convection air cooling, composite biobased phase change material (CBPCM) and its combination with copper fins is numerically investigated using multi-scale multi dimension - Newman, Tiedenann, Gu and Kim (MSMD-NTGK) battery model in Ansys Fluent at an ambient temperature of 306 K. Natural convection air cooling was found effective at discharge rates of 1C to 3C, maintaining cell temperature below the safe limit of 318 K for 80
Srivastav, DurgeshPatil, Nagesh DevidasShukla, Pravesh Chandra
Interest in Battery-Driven Electric Vehicles (EVs) has significantly grown in recent years due to the decline of traditional Internal Combustion Engines (ICEs). However, malfunctions in Lithium-Ion Batteries (LIBs) can lead to catastrophic results such as Thermal Runaway (TR), posing serious safety concerns due to their high energy release and the emission of flammable gases. Understanding this phenomenon is essential for reducing risks and mitigating its effects. In this study, a digital twin of an Accelerated Rate Calorimeter (ARC) under a Heat-Wait-and-Seek (HWS) procedure is developed using a Computational Fluid Dynamics (CFD) framework. The CFD model simulates the heating of the cell during the HWS procedure, pressure build-up within the LIB, gas venting phenomena, and the exothermic processes within the LIB due to the degradation of internal components. The model is validated against experimental results for an NCA 18650 LIB under similar conditions, focusing on LIB temperature
Gil, AntonioMonsalve-Serrano, JavierMarco-Gimeno, JavierGuaraco-Figueira, Carlos
Efficient and robust optimization frameworks are essential to develop and parametrize battery management system (BMS) controls algorithms. In such multi-physics application, the tradeoff between fast-charging performance and aging degradation needs to be solved while simultaneously preventing the onset of thermal runaway. To this end, a multi-objective optimization framework was developed for immersion-cooled battery systems that provides optimal charging rates and dielectric flowrates while minimizing aging and charging time objectives. The developed production-oriented framework consists of a fully coupled, lumped electro-thermal-aging model for cylindrical cells with core-to-surface and immersion-cooling heat transfer, the latter controlled by the dielectric fluid flowrate. The modeled core temperatures are inputs to a semi-empirical aging degradation model, in which a fast-aging solver computes the updated capacity and internal resistance over multiple timescales, which in turn
Suzuki, JorgeTran, Manh-KienTyagi, RamavtarMeshginqalam, AtaZhou, ZijieNakhla, DavidAtluri, Prasad
With the increasingly prominent environmental problems and energy crisis, wind power, solar power and other new energy has been rapid development, and energy storage technology is of great significance to the development of new energy. Compared with the power batteries applied in electric vehicles, battery energy storage systems gather a larger number of batteries and a larger scale, usually up to megawatts or 100 megawatts. During the operation of the energy storage system, the lithium-ion battery continues to charge and discharge, and its internal electrochemical reaction will inevitably generate a lot of heat. If the heat is not dispersed in time, the temperature of the lithium-ion battery will continue to rise, which will seriously affect the service life and performance of the battery, and even cause thermal runaway leading to explosion. It is of great significance for promoting the development of new energy technologies to carry out research on the thermal model of lithium-ion
Chen, JianxiangLi, LipingZhou, FupengLi, ChunchengShangguan, Wen-Bin
As the main power source for modern portable electronic devices and electric vehicles, lithium-ion batteries (LIBs) are favored for their high energy density and good cycling performance. However, as the usage time increases, battery performance gradually deteriorates, leading to a heightened risk of thermal runaway (TR) increases, which poses a significant threat to safety. Performance degradation is mainly manifested as capacity decline, internal resistance increase and cycle life reduction, which is usually caused by internal factors of LIBs, such as the fatigue of electrode materials, electrolyte decomposition and interfacial chemical reaction. Meanwhile, external factors of LIBs also contribute to performance degradation, such as external mechanical stresses leading to internal structural damage of LIBs, triggering internal short-circuit (ISC) and violent electrochemical reactions. In this paper, the performance degradation of LIBs and TR mechanism is described in detail, as well
Zhou, JingtaoZhong, XiongwuWang, KunjunZhou, YouhangYou, GuojianTang, Xuan
aThe lengthy charging time of lithium-ion batteries for electric vehicles (EVs) significantly affect their acceptance. Reducing charging time requires high-power fast charging. However, such fast charging can trigger various side reactions, leading to safety and durability issues. Among these, lithium plating is a major concern as it can reduce battery capacity and potentially cause internal short circuits or even thermal runaway. Currently, multi-stage constant current charging (MCCC) protocols are widely adopted. However, the difficulty in effectively detecting lithium plating during the MCCC process significantly limits the charging power. Therefore, it is urgent to explore a method to detect lithium plating during the MCCC process. In this study, the impedance evolution during the MCCC procedure was first investigated. Then a method based on the impedance variation patterns was proposed to detect lithium plating. Besides, the reason for the behavior of impedance changes was further
Shen, YudongWang, XueyuanWu, HangWei, XuezheDai, Haifeng
Battery safety is a paramount concern in the development of electric vehicles (EVs), as failures can lead to catastrophic consequences, including fires and explosions. With the rapid global adoption of EVs, understanding how battery cells perform under extreme conditions such as mechanical or thermal abuse is crucial for ensuring vehicle safety. This study investigates the abuse response of lithium-ion batteries under high-speed mechanical loading. Our research systematically examines the response of these cells at different states of charge (SOC) through controlled dynamic tests. These tests offer insights into the failure response of the cells. By analyzing the data, we gain a deeper understanding of the conditions that could trigger thermal runaway under mechanical abuse loadings, representative of EV crashes, a critical safety concern in EV battery systems. The experimental setup and methodologies are presented in this paper, alongside key findings that highlight the importance of
Patanwala, HuzefaKong, KevinChalla, VidyuDarvish, KuroshSahraei, Elham
The number of electric vehicles (EVs) has significantly increased in recent years. Safety performance of EVs is at least at the same level as that of conventional vehicles. To evaluate battery safety and ensure passenger protection, several standard tests and regulations for EV batteries have been established, including IEC 62660-3, ISO 6469-1, and UN/ECE/R100 Revision 3. ISO 6469-1:2019/Amd 1 specifies thermal propagation (TP) test to evaluate battery robustness against thermal runaway (TR) in a single cell. Moreover, UN/ECE/R100 Revision 3 aims to provide sufficient egress time to protect passengers in the event of a TR in a single cell. Typically, these tests initiate TR in a cell within a battery pack using either a heater or nail. In the heater method, if the gap between cells is larger than the heater’s thickness and there are no installation constraints due to components, almost any cell can be chosen as the initiating cell. However, if the gap between cells is smaller than the
Maeda, KiyotakaTakahashi, Masashi
The use of lithium-ion batteries in electric vehicles marks a major progression in the automotive sector. Energy storage systems extensively make use of these batteries. The extended life cycle, low self-discharge rates, high energy density, and eco-friendliness of lithium-ion batteries are well-known. However, Temperature sensitivity has an adverse effect on lithium-ion battery safety, durability, and performance. Thus, maintaining ideal operating conditions and reducing the chance of thermal runaway depend heavily on efficient thermal management. To address this, experimental study was conducted on various battery thermal management techniques, including active, passive, and hybrid approaches. These techniques were investigated for their cooling efficiencies under different operating conditions. The electro-thermal behavior of cylindrical lithium-ion battery cells, battery packs, and supervisory control techniques were simulated in the study using MATLAB Simulink, Simscape, and
Thangaraju, ShanmuganathanN, MeenakshiGanesan, Maragatham
This Paper will focus on simulating thermal runaway propagation within a battery cell and module. The thermal runaway model parameters are derived from accelerating rate calorimeter (ARC). The simulation involves a thermal runaway propagation model that converts the stored energy of the battery materials into thermal energy, thereby simulating the propagation of thermal runaway. The initiation of thermal runaway is modelled through a nail penetration event, represented by a heat profile in the nail region. The resulting temperature rise in this area triggers the short propagation model, leading to the spread of thermal runaway. For the single-cell simulation, the 1-equation thermal runaway model is used, focusing on the direct energy conversion and propagation within the cell. In contrast, the module simulation involves a more complex scenario. Here, an initial temperature rise near the nail region activates a short propagation model, which subsequently triggers the 4-equation thermal
Wakale, AnilMa, ShihuHu, Xiao
Thermal runaway in battery cells presents a critical safety concern, emphasizing the need for a thorough understanding of thermal behavior to enhance battery safety and performance. This study introduces a newly developed AutoLion 3D thermal runaway model, which builds on the earlier AutoLion 1D framework and offers significantly faster computational performance compared to traditional CFD models. The model is validated through simulations of the heat-wait-search mode of the Accelerating Rate Calorimeter (ARC), accurately predicting thermal runaway by matching experimental temperature profiles from peer-reviewed studies. Once validated, the model is employed to investigate the thermal behavior of 3D LFPO cells under controlled heating conditions, applying heat to one or more surfaces at a time while modeling heat transfer from non-heated surfaces. The primary objective is to understand how these localized heating patterns impact temperature profiles, including average core temperatures
Hariharan, DeivanayagamGundlapally, Santhosh
Thermal runaway is a critical phenomenon in lithium batteries, characterized by a self-sustaining process due to internal chemical reactions, that is triggered once a certain temperature is reached within the cell. This event is often caused by overheating due to charge and discharge cycles and can lead to fires or explosions, posing a significant safety threat. The aim of this study is to induce thermal runaway on single cells in different ways to characterize the phenomenon and validate the simulation models present in Altair SimLab®. The work was conducted in several key phases. Initially, an experimental test was performed in a calorimeter (EV ARC HWS test) to collect temperature data of the Molicel 21700 P45B cell during thermal runaway under adiabatic conditions. These data were used for a simulation on a single cell, allowing a detailed comparison with the experimental results. Subsequently, a test was conducted on a single cell under operational conditions, overheated using a
Giuliano, LucaScrimieri, LuigiReitano, SimoneBerti Polato, DavideFerraris, AlessandroComerford, AndrewBhatnagar, Saakaar
A vital aspect of Ultra-Fast Charging (UFC) Li-Ion battery pack is its thermal management system, which impacts safety, performance, and cell longevity. Immersion cooling technology is more effective compared to indirect cold plate as heat can dissipate much quicker and has a potential to mitigate the thermal runaway propagation, improve pack overall performance, and cell life significantly. For design optimization and getting better insight, high fidelity Multiphysics-Multiscale simulations are required. Equivalent Circuit Model (ECM) based electro-thermally coupled multi-physics CFD simulations are performed to optimize the innovative busbar design, of a recently developed immersion cooled battery pack, which enables the capability to remove individual cell. Further, high fidelity 3D transient flow-thermal simulations have helped in optimizing the coolant flow direction, inlet positions, cell spacing and separator design for efficient flow distribution in the module. While high
Tyagi, RamavtarNegro, SergioBaranowski, AlexAtluri, Prasad
Thermal management is a key challenge in the design and operation of lithium-ion batteries (LIBs), particularly in high-stress conditions that may lead to thermal runaway (TR). Immersion cooling technology provides a promising solution by offering uniform cooling across all battery cells, reducing the risk of hotspots and thermal gradients that can trigger TR. However, accurately modeling the thermal behavior of such systems, especially under the complex conditions of immersion cooling, presents significant challenges. This study introduces a comprehensive multiscale and Multiphysics modeling framework to analyze thermal runaway and its propagation (TRP) in battery systems cooled by immersion in dielectric fluids. The model integrates both 1D and 3D simulations, focusing on calibrating energy terms at the single-cell level using 3D Computational Fluid Dynamics (CFD). The calibration process includes a detailed analysis of cell chemistries, exothermic heat release, and thermal runaway
Negro, SergioTyagi, RamavtarKolaei, AmirPugsley, KyleAtluri, Prasad
Detailed modeling of battery thermal runaway and propagation often requires a source term that represents the chemical heat release of the cell as a function of temperature. The shape of this heat release trend typically comes from cell testing data. Accelerating rate calorimetry (ARC) tests provide concise information on cell self-heating, since the cell is kept nearly isothermal and adiabatic. Also, compared to differential scanning calorimetry (DSC) tests of battery component materials, it contains all interactions between components. Converting the temperature rise rate data to heat release rate is theoretically very simple, only requiring the heat capacity of the cell. Practically, however, careful analysis is required to avoid artifacts arising from limitations of the test setup. This study uses a simple one-dimensional transient heat transfer model to illustrate the runaway process inside a cell and describe two error sources present in many ARC tests. As the cell temperature
Vanderwege, BradPetersen, Ben
The scope of this information report is battery packs containing lithium-ion battery cells with liquid electrolyte, focusing on automotive applications like passenger cars and trucks. Considering different operating conditions as well as durability and safety requirements, some of its contents might provide guidance for other applications. The same applies to battery cell chemistries not covered in this report (e.g., sodium-ion or solid-state battery cells).
Battery Pack Venting Committee
After the defected gears are determined, a novel method, combined with wavelet packet decomposition, complementary ensemble empirical mode decomposition with adaptive noise and singular value decomposition, is put forward. It is utilized to exclude disturbance of irrelevant signals that generated by the defect gears. Firstly, wavelet packet decomposition is used to extract the defect signals and retain original features. The processed signal is called S1 and the irrelevant frequency bands could be filtered out. Secondly, complementary ensemble empirical mode decomposition with adaptive noise decomposes S1 into a series of intrinsic modal functions. The correlations between S1 and intrinsic modal functions are analyzed. The intrinsic modal functions that are highly correlated with S1 are screened out and reconstructed into a new signal, called S2. The disturbance of irrelevant signals could be further filtered out, but some of them still disturb the judgement. Thirdly, singular value
Gu, JunqingZuo, YueyunZhang, NiDeng, FengWu, Xiaolong
Lithium-ion batteries are prone to thermal failures under extreme conditions, leading to thermal runaway and safety risks such as fire or explosion. Therefore, effective temperature prediction and diagnosis are crucial. This paper proposes a thermal fault diagnosis method based on the Informer time series model. By extracting temperature-related features and conducting correlation analysis, a 9-dimensional input parameter matrix is constructed. Experimental results show that the model can maintain an absolute temperature prediction error within 0.5°C when predicting 10 seconds in advance, with higher accuracy than the LSTM model. Additionally, a three-level warning mechanism based on the forgetting coefficient further enhances diagnostic accuracy. Validation using test data and real vehicle data demonstrates that this method can efficiently diagnose and locate thermal faults in batteries, with low computational costs, making it suitable for online applications.
Sun, YefanZhu, XiaopengZhang, ZhengjiePeng, ZhaoxiaYang, ShichunLiu, Xinhua
Thermal management system of electric vehicles (EVs) is critical for the vehicle's safety and stability. While maintaining the components within their optimal temperature ranges, it is also essential to reduce the energy consumption of thermal management system. Firstly, a kind of architecture for the integrated thermal management system (ITMS) is proposed, which can operate in multiple modes to meet various demands. Two typical operating modes for vehicle cooling in summer and heating in winter, which utilizes the residual heat from the electric drive system, are respectively introduced. The ITMS based on heat pump enables efficient heat transfer between different components. Subsequently, an ITMS model is developed, including subsystems such as the battery system, powertrain system, heat pump system and cabin system. The description of modeling process for each subsystem is provided in detail. The model is tested under world light vehicle test cycle (WLTC) condition of six different
Zhao, LuhaoTan, PiqiangYang, XiaomeiYao, ChaojieLiu, Xiang
The internal short circuit of a traction battery is one of the most typical failure mechanisms that can lead to thermal runaway, potentially triggering thermal propagation across the entire battery system. This phenomenon poses significant safety risks, especially in electric vehicles and large-scale energy storage systems. Therefore, it is essential to explore and understand the internal short circuit behavior to mitigate these risks. One of the most effective testing methods for reproducing an internal short circuit is the penetration test, where specific test conditions must be carefully designed based on the failure behavior. Among these conditions, the penetration step length plays a crucial role, as it directly influences the short circuit dynamics. Despite the importance of penetration step length, there is currently no standardized test procedure that dictates how to select the appropriate step size for different battery samples. This gap in standardization complicates the
Wang, FangSun, ZhipengMa, TianyiDai, XiaoqianDai, CeYan, PengfeiMa, XiaoleChen, LiduoMa, HaishuoShen, Shaopeng
Lithium-iron phosphate batteries are widely used in energy storage systems and electric vehicle for their favorable safety profiles and high reliability. The designing of an efficient cooling system is an effective means of ensuring normal battery operation, improving cycle life, and preventing thermal runaway. In this paper, we proposed a forced-convection air cooling structure aiming at uniform temperature distribution and reducing the maximum temperature. The initial step was constructing a heating model for a single LiFeO4 battery. A source function was derived from the experimental data, which described the variation in heating power with discharge depth. This function was then used to create a dynamic loading of the battery heating model. Subsequently, a three-dimensional model of a 7-series and 2-parallel battery pack was constructed. Seven schemes were designed on the basis of the traditional Z-shaped structure, with the position of the air inlet and outlet altered. The
Zhang, JunhongLiu, TingDai, HuweiLin, Jiewei
Thermal runaway propagation (TRP) within lithium-ion batteries (LIBs) poses critical barriers to the safe operation and large-scale application of cell-to-chassis (CTC) batteries. Such events can lead to severe safety incidents, including explosions and fires, in systems utilizing these batteries. However, there is a lack of research on the thermal runaway model coupled with vented gases at the CTC systems. In this study, a thermal runaway coupling model for the battery pack system was established utilizing Star-CCM+ software, allowing for the examination of thermal runaway propagation characteristics and vented gas characteristics a within power battery systems based on the measured parameters of battery thermal safety characteristic. The simulation results indicated that once thermal runaway becomes uncontrollable, combustible flue gases escape through the exhaust hole located on the side plate of the cell, thereby facilitating heat transfer to adjacent cells. The primary components
Ma, NiyaZhang, AnweiZhou, WentaiZhou, YouJia, YuanFan, Zehong
With the growing demand for electric vehicles (EVs), ensuring the safety and efficiency of battery systems is critical. This paper presents a methodology integrating 3D Finite Element Methods (FEM) and Computational Fluid Dynamics (CFD) to analyze battery systems, effectively mitigating thermal runaway phenomena. By combining FEM and CFD, our methodology provides a comprehensive approach to assess thermal management strategies within battery systems. This integration enables engineers to accurately simulate thermal behavior, predict hotspots, and optimize cooling strategies, thereby mitigating the risk of thermal runaway. Furthermore, our methodology minimizes the reliance on costly and time-intensive physical prototypes and testing. By leveraging virtual simulations, engineers can rapidly iterate through design modifications, assess their impact on thermal performance, and make informed decisions early in the development process. This article demonstrates the efficacy and accuracy of
Melo, Caiuã CaldeiraAraujo, Pedro HenriqueCastro Orefice, FabioCury, Davi MachadoVieira, Tiago Augusto SantiagoAbdu, Aline Amaral QuintellaMonteiro, Henrique Carlos
Electrified powertrain is the essential need to meet the C02 and NOX emissions compliance. Thereby focus of automotive industry is shifting towards to Electric Vehicle (EV). Thermal Runaway (TR) is still a big challenge to the safety of the EV. The major cause of TR is internal short-circuit of batteries under external mechanical abuse. When Anode and cathode of the battery comes in contact and short circuit happens. Internal short circuit is causing high amount of current flow and energy generation which leads to high increase in temperature. The approach that is used till date by OEMs is to protect the battery pack from structural damage during crash resulting into overdesigning of the vehicle. In this paper, detailed FE modeling of the battery system is considered for evaluating internal short circuit and TR. Solid Randle circuit is used for Multiphysics coupling simulation in Ls-dyna. Solid Randle circuits solves this Multiphysics and derives these electrical and thermal parameters
Jain, TriptiBonala, SastryDangare, Anand
Today's battery management systems include cloud-based predictive analytics technologies. When the first data is sent to the cloud, battery digital twin models begin to run. This allows for the prediction of critical parameters such as state of charge (SOC), state of health (SOH), remaining useful life (RUL), and the possibility of thermal runaway events. The battery and the automobile are dynamic systems that must be monitored in real time. However, relying only on cloud-based computations adds significant latency to time-sensitive procedures such as thermal runaway monitoring. Because automobiles operate in various areas throughout the intended path of travel, internet connectivity varies, resulting in a delay in data delivery to the cloud. As a result, the inherent lag in data transfer between the cloud and cars challenges the present deployment of cloud-based real-time monitoring solutions. This study proposes applying a thermal runaway model on edge devices as a strategy to reduce
Sarkar, PrasantaPardeshi, RutujaKharwandikar, AnandKondhare, Manish
A BDT (Battery digital Twin) is a virtual representation of a vehicle's physical battery system, combining electrochemical and machine learning models to provide insights into key battery parameters like State of Charge (SOC), State of Health (SOH), Internal Resistance (IR), and Remaining Useful Life (RUL). This BDT model is calibrated using cell testing throughout its degradation process up to 80% SOH, alongside vehicle data for accurate predictions under diverse conditions. By continuously monitoring the battery under various operating scenarios, the BDT aids in effective battery management, identifying cells that degrade more quickly and the likely causes of this degradation. Current and temperature profiles offer insights into battery usage patterns. The BDT aggregates fleet-wide parameters and analyzes individual cell performance, providing critical information on SOC, SOH, IR, RUL, and voltage. Additionally, the BDT includes prognostic capabilities to alert users of potential
Sasi Kiran, TalabhaktulaKondhare, ManishPatil, SuyogNath, SubhrajyotiCH, Sri RamTank, PrabhuSarkar, Prasanta
The advent of electric vehicles has increased the complexity of air conditioning systems in vehicles which now must maintain the safety and comfort of occupants while ensuring that the high voltage battery temperature is kept within safe limits. This new task is critical due to the influence of the cell and battery pack temperature on the efficiency. Moreover, high temperatures within the battery pack can lead to undesirable effects such as degradation and thermal runaway. Classical solutions to this problem include larger air conditioning components to support worst case scenario conditions where the cooling request from the battery and the cabin happen at the same time. In such conditions, for the safety of the battery, the cooling request is assigned to battery system which may cause discomfort to the passengers due the significant temperature increase in the cabin during such events. The probability of such events happening is certainly dependent on the weather conditions but in
Palacio Torralba, JavierKulkarni, Shridhar DilipraoShah, GeetJaybhay, SambhajiKapoor, SangeetLocks, Olaf
Recently, there has been a growing emphasis on Thermal Management Systems (TMS) for Lithium-ion battery packs due to safety concerns related to fire risks when temperatures exceed operating limits. Elevated temperatures accelerate electrochemical reactions, leading to cell degradation and reduced electronic system performance. These conditions can cause localized hotspots and hinder heat dissipation, increasing the risk of thermal runaway due to high temperatures, flammable gases, and heat-producing reactions. To tackle these issues, many automotive manufacturers employ indirect liquid cooling techniques to maintain battery pack and electronic system temperatures within safe limits. Engineered nanofluids, particularly those containing multi-nanoparticles dispersed in water and ethylene glycol, are being explored to enhance electrical safety in case of accidental exposure to electrical systems in EVs. This paper focuses on the experimental characterization of nanofluid containing
Nahalde, SujayHonrao, GauravMore, Hemant
This breakthrough promises to significantly enhance the safety and performance of lithium-ion batteries (LIBs), addressing a critical challenge in energy storage technology.
In the realm of low-altitude flight power systems, such as electric vertical take-off and landing (eVTOL), ensuring the safety and optimal performance of batteries is of utmost importance. Lithium (Li) plating, a phenomenon that affects battery performance and safety, has garnered significant attention in recent years. This study investigates the intricate relationship between Li plating and the growth profile of cell thickness in Li-ion batteries. Previous research often overlooked this critical aspect, but our investigation reveals compelling insights. Notably, even during early stage of capacity fade (~ 5%), Li plating persists, leading to a remarkable final cell thickness growth exceeding 20% at an alarming 80% capacity fade. These findings suggest the potential of utilizing cell thickness growth as a novel criterion for qualifying and selecting cells, in addition to the conventional measure of capacity degradation. Monitoring the growth profile of cell thickness can enhance the
Zhang, JianZheng, Yiting
The life and safety of a battery are closely linked to temperature. Designing an effective thermal management system relies on a thorough understanding and analysis of the thermal properties and mechanisms of the battery. Over time, as batteries are used, their thermal characteristics change due to variations in internal SEI thickness, the deterioration of the active material structure, gas production, and electrolyte consumption, all of which are associated with the aging process. In this paper, experiments on both NCM and LFP batteries were made to measure the heat generation characteristics by adiabatic calorimeter. The results showed that the impact of calendar aging on battery heat generation exhibited completely different patterns for the lithium-ion batteries of the two material systems mentioned above. This paper provides guidance for the optimization of heat generation characteristics of battery and the calibration of heat source in the design of battery thermal management
Li, HaibinZhao, HongweiLiu, DinghongHu, Qiaosheng
Lithium-ion and lithium-metal battery cells are susceptible to a phenomenon known as thermal runaway under failure conditions. Given their widespread use in applications such as electric vehicles, portable electronics, and energy storage systems, early detection of thermal runaway is crucial for ensuring the safety of these battery systems. Thermal runaway entails a rapid escalation in battery cell temperature accompanied by the emission of flammable lithium ions, particulates, electrons, hydrocarbons, and hydrogen gases. These gases pose a significant ignition risk, potentially leading to fires and endangering occupants and bystanders. Therefore, the timely detection of thermal runaway is paramount for ensuring safety in proximity to such battery systems. Traditionally, thermal runaway sensors comprise intricate assemblies of pressure, temperature, and gas sensors, strategically positioned at the pressure relief valve of battery modules. Calibration of all sensors is essential to
Mansour, Youssef
Letter from the Focus Issue Editors
Shen, RuiqingWang, Qingsheng
Electric Vehicles numbers are increasing at a rapid pace in the Indian market. As per the different feedbacks from the customers and reports available in media, there is an increase in Electric Vehicle (EV) battery fire accidents. The same is because of increased EV numbers, malfunctioning of battery and improper handling of EV systems. EV industry is looking for a solution for preventing these mis happenings by using advanced safety technology. This includes improvement in existing safety system through advanced warning backed by artificial intelligence, programming tools using new computing languages such as Python, Java etc. In present work temperature which happens to be major contributor in battery fire cases is being monitored with the help of programming used in battery management systems. In this process algorithm is being developed with the help of python as programming language. The same was test run on the selected parameters for validation of the developed programs for
Vashist, DevendraSharma, AryanAnand, Aditya
To understand effect of thermal hazards of LIBs during TR event, it is important to study flame propagation behaviour of LIBs during storage and transport applications. The process of flame propagation involves complex phenomena of gas phase behavior of LIBs. Present paper attempts a numerical investigation to portray this complex phenomenon. This paper investigates 18650 lithium cell considering two different chemistries NMC and LFP. A 3D numerical CFD model has been constructed to predict the gas phase behavior, threshold internal pressure, and cell gas venting of an 18650-lithium cell under thermal runaway conditions. The gas phase processes are modelled using the 4-equation thermal abuse model, while the cell's venting mechanism is modelled using Darcy's equation. Present work is divided into two parts: 1) Venting gas Internal pressure prediction 2) modeling thermal runaway event. Both procedures are implemented on two different cell chemistries to understand and evaluate following
Gudi, AbhayBonala, Sastry
With the growing popularity of electric vehicles (EVs) Lithium-ion batteries (LIBs) exhibit unique characteristics such as long life, high specific energy, significant storage capacity, and remarkable energy density. The continual difficulty temperature non-uniformity over the battery surface and inside the battery pack, remains a major barrier in battery technology, significantly contributing to the tendency towards Thermal Runaway (TR). The hot gases discharged from a lithium-ion cell’s safety vent during a thermal runaway event carry flammable elements. If ignited, these gases heighten the potential for thermal runaway to spread to other cells within a multi-cell pack configuration. The study scrutinizes the effects of TR on the venting process. It explores contemporary approaches to minimize it, employing a variety of modeling methodologies such as Multiphysics, Computational Fluid Dynamics (CFD), and electrochemical-thermal, in addition to experimental methods. The objective of
Nogdhe, YogeshGarg, RaviSingh, Shobit Kumar
Thermal runaway is a critical safety concern in lithium-ion battery systems, emphasising the necessity to comprehend its behaviour in various modular setups. This research compares thermal runaway propagation in different modular configurations of lithium-ion batteries by analysing parameters such as cell spacing and applying phase change materials (PCMs) and Silica Aerogel. The study at the module level includes experimental validation and employs a comprehensive model considering heat transfer due to thermal runaway phenomena. It aims to identify the most effective modular configuration for mitigating thermal runaway risks and enhancing battery safety. The findings provide valuable insights into the design and operation of modular lithium-ion battery systems, guiding engineers and researchers in implementing best practices to improve safety and performance across various applications.
Garcia, AntonioMonsalve-Serrano, JavierDreif, AminGuaraco-Figueira, Carlos
Increasing awareness of the harmful effects on the environment of traditional Internal Combustion Engines (ICE) drives the industry toward cleaner powertrain technologies such as battery-driven Electric Vehicles (EV). Nonetheless, the high energy density of Li-Ion batteries can cause strong exothermic reactions under certain conditions that can lead to catastrophic results, called Thermal Runaway (TR). Hence, a strong effort is being made to understand this phenomenon and increase battery safety. Specifically, the vented gases and their ignition can cause the propagation of this phenomenon to adjacent batteries in a pack. In this work, Computational Fluid Dynamics (CFD) is employed to predict this venting process in an LG18650 cylindrical battery. The shape of the venting cap deformation obtained from experimental results was introduced in the computational model. The ejection of the generated gases was considered to analyze its dispersion in the surrounding volume through a Reynolds
Gil, AntonioMicó, CarlosMarco-Gimeno, JavierCastro Espín, Mar
With the rapid development of electric vehicles, the demands for lithium-ion batteries and advanced battery technologies are growing. Today, lithium-ion batteries mainly use liquid electrolytes, containing organic compounds such as dimethyl carbonate and ethylene carbonate as solvents for the lithium salts. However, when thermal runaway occurs, the electrolyte decomposes, venting combustible gases that could readily be ignited when mixed with air and leading to pronounced heat release from the combustion of the mixture. So far, the chemical behavior of electrolytes during thermal runaway in lithium-ion batteries is not comprehensively understood. Well-validated compact chemical kinetic mechanisms of the electrolyte components are required to describe this process in CFD simulations. In this work, submechanisms of dimethyl carbonate and ethylene carbonate were developed and adopted in the Ansys Model Fuel Library (MFL). Further improvements were made to enhance the kinetic consistency
Zhang, KuiwenPuduppakkam, KarthikShelburn, Anthony
Li-ion batteries are commonly used in Electric Vehicles (EVs) due to its high-power density and higher life cycle performance. Individual cells in such battery packs may sometimes lead to thermal runaway conditions under the effect of localized heat generation and faults. Battery liquid cooling methods are normally being employed to resolve this problem with limitations of limited temperature operating range and difficulty in reaching the intricate spaces between the cells. Introducing phase change material (PCM) can mitigate these limitations. The present study deals with a detailed numerical study of a single (Li-ion) cell in ANSYS Fluent using multi-scale multi dimension (MSMD) - Newman, Tiedenann, Gu and Kim (NTGK) model. The single cell model is investigated for the evaluation of its temperatures at varying air velocity surrounding the cell at higher C-rating (load) values. It was observed that the maximum cell surface temperatures were as 322.6, 319.8, 318.1, 316.9, 314.4 and
Srivastav, DurgeshPatil, Nagesh DevidasShukla, Pravesh Chandra
In the realm of electric vehicles (EVs), effective battery thermal management is critical to avert thermal runaway, overheating, and extend the operational lifespan of batteries. The process of designing thermal management systems can be substantially expedited through the utilization of modeling and simulation techniques. However, the high-fidelity 3D computational fluid dynamics (CFD) simulations often demand significant computational resources to provide comprehensive results under varying conditions. In this paper, we develop a reduced order model (ROM) to capture the battery thermal dynamics employing a sub-space method. To construct this ROM, we use high-fidelity CFD simulations to generate step responses of battery temperature with respect to the heat generation and cooling power. These step responses are subsequently used as training data for the ROM. To minimize computational expenses while preserving accuracy, we determine the minimal dimensionality of the ROM through the
Hu, QiuhaoDing, PeiranJiang, WeiranFung, Kenny
With the rapid development of electric vehicles (EVs), lithium-ion batteries (LIBs) with high energy and power density have been widely applied as the power producer of EVs. However, the range of EVs has been criticized. To meet consumer demand for high power and long driving distances, the energy and power density of LIBs are getting higher and higher. However, LIBs with higher energy density are more prone to catastrophic thermal runaway (TR). In recent years, EV accidents due to TR of LIBs have been frequently reported, which makes consumers lose confidence in EVs. To solve the problem, we must understand the mechanism of LIBs TR, thereby reducing the likelihood of TR in EVs. However, the induction mechanism of LIB TR induced by mechanical abuse is sophisticated. This paper focuses on recent advances in the study of thermal TR characteristics of batteries caused by mechanical abuse, including bending, collisions, and penetration. The impact of various mechanical abuses on the TR
Hao, Wang ZhiTang, XuanZhou, Youhang
This study investigates the impact of cycling aging on the safety performance of lithium-ion batteries, specifically 18650 cells and pouch cells. These cells are cycled at 0 °C with charging rates of 2 C and 0.8 C, respectively, upon reaching different states-of-health, and their mechanical-electrical-thermal responses are analyzed post-indentation tests. The compressive behavior of anodes and cathodes at different states-of-health is also examined. The failure mechanisms of battery components are discussed based on indentation results at cell level, compression results of components, electrochemical impedance spectroscopy, and visual observations. The study reveals that aged 18650 cells exhibit increased stiffness (evidenced by left-shifted force-displacement curves) during cell indentation, while the compressions test results of aged electrodes show decreased stiffness (right-shifted force-displacement curves) which is similar to the stiffness behavior of the pouch cells. As aging
Spettmann, ChristopherShin, JonghyeonQu, YunlongLiu, YuanjieXia, Yong
The growing global adoption of electric vehicles (EVs) emphasizes the pressing need for a comprehensive understanding of thermal runaway in lithium-ion batteries. Prevention of the onset of thermal runaway and its subsequent propagation throughout the entire battery pack is one of the pressing challenges of lithium-ion batteries. In addition to generating excess heat, thermal runaway of batteries also releases hazardous flammable gases, posing risks of external combustion and fires. Most existing thermal runaway models in literature primarily focus on predicting heat release or the total amount of vent gas. In this study, we present a model capable of predicting both heat release and the transient composition of emitted gases, including CO, H2, CO2, and hydrocarbons, during thermal runaway events. We calibrated the model using experimental data obtained from an 18650 cell from the literature, ensuring the accuracy of reaction parameters. We employ this developed model to investigate
Hariharan, DeivanayagamGundlapally, Santhosh
Battery electric vehicles (EVs) bring significant benefits in reducing the carbon footprint of fossil fuels and new opportunities for adopting renewable energy. Because of their high-energy density and long cycle life, lithium-ion batteries (LIBs) are dominating the battery market, and the consumer demand for LIB-powered EVs is expected to continue to boom in the next decade. However, the chemistry used in LIBs is still vulnerable to experiencing thermal runaway, especially in harsh working conditions. Furthermore, as LIB technology moves to larger scales of power and energy, the safety issues turn out to be the most intolerable pain point of its application in EVs. Its failure could result in the release of toxic gases, fire, and even explosions, causing catastrophic damage to life and property. Vehicle fires are an often-overlooked part of the fire problem. Fire protection and EV safety fall into different disciplines. To bridge the gap between these two disciplines and summarize the
Shen, RuiqingQuan, YufengMcIntosh, James D.Salem, AsadWang, Qingsheng
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