Browse Topic: Diesel / compression ignition engines
As hydrogen internal combustion engines (H2-ICE) gain traction, optimizing exhaust aftertreatment technologies for nitrogen oxide (NOx) control has become increasingly critical. While selective catalytic reduction (SCR) systems remain the primary approach for NOx mitigation, oxidation catalysts are also being explored to facilitate hydrogen oxidation and improve overall exhaust treatment efficiency. This work presents a multifunctional catalyst (MFC) concept that combines supported Pd and Cu-zeolite to enable simultaneous NOx reduction and hydrogen oxidation within a single catalytic unit. Preliminary results show that hydrogen oxidation on supported Pd occurs above 300 °C, while Cu-zeolite achieves nearly complete NOx conversion. Experiments on individual components indicate that supported Pd initiates ammonia oxidation only after hydrogen is depleted. In the presence of hydrogen, ammonia conversion remains below 20%, indicating that hydrogen availability suppresses ammonia oxidation
Fe/zeolite selective catalytic reduction (SCR) catalysts are commercially used for NOx emissions reduction from diesel engines. In comparison to Cu/zeolite, these catalysts are widely reported to form less N2O as a byproduct of the SCR reactions. However, Fe/zeolite SCR is less active than Cu/zeolite for low temperature NOx conversion under standard SCR conditions. In this study, a state-of-the-art Fe/zeolite SCR catalyst is probed with a combination of N2 physisorption, SEM/EDX, reactor-based performance and active site quantification. Measurements investigate the impact of degreening, mild and extreme hydrothermal aging. In a degreened condition, the impact of water vapor on standard and fast SCR and isothermal desorption of NH3 is assessed. The Fe/zeolite catalyst’s hydrothermal durability is studied following hydrothermal aging at temperatures from 550°C up to 950°C. NH3 adsorption and temperature programmed desorption (TPD) and NO2 adsorption and TPD experiments are used to
In the pursuit of achieving stringent BS VI emission standards, maintaining the efficiency of Selective Catalytic Reduction (SCR) systems is paramount, especially in vehicles operating under low duty cycles. A significant concern in such scenarios is the accumulation of urea deposits within the SCR, which can lead to detrimental push-out effects and compromised catalyst performance. This issue is particularly prevalent during low-temperature operations, where the conditions are less favorable for the effective conversion of nitrogen oxides (NOx). To address this challenge, an innovative software control system has been developed to monitor operating conditions and detect potential urea deposit faults. The software continuously evaluates parameters such as temperature and vehicle duty cycle, identifying conditions that may lead to urea crystallization within the SCR system. When unfavorable conditions are detected, the software triggers a fault alert that activates a regeneration
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