Browse Topic: Gases

Items (3,863)
In response to the evolving landscape of exhaust gas regulations for small powertrains, reducing NOx emission is increasingly important. This study deeply investigated the feasibility of a NOx storage catalyst (NSC) containing cerium oxide (CeO2) and barium oxide (BaO) for reducing NOx emission. The key functions, NOx storage and reduction performances were evaluated, and deterioration mechanisms were explored through performance evaluations and physical property analyses. The findings revealed a strong correlation between the size of CeO2 crystals and NOx storage performance at low temperature, such as those encountered during city driving conditions. Conversely, at high temperature, such as those during highway driving conditions, NOx storage performance correlated well with sulfur deposition, suggesting that the formation of barium sulfate (BaSO4) contributes to the deactivation. This experiment also showed a strong correlation between NOx reduction performance and BaSO4 formation
Nakano, FumiyaKoito, Yusuke
The relation between the multiple auto-ignition in the premixed charge with fuel concentration distribution and associated pressure wave are numerically investigated. This study assumes that the auto-ignition phenomenon in the end-gas of PCCI combustion, a next-generation combustion method which is expected to achieve both low fuel consumption and low emissions at a high level. Detailed numerical analysis considering the elementary chemical reactions of the compressible reacting fluid flow described in the one-dimensional coordinate system with high spatial and time resolution was performed to clarify the detailed phenomena of the onset of the multiple auto-ignition and the pressure wave propagation in the gas.
Iizumi, KotaYoshida, Kenji
The hot surface-assisted spark ignition (HSASI) pre-chamber spark plug, which was developed at the Karlsruhe University of Applied Sciences, increases the dilution limit with excess air and the tolerance to residual gas in the pre-chamber compared to a conventional passive pre-chamber spark plug. In this study, the conventional glow plug which is integrated in the pre-chamber of the HSASI pre-chamber spark plug was replaced by a pressure sensor glow plug (PSG) from BERU. This allows for a detailed combustion analysis in the pre-chamber. The signal of the PSG was validated with a piezoelectric cylinder pressure sensor and a method to analyse the pre-chamber heat release was introduced. Experimental investigations were carried out on a single-cylinder gasoline engine. A series of operating points diluted with excess air and a variation in load were conducted. The gas flow rate through the orifices of the pre-chamber was calculated from the pressure difference between the pre-chamber and
Holzberger, SaschaKettner, MauriceKirchberger, Roland
Automotive industry is growing rapidly with innovations leading to increase in new features and improving the Quality of vehicles. These new components are developed with the available design standards across global OEMs. This Quality research paper aims to address the need of revision of design standards due to environmental factors prevailing in India. With the increase towards autonomous mobility, the number of electronics is also increasing, and this involves hardware & software evaluation. The hardware testing is a point of concern due to increase in the failure rate from the markets. Environment changes are very much evident with the growing economies and OEMs are developing the components with innovation, but if the basic design standards are not revised in parallel with the changing environment, the issues will continue to trouble the end customers. The failed cases data received from across the country was analyzed and observed that the cases are majorly reported from urban
Marwah, RamnikPyasi, PraveenBindra, RiteshGarg, Vipin
In order to comply with the tightening of global regulations on automobile exhaust gas, further improvements to exhaust gas control catalysts and upgrades to on-board diagnostics (OBD) systems must be made. Currently, oxygen storage capacity (OSC) is monitored by front and rear sensors before and after the catalyst, and deterioration is judged by a decrease in OSC, but it is possible that catalyst deterioration may cause the rear sensor to detect gas that has not been sufficiently purified. It is important to observe the activity changes when the catalyst deteriorates in more detail and to gain a deeper understanding of the catalyst mechanism in order to create guidelines for future catalyst development. In this study, we used a μ-TG (micro thermogravimetric balance) to analyze in detail how differences in design parameters such as the type of precious metal, detection temperature, and mileage (degree of deterioration) affect the OSC rate in addition to the OSC of the ceria-based
Hamada, ShotaUegaki, ShinyaTanabe, HidetakaNakayama, TomohitoJinjo, ItsukiKurono, SeitaOishi, ShunsukeNarita, KeiichiOnishi, TetsuroYasuda, KazuyaMatsumura, DaijuTanaka, Hirohisa
The paper presents novel studies on the electrical-to-thermal energy deposition to gas at different phases of a spark. The experiments utilized a 10.9 milliliter custom-built spark calorimeter. The energy transfer efficiencies across spark phases—breakdown+arc, and glow are quantified, emphasizing their importances in ensuring robust ignition. An AC capacitive ignition system was considered in the experiments. The spark plugs used in the experiments were of dual-nickel standard J-gap design of a fixed electrode gap. Test results show the breakdown+arc phases are highly efficient in converting electrical to thermal energy, crucial for ignition. The glow phase, offering control flexibility, is found to be less effective in energy transfer from spark to gas. In addition, a maximum threshold for both glow current and duration is found. Exceeding the threshold reduces the net energy deposition to the gas, indicating an increase in thermal energy losses, primarily to the spark plug
Saha, AnupamTunestal, PerAengeby, JakobAndersson, Oivind
Copper Antimony Sulfide (CuSbS2) is a promising ternary semiconductor for use as an absorber layer in third-generation thin film heterojunction solar cells. This newly developed optoelectronic material offers a viable alternative to cadmium telluride (CdTe) and copper indium gallium di-selenide (Cu(In,Ga)Se2) due to its composition of inexpensive, readily available, and non-toxic elements. These films were successfully produced at an optimal substrate temperature of 533 K using the conventional spray technique. X-ray diffraction and Raman studies confirm that the films exhibit a chalcostibite structure. Characterization studies reveal that the films possess lattice parameters of a = 0.60 nm, b = 0.38 nm, and c = 1.45 nm, with an absorption coefficient of 105 cm-1 and a band gap of 1.50 eV. Notably, the films exhibit p-type conductivity. All of these studies confirm that CuSbS2 is an excellent choice for the absorber layer in solar cell applications. An attempt was made in this study to
Kumar, YB KishoreYb, KiranTarigonda, HariprasadReddy M, Surya Sekhar
Magnesium is the lightest material than aluminium and has a better specific strength, which is utilized for weight management applications. This research developed the magnesium (Mg) matrix with 0.1, 0.2, 0.3, and 0.5 percentages in weight (wt%) of zirconium (Zr) particles (grain refinement agent) via the squeeze cast technique. The argon inert gas is limit oxidation during the melting of Mg. The influence of Zr on the functional properties of Mg is studied and related to monolithic Mg without the Zr phase. The microstructural analysis provides the Zr particles are dispersed uniformly in the Mg matrix and exposed to superior mechanical properties. The Mg processed with 0.5 wt% of Zr offered maximum hardness, ultimate tensile strength, and elongation percentage, which are 53, 48.8, and 43.5 % better than the values of monolithic Mg. Besides, the optimum Mg refining with 0.5 wt% Zr microstructure is detailed with EDS and conforms to the contribution of Zr. This is used for automotive
Venkatesh, R.Manivannan, S.Das, A. DanielMohanavel, VinayagamSoudagar, Manzoore Elahi Mohammad
LIDAR-based autonomous mobile robots (AMRs) are gradually being used for gas detection in industries. They detect tiny changes in the composition of the environment in indoor areas that is too risky for humans, making it ideal for the detection of gases. This current work focusses on the basic aspect of gas detection and avoiding unwanted accidents in industrial sectors by using an AMR with LIDAR sensor capable of autonomous navigation and MQ2 a gas detection sensor for identifying the leakages including toxic and explosive gases, and can alert the necessary personnel in real-time by using simultaneous localization and mapping (SLAM) algorithm and gas distribution mapping (GDM). GDM in accordance with SLAM algorithm directs the robot towards the leakage point immediately thereby avoiding accidents. Raspberry Pi 4 is used for efficient data processing and hardware part accomplished with PGM45775 DC motor for movements with 2D LIDAR allowing 360° mapping. The adoption of LIDAR-based AMRs
Feroz Ali, L.Madhankumar, S.Hariush, V.C.Jahath Pranav, R.Jayadeep, J.Jeffrey, S.
This research investigates the impact of friction stir welding (FSW) used to join micro-alloyed steel, on the material and its mechanical characteristics. FSW increases the metallurgical and mechanical qualities of joints made from micro-alloyed steel. However, Friction Stir Welding has produced only modest improvements in connecting steels. Automobile chassis, offshore platforms, oil and gas pipelines, mining, shipbuilding and railroad carriages, pressure vessels, bridges, and storage tanks are just some of the many places and find micro-alloyed steels employed. Frictional heat and tool movement over the joint cause micro defects occurred. Tungsten carbide tools are used in this investigation. Welding shares the same process characteristics, such as the tool's rotating speed (900 rpm) and axial force (10 kN). The table's traverse speed options are available, including 50 mm/min, 60 mm/min, and 70 mm/min. Vickers microhardness testing machines and tensile testing machines are used to
Rajan, C. SakthiKumar, N. MathanKumar, K. VetrivelKannan, S.Soundararajan, S.
Recently, there has been a growing emphasis on Thermal Management Systems (TMS) for Lithium-ion battery packs due to safety concerns related to fire risks when temperatures exceed operating limits. Elevated temperatures accelerate electrochemical reactions, leading to cell degradation and reduced electronic system performance. These conditions can cause localized hotspots and hinder heat dissipation, increasing the risk of thermal runaway due to high temperatures, flammable gases, and heat-producing reactions. To tackle these issues, many automotive manufacturers employ indirect liquid cooling techniques to maintain battery pack and electronic system temperatures within safe limits. Engineered nanofluids, particularly those containing multi-nanoparticles dispersed in water and ethylene glycol, are being explored to enhance electrical safety in case of accidental exposure to electrical systems in EVs. This paper focuses on the experimental characterization of nanofluid containing
Nahalde, SujayHonrao, GauravMore, Hemant
R-1234yf is used in almost every new car sold in the U.S., but the EU is discussing a ban and the industry is investigating alternatives like CO2 and propane. According to its manufacturer, Chemours, use of R-1234yf has grown so much since the refrigerant replaced the long-established R-134a that it's now used in 95% of new cars sold in the U.S. An estimated 220 million cars on global roads are also using it. The problem with R-134a, which came in cars and trucks in the 1990s, is that it's a gas with “a global warming potential (GWP) that is 1,430 times that of CO2,” according to the EPA. Since 2017, EU legislation has banned the use of any refrigerant in new vehicles with a GWP higher than 150. That rule doomed R-134a but opened the door for R-1234yf, which has a GWP of only four. The EU is currently revisiting R-1234yf emissions rules and may ban the substance in a few years. In the U.S., the EPA stands by its use.
Motavalli, Jim
To gain high efficiencies and long lifetimes, polymer electrolyte membrane fuel cell systems require precise control of the relative humidity of the cathode supply air. This is usually achieved by the use of membrane humidifiers. These are passive components that transfer the product water of the cathode exhaust air to humidify the supply air. Due to the passive design, controllability is achieved via a bypass. It is possible to use map-based control strategies to avoid the use of humidity sensors. Such map-based control requires deep insights into the humidifier behavior in all possible thermodynamic operating states, including various water loads. This paper focuses on typical operating conditions of heavy-duty application at high load, specifically on the occurrence of liquid water in the cathode exhaust gas, which has not been sufficiently investigated in the literature yet. In order to simulate these conditions, we built a test rig with an optically accessible single-channel set
Mull, SophieWeiss, LukasWensing, Michael
A major challenge for auto industries is reducing NOx and other exhaust gas emissions to meet stringent Euro 7 emission regulations. A urea Selective Catalyst Reduction (SCR) after-treatment system (ATS) commonly uses upstream urea water injection to reduce NOx from the engine exhaust gas. The NOx emission conversion rate in ATSs is high for high exhaust gas temperatures but substantially low for temperatures below 200°C. This study aims to improve the NOx conversion rate using urea pulse injection in a mass-production 2.2 L diesel engine equipped with an SCR ATS operated under low exhaust gas temperature. The engine experimental results show that, under 200°C exhaust temperature and 3.73x104 h-1 gross hourly space velocity (SV), the NOx conversion rate can be improved by 5% using 5-sec ON and 12-sec OFF (denoted as 5/12 s) urea pulse supply compared to the constant supply under time-averaged 1.0 urea equivalence ratio. It is experimentally observed that the urea pulse supply’s
Yoshida, FukaTakahashi, HideakiKotani, YuyaZu, QiuyueSok, RatnakKusaka, Jin
Details of combustion — the chemical reactions that take place when, for example, a flame is lit — are fleeting and therefore, difficult to study. But scientists would like to better understand the complex processes that occur in those billionths of seconds, not only to make engines more efficient but also to shed light on how candle flames, cars, and airplanes produce gases and particles that are harmful to humans and the environment.
Ultrasound imaging and ultrasound-mediated gene and drug delivery are rapidly advancing diagnostic and therapeutic methods; however, their use is often limited by the need for microbubbles, which cannot transverse many biological barriers due to their large size. A team of researchers from Rice University have introduced 50-nm gas-filled protein nanostructures derived from genetically engineered gas vesicles(GVs) that are referred to as 50 nmGVs.
American drivers have long been accustomed to quickly filling up at a gas station with plenty of fuel available, and electric vehicle drivers want their pit stops to mimic this experience. Driver uncertainty about access to charging during long trips remains a barrier to broader EV adoption, even as the U.S. strives to combat climate change by converting more drivers.
To understand effect of thermal hazards of LIBs during TR event, it is important to study flame propagation behaviour of LIBs during storage and transport applications. The process of flame propagation involves complex phenomena of gas phase behavior of LIBs. Present paper attempts a numerical investigation to portray this complex phenomenon. This paper investigates 18650 lithium cell considering two different chemistries NMC and LFP. A 3D numerical CFD model has been constructed to predict the gas phase behavior, threshold internal pressure, and cell gas venting of an 18650-lithium cell under thermal runaway conditions. The gas phase processes are modelled using the 4-equation thermal abuse model, while the cell's venting mechanism is modelled using Darcy's equation. Present work is divided into two parts: 1) Venting gas Internal pressure prediction 2) modeling thermal runaway event. Both procedures are implemented on two different cell chemistries to understand and evaluate following
Gudi, AbhayBonala, Sastry
Residual thermal energy, a by-product of automobiles, contributes notably to climate change and global warming. This energy is produced as exhaust gases in vehicles with internal combustion engines and as heat from batteries and fuel cells in eco-friendly vehicles. A thermo-electric generator (TEG) can transform this waste heat into useful electrical energy. The efficiency of the TEG is influenced by several factors, including the properties of the materials used, the geometrical design (form factor), and the conditions under which it operates. In this study, we examine how the choice of materials for the semiconductors, electrodes, ceramics, and joining components influences the overall performance of the TEG. We evaluate the TEG’s performance based on output power, and efficiency. The findings from these measurements allow us to determine which material and its properties significantly impact the TEG’s performance. For optimal TEG performance, seek materials with high Seebeck
Ponangi, Babu RaoMutagi, MeghaBali, Gaurav
Growing environmental concerns drive the increasing need for a more climate-friendly mobility and pose a challenge for the development of future powertrains. Hydrogen engines represent a suitable alternative for the heavy-duty segment. However, typical operation includes dynamic conditions and the requirement for high loads that produce the highest NOx emissions. These emissions must be reduced below the legal limits through selective catalytic reduction (SCR). The application of such a control system is time-intensive and requires extensive domain knowledge. We propose that almost human-like control strategies can be achieved for this virtual application with less time and expert knowledge by using Deep Reinforcement Learning. A proximal policy optimization (PPO) -based agent is trained to control the injection of Diesel exhaust fluid (DEF) and compared with the performance of a manually tuned controller. The performance is evaluated based on the restrictive emission limits of a
Itzen, DirkAngerbauer, MartinHagenbucher, TimoGrill, MichaelKulzer, Andre
If an external force with changing amplitude acts on an elastic medium such as a gas, a liquid or a solid, an undulating propagation of pressure and density fluctuation occurs in space and time, starting from the point where the force is applied. This is known as sound. The frequency of sound waves ranges from a few hertz (Hz) up to several gigahertz (see Figure 1). Infrasound, the sound humans cannot hear, lies at frequencies below 16 Hz. It is followed by the hearing range, which reaches up to 20 kHz. Ultrasonic waves, which cannot be heard, lie in the frequency range from 20 kHz to 1.6 GHz, which equals 16 billion cycles per second. A prominent application example in medical technology is the use of ultrasound for diagnostic imaging techniques. In industry and research, ultrasound is mainly used in measurement technology, where sound waves with low power are used. The intensity of the sound describes the power that hits a certain surface. If it exceeds 10 W/cm2, we speak of power
The study demonstrates the possibility and in particular the method to derive the efficiency of the entire fuel cell power system by measuring specific data of the recirculation path of the anode circuit of a fuel cell system. The results demonstrate the capabilities of the existing test rig and enable investigations on the suitability of auxiliary components. This study focuses on the hydrogen recirculation path equipped with multiple sensors and a needle valve to enable the required operating conditions of the fuel cell. Running a startup load profile without reaching the equilibrium state at all steps, the dynamic of the system and the requirements to the sensor parameters, such as sampling rate and precision, was seen. Additionally, it became obvious that the recirculation pump used is oversized, but a load point shift compensated this artifact. In detail, the stoichiometry and the efficiency of the entire system was evaluated. It was seen that the hydrogen concentration is
Allmendinger, FrankMartin, BenediktSchmidtmann, Marlen
Previous studies have shown that dosing AdBlue into the exhaust system of diesel engines to reduce nitrogen oxides can lead to an increase in the number of particles (PN). In addition to the influencing factors of exhaust gas temperature, exhaust gas mass flow and dosing quantity, the dosed medium itself (AdBlue) is not considered as a possible influence due to its regulation in ISO-standard 22241. However, as the standard specifies limit value ranges for the individual regulated properties and components for newly sold AdBlue, in reality there is still some margin in the composition. This paper investigates the particle number increase due to AdBlue dosing using several CPCs. The increase in PN is determined by measuring the number of particles after DPF and thus directly before dosing as well as tailpipe. Several AdBlue products from different sources and countries are measured and their composition is also analyzed with regard to the limit values regulated in the standard. This
Herold, TimNoone, PatrickBeidl, ChristianBoldt, ThomasHochholzner, MichaelKontin, Sinisa
AISI H13 hot work tool steel is commonly used for applications such as hot forging and hot extrusion in mechanical working operations that face thermal and mechanical stress fluctuations, leading to premature failures. Cryogenic treatment was applied for AISI H13 steel to improve the surface hardness and thereby fatigue resistance. This work involves failure analysis of H13 steel specimens subjected to cryogenic treatment and gas nitriding. The specimens were heated to 1020°C, oil quenched followed by double tempering at 550°C for 2 h, and subsequently, deep cryogenically treated at −185°C in the cryochamber. Gas nitriding was carried out for 24 h at 500°C for 200 μm case depth in NH3 surroundings. The specimens were subjected to rotating bending fatigue at constant amplitude loading at room temperature. Measurement of surface roughness, hardness, and microstructural analysis indicated improved fatigue life for cryogenically treated specimens as compared to gas nitride, which could be
Shinde, TarangMutalikdesai, SachinJomde, AmitShamkuwar, Sonal
Fossil fuel reserves are swiftly depleting when consumer demand for these fuels continues to rise. In order to meet the demand and diminish the pollution derived through conventional fuels, it is crucial to employ cleaner fuels made from substitutes such as waste biomass. Also, converting waste biomass to fuel can lower usage of landfills. There are many biomass resources that are suitable for fuel production, out of which groundnut is also a potential feedstock. Groundnut shell biomass was chosen for this study, as it is a waste leftover during shelling of groundnuts for various commercial applications. The procured groundnut shells were converted to oil using pyrolysis process and was distilled. Both the pyrolysis oil and the distilled oil were analyzed using Fourier transform infrared instrument wherein the presence of functional groups such as alcohols, amines, and carboxylic acids were identified. Further analysis of the distilled oil using gas chromatography and mass spectrometry
Chelladorai, PrabhuBalakrishnan, Navaneetha KrishnanKeerthiga, G.Singhvi, SambhavAtekov, Parahat
With the rapid development of electric vehicles, the demands for lithium-ion batteries and advanced battery technologies are growing. Today, lithium-ion batteries mainly use liquid electrolytes, containing organic compounds such as dimethyl carbonate and ethylene carbonate as solvents for the lithium salts. However, when thermal runaway occurs, the electrolyte decomposes, venting combustible gases that could readily be ignited when mixed with air and leading to pronounced heat release from the combustion of the mixture. So far, the chemical behavior of electrolytes during thermal runaway in lithium-ion batteries is not comprehensively understood. Well-validated compact chemical kinetic mechanisms of the electrolyte components are required to describe this process in CFD simulations. In this work, submechanisms of dimethyl carbonate and ethylene carbonate were developed and adopted in the Ansys Model Fuel Library (MFL). Further improvements were made to enhance the kinetic consistency
Zhang, KuiwenPuduppakkam, KarthikShelburn, Anthony
Certain sports utility vehicles (SUVs) utilize dual latches and gas struts in their hood design. This is primarily driven by the larger size of the hood and specific architectural requirements. These hoods can be securely latched either by a dynamic single stroke closing method or by quasistatic two stroke closing method. In dynamic method, the hood is closed with a single, high-velocity motion for the final primary latching, whereas in quasistatic method, force is initially applied for the secondary latching and then for the final primary latching. In this study, both the dynamic and quasistatic closing methods are compared in terms of closing force and velocity and hood over travel distance. A load cell is used for measuring the closing force, velocity meter is used for velocity measurement and a rope sensor is used for measuring the hood over travel distance. It is evident from the study that the velocity required for hood closing is higher in the dynamic method, than the quasi
Selvan, VeeraSakthivel, GowthamR, BalajiAS, KevinA, SankaranarayananKamat, RohanUnadkat, SiddharthPandurangan, Venugopal
Water removal from Proton Exchange Membrane (PEM) Fuel Cell (FC) mainly involves two phenomena: some of the emerging droplets will roll on the Gas Diffusion Layer (GDL), others may impact channel walls and start sliding along the airflow direction. This different behaviour is linked to the hydrophobic/hydrophilic nature of the surface the water is moving on. In this paper, the walls of the channel of a FC were characterized by applying optical techniques. The deposition of droplets on the channel wall led to an evaluation of the proper range for Contact Angle Hysteresis (CAH = 55° - 45°), and due to the high wettability of the surface, droplets dimension was defined with a dimensionless parameter B/H. Under high crossflow condition (15 m/s) a sliding behaviour was observed. The channel features determined through image processing were used as boundary conditions for a 2D CFD two phase simulation employing the Volume of Fluid (VOF) model to keep track of the fluids interface. A droplet
Antetomaso, ChristianMerola, Simona SilviaIrimescu, AdrianVaglieco, Bianca MariaJannelli, Elio
Modern automobiles are dependent on complex networks of electronic sensors and controls for efficient and safe operation. These electronic modules are tested for stringent environmental load conditions where product validation consists of one or a combination of loads such as Vibration, Mechanical Shock, Temperature, Water, Humidity, Dust, Chemicals, and Radiation. Exposure of electronics to water leads to many harmful effects resulting in the failure of electronic systems. Previously published technical paper [1] SAE 2023-01-0157 described a methodology to estimate risk in a humid environment, where water is dispersed in air as a gas phase. The present paper extends the scope of virtual validation using Computational Fluid Dynamics (CFD) simulation tools to an environment with water in the liquid phase. In this paper, a non-sealed automotive electronic module subjected to a water drip test is evaluated using the CFD model. A transient 3D multiphase simulation is performed using the
Kumar, VinayViswanathan, SwaminathanDhanasekaran, Prem
The piston and piston ring are used in a severe contact environment in engine durability tests, which causes severe wear to the piston ring groove, leading to significant development costs for countermeasures. Conventionally, in order to ensure functional feasibility through wear on the piston top ring groove (hereinafter “ring groove”), only functional evaluations through actual engine durability testing were performed, and there was an issue in determining the limit value for the actual amount of wear itself. Because of this, the mechanism that may cause wear on the ring groove was clarified through past research, but this resulted in judgment criteria with some leeway from the perspective of functional assurance. To establish judgment criteria, it was necessary to understand both functional effect from ring groove wear and the mechanism behind it. For this research, the functional effect from wear on the upper surface of the ring groove and the mechanism that may cause this were
Yoshii, KentaTakahashi, KatsuyukiSato, KenjiHitosughi, HideshiNakada, Fumihiro
To satisfy the stringent regulations for exhaust gas emissions from gasoline-powered vehicles, large amounts of Rh and Pd have often been employed in three-way catalysts (TWCs) as the main active components. On the other hand, Pt-based TWCs are not often used in gasoline vehicles because Pt is readily sintered by its exhaust gases at approximately 1000 °C [1, 2]. In general, Pt-based TWCs must be located away from large thermal loads to maintain the active sites for gas purification. Based on this background, we previously reported that employing a small amount of CeO2 calcined at 1000 °C (cal-CeO2) in Pt-based TWCs was one of the most effective approaches for improving the catalytic activity without increasing the amount of Rh and Pd [3]. The effect of cal-CeO2 was attributed to the higher redox performance and Pt dispersion derived from the strong interactions between Ce and Pt. Therefore, the resulting Pt-based TWCs exhibited high catalytic performance, despite the low specific
Morita, ItaruTanaka, HirokiSaeki, ShoheiIsayama, AkihiroIwashina, KatsuyaNagao, YukiEndo, YoshinoriWakabayashi, TakashiHaneda, Masaaki
Super duplex stainless steel (SDSS) is a type of stainless steel made of chromium (Cr), nickel (Ni), and iron (Fe). In the present work, a 1.6 mm wide thin sheet of SDSS is joined using gas tungsten arc welding (GTAW). The ideal parameter for a bead-on-plate trial is found, and 0.216 kJ/mm of heat input is used for welding. As an outcome of the welding heating cycle and subsequent cooling, a microstructural study revealed coarse microstructure in the heat-affected zone and weld zone. The corrosion rate for welded joints is 9.3% higher than the base metal rate. Following the corrosion test, scanning electron microscope (SEM) analysis revealed that the welded joint’s oxide development generated a larger corrosive attack on the weld surface than the base metal surface. The percentages of chromium (12.5%) and molybdenum (24%) in the welded joints are less than those in the base metal of SDSS, as per energy dispersive X-ray (EDX) analysis. Corrosion modeling is done using the COMSOL
Kumar, SujeetKumar, YogeshE. K., Vimal K.
Solid rods of dissimilar metals are easily welded by friction welding. This process is a solid-state process where no fumes or gases are released which is friendly to the environment. In advanced engineering practice, joining Titanium (Ti) alloy and stainless steel (SS) is very important due to poor bonding strength in direct joining. These materials are easily joined by an interlayer technique using materials like nickel, silver, niobium, aluminum, and copper. Special surface geometry techniques hold the interlayer materials between dissimilar metals in different forms like coating, foils, and solid metals. In this investigation, the finite element method is used for modeling the process, and the Johnson-cook equation was used to find the analysis of output values with the defined material properties. The heat generated is calculated and numerically compared and analyzed with experimental results. Observations such as metallography, hardness, and tensile test were studied. The results
Balasubramanian, M.Prathap, P.Madhu, S.
Mild steel and AISI 304 L have gained widespread usage across diverse industries, such as naval vessels, boilers, aviation, and automobile sector, due to their ready availability and distinct attributes. Fusion welding techniques have been employed to join this alloy, which is known for its specific qualities. The strength of welded joints is directly proportional to a certain percentage of the strength exhibited by the base materials. However, the welding process becomes intricate when dissimilar steels need to be joined. In such cases, achieving consistent and reliable welding become a challenge. Therefore, meticulous attention is required in the selection of electrodes, filler wires, and other operational parameters, such as current, voltage, and shielding gas. Among the solid-state joining methods, FW (Friction Welding) stands out as an excellent approach to achieving robust joints. This technique ensures strong joint formation. In this study, two pivotal FW parameters viz
Hari Prasath, S.Abishek, D.Hamshavardhan, S.Sankar Guru, K.Gunasekaran, K.N.
A significant contribution towards climate change and global warming is the residual thermal energy generated from automobiles as exhaust gases in IC engine-based vehicles and from batteries and fuel cell heating in green vehicles. This waste heat, also known as thermal energy, has the potential to be transformed into valuable electrical energy through the utilization of a thermo-electric generator (TEG). The performance of the TEG depends on various parameters such as material properties, geometries (form factor), and operating conditions. Current research focuses on the effect of the form factor, i.e., the semiconductor’s length, width, and height (thermocouple), on the overall performance of the TEG. Eleven cases are examined by varying the length, width, and height of the thermocouple. The TEG’s performance is measured using its internal resistance, open circuit voltage, maximum current, output power, and efficiency. Current work reveals that there is a significant impact on TEG’s
Bali, GauravMutagi, Megha DharnendraPonangi, Babu Rao
Due to the limitations of current battery manufacturing processes, integration technology, and operating conditions, the large-scale application of lithium-ion batteries in the fields of energy storage and electric vehicles has led to an increasing number of fire accidents. When a lithium-ion battery undergoes thermal runaway, it undergoes complex and violent reactions, which can lead to combustion and explosion, accompanied by the production of a large amount of flammable and toxic gases. These flammable gases continue to undergo chemical reactions at high temperatures, producing complex secondary combustion products. This article systematically summarizes the gas generation characteristics of different types and states of batteries under different thermal runaway triggering conditions. And based on this, proposes the key research directions for the gas generation characteristics of lithium-ion batteries.
Qi, ChuangLiu, ZhenyanLin, ChunjingHu, Yuanzhi
Small mobile robots carrying sensors could perform tasks like catching gas leaks or tracking warehouse inventory. But moving robots demands a lot of energy, and batteries, the typical power source, limit lifetime and raise environmental concerns. Researchers at the University of Washington have now created MilliMobile, a tiny, self-driving robot powered only by surrounding light or radio waves.
Dissimilar metal welding (DMW) gives a distinctive and complex process because each zone in the different welding area has unique structures and characteristics. The customized weld zone has a unique structure and may have a heating effect on weld metal properties. DMW is used in aerospace, marine, oil refineries, petrochemical industries, power plants including nuclear and other engineering applications due to economic considerations and offered lightweight in design. This paper's main objective is to investigate the microstructure evolution and impact strength of a joint Austenitic AISI 321 plates and Duplex UNS32205 stainless steel welded using pulsed current GTAW (PCGTAW). The base plates were joined by ER2209 filler metal and the microstructure of base and weld metal zones was observed. The selected filler metal was a duplex in nature and contains equal ratio of austenite and ferrite phase in the different weld metal zones of UNS32205 and AISI 321 weldments. The fractography
Kumar, S PraveenKilari, Naveen
A urea-selective catalytic reduction (SCR) system is used for the reduction of NOx emitted from diesel engines. Although this SCR catalyst can reduce NOx over a wide temperature range, improvements in NOx conversion at relatively low temperatures, such as under cold-start or low-load engine conditions, are necessary. A close-coupled SCR (cc-SCR), which was set just after the engine exhaust manifold, was developed to address this issue. The temperature of the SCR catalyst increases rapidly owing to the higher exhaust temperatures, and NOx conversion is then enhanced under cold-start conditions. However, since the diesel oxidation catalyst is not installed before the SCR catalyst, hydrocarbon (HC) emissions pass directly through the SCR catalyst and poison it, leading to lower NOx conversion. Therefore, the mechanism of NOx conversion reduction on HC-poisoned SCR catalysts are required to be studied. In this study, the effects of HC poisoning on the NOx conversion of Cu-CHA catalysts
Tanaka, KotaroDobashi, IbukiSakaida, SatoshiKonno, Mitsuru
The supercritical fluid combustion technology was regarded as an effective method to increase fuel gas mixing rate and performance. During the injection process, critical characteristics dominate the jet development to behave as different spray structure. Due to the limited researches about supercritical gasoline-like fuel injection characteristics, macroscopic and near-nozzle microscopic spray structures of supercritical n-heptane injected into atmosphere condition were observed and compared with the injection of cryogenic nitrogen in this work. A supercritical fuel injection device was designed able to heat the fuel temperature up to 773 K and maintain the fuel injection pressure stable at 4 MPa. Backlight illumination and schlieren imaging technologies were applied to capture the liquid and overall jet structure. The effect of initial fuel temperature on the spray structure was analyzed and some novel near-nozzle structures were also discussed. Results show that with the increase of
Liu, RuiHuang, LiNi, XinminJu, DehaoYi, RanMa, Yue
This paper presents a simulation study of hydrogen leakage from an onboard hydrogen supply system in open, closed, and semi-closed spaces. The simulations investigate the effects of environmental factors and conditions such as obstacles on the diffusion process of hydrogen leaks. The results show that when hydrogen gas leaks, the direction of the leak determines the potential risk. If the leak is directed toward the cab, the gas will accumulate in the gap between the cab and the hydrogen supply system, posing a significant risk to the driver. On the other hand, if hydrogen leaks toward the rear, a combustible cloud forms mainly behind the vehicle at a safe distance of 3.8 meters. The study also investigated the effects of wind speed, wind direction, and ambient temperature. It was found that headwinds can cause hydrogen to spread near the vehicle, increasing the risk of an accident. The paper also investigates the effect of obstacles that inhibit the horizontal diffusion of hydrogen
Zhang, YongtaoYu, JiangbinYang, ZirongHao, DongZhang, Xin
Laser powder bed fusion is one of the metal additive manufacturing technologies, so-called 3D printing. It has attracted great attentions due to high geometrical flexibility and remarkable metallurgical characteristics. An oil catch tank has been widely used in automotive industries for filtering oil vapors or carbon sludge from blow-by gas as a conventional usage. A pneumatic valve system mainly adopted to high-performance engines is also a potential application of it because undesirable oil infiltrates into air springs during engine operation, resulting in an excess spring pressure. This work focused on developing a lightweight oil catch tank which can be applied to a pneumatic valve system by taking advantage of additive manufacturing techniques. Al-Mg-Sc alloy powder with high tensile strength as well as high ductility were used under the consideration of specific strength, printability and availability. Test specimens fabricated with optimal printing parameters exhibited
Watanabe, KeitaKurita, HirotakaIwasaki, ShinyaMitsui, RikuNagao, TakashiTashiro, TsuguharuIchimura, MakotoKano, YoshiakiKusui, Jun
To understand the effect of discharge frequency and discharge energy of dielectric barrier discharges (DBD) on the flame kernel development process, the observation of the discharges and ignition trials were performed in a constant volume vessel. Results showed that the energy of DBD released during a single cycle of discharge decreases, but the power of the discharges increases with the frequency increases. The ignition probability improved and the time for the flame propagation decreased under high frequency because the power of the discharges efficiently rises the local gas temperature near the electrodes.
AGRAWAL, SaurabhYAMAMOTO, ShuyaHORIBE, NaotoHAYASHI,, JunKAWANABE, Hiroshi
The influence of ethanol volume fraction on the spontaneous ignition of homogeneous premixed gas reformed by non-equilibrium plasma was investigated. The HCCI experiments of the gas was carried out using a Rapid Compression Machine (RCM). The spontaneous ignition process and reforming process were numerically investigated by reaction simulation in OD. A simplified model was proposed to explain the influence of the reforming of the gas with different ethanol volume fractions, and the model was validated. These results indicate that the influence of the reforming on ignition delay of cool flame is almost irrespective of the ethanol volume fractions.
Otani, MasakiTakagi, KeigoGomi, KoichiSakurai, EitaSasaki, YusukeSaito, MasanoriTanabe, Mitusuaki
The Euro 7 emission regulations currently under consideration by the EU will adopt on-road emissions test as the main Type Approval procedure, and it has been proposed that the number of gas components to be measured will be increased. Therefore, the Portable Emissions Measurement System (PEMS) used for on- road emissions testing must be able to simultaneously measure more components with higher precision while maintaining the same compact and lightweight structure as in the existing PEMS. The authors have applied a relatively new technique, quantum cascade laser infrared spectroscopy (QCL-IR), to an on-board multi-component gas analyzer. Comparison with laboratory tests on a gasoline passenger car on a dynamometer showed that the newly developed QCL- IR PEMS correlated well with conventional PEMS and stationary conventional analyzers. Signal noise and interference from other gases was also confirmed to show the expected performance, which was equal to or better than that of
Kondo, YosukeHamauchi, ShotaKowada, YoshihitoShibuya, KyojiOtsuki, Yoshinori
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