Browse Topic: Octane

Items (942)
The integration of low-octane gasoline with a compression ignition combustion system has been proposed as a strategy to reduce Well-to-Wheel CO2 emissions from automobiles using petroleum-based fuel. In the current situation where low-octane gasoline is not widely available in the market, onboard reforming of commercial gasoline to increase the cetane number (lower the octane number) allows for compression ignition combustion even with commercial gasoline. This requires “Cetane on Demand” technology, which enables compression ignition combustion with both commercial gasoline and low-octane gasoline. It is known that the ignition property of fuel is enhanced when the fuel is oxidized to generate hydroperoxides. Moreover, the use of N-hydroxyphthalimide (NHPI) as a catalyst promotes hydroperoxide generation at low temperatures. The objective of this study is to develop a device that enhances the ignition properties of gasoline through onboard fuel reforming. Initially, from the seven
Hashimoto, KohtaroYamada, YoshikazuMatsuura, KatsuyaKudo, TomohideChishima, HiroshiAl-Taher, MaryamKalamaras, ChristosAlbashrawi, Reem
Series hybrid vehicles with internal combustion range extenders are a promising solution for sustainable transportation. In this application, net zero carbon emissions can be achieved using renewable fuels. Fischer-Tropsch-derived e-gasolines/naptha allow for high energy density and safe liquid fuels. However, Fischer-Tropsch naptha fuel derivatives must undergo several processing stages to reach current engine-grade octane ratings, negatively affecting the synthesis's profitability and energy efficiency. Gasoline engine technologies capable of operating with low-octane fuels could allow the adoption of unprocessed Fischer-Tropsch gasoline. The rotary Wankel engine design suits range extenders thanks to its high power-to-size ratio. In this study, the knocking tendency of homogenous charge spark-ignition rotary Wankel engines is numerically assessed through Chemkin-Pro spark-ignition engine zonal model for knock assessment. Rotary Wankel engines are modeled by providing the
Brunialti, SirioVorraro, GiovanniTurner, JamesSarathy, Mani
The integration of low-octane gasoline with a compression ignition combustion system has been proposed as a strategy to reduce Well-to-Wheel CO2 emissions from automobiles in petroleum-based fuel. However low-octane gasoline is not widely available in the market currently. Onboard reforming of commercial gasoline to increase the cetane number (lower the octane number) allows for compression ignition combustion even with commercial gasoline. To reform commercial gasoline, a reformer with a spiral structure reactor and mechanical stirring air introduction was designed and prototyped based on the results of toluene reforming tests (A Study on Cetane on Demand Technology Part 1: Development of fuel reformer to improve fuel ignitability). Using N-hydroxyphthalimide (NHPI)-supported ZSM-5 as a catalyst, commercial gasoline was reformed. As a result, 25.5 liters of reformed gasoline was obtained. The hydroperoxide concentration in the entirety of our reformulated gasoline was determined to be
Matsuura, KatsuyaHashimoto, KohtaroYamada, YoshikazuAl-Taher, MaryamKalamaras, ChristosVoice, AlexanderBhadra, Kaustav
The challenges with electrification in the automotive industry have led to rethinking the decisions to ban internal combustion engines. Nonetheless, decarbonization of transportation remains a regulatory priority in many countries, irrespective of the energy source for automotive powertrains. Renewable oxygenated fuel components can help with the rapid decarbonization of gasoline fuels in the current fleet. Ethanol is one of the primary renewable components typically used for blending in gasoline primarily at 10% v/v but up to 20% v/v substitution which corresponds to 3.7 to 8.0% oxygen by mass. However, a range of oxygenates could be used instead of ethanol. This study aimed to determine if the engine could discriminate between different oxygenates in gasoline fuels blended at the same octane (RON) and oxygen levels. Oxygenates such as methyl-tert-butyl-ether (MTBE) and ethyl-tert-butyl-ether (ETBE) were considered in this study. Blends were made using a combination of n-heptane, iso
Kalaskar, VickeyMitchell, RobertPourreau, Daniel
Drop-in gasoline fuels that originate from renewable, low-net-carbon sources, such as methanol-to-gasoline (MTG), are an important bridge in the transition between traditional fossil fuels and electrification of the transportation sector. The composition of these fuels can be tuned by adjusting the settings of the chemical processes used to create them, which can be leveraged to formulate optimized fuels for higher knock resistance or higher flame speed. This study investigated how the distribution of hydrocarbon classes and molecular structure of a renewable MTG gasoline surrogate affected knock and flame speed using chemical kinetic modeling. The original MTG surrogate was modified by increasing the relative amount of a certain hydrocarbon class while the concentration of other hydrocarbon classes is reduced equally. Increasing normal- and iso-alkanes increased reactivity and penalized octane sensitivity, olefins increased octane sensitivity while keeping the research octane number
MacDonald, JamesLopez Pintor, DarioMatsubara, NaoyoshiKitano, KojiYamada, Ryota
The present study aims to determine the comparative performance evaluation in terms of fuel economy (kmpl) and wide open throttle (WOT) power derived from set of different blends of high octane gasoline fuel(s) i.e., Neat Gasoline (E0), E10 & E20 (With different dosages of additives) in high compression ratio (HCR) motorcycle on chassis dynamometer facility. With the Government of India focus on use of alcohol as co-blend of gasoline with the endeavour to save foreign exchange and also to reduce greenhouse gases (GHG) emissions. The commercially available blended fuels, E10 & E20, have high research octane number (RON, 92-100) and as per the available literature high RON fuel have the better anti-knocking tendencies thereby lead to higher fuel economy. There are various routes to formulate high octane fuel (refining technologies, additive approach & ethanol blending route) in the range of 92-100 octane number which are currently commercialized in Indian market. In the present study
Saroj, ShyamsherKalita, MrinmoyKumar, PrashantKant, ChanderPatanwal, PradeepChakradhar, MayaSithananthan, MArora, Ajay KumarHarinarain, Ajay KumarMaheshwari, Mukul
Surrogate fuels that reproduce the characteristics of full-boiling range fuels are key tools to enable numerical simulations of fuel-related processes and ensure reproducibility of experiments by eliminating batch-to-batch variability. Within the PACE initiative, a surrogate fuel for regular-grade E10 (10%vol ethanol) gasoline representative of a U.S. market gasoline, termed PACE-20, was developed and adopted as baseline fuel for the consortium. Although extensive testing demonstrated that PACE-20 replicates the properties and combustion behavior of the full-boiling range gasoline, several concerns arose regarding the purity level required for the species that compose PACE-20. This is particularly important for cyclo-pentane, since commercial-grade cyclo-pentane typically shows 60%–85% purity. In the present work, the effects of the purity level of cyclo-pentane on the properties and combustion characteristics of PACE-20 were studied. Chemical kinetic simulations were performed to
Lopez-Pintor, DarioAbboud, RamiMacDonald, JamesLee, Sanguk
Fuel efficiency is one of the most important customer requirement in Indian market as well as very crucial to meet the upcoming regulation like CAFÉ for Indian Automotive manufacturers. Most of the technology changes to meet this challenge, always come with a cost penalty with hardware addition. To counter the above challenge, a strategy has been identified in the EMS software that will dynamically adapt the spark timing based on fuel octane rating. This strategy has resulted in fuel efficiency improvement on Modified Indian Drive Cycle on chassis dynamometer test and as well as on real life road tests using fuels with various octane number.
Tyagarajan, SethuramalingamKavekar, PratapSuna, BhagyashreeAgarwal, NishantShaikh, Wasim
Tank-to-wheels (TTW) CO2 reduction for ethanol blends is determined from either gasoline composition or vehicle exhaust measurements. Fuels are characterized using a carbon intensity (CI), which is the ratio of carbon (as CO2 mass) in the fuel to the net heating value. Our objective is to assess changes in CI of market gasoline with varying ethanol content that can be used to appreciate change in vehicle tailpipe greenhouse gases (GHG) in response to policy controlling the ethanol level in market fuels. Ethanol has both a reduced carbon content and a reduced net (lower) heating value relative to petroleum species, with a CI slightly lower than that of typical petroleum gasoline. However, ethanol blending offers additional CI reduction because it enables a reduction of aromatics in the petroleum blendstock for oxygenate blending (BOB) while maintaining octane rating of the blend. Aromatics have a CI about 20% higher than paraffins. The primary refinery option for aromatic reduction is
Clark, Nigel N.Klein, TammyHiggins, TerrenceMcKain, David
Reducing the carbon emissions associated with ICE- containing vehicles is a complimentary step towards carbon neutrality alongside the introduction of vehicles using newer energy vectors. In this study, the authors investigated emissions and efficiency impact of fully renewable E10-grade gasoline fuels blended with sustainable components at both 90 RON and 96 RON in comparison with reference regular E0 and premium certification gasolines across a range of ICE vehicle applications. Both renewable fuels were blended to the Japan JIS K2022 2012 E10 specification. The study shows very low carbon gasolines are technically feasible and potentially have an important role to play in decarbonizing both new advanced technology ICE vehicles and, critically, the existing ICE vehicle parc in the transition towards a zero emissions future.
Yates, TimothyAli, RanaSuzuki, MayuMatsubara, NaoyoshiYokoo, NozomiMorii, TakuyaAkiyama, ShotaIshizaki, Keita
It is useful for research purposes to define simple surrogate gasoline compositions that can replicate the chemical and physical properties of more complex mixtures. Ethanol is used in commercially available gasolines around the world as part of the pathway to the decarbonization of the transportation sector. In this study equations were developed to predict the Research Octane Number (RON), Motor Octane Number (MON) and Dry Vapour Pressure Equivalent (DVPE) of gasoline surrogates containing ethanol (10-25 vol%), isopentane, n-heptane, isooctane and toluene. The non-linear blending behaviour associated with ethanol is found to necessitate coefficients in the equations developed for MON that are a function of ethanol content, whereas surprisingly the equations for RON and DVPE do not need this added level of complexity. Using the equations developed the RON and DVPE of the ethanol-containing surrogates can be calculated using one set of coefficients for any ethanol concentration between
Kaliafetis, FilimonasCracknell, Dr. Roger F.
To have a more complete understanding of the fuel effects on each subsequent stage of a stochastic preignition event in a spark-ignition engine and to build on the previous work of understanding the propensity of fuel to initiate and sustain a preignition flame, this work is focused on examining the role of fuel on the onset of knock and the intensity of superknock once the unburned mixture reaches certain conditions ahead of the preignition flame. Using a “skip advance” spark test method to simulate preignition flames initiated at different cylinder conditions, more than 20 single- and multicomponent fuels were ranked based on the condition required to reach the onset of knock (the start of end-gas autoignition) and the condition that leads to severe superknock intensities. It was found that average knock intensity can be mainly explained by the unburn mixture fraction and the thermodynamic condition of the unburned mixture and, not surprisingly, that the fuel ranking for the onset of
Yu, XinCostanzo, VincentChapman, ElanaDavis, Richard
Methanol has recently emerged as a promising fuel for internal combustion engines due to its multiple carbon-neutral production routes and advantageous properties when combusting. Methanol is intrinsically more suitable for spark-ignition (SI) operation thanks to its high octane number, but its potential in heavy-duty applications also encourages engine manufacturers in this field to retrofit their existing compression-ignition products into methanol/diesel dual-fuel (DF) operation. For both SI operation and DF operation, injecting methanol into the engine’s intake path at low pressure is a relatively simple and robust method to introduce methanol into the cylinders. However, the much higher heat of vaporization (HoV) of methanol compared to conventional SI fuels like gasoline can be a double-edged sword. On the one hand, its enhanced cooling effect may increase volumetric efficiency and lower knock tendency, on the other hand, the extra heat it absorbs when evaporating may pose cold
Pu, Yi-HaoLarsson, TaraRobeyn, TomDe Paepe, MichelVerhelst, Sebastian
A viable option to reduce global warming related to internal combustion engines is to use renewable fuels, for example methanol. However, the risk of knocking combustion limits the achievable efficiency of SI engines. Hence, most high load operation is run at sub-optimal conditions to suppress knock. Normally the fuel is a limiting factor, however when running on high octane fuels such as methanol, other factors also become important. For example, oil droplets entering the combustion chamber have the possibility to locally impact both temperature and chemical composition. This may create spots with reduced octane number, hence making the engine more prone to knock. Previous research has confirmed a connection between oil droplets in the combustion chamber and knock. Furthermore, previous research has confirmed a connection between oil droplets in the combustion chamber and exhaust particle emissions. However, the co-variation between oil originating particle emissions and knock has not
Ainouz, FilipAdlercreutz, LudvigCronhjort, AndreasStenlaas, Ola
Regulations limiting greenhouse gas (GHG) emissions in the transport sector have become more restrictive in recent years, drawing interest to synthetic fuels such as e-fuels and biofuels that could “decarbonize” existing vehicles. This study focuses on the potential to increase the thermal efficiency of spark-ignition (SI) engines using ethanol as a renewable fuel, which requires a deep understanding of the effects of ethanol on combustion behavior with high compression ratios (CRs). An important phenomenon in this condition is pre-spark heat release (PSHR), which occurs in engines with high CRs in boosted conditions and changes the fuel reactivity, leading to changes in the burning velocity. Fuel blends containing ethanol display high octane sensitivity (OS) and limited low-temperature heat release (LTHR). Consequently, their burning velocities with PSHR may differ from that of gasoline. This study therefore aimed to clarify the effects of ethanol on SI combustion behavior under PSHR
Yoshimura, KeiIsobe, KoheiKawashima, MitsutakaYamaguchi, KyoheiSok, RatnakTokuhara, SatoshiKusaka, Jin
This SAE Recommended Practice presents recommendations for test fuels and fluids that can be used to simulate real world fuels. The use of standardized test fluids is required in order to limit the variability found in commercial fuels and fluids. Commercial fuels can vary substantially between manufacturers, batches, seasons, and geographic location. Further, standardized test fluids are universally available and will promote consistent test results for materials testing. Therefore, this document: a Explains commercial automotive fuel components b Defines standardized components of materials test fluids c Defines a nomenclature for test fluids d Describes handling and usage of test fuels e Recommends fluids for testing fuel system materials The test fluid compositions specified in Section 7 of this document are recommended solely for evaluating materials. They are not intended for other activities, such as engine development, design verification, or process validation unless agreed
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In the search for sustainable transportation fuels that are not in competition with food production, considerable efforts are made in the development of so-called second-generation (2G) biofuels. This paper looks into the results of a novel 2G biofuel production technique that is based on a catalytic process that operates at low temperature and that converts woody biomass feedstock into a stable light naphtha. The process development is integrated in the Belgian federal government funded Ad-Libio project and the process outcome is mainly consisting of hydrocarbons containing five to six carbon atoms. Their composition can be altered, resulting in a large amount of different possible fuel blends. The ultimate goal is to produce a drop-in fuel that can be fully interchanged with the gasoline fuels in use today. This is a challenge, since the Ad-Libio fuel components differ significantly from gasoline fuel components. For an initial assessment of the suitability of a novel blend, a fuel
Robeyn, TomLarsson, TaraDemeersseman, JonathanVan Biesen, JonasVerhelst, Sebastian
This paper is the first of three papers stemming from a dual fuel Chrysler prototype engine which uses both diesel and gasoline direct injection running at stoichiometric conditions, as part of a project to explore the viability of incorporating an engine platform which utilizes low temperature combustion regimes into a modern automotive application. The combustion system used high rates of EGR while maintaining combustion stability by using high charge motion intake port and a high energy ignition system. The engine ran highly dilute SI combustion at low loads, Diesel Assisted Spark Ignition at medium loads and a transition to Diesel Micro Pilot ignition at medium to high load. This paper explores diesel assisted spark ignited combustion at medium loads 6.5 bar to 12.7 bar BMEP. The second paper will explore the use of diesel micro-pilot ignition at high loads 10.6 bar to 14.5 bar BMEP and the third paper to be published in 2024 will explore fuel property effects (mainly Cetane and
Church, WilliamMcConnell, Steven
This paper is the second of three papers stemming from a dual fuel Chrysler prototype engine which uses both diesel and gasoline direct injection running at near-stoichiometric conditions, as part of a project to explore the viability of incorporating an engine platform which utilizes low temperature combustion regimes into a modern automotive application. The combustion system was designed to tolerate high rates of EGR while maintaining combustion stability by using high charge motion intake port and a high energy ignition system. The engine ran on highly dilute SI combustion at low loads, Diesel Assisted Spark Ignition at medium loads and a transition to Diesel Micro Pilot ignition at medium to high load. The first paper explored the use of Diesel Assisted Spark Ignited at moderate loads 6.5 bar to 12.7 bar BMEP and the third paper to be published in 2024 will explore fuel property effects (mainly Cetane and Octane) through the use of alternative fuels. This paper explores the use of
Church, WilliamMcConnell, Steven
The current transportation fuels have been one of the biggest contributors towards climate change and greenhouse gas emissions. The use of carbon-free fuels has constantly been endorsed through legislations in order to limit the global greenhouse gas emissions. In this regard, ammonia is seen as a potential alternative fuel, because of its carbon-free nature, higher octane number and as hydrogen carrier. Furthermore, many leading maritime companies are doing enormous research and planning projects to utilize ammonia as their future carbon-free fuel by 2050. Flash boiling phenomenon can significantly improve combustion by enhancing the spray breakup process and ammonia possessing low boiling point, has a considerable potential for flash boiling. However, present literature is missing abundant research data on superheated ammonia sprays. Therefore, this research work aims to optically investigate the behavior of ammonia sprays under different conditions of fuel temperatures for varying
Akram, Muhammad SaadYeganeh, MaryamCheng, QiangKaario, OssiLarmi, Martti
The current Indian biofuel policy focuses on the use of alcohol as a potential gasoline blending component to achieve a target of 20% alcohol in gasoline by 2025. The automotive vehicle fuel system uses a variety of metals and non-metals (elastomers and plastics). The fuel system is designed to run with a dedicated fuel, say gasoline or diesel. The use of alternative fuels, i.e., fuels that blend with straight gasoline or diesel, is increasing, and it is critical to understand the impact of these fuels on engine fuel system components. High octane fuels like ethanol and methanol are blended with gasoline to increase engine performance and reduce exhaust emissions, but the alcohols are hygroscopic and corrosive in nature. These fuels' permeation, swelling, and other effects cause changes in material properties. The test fuel is a gasoline-ethanol-methanol (GEM blend of A20 blend), which contains 5% ethanol, 15% methanol, and 80% gasoline. There is no data available on the use of A20 in
Chakradhar, Dr. MayaRamadhas, A SShanti, PrakashJustin, P RajArora, AjayMaheshwari, M
Spark ignition engines have low tailpipe criteria pollutants due to their stoichiometric operation and three-way catalysis and are highly controllable. However, one of their main drawbacks is that the compression ratio is low due to knock, which incurs an efficiency penalty. With a global push towards low-lifecycle-carbon renewable fuels, high-octane alternatives to gasoline such as ethanol are attractive options as fuels for spark ignition engines. Under premixed spark ignition operating conditions, ethanol can enable higher compression ratios than regular-grade gasoline due to its high octane number. The high cooling potential of high-ethanol content gasolines, like E85, or of ethanol-water blends, like hydrous ethanol, can be leveraged to further reduce knock and enable higher compression ratios as well as further downsizing and boosting to reduce frictional and throttling losses. In this work, a split injection strategy is used, where 5-15% of the total injected fuel is injected
Gainey, BrianGandolfo, JohnGao, MingyangLawler, Benjamin
Rapid compression machines can be used to measure a fuel’s ignition delay time and develop an understanding of its resistance to autoignition. Continuing developments in engine design demand higher octane fuels that are resistant to autoignition. Substituted phenols are members of the aromatic hydrocarbon family, and aromatics like toluene are often added to pump-grade gasoline to increase the fuel octane number. Previous numerical and experimental studies have found that substituted phenols included at additive levels in gasoline surrogates, such as the toluene reference fuel in this study, may have a lengthening effect on the ignition delay time of the base fuel they are added to. In this study, the substituted phenols 2,4-xylenol and 3,5-xylenol were added to their own respective toluene reference fuel at 2% by mole, and the ignition delay times of the base fuel mixtures including substituted phenols were compared to the base fuel without additives at engine-relevant conditions for
Trombley, GraceToulson, Elisa
The combustion instability at low loads is one of the key technology risks that needs to be addressed with the development of gasoline compression ignition (GCI) engine. The misfires and partial burns due to combustion instability leads to excessive hydrocarbon (HC) and carbon monoxide (CO) emissions. This study aims to improve the combustion robustness and reduce the emissions at low loads. The GCI engine used in this study has unique hardware features of a spark plug placed adjacent to the centrally mounted gasoline direct injector and a shallow pent roof combustion chamber coupled with a bowl in piston geometry. The engine experiments were performed in a single cylinder GCI engine at 3 bar indicated mean effective pressure (IMEP) and 1500 rpm for certified gasoline with research octane number (RON) = 91. Enabling strategies such as internal exhaust gas recirculation (i-EGR), compression ratio (CR = 16 & 18) and spark assisted ignition were investigated to improve the combustion
Raman, VallinayagamViollet, YoannChang, Junseok
An increasing need to lower greenhouse gas emissions, and so move away from fossil fuels like diesel and gasoline, has greatly increased the interest for methanol. Methanol can be produced from renewable sources and eliminate soot emissions from combustion engines [1]. Since compression ignition (CI) engines are used for the majority of commercial applications, research is intensifying into the use of methanol, as a replacement for diesel fuel, in CI engines. This includes work on dual-fuel set-ups, different fuel blends with methanol, ignition enhancers mixed with methanol, and partially premixed combustion (PPC) strategies with methanol. However, methanol is difficult to ignite, using compression alone, at low load conditions. The problem comes from methanol’s high octane number, low lower heating value and high heat of vaporization, which add up to a lot of heat being needed from the start to combust methanol [2]. This paper investigates methanol combustion at low load and compares
Svensson, MagnusTuner, MartinVerhelst, Sebastian
A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept. Therefore, the main objective of this research is to experimentally characterise the impact of E85 on performance and emissions of a heavy-duty (HD) direct ignition compression ignition (DICI) engine
Novakovic, MajaTuner, MartinGarcia, AntonioVerhelst, Sebastian
In this study, fuel octane number boosters such as toluene, ethanol, methanol, 2-methylfuran (MF), and 2,5-dimethylfuran (DMF) are blended with primary reference fuels (PRFs) in a cooperative fuel research (CFR) engine at research octane number (RON) relevant conditions. In addition to RON determination, engine operation is characterized by measuring (i) cylinder, intake and exhaust pressure, (ii) averaged intake and exhaust temperature, and (iii) air-fuel-ratio. For known fuel blends, the measured RON corresponds well with existing literature. The addition of MF in PRF yields a significant increase in RON and blending octane numbers (indicating booster impact) up to 216. Cylinder pressure fluctuations, the classical definition of knock intensity, are however not consistent, deviating between PRFs and all boosted blends at higher RON values. Moreover, some fuel blends exhibit scarcely any knocking behavior in the test conditions. The differences cannot be explained purely by ignition
Keskinen, KarriBhattacharya, AtmadeepKaario, OssiBlomstedt, OttoRanta, OlliTripathi, RupaliSarjovaara, Teemu
Renewable synthetic fuels offer the opportunity to significantly reduce carbon dioxide (CO2) emissions worldwide if burned in the internal combustion engines of existing and future passenger car fleets. To evaluate this potential, two renewable synthetic gasoline fuels and alcohol blends that can be produced via the methanol-to-gasoline (MtG) synthesis process are evaluated in this study. The first synthetic gasoline, hereafter referred to as MtG, was developed by Chemieanlagenbau Chemnitz GmbH and Technische Universität Bergakademie Freiberg, produced within the closed carbon cycle mobility (C3-Mobility) project, and was blended with 10%(V/V) ethanol (MtG-E10), 20%(V/V) ethanol (MtG-E20), 15%(V/V) methanol (MtG-M15), and 15%(V/V) 2-butanol (MtG-2Bu15). The second synthetic fuel, named POSYN (POrsche SYNthetic fuel), was developed by Porsche. The suitability of the synthetic fuels was experimentally investigated in a spark-ignition (SI) single-cylinder research engine with a
Wouters, ChristianLehrheuer, BastianPischinger, StefanSeifert, PeterRaabe, ToniKolbeck, MichaelRausch, BenjaminMenger, LarsCasal Kulzer, André
The RON(Research Octane Number) is the most important indicator of motor petrol, and the petrol refining process is one of the important links in petrol production. However, RON is often lost during petrol refining and RON Loss means the value of RON lost during petrol refining. The prediction of the RON loss of petrol during the refining process is helpful to the improvement of petrol refining process and the processing of petrol. The traditional RON prediction method relied on physical and chemical properties, and did not fully consider the high nonlinearity and strong coupling relationship of the petrol refining process. There is a lack of data-driven RON loss models. This paper studies the construction of the RON loss model in the petrol refining process. The main innovation is to use frequency statistics to summarize the operating range of data variables and preprocess the dataset, and use the variance selection method to filter out some invalid variables, then use the multi
Zhang, SuminYang, GangLi, ShuaiLi, Wenju
To speed up the development of the next-generation combustion engines with renewable fuels, the importance of reliable and robust simulations cannot be overemphasized. Compared to gasoline, methanol is a promising fuel for spark-ignited engines due to its higher research octane number to resist auto-ignition, higher flame speed for faster combustion and higher heat of vaporization for intake charge cooling. These advantageous properties all contribute to higher thermal efficiency and lower knock tendency, and they need to be well-captured in the simulation environment in order to generate accurate predictions. In this paper, the sub-models which estimate the burning velocities and ignition delay of methanol are revisited. These building blocks are implemented and integrated in a quasi-dimensional simulation environment to predict the combustion behavior, which are subsequently validated against test data measured on both light-duty and heavy-duty engines. The light-duty application is
Pu, Yi-HaoVerhelst, Sebastian
This is the second part of a study on using port water injection to quantifiably enhance the knock performance of fuels. In the United States, the metric used to quantify the anti-knock performance of fuels is Anti Knock Index (AKI), which is the average of Research Octane Number (RON) and Motor Octane Number (MON). Fuels with higher AKI are expected to have better knock mitigating properties, enabling the engine to run closer to Maximum Brake Torque (MBT) spark timing in the knock limited region. The work done in part I of the study related increased knock tolerance due to water injection to increased fuel AKI, thus establishing an ‘effective AKI’ due to water injection. This paper builds upon the work done in part I of the study by repeating a part of the test matrix with Primary Reference Fuels (PRFs), with iso-octane (PRF100) as the reference fuel and lower PRFs used to match its performance with the help of port water injection. Additionally, the unburned gas pressure-temperature
Gopujkar, SiddharthWorm, JeremyBarros, SamBonfochi Vinhaes, ViniciusHansley, William
Aromatics have long been used in pump-grade gasoline to inhibit engine knock and enhance a fuel’s octane number, therefore this study focuses on how the addition of aromatics at 2% by mole affects the ignition characteristics of a Toluene Reference Fuel (TRF). The additives investigated in this study are the substituted phenols p-cresol and 2,6-xylenol. In addition to fuel composition, exhaust gas recirculation dilution can be used to lower the combustion temperature and consequently lengthen the ignition delay time of a given fuel-air mixture. This study replicated exhaust gas recirculation dilution by using N2, as it was inert and did not interfere with reactions between the fuel and oxidizer. Determination of whether the similar structures of p-cresol and 2,6-xylenol result in different autoignition inhibiting characteristics was performed on a rapid compression machine. Each fuel mixture was tested over a range of engine-relevant compressed temperatures, equivalence ratios, and N2
Trombley, GraceWadkar, ChaitanyaDuva, Berk CanToulson, Elisa
The European Commission has released strict emission regulations for passenger cars in the past decade in order to improve air quality in cities and limit harmful emission exposure to humans. In the near future, even stricter regulations containing more realistic/demanding driving scenarios and covering more exhaust gas components are expected to be released. Passenger cars fueled with gasoline are one contributor to unhealthy air conditions, due to the fact that gasoline engines emit harmful air pollutants. One option to minimize harmful emissions would be to utilize specifically tailored, low emission synthetic fuels or fuel blends in internal combustion engines. Methyl formate and dimethyl carbonate are two promising candidates to replace or substitute gasoline, which in previous studies have proven to significantly decrease harmful pollutants. This is especially in regard to particle emissions, while offering beneficial properties for SI combustion, such as high octane rating and
Kraus, ChristophJakubec, PhilippGirhe, SanketFellner, FelixHärtl, MartinJaensch, MalteWachtmeister, GeorgPitsch, Heinz
With the introduction of EV technology into the light-duty vehicle market, the demand for gasoline in conventional spark ignition engines is projected to decline in the coming decades. Therefore, researchers have been investigating the use of gasoline and other light fuels in heavy-duty engine applications. In heavy-duty engines, the combustion mode will likely be non-premixed, mixing-controlled combustion, where the rate of combustion is determined by the fuel-air mixing process. This creates a range of mixture conditions inside the engine cylinder at every instance in time. The goal of this research is to experimentally quantify the sooting behaviors of light fuels under a range of compression ignition engine mixture conditions (i.e., a range of equivalence ratios). Accordingly, an optical rapid compression machine (RCM) was used to compress charges of iso-octane and ethanol to autoignition conditions, which varied between a fuel-air equivalence ratio of 1.6 to 2.3 and 1.9 to 2.5
Kempf, JohnDempsey, AdamAllen, Casey
Knock in gasoline engines at higher loads is a significant constraint on torque and efficiency. The anti-knock property of a fuel is closely related to its research octane number (RON). Ethanol has superior RON compared to gasoline and thus has been commonly used to blend with gasoline in commercial gasolines. However, as the RON of a fuel is constant, it has not been used as needed in a vehicle. To wisely use the RON, an On-Board Separation (OBS) unit that separates commercial gasoline with ethanol content into high-octane fuel with high ethanol fraction and a lower octane remainder has been developed. Then an onboard Octane-on-demand (OOD) concept uses both fuels in varying proportion to provide to the engine a fuel blend with just enough RON to meet the ever changing octane requirement that depends on driving pattern. In this work, the authors assessed the OOD concept on a state-of-art high-efficiency SI engine in three tasks: (1) Comparison of performance characteristics of an up
Chen, YuKasseris, EmmanuelHeywood, JohnHan, DongheeKim, JaeheunLee, KwanheeKang, HyunjinZhou, JinshengMizuno, KazuhikoSeitz, ScottKim, SeongjuMin, SeungbaePeters, NathanSubramanyam, Sai Krishna P.Bunce, Michael
Octane number (ON) and octane sensitivity (S), the fuel anti-knock indices, are critical for the design of advanced jet ignition engines. In this study, ten fuels with different research octane number (RON) and varying S were formulated based on ethanol reference fuels (ERFs) to investigate the effect of S on combustion of jet ignition engine. To fully understand S effects, the combustion characteristics under EGR dilution and lean burn were further investigated. The results indicated that increasing S resulted in higher reactivity with shorter ignition delay and combustion duration. The increase of reactivity led to heavier knocking intensity. The competition between the flame speed and the reactivity of the mixture determined the auto-ignition fraction of mixture and the knocking onset crank angle as S varied. Medium S (S=3) was helpful to improve the combustion speed, reduce the auto-ignition fraction of mixture and retard the knocking onset crank angle. For high RON (RON=100) and
Zhao, ZiqingCai, KaiyuanWang, WeiLi, Yanfei
Ethanol and gasoline are widely used with fuels in Otto cycle engines. These fuels have different heating power and octane number and the engine behaves differently depending on the type of fuel used. The objective of this study is to measure, compare and investigate the factors that affect the block vibration of an internal combustion engine as a function of the fuel used ethanol or gasoline. The experiment consisted of instrumenting the side of the engine block with an accelerometer to measure the level of vibration intensity of the engine running on a bench dynamometer varying engine speed and load conditions. The results showed that the engine vibration level increases with the increase in engine speed and load. The highest level of vibration was achieved in the region of maximum torque and maximum pressure combustion. The combustion process is mainly responsible for the highest level of vibration achieved with ethanol. In all operating conditions the vibration level of the engine
Santana, Claudio MarcioBarros, Jose Eduardo Mautonede Almeida Junior, Helder Alves
This is the second part of a two-phase study revolving around the determination of fuel K-factor for different fuels in a 2.0L, 4-cylinder, direct-injected, turbocharged spark-ignition (SI) engine for different engine speeds and loads. Prior studies relating to K-factor claim that K depends only on the engine’s combustion system and operating condition, but Phase 1 of this study detected contrary results. Experimental determination of K at multiple test points showed the K value was different for the Environmental Protection Agency (EPA) certification Tier 2 and Tier 3 regular fuels. That study also found strong correlations of the K value with macroscopic parameters (e.g., speed, load, and combustion phasing) and end gas conditions, irrespective of the fuel. This second phase of the study showed that the effect of variation in day-to-day conditions on the K-factor is negligible and that K-factor stays the same with changes in intake air temperature (IAT) for a specific speed-load
Gopujkar, Siddharth B.Worm, JeremyDavis, Richard S.
Auto-ignition quality is one of the most important properties in gasoline. Auto-ignition quality is today described by the Motor Octane Number (MON) and the Research Octane Number (RON). For modern, light duty, gasoline engines it has been quite well established that RON is the most accurate number. However, no study has been performed on hand held forest and garden products, such as chainsaws. Is the auto-ignition quality best described in the same way for these engines as for light duty engines? In this paper, a matrix of six different fuels with different combinations of MON and RON values were tested on a Husqvarna 550 XP Mark II, a modern air cooled, sequential stratified scavenging 2-stroke chainsaw engine. Ignition timing sweeps were performed and knock limited spark advance (KLSA) were calculated. Then the data has been analyzed with a multi-variate analysis of KLSA against both MON and RON to try to determine how MON and RON should be combined to best describe the anti-knock
Risberg, PerElm, ThomasBergman, MikaelHellquist, FredrikKarvo, AnnaTripathi, Rupali
In order to maximize the efficiency of light-duty gasoline engines, the Co-Optimization of Fuels and Engines (Co-Optima) initiative from the U.S. Department of Energy is investigating multi-mode combustion strategies. Multi-mode combustion can be describe as using conventional spark-ignited combustion at high loads, and at the part-load operating conditions, various advanced compression ignition (ACI) strategies are being investigated to increase efficiency. Of particular interest to the Co-Optima initiative is the extent to which optimal fuel properties and compositions can enable higher efficiency ACI combustion over larger portions of the operating map. Extending the speed-load range of these ACI modes can enable greater part-load efficiency improvements for multi-mode combustion strategies. In this manuscript, we investigate fuel effects for six different fuels, including four with a research octane number (RON) of 98 and differing fuel chemistries, iso-octane, and a market
Powell, TommySzybist, James
Prior research studies have investigated a wide variety of gasoline compression ignition (GCI) injection strategies and the resulting fuel stratification levels to maintain control over the combustion phasing, duration, and heat release rate. Previous GCI research at the US Department of Energy’s Oak Ridge National Laboratory has shown that for a combustion mode with a low degree of fuel stratification, called “partial fuel stratification” (PFS), gasoline range fuels with anti-knock index values in the range of regular-grade gasoline (~87 anti-knock index or higher) provides very little controllability over the timing of combustion without significant boost pressures. On the contrary, heavy fuel stratification (HFS) provides control over combustion phasing but has challenges achieving low temperature combustion operation, which has the benefits of low NOX and soot emissions, because of the air handling burdens associated with the required high exhaust gas recirculation rates. This work
Curran, ScottSzybist, JamesKaul, BrianEaster, JordanSluder, Scott
The increasing demand for high-octane fuels is pushing the combustion research towards investigating new potential fuels and octane boosters. In addition to their high-octane, those additives should be environmentally friendly. In this study, the anti-knock properties of Dicyclopentadiene (DCPD) as an additive to primary reference fuels (PRF) and toluene primary reference fuels (TPRF) have been investigated. The Research octane number (RON) and Motor octane number (MON) were measured using Cooperative Fuels Research (CFR) engine for four different fuel blends; PRF 60 + 10% DCPD, PRF 60 + 20% DCPD, PRF 70 + 10% DCPD and TPRF 70 + 10% DCPD. In addition, homogenous charge compression ignition (HCCI) was also performed using the CFR engine to show the effect of DCPD on suppressing low temperature chemistry of reference fuels. Moreover, the ignition delay times of these mixtures were measured in the rapid compression machine (RCM) at 20 bar and stoichiometric mixtures over a temperature
Al-Khodaier, Mohannad
Autoignition delay times of two full blend gasoline fuels (high and low RON) were explored in a rapid compression machine. CO2 dilution by mass was introduced at 0%, 15%, and 30% levels with the O2:N2 mole ratio fixed at 1:3.76. This dilution strategy is used to represent exhaust gas recirculation (EGR) substitution in spark ignition (SI) engines by using CO2 as a surrogate for major EGR constituents(N2, CO2, H2O). Experiments were conducted over the temperature range of 650K-900K and at 10 bar and 20 bar compressed pressure conditions for equivalence ratios of (Φ =) 0.6-1.3. The full blend fuels were admitted directly into the combustion chamber for mixture preparation using the direct test chamber (DTC) approach. CO2 addition retarded the autoignition times for the fuels studied here. The retarding effect of the CO2 dilution was more pronounced in the NTC region when compared to the lower and higher temperature range. The effect of dilution was more pronounced for the higher RON fuel
Chinnathambi, PrasannaWadkar, ChaitanyaGudiyella, SoumyaEstefanous, FadiToulson, Elisa
Ethanol is regarded as a potential alternative fuel for combustion engine as it provides lower exhaust emissions, higher efficiency and higher octane rating. However, the solubility of ethanol in oil can effect lubricant quality. The impact of ethanol-blend gasoline on lubricants is a matter of concern that must be addressed. With this in mind, the current study investigates the effect of blending ethanol with gasoline on the oil layer adsorption/desorption mechanism. The blends used for the study are E0, E5, E10, and E15. The study is carried out with the help of a mathematical model that predicts the fuel adsorbed/desorbed in the oil layer of an engine. The mathematical model predictions are compared to experimental results obtained on a single-cylinder gasoline engine. Fuel adsorbed in the oil layer ranges from 0.46% for E0 fuel to 0.35% for E15 fuel. Similarly, the desorbed fuel ranges from 0.45% to 0.29% as the ethanol fraction increases from 0% to 15%. Despite the fact that the
Kushwaha, GarimaSaraswati, SamirPaul PhD, Bireswar
Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano). In this work, the aromatic module of the combined model for PAHs chemistry is discussed, which was revised and updated to improve predictive capabilities in
Pratali Maffei, LunaPelucchi, MatteoFaravelli, TizianoPitsch, HeinzMao, QianNobili, Andrea
The development of highly boosted and high compression spark-ignition engines with enhanced thermal efficiencies is primarily limited by knock and super-knock. Super-knock is an excessively high intensity knock which has been related to a developing detonation process. This study investigates the knocking tendency of different gasoline surrogate fuels with varying research octane numbers (RON), octane sensitivity (S) and composition. The ξ/ɛ diagram with an enclosed detonation peninsula is used to assess the knocking tendency of different fuels. The diagram plots ξ, the ratio of acoustic to auto-ignitive velocity, against ɛ, the ratio of the transit time of an acoustic wave through a hot spot, to the heat release time (τe). Constant volume simulations of auto-ignition delay times (τi) and excitation times (τe) obtained from chemical kinetic calculations, enable calculations of ξ and ɛ. Their location for different fuels and operating conditions on the ξ/ɛ diagram, relative to the
Gorbatenko, InnaSingh, EshanSarathy, ManiNicolle, Andre
Over the years, spark-ignition engine operation has changed significantly, driven by many factors including changes in operating conditions. The variation in operating conditions impacts the state of the end-gas, and therefore, its auto-ignition. This can be quantified in terms of K-factor, which weighs the relative contribution of Research Octane Number (RON) and Motor Octane Number (MON) to knocking tendency at any operating condition. The current study investigates the fuel requirements when operating an engine at increasing intake air pressures. A model engine was operated at varying intake air pressure in GT-Power software, from naturally aspirated intake air to heavily boosted intake air pressure of 4 bar absolute. The pressure-temperature information from the GT-Power model was used to calculate ignition delay times of the unburnt end-gas composed of a sensitive and a non-sensitive fuel in ChemKin software. The results show that high octane sensitivity is desired at negative K
Singh, EshanMohammed, AbdulrahmanGorbatenko, InnaSarathy, Mani
Anti-knock index (AKI) is a metric that can be used to quantify the anti-knock performance of a fuel and is the metric used in the United States. AKI is the average of Research Octane Number (RON) and Motor Octane Number (MON), which are calculated for every fuel on a Cooperative Fuel Research (CFR) engine under controlled conditions according to ASTM test procedures. Fuels with higher AKI have better knock mitigating properties and can be run with a combustion phasing closer to MBT in the knock limited operating region of a gasoline engine. However, fuels with higher AKI tend to be costlier and less environmentally friendly to produce. As an alternative, the anti-knock characteristics of lower AKI fuels can be improved with water injection. In this sense, the water injection increases the ‘effective AKI’ of the fuel. The injected water absorbs heat, which lowers the in-cylinder temperatures and mitigates knock, which permits advancing the knock limited CA50 (KLCA50) and reducing fuel
Gopujkar, SiddharthWorm, JeremyBarros, SamChristensen, Cord
With the implementation of the China VI gasoline standards, the use of ethanol is expanding and is intended to further reduce vehicle criteria gaseous and particulate emissions. However, due to the constraints of biomass ethanol production, petroleum derived Methyl tert-Butyl Ether (MTBE) is being used in addition to ethanol to improve fuel octane and maintain oxygen content. The impact of these mixed oxygenates on vehicle emissions are studied in this paper. The correlation of fuel characteristics to vehicle particulate emissions and their predictive indices has been investigated. The results from this study suggest some alternatives to existing fuel indices due to oxygenate contribution. Additionally, this paper studies, the emissions of three direct-injection turbocharged vehicle models focusing on particulate emissions from the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The test fuels were China VIb gasoline, blended with different ratios of ethanol and MTBE. The
Tian, HuanyuHan, LuGuo, XinGeng, PatSun, WenZhang, SusanZhou, HaitaoKong, XiaoshuangZhang, Ni
Expanding upon the authors’ previous work which utilized a GT-Power model of the Cooperative Fuels Research (CFR) engine under Research Octane Number (RON) conditions, this work defines the boundary conditions of the CFR engine under Motored Octane Number (MON) test conditions. The GT-Power model was validated against experimental CFR engine data for primary reference fuel (PRF) blends between 60 and 100 under standard MON conditions, defining the full range of interest of MON for gasoline-type fuels. The CFR engine model utilizes a predictive turbulent flame propagation sub-model, and a chemical kinetic solver for the end-gas chemistry. The validation was performed simultaneously for thermodynamic and chemical kinetic parameters to match in-cylinder pressure conditions, burn rate, and knock point prediction with experimental data, requiring only minor modifications to the flame propagation model from previous model iterations. A recently published chemical kinetic mechanism was
Reddy Vallapureddy, AnveshZhuang, HaochuanLi, JiaqiDelVescovo, DanKolodziej, Christopher P.Hoth, Alexander
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