Browse Topic: Fuel additives

Items (593)
Aluminum oxide (Al₂O₃) nanoparticles are considered a promising fuel additive to enhance combustion efficiency, reduce emissions, and improve fuel economy. This study investigates the spray characteristics of diesel fuel blended with aluminum oxide nanoparticles in a constant volume chamber. The blends were prepared by dispersing Al₂O₃ nanoparticles in diesel at varying concentrations (25, 50, and 100 mg of aluminum oxide nanoparticles into 1 L of pure diesel, respectively) using a magnetic stirrer and ultrasonication to ensure stable suspensions. Spray characterization was conducted in a high-pressure and high-temperature constant volume chamber, simulating actual engine conditions. The ambient temperatures for this experiment were set from 800 to 1200 K, and the oxygen concentrations were set from 21% to 13%. The study focused on key spray parameters such as spray penetration length, spray angle, and spray area, analyzed using high-speed imaging and laser diffraction techniques
Ji, HuangchangZhao, Zhiyu
Dimethyl ether (DME) is widely regarded as a suitable energy source for compression ignition power systems because of its high reactivity. It has been widely reported that DME possesses a significantly low propensity to form soot, hindering the innate NOx-soot trade-off encountered with diesel fuel operation. Beyond the fuel-borne oxygen content of DME, its unique physical properties present a contrasting combustion behavior which may be advantageous to direct injection systems, especially concerning the mixing-controlled combustion mode. This work aims to detail the energy conversion efficacy of DME through heat release characterization and exhaust emission speciation. The tests were controlled within a single-cylinder research engine with an off-board high-pressure injection system to handle liquified DME up to 1000bar. To mitigate interference in fuel additives over the combustion behavior, the high-pressure fuel system specifically managed neat DME. The in-cylinder pressure was the
Leblanc, SimonCong, BinghaoLeach, JaceYu, XiaoReader, GrahamZheng, Ming
A numerical investigation has been performed in the current work on reactivity-controlled compression ignition (RCCI), a low-temperature combustion (LTC) strategy that is beneficial for achieving lower oxides of nitrogen (NOx) and soot emission. A light-duty diesel engine was modified to run in RCCI mode. Experimental data were acquired using diesel as HRF (high-reactivity fuel) and gasoline as LRF (low reactivity fuel) to check the accuracy and fidelity of predicted results. Blends of ethanol and gasoline with DTBP (di-tert-butyl peroxide) addition in a small fraction on an energy basis were used in numerical simulations to promote ignitability and reactivity enhancement of PFI charge. Achieving stable, smooth, and gradual combustion in RCCI is challenging at low loads, especially in light-duty engines, due to misfiring and poor combustion stability. DTBP is known for enhancing cetane number and accelerating combustion, and it is mixed in a PFI blend to avoid combustion deterioration
Tripathi, SaurabhKrishnasamy, Anand
Global warming has intensified environmental challenges such as more intense heat waves due to the accumulation of greenhouse gases, primarily carbon dioxide (CO2), which is heavily produced in power generation and transportation sectors, traps heat and raises the Earth’s temperature. Significant measures must be taken to reduce its production and impact on our environment. Hydrogen (H2) enrichment is a promising technology that enables higher thermal efficiencies and lower exhaust emissions. However, various parameters need to be optimized for internal combustion engines (ICE), which increases experimental and computational costs. The main goal of this work is to offer a reliable correlation that can be used as an input parameter for turbulent combustion models to enhance predictions and lower the cost of running simulations. Thus, the laminar burning velocity (LBV) of binary fuel mixtures is investigated numerically over a wide range of initial conditions (300–600 K and 1–11 atm) and
Almansour, Bader
The aim of this work was to investigate the influence of different combinations of engine oil and oil additive as well as additivated and unadditivated fuel on particulate emissions in gasoline engines. To accomplish this, load, speed, and type of oil injection were varied on a single-cylinder engine, and the influence on particle number concentration and size distribution were evaluated. The tests were supplemented by an optical investigation of their in-cylinder soot formation. The investigation of fuel additives showed no significant differences compared to the reference fuel without additives. However, in the case of oil additives, detergents led to a significant increase in the number of particles in the <20 nm range. This effect occurred when used as both a single additive and a component in the standard engine oil. While viscosity improvers also lead to a measurable, but less pronounced, increase in the particle number concentration, no significant influence can be determined
Böhmeke, ChristianHeinz, LukasWagner, UweKoch, Thomas
The present work deals with the effects of nano-additives on ternary blend biodiesel fuel added in diesel engine. The ternary blend comprises of mustard oil biodiesel and rice bran oil biodiesel, synthesized by means of transesterification and diesel. Nano-additives used in the current study include carbon nanotubes (CNT) and MgO/MgAl2O4 spinel, which were added in a suitable concentration to the biodiesel. CNTs were procured from the market and MgO/MgAl2O4 spinel was prepared by co-precipitation via ball milling process. The nano-additives were characterized by means of FTIR (Fourier transform infrared spectroscopy), AFM (atomic force microscopy), and DSC (differential scanning calorimetry) analysis. Biodiesel blend samples were prepared such as B20 (20% biodiesel + 80% diesel), B20 + CNT (1000 PPM), B20+MgO/MgAl2O4 spinel (1000 PPM), and B20+CNT+MgO/MgAl2O4 spinel (1000 PPM) were tested against diesel fuel. The maximum increase in brake thermal efficiency (BTE), oxides of nitrogen
Jeyakumar, NagarajanDhinesh, BalasubramanianPapla Venugopal, Inbanaathan
Ammonia has attracted the attention of a growing number of researchers in recent years. However, some properties of ammonia (e.g., low laminar burning velocity, high ignition energy, etc.) inhibit its direct application in engines. Several routes have been proposed to overcome these problems, such as oxygen enrichment, partial fuel cracking strategy and co-combustion with more reactive fuels. Improving the reactivity of ammonia from the oxidizer side is also practical. Ozone is a highly reactive oxidizer which can be easily and rapidly generated through electrical plasma and is an effective promoter applicable for a variety of fuels. The dissociation reaction of ozone increases the concentration of reactive radicals and promotes chain-propagating reactions. Thus, obtaining accurate rate constants of reactions related to ozone is necessary, especially at elevated to high pressure range which is closer to engine-relevant conditions. In present work, rate constants of ozone dissociation
Zhang, ZhenyingnanLi, AngLi, ZhuohangZhu, LeiHuang, Zhen
The European Union’s pro-ecological policy imposes a requirement to use biofuel additives in diesel fuel which is supposed to support the sustainable development of transport and limit its negative impact on the natural environment. The study presents an analysis of the exhaust gas components and the amount of solid particles carried out for internal combustion engines fueled with mixtures of diesel fuel and fatty acid methyl esters. Additionally, the computer software of the tested power units was modified by changing the amount of fuel to be supplied and the air intake. The goal of the tests was to find out how the fuel mixture and reprogramming of the computer control systems would impact the emission of exhaust gas components. Based on the tests, it was found that an additive of fatty acid methyl esters to diesel does have an influence on the tested unit parameters. The highest values were found for a mixture containing 90% diesel fuel and 10% fatty acid methyl esters, whereas the
Markiewicz, MariettaMuślewski, ŁukaszPająk, Michał
In transportation sector, higher engine thermal efficiency is currently required to solve the energy crisis and environmental problems. In spark ignition (SI) engine, lean-burn strategy is the promising approach to improve thermal efficiency and lower emissions. Olefins are the attractive component for gasoline additives, because they are more reactive and have advantage in lean limit extension. However, owing to lower research octane number (RON), it is expected to exhibit the drawback to reducing the anti-knock performance. The experiments were performed using a single-cylinder engine for 6 fuel types including gasoline blends which have difference in RON varying between 90.4 and 100.2. The results showed that adding olefin content to the premium gasoline provided unfavorable effect on auto-ignition as the auto-ignition happened at unburned gas temperature of 808 K which was 52 K lower at excess air of 2.0. Thus, it reduced anti-knock performance. Additional oxygenated fuels such as
Shinabuth, DittapoomOhmori, YuyaKitajima, KatsukiOno, TomoyaSakaida,, SatoshiSakai, YasuyukiKonno, MitsuruTanaka, Kotaro
Diesel engines operated at high altitudes would experience performance degradation due to the fuel-air amount mismatch, resulting in combustion deterioration. Technologies that supplement oxygen concentration, such as intake oxygen enrichment, turbocharging and the addition of oxygenated fuel additives, can help restore performance at high altitudes, but each has its own limitations Operating diesel engines at high altitudes still generates extremely lean fuel-air mixtures, making the improved utilization of excess air the most economically efficient approach to optimize engine performance under such conditions. The objective of this paper is to investigate the effects of injector nozzle-hole numbers on diesel engines operated at high altitudes, a topic that has been limitedly discussed in existing literature, with the aim of enhancing understanding regarding the potential of this cost-effective approach and aiding in the design of a cooperative approach between oxygen concentration
Zhao, JunliangYang, RuomiaoYan, YuchaoOu, JuanLiu, ZhentaoLiu, Jinlong
The worldwide adoption of renewable energy mandates, together with the widespread utilization of biofuels has created a sharp increase in the production of biodiesel (fatty acid alkyl esters). As a consequence, the production of glycerol, the main by-product of the transesterification of fatty acids, has increased accordingly, which has led to an oversupply of that compound on the markets. Therefore, in order to increase the sustainability of the biodiesel industry, alternative uses for glycerol need to be explored and the production of fuel additives is a good example of the so-called glycerol valorization. The goal of this study is therefore to evaluate the suitability of a number of glycerol-derived compounds as diesel fuel additives. Moreover, this work concerns the assessment of low-concentration blends of those glycerol derivatives with diesel fuel, which are more likely to conform to the existing fuel standards and be used in unmodified engines. The various blends described in
Olson, André L.Alemahdi, NikaTunér, MartinVerhelst, Sebastian
In the rapidly changing scenario of the energy transition, data-driven tools for kinetic mechanism development and testing can greatly support the evaluation of the combustion properties of new potential e-fuels. Despite the effectiveness of kinetic mechanism generation and optimization procedures and the increased availability of experimental data, integrated methodologies combining data analysis, kinetic simulations, chemical lumping, and kinetic mechanism optimization are still lacking. This paper presents an integrated workflow that combines recently developed automated tools for kinetic mechanism development and testing, from data collection to kinetic model reduction and optimization. The proposed methodology is applied to build a consistent, efficient, and well-performing kinetic mechanism for the combustion of oxymethylene ethers (OMEs), which are promising synthetic e-fuels for transportation. In fact, OMEs are easily mixed with conventional fuels and share similar ignition
Dinelli, TimoteoPratali Maffei, LunaPegurri, AlessandroPuri, AmedeoStagni, AlessandroFaravelli, Tiziano
The use of straight vegetable oil in diesel engines leads to undesirable consequences due to the peculiar physicochemical properties of vegetable oils. In this regard, the use of pure and unmodified vegetable oils requires their obligatory dilution with petroleum fuels, usually diesel fuel. However, blends of diesel fuel with vegetable oil have a significantly higher density and viscosity than pure diesel fuels. Therefore, in this article, it was proposed to use blends of vegetable oil with aviation kerosene since kerosene has lower density and viscosity compared to diesel fuel. In addition, kerosene is less prone to coking of injectors, has a higher calorific value, and has a lighter hydrocarbon composition, which makes starting the engine easier. Within the framework of the study, engine tests of a full-size four-cylinder diesel engine, MMZ D-245.12.C, were carried out at maximum load in the range of crankshaft speeds from minimum (1000 min−1) to nominal (2400 min−1). Various blends
Cherepanova, AnnaUkhanov, DenisSavel’ev, EvgeniySapunov, Valentin
A reliable toolchain for the validation and evaluation of numerical spray break-up simulation for the potentially carbon-neutral fuels polyoxymethylene dimethylether (POMDME, or short OME) is developed and presented. The numerical investigation is based on three-dimensional computational fluid dynamics (3D-CFD) with the commercial code STAR-CD v2019.1 using a Reynolds-averaged Navier-Stokes (RANS) equations approach. Fuel properties of the representatives OME1 and OME3 are implemented into the software and with that the fuels are investigated numerically. For validation purposes, optical experimental results in a heated spray chamber with inert nitrogen-pressurized atmosphere are presented. The measurement data are based on Mie scattering of the liquid phase and Schlieren imaging of the vapor phase. Solely experimental results are shown for OME1b and OME3–6 to assess if the knowledge from the numerical modeling with OME1 and OME3 can also be transferred to the corresponding
Gaukel, KaiPélerin, DominikDworschak, PatrickHärtl, MartinJaensch, Malte
Thermal control coatings, i.e. coatings with different visible versus infrared emission, have been used by NASA on the Orbiter and Hubble Telescope to reflect sunlight, while allowing heat rejection via infrared emission. However, these coatings absorb at least 6 percent of the Sun’s irradiant power, limiting the minimum temperature that can be reached to about 200 K. NASA needs better solar reflectors to keep cryogenic fuel and oxidizers cold enough to be maintained passively in deep space for future missions.
This SAE Recommended Practice presents recommendations for test fuels and fluids that can be used to simulate real world fuels. The use of standardized test fluids is required in order to limit the variability found in commercial fuels and fluids. Commercial fuels can vary substantially between manufacturers, batches, seasons, and geographic location. Further, standardized test fluids are universally available and will promote consistent test results for materials testing. Therefore, this document: a Explains commercial automotive fuel components b Defines standardized components of materials test fluids c Defines a nomenclature for test fluids d Describes handling and usage of test fuels e Recommends fluids for testing fuel system materials The test fluid compositions specified in Section 7 of this document are recommended solely for evaluating materials. They are not intended for other activities, such as engine development, design verification, or process validation unless agreed
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Despite recent advances towards powertrain electrification as a solution to mitigate pollutant emissions from road transport, synthetic fuels (especially e- fuels) still have a major role to play in applications where electrification will not be viable in short-medium term. Among e-fuels, oxymethylene ethers are getting serious interest within the scientific community and industry. Dimethoxy methane (OME1) is the smaller molecule among this group, which is of special interest due to its low soot formation. However, its application is still limited mainly due to its low lower heating value. In contrast, other fuel alternatives like hydrogenated vegetable oil (HVO) are considered as drop-in solutions thanks to their very similar properties and molecular composition to that of fossil diesel. However, their pollutant emission improvement is limited. This work proposes the combination of OME1 and HVO as an alternative to fossil diesel, to achieve noticeable soot emission reductions while
Garcia-Oliver, Jose MNovella, RicardoLopez Pintor, DarioMicó, CarlosBin-Khalid, Usama
Lean combustion is an approach to achieving higher thermal efficiency for spark ignition engines. However, it faces low burning velocity and unstable combustion problems near the lean flammability limits region. The current work is attempting to investigate the combustion characteristics of iso-octane flame with 0% and 30% H2 up to near lean limits (λ = 1.7) at 100-300 kPa and 393-453 K. The flame appeared spherically by 37 mJ spark energy at λ = 0.8-1.2, whereas the ultra-lean mixtures, λ ≥ 1.3, ignited at 3000 mJ under wrinkles and buoyancy effects. The impact of initial pressure and temperature on the lean mixture was stronger than the stoichiometric mixture regarding flame radius and diffusional-thermal instability. The buoyancy appeared at the highest burning velocity of 27.41 cm/s. The buoyancy region extended from λ = 1.5 to λ = 1.3 at 393 K, λ = 1.6 to λ= 1.4 at 423 K and λ = 1.7 to λ = 1.5 at 453 K with an increase in initial pressure (higher pressure, more λ under buoyancy
Akram, M. ZuhaibAziz, MuhammadMa, FanhuaDeng, YangboAkram, M. WaqarAkhtar, Ali
This SAE Aerospace Information Report (AIR) provides general information on the developing subject of synthetic jet fuels derived from non-petroleum feed stocks. It addresses synthetic jet fuel properties and other topics associated with their use and is intended as a guide to assist aviation fuel system designers in considering important information on fuel properties when designing aircraft fuel systems and components. The AIR is limited to “drop-in” fuels that meet the requirements of the respective fuel specifications and are compatible with typical aircraft and ground refueling systems. While some key properties are included in this AIR for discussion, the reader should utilize documents such as MIL-HDBK-510 or the ASTM International research reports for a more-detailed review of fuel properties. AIR7484 also gives more details on fuel properties, specifically as they relate to airframe fuel system design.
AE-5A Aerospace Fuel, Inerting and Lubrication Sys Committee
Butanol is a potential alternative fuel for diesel in compression ignition (CI) engines. Many of the physico-chemical properties of butanol such as low carbon-to-hydrogen (C/H) ratio compared to diesel, higher heating value, lower heat of vaporization and suitable density-viscosity values compared to ethanol and methanol makes it suitable as an alternative fuel. However, poor cetane number and miscibility are the limitations associated with butanol. The use of fuel additives as ignition improver could be beneficial in overcoming the issues associated with alcohols. In this work, an experimental investigation in a twin-cylinder CI engine was carried out to assess the effect of doped cetane improving additives (Diethyl ether (DEE), Diglyme (DEGME) and Ethyl diglyme (DEGEE)) for diesel-butanol blend (B15). Cylinder pressure trace, heat release rate (HRR), location of maximum in-cylinder pressure (Pmax) and maximum rate of heat release (HRRmax), engine performance (brake thermal efficiency
Sahu, Tomesh KumarShukla, Pravesh Chandra
Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines. As shown in the data, there are more than just one risk with these fuels in
Chapman, ElanaGeng, PatKonzack, AnkeHeppes, StefanWerner, Sabine
Gasoline Direct Injection (GDI) fuel injectors are fouled when carbon deposits build-up on the injector tip, impeding fuel droplet atomization and dispersion. These issues, if left untreated, can lead to losses in engine power and fuel economy, as well as increased emissions of particulate matter (PM). Bottled aftermarket gasoline detergents are commonly used to remove deposits and restore injector performance. A performance analysis of three classes of bottled gasoline additives was performed, focusing on products that do not contain nitrogen-based detergents; products containing nitrogen-based detergents; and a new class of gasoline detergent formulations designed specifically for GDI injector fouling. Analyses completed included additive chemical analysis to confirm the presence of nitrogen-based gasoline detergents in the bottled product; engine testing to establish injector clean-up performance quantified through injected fuel spray volume as well as visual inspection of reduced
Kuo, Chung-HaoSmocha, RuthLoeper, PaulMukkada, NicholasSimpson Green, Felicia
Engine design and selection of fuels for automotive applications are required to minimize noise and exhaust emissions without compromising fuel economy. The knocking combustion investigation is essential as it directly affects the performance and durability as well as the thermal efficiency of the engine. Several fuel additives were suggested in the previous studies to mitigate the knocking combustion in spark ignition (SI) engines. The present study reviews the effect of antiknock fuel additives such as ethanol, methanol, prenol, n-butanol, furan mixtures, etc., on knocking behavior in SI engines. Additionally, this paper aims to present a systematic review of the studies conducted to investigate the effect of EGR on the knocking in SI engines. The EGR is often considered an effective means to suppress knocking in SI engines. The thermal effect of EGR in controlling the knocking is well known as EGR affects the temperature and pressure history of the combustion chamber. The main
Gupta, PrashantSaxena, Mohit RajMaurya, Rakesh Kumar
Exhaust Gas Recirculation (EGR) is employed in diesel engines to reduce engine-out NOx emissions. Despite the concerted design efforts of manufacturers, high-pressure Exhaust Gas Recirculation (HP-EGR) systems can be susceptible to fouling as the particulate matter, hydrocarbons and other entrained species deposit from the exhaust gas flow as it cools on its passage through the EGR system. Such deposits can lead to a number of problems including deterioration of emissions, fuel efficiency, performance and drivability, as well as breakdowns. The development of an engine test method to enable the study of the impact of fuel on deposits in the HP-EGR system was reported in 2020. In the test, a 4-cylinder light-duty diesel engine of 1.6L displacement runs at conditions conducive to EGR deposit formation over 24 hours and the impact of fuels on deposit formation is determined through weighing of the EGR system components before and after the test. This paper describes the application of the
Williams, RodBera, TusharCook, StephenForster, MichaelReid, JacquelineRimmer, JohnRoss, AlanBroom, NigelLucas, Stephanie
Aromatics have long been used in pump-grade gasoline to inhibit engine knock and enhance a fuel’s octane number, therefore this study focuses on how the addition of aromatics at 2% by mole affects the ignition characteristics of a Toluene Reference Fuel (TRF). The additives investigated in this study are the substituted phenols p-cresol and 2,6-xylenol. In addition to fuel composition, exhaust gas recirculation dilution can be used to lower the combustion temperature and consequently lengthen the ignition delay time of a given fuel-air mixture. This study replicated exhaust gas recirculation dilution by using N2, as it was inert and did not interfere with reactions between the fuel and oxidizer. Determination of whether the similar structures of p-cresol and 2,6-xylenol result in different autoignition inhibiting characteristics was performed on a rapid compression machine. Each fuel mixture was tested over a range of engine-relevant compressed temperatures, equivalence ratios, and N2
Trombley, GraceWadkar, ChaitanyaDuva, Berk CanToulson, Elisa
This study presents the developmental work of two reduced kinetic models, namely, methyl-cyclo-hexane (MCH) and pentanol. MCH is the representative of the cyclo-alkane component for diesel. Pentanol is used as a fuel additive to aid in emission reduction. The final 86-species MCH model and the final 55-species pentanol model are about 90% smaller than their respective detailed counterparts. Upon extensive validation exercises in zero-dimensional (0-D) kinetic simulations, the MCH model was integrated with the formerly derived models for linear (n-hexadecane) and branched (2,2,4,4,6,8,8-heptamethylnonane) alkanes to form a 144-species kinetic model, namely, D_144. The “reduced-prior-to-combination” approach was adopted in merging the fuel constituents. The D_144 model can be used as a surrogate model for diesel in numerical computational fluid dynamics (CFD) modelling. Successively, a 162-species model for diesel and alcohol mixtures, namely, DA_162, was formulated by integrating the
Tan, JohninNg, Chun JianSaw, Lip HuatPoon, Hiew Mun
The U.S. Environmental Protection Agency (EPA) certifies gasoline deposit control additives for intake valve deposit (IVD) control utilizing ASTM D5500, a vehicle test using a1985 BMW 318i. Concerns with the age of the test fleet, its relevance in the market today, and the availability of replacement parts led the American Chemistry Council’s (ACC) Fuel Additive Task Group (FATG) to begin a program to develop a replacement. General Motors suggested using a 2.4L LE9 test engine mounted on a dynamometer and committed to support the engine until 2030. Southwest Research Institute (SwRI®) was contracted to run the development program in four Phases. In Phase I, the engine test stand was configured, and a test fuel selected. In Phase II, a series of tests were run to identify a cycle that would build an acceptable level of deposits on un-additized fuel. In Phase III, the resultant test cycle was examined for repeatability. In Phases IVa and IVb, two discrimination matrices evaluated the
Shoffner, BrentCloud, BrandonKulinowski, AlexanderHayden, ThomasStevens, Colleen
Global warming due to exhaust emissions, rapid depletion of crude oil, and strict carbon control legislation has forced researchers to search biofuels as substitute for petroleum diesel fuels. Biodiesel is a renewable and oxygenated fuel. It is free from sulfur, non-toxic and a biodegradable. The different non-edible vegetable oils such as Algae, Karanja and Jatropha could be used to produce biodiesel. Biodiesel is a green fuel with an exception that it emits 15-20% more NOx as compared to diesel fuel. The emissions of nanoparticles are more hazardous to human health. The nanoparticles emission of biodiesel must be measured according to the new strict regulations. The engine performance and the lower emission characteristics, except for NOx emission, for Algae, Karanja and Jatropha oil biodiesels are similar to those of diesel fuel. Present study has investigated the performance, combustion and emissions, including nanoparticle emissions, for Algae, Karanja and Jatropha oil biodiesel
Pandey, AnandNandgaonkar, MilankumarLaad, MeenaKotecha, Ketansambasivan, Sureshsonawane, CKumbhar, Vishal
The transport of fuel-borne additives into the engine oil is a critical factor for the efficacy with which the additive functionality can be imparted on the engine. This paper describes the combination of Laser Induced Fluorescence (LIF) and Liquid Chromatography (LC) to determine the real-time additive concentrations and transfer ratios in a spark-ignition, 2-liter GM LHU engine. The current research used a continuous sample circuit from the engine sump which passed through an integrating cavity flow cell to enhance the LIF signal. In the absence of a fluorescence signature of any of the native additive species, a suitable fluorescing dye was selected to simulate the additive. After establishing rigorous calibration curves, LC was employed as a referee method to do a direct comparison with the LIF determined dye concentrations. The impact of the oil age and fuel dilution on the dye LIF signal was aggregated to a scaling factor which was a function of the relative absorption (RA) of
Swarts, AndreWallace, JulianMoore, ThomasFavela, KristinXu, YiWang, Chengrong
Sustainable fuels can help to decrease carbon dioxide emissions in road transportation compared to standard fossil fuels. The most common sustainable fuels used today in heavy-duty applications are biodiesel and hydrogenated vegetable oil (HVO). Biodiesel and HVO are known as drop-in fuels since they are fuels that can be blended with standard diesel. However, due to changes in the chemical properties when the fuels are mixed, solubility problems in terms of precipitates may be formed. These insolubilities can lead to deposits in the fuel system, e.g., blocked fuel filters and internal injector deposits, and thus driveability problems. This study is a part of a project where the goal is to study the processes that cause the formation of deposits inside the injectors in heavy-duty vehicles. The deposits inside the injectors are known as internal diesel injector deposits (IDID). To study the formation of IDID, a number of injectors from heavy duty vehicles were collected from two
Pach, MayteHittig, HenrikCronhjort, AndreasBernemyr, Hanna
Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine. In this
Chapman, ElanaStudzinski, WilliamMonroe, RebeccaTolou, AtiWagle, MangrishCiaravino, JosephTomazic, Dean
In this work, the effects of ozone, hydrogen, carbon monoxide, and exhaust gas recirculation (EGR) addition to Haltermann gasoline combustion were investigated. For these additives, laminar and turbulent flame speeds were experimentally determined using spherically propagating premixed flames in a constant volume combustion vessel. Two initial mixture pressures of Po = 1 and 5 bar, two initial mixture temperatures of 358 and 373 K and a range of equivalence ratios (Ф) from 0.5 to 1 were investigated. The additives were added as single, binary and ternary mixtures to Haltermann gasoline over a wide range of concentrations. For the stoichiometric mixture, the addition of 10% H2, 5% CO and 1000 ppm O3 shows remarkable enhancement (80%) in SL0compared to neat Haltermann gasoline. In addition, for this same blend, increasing the mixture initial temperature and pressure results in a significant increase in SL0compared to the neat gasoline. Thus it can be inferred that ternary additives
Khan, FarhaElbaz, AymanKatoch, AmitBadra, JihadCostanzo, VincentRoberts, William
Energetic composites are mixtures of solid fuel and oxidizer particles that, when combined, offer higher calorific output than monomolecular explosives. The composites traditionally deliver energy as diffusion limited reactions and, thus, their power available from reaction is much smaller than any explosive.
This SAE Aerospace Information Report (AIR) is intended as a source of comparative information and is subject to change to keep pace with experience and technical advances. This document describes currently used fuels and fuels which may be used in the future. Conventional gasoline and diesel fuels are intentionally omitted from this document.
AGE-3 Aircraft Ground Support Equipment Committee
Since the Euro VI/6 regulation came into force in 2013/2014, most of the Diesel applications are equipped with both selective catalytic reduction (SCR) systems and Diesel particulate filters (DPF). On the one hand, SCR requires ammonia for the reduction of nitrogen oxides (NOx) created during the combustion process. An aqueous urea solution (AUS) containing 32.5% wt. urea, such as AdBlue® is injected into the hot exhaust gas upstream of the SCR catalyst to produce ammonia for NOx reduction. On the other hand, DPF demonstrates very high particle filtration efficiency, but requires to be periodically regenerated at high temperature to burn off accumulated soot. The regeneration temperature and duration can be significantly lowered by using fuel additives (fuel-borne catalyst or FBC) or by washcoating a catalyst into the DPF (catalyzed DPF or cDPF). However, this second technique is no longer applicable when SCR catalyst is implemented on filters); continuous combustion of soot is
Zinola, StephaneRaux, StephanePasquier, DavidTrela-Baudot, EmmanuelleMelgar, JorisObiols, JeromeCallu, CyrilleCollin, Annabelle
Over the last decade, there has been an impetus in the automobile industry to develop new diesel injector systems, driven by a desire to reduce fuel consumption and proscribed by the requirement to fulfil legislation emissions. The modern common-rail diesel injector system has been developed by the industry to fulfil these aspirations, designed with ever-higher tolerances and pressures, which have led to concomitant increases in fuel temperatures after compression with reports of fuel temperatures of ~150°C at 1500-2500 bar. This engineering solution in combination with the introduction of Ultra Low Sulphur diesel fuel (ULSD) has been found to be highly sensitive to deposit formation both external injector deposits (EDID) and internal (IDID). The deposits have caused concerns for customers with poor spray patterns misfiring injector malfunction and failure, producing increased fuel consumption and emissions. The importance to the industry of understanding the nature of diesel injector
Barker, JimReid, JacquelineWilmot, EdwardMulqueen, SimonAngel Smith, SarahScurr, DavidSnape, ColinKersting, ReinhardGauld, RichardMulvey, Robert
Gasoline Direct Injection (GDI) vehicles now make up the majority of European new car sales and a significant share of the existing car parc. Despite delivering measurable engine efficiency benefits, GDI fuel systems are not without issues. Fuel injectors are susceptible to the formation of deposits in and around the injector nozzles holes. It is widely reported that these deposits can affect engine performance and that different fuels can alleviate the buildup of those deposits. This project aims to understand the underlying mechanisms of how deposit formation ultimately leads to a reduction in vehicle performance. Ten GDI fuel injectors, with differing levels of coking were taken from engine testing and consumer vehicles and compared using a range of imaging and engine tests. At the time of writing, a new GDI engine test is being developed by the Co-ordinating European Council (CEC) to be used by the fuel and fuel additive industry. One such test was used to precondition six of the
Pilbeam, Jonathan JamesThomson, Alex RobertSahu, Amrit B.Liu, HaoyeXu, Hongming
Sludge and Varnish deposits that can build up in the crankcase originate in large part from fuel and fuel components that enter the crankcase through blow-by. These deposits can lead to a variety of engine issues including piston skirt deposits, cylinder bore scuffing, stuck lifters and oil filter plugging. A test has been developed to evaluate the contribution of “Complete Fuel System Cleaner” (CFSC) aftermarket fuel additives to crankcase sludge and varnish deposit formation. CFSC aftermarket fuel additives are typically formulated with polyether amine (PEA) chemistry and at concentrations that exceed 2000ppm. Three different commercially-available CFSC products were tested, containing two different classes of PEA chemistry - propylene oxide-based PEA (“PO-PEA”) and butylene oxide-based PEA (“BO-PEA”). Two of the three products contained the same PO-PEA chemistry, but at different concentrations, to show the effect of additive dosage. Using the Sequence VG sludge and varnish test
Smocha, Ruth
Reducing carbon dioxide (greenhouse gas) is one of the most important drivers to promote biofuels. Fuel from biomass has the potential to reduce greenhouse gas emissions and can gradually reduce the dependence on fossil fuels. However, fuel properties can differ significantly from standard diesel fuel and this will affect exhaust emissions and environmental pollution. Diesel – ethanol fuel blends development and specification are currently driven by the engine technology, existing fossil fuel specification and availability of feedstock. Thus, the aims of this study to investigate the effects of fuel additives with diesel–ethanol fuel blend under steady-state conditions. In the present study, the additives were palm diesel, n-butanol, ethyl acetate and di-tert-butyl peroxide (DTBP). The ratio of conventional diesel fuel to ethanol fuel to fuel additive are 80:15:5 by volume of fuel blends. The comparative studies on the effects of fuel additives in the engine performance and phase
Theinnoi, KampanartSawatmongkhon, BoonlueWongchang, ThawatchaiSukjit, EkarongChuepeng, Sathaporn
Improved fuel economy is increasingly a key measure of performance in the automotive industry driven by market demands and tighter emissions regulations. Within this environment, one way to improve fuel economy is via fuel additives that deliver friction- reducing components to the piston-cylinder wall interface. Whilst the use of friction modifiers (FMs) in fuel or lubricant additives to achieve fuel economy improvements is not new, demonstrating the efficacy of these FMs in vehicles is challenging and requires statistical design together with carefully controlled test conditions. This paper describes a bespoke, efficient, high-precision vehicle testing procedure designed to evaluate the fuel economy credentials of fuel-borne FMs. By their nature, FMs persist on engine surfaces and so their effects are not immediately reversible upon changing to a non FM-containing fuel (“carryover” effect), therefore requiring careful design of the test programme. The solution presented here
Yow, ShuhuiZiman, PaulineSmith, Sue J.Walter, Dr. MarcBacchi, Robert J.
There is increasing pressure to reduce well-to-wheel CO2 emissions in the internal combustion engine (ICE). This will require improvements in engine technology. An important aspect will include identification of the right fuel to match the new ICE’s requirements. It will likely require fuel production to move away from current production types. This is an additional optimisation that refineries will have to consider along with the other factors they balance to remain profitable. The use of additives is a key enabler to ensure that the fuels produced are fit-for-purpose whilst increasing refinery flexibility and hence profitability. However, for fuels, such as diesel, it has proved difficult to understand the variability of additive response with changes in fuel composition. This is particularly true for the cold flow response where subtle differences in fuels can impact additive appetite. This paper describes how we have employed novel systematic ways of characterising and analysing
Goberdhan, Dhanesh
Rapid depletion of petroleum reserves, stringent emission legislations and global warming has given us an opportunity to find biodiesel as an alternative to diesel fuel. Biodiesel is a biogradable, renewable, sulphur free, non-toxic, and oxygenated green fuel. Recent emission legislations have also restricted the nano particles emission in addition to particulate matter, due to their adverse impact on health. Karanja and Jatropha oils are non-edible vegetable oils. Karanja and Jatropha oil methyl ester biodiesel are prepared by the process of transesterification. Biodiesel emits lesser gaseous emission as compared to diesel fuel. However, the only major concern in the use of biodiesel is that it increases NOx emission. Nano particle fuel additive is one of the essential techniques to overcome the NOx emission drawback of biodiesel. In the present study, the engine performance and emission of CO, UHC, NOx and PM including nano particle emission, were compared for diesel, Karanja and
Pandey, Anand KumarNandgaonkar, MilankumarSuresh, SVarghese, Anil
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