Browse Topic: Battery cell chemistry

Items (192)
With current and future regulations continuing to drive reductions in carbon dioxide equivalent (CO2e) emissions in the on-road industry, the off-road industry is also likely to be regulated for fuel and CO2e savings. This work focuses on converting a heavy-duty off-road material handler from a conventional diesel powertrain to a plug-in series hybrid, achieving a 49% fuel reduction and 29% CO2e reduction via simulation. Control strategies were refined for energy savings, including a regenerative braking strategy to increase regenerative braking and a load-following hydraulic strategy to decrease electrical energy consumption. The load-following hydraulic control shuts off the hydraulic electric machine when it is not needed—an approach not previously seen in a load-sensing, pressure-compensated system. These strategies achieved a 24.1% fuel savings, resulting in total savings of 61% in fuel and 41% in CO2e in the plug-in series compared to the conventional machine. Beyond control
Goodenough, BryantCzarnecki, AlexanderRobinette, DarrellWorm, JeremySubert, DavidKiefer, DylanHeath, MatthewBrunet, BobKisul, RobertLatendresse, PhilWestman, JohnBlack, Andrew
The world is moving towards a green transportation system. Governments are also pushing for green mobility, especially electric vehicles. Electric vehicles are becoming more popular in Europe, China, India, and developing countries. In EVs, the customer's range anxiety and the perceived real-world range are major challenges for the OEMs. The OEMs are moving towards a higher power-to-weight ratio. Energy density plays a crucial role in the battery pack architecture to increase the vehicle range. Higher capacity battery packs are needed to improve the vehicle's range. The battery pack architecture is vital in defining the gravimetric and volumetric energy densities. The cell-to-pack battery technique aims to achieve a higher power-to-weight ratio by eliminating unnecessary weight in the battery architecture. The design of battery architecture depends on the cell features such as the cell shape & size, cell terminal positions, vent valve position, battery housing strength requirements
K, Barathi Raja
The internal short circuit of a traction battery is one of the most typical failure mechanisms that can lead to thermal runaway, potentially triggering thermal propagation across the entire battery system. This phenomenon poses significant safety risks, especially in electric vehicles and large-scale energy storage systems. Therefore, it is essential to explore and understand the internal short circuit behavior to mitigate these risks. One of the most effective testing methods for reproducing an internal short circuit is the penetration test, where specific test conditions must be carefully designed based on the failure behavior. Among these conditions, the penetration step length plays a crucial role, as it directly influences the short circuit dynamics. Despite the importance of penetration step length, there is currently no standardized test procedure that dictates how to select the appropriate step size for different battery samples. This gap in standardization complicates the
Wang, FangSun, ZhipengMa, TianyiDai, XiaoqianDai, CeYan, PengfeiMa, XiaoleChen, LiduoMa, HaishuoShen, Shaopeng
The cost of electric vehicles (EVs) is significantly influenced by lithium-ion batteries, which typically account for about 40% of the total price, primarily due to the critical minerals content. Notably, minerals for cathode production are prone to scarcity and market price fluctuations. Moreover, the extraction of these minerals through mining activities poses substantial environmental challenges, including carbon emissions and resource depletion. In response to these concerns, recycling emerges as strategic to ensure the sustainability of electrification and secure the mineral supply chain. This paper presents findings from a study on recycling EV batteries using hydrometallurgical processes, encompassing the resynthesis of cathode materials utilizing recycled resources. The hydrometallurgical method exhibited an extraction efficiency surpassing 90%, with no direct CO2 emissions. Validation of the resynthesis phase involved the fabrication of cells with resynthesized cathodes
Obara, Rafael BrisollaErthal, LeopoldoSouza, Cleiton OliveiraRoggerio, LeonardoFreitas, Heverson RenanLima, Ana Luiza LorenzenBassani, Jean Carlos
In recent years, Lithium Iron Phosphate (LFP) has become a popular choice for Li-ion battery (LIB) chemistry in Electric Vehicles (EVs) and energy storage systems (ESS) due to its safety, long lifecycle, absence of cobalt and nickel, and reliance on common raw materials, which mitigates supply chain challenges. State-of-charge (SoC) is a crucial parameter for optimal and safe battery operation. With advancements in battery technology, there is an increasing need to develop and refine existing estimation techniques for accurately determining critical battery parameters like SoC. LFP batteries' flat voltage characteristics over a wide SoC range challenge traditional SoC estimation algorithms, leading to less accurate estimations. To address these challenges, this study proposes EKF and PF-based SoC estimation algorithms for LFP batteries. A second-order RC Equivalent Circuit Model (ECM) was used as the dynamic battery model, with model parameters varying as a function of SoC and
Ns, Farhan Ahamed HameedJha, KaushalShankar Ram, C S
The life and safety of a battery are closely linked to temperature. Designing an effective thermal management system relies on a thorough understanding and analysis of the thermal properties and mechanisms of the battery. Over time, as batteries are used, their thermal characteristics change due to variations in internal SEI thickness, the deterioration of the active material structure, gas production, and electrolyte consumption, all of which are associated with the aging process. In this paper, experiments on both NCM and LFP batteries were made to measure the heat generation characteristics by adiabatic calorimeter. The results showed that the impact of calendar aging on battery heat generation exhibited completely different patterns for the lithium-ion batteries of the two material systems mentioned above. This paper provides guidance for the optimization of heat generation characteristics of battery and the calibration of heat source in the design of battery thermal management
Li, HaibinZhao, HongweiLiu, DinghongHu, Qiaosheng
Rapid advancement of electric vehicle (EV) technology has propelled the need for reliable and efficient methods of battery data. This has vital importance – to ensure safety aspects and efficient design of EV system. Traditional data collection methods for battery characterization is a large subject for the design of experiments and is often expert’s skill intensive, time-consuming, and do not allow scalability. This study proposes an approach which bases on Generative Artificial Intelligence (GenAI) for two activities. First, to assist the DOE in characterizing cell/batteries at different C-rates and temperatures considering different degradation rates. Second, for manipulation of characterization data taking into account measurement and data recording errors. The study compares GenAI models like Generative Adversarial Networks (GANs), Variational Autoencoders (VAEs), and transformer-based (Time-GPT) models in generating and validating EV battery characterization data. This is not a
Sing, SandipPawar, RushikeshHivarkar, Umesh N.
While Daimler Truck and Paccar are pursuing LFP battery cells, Volvo Trucks employs lithium-ion batteries in which lithium nickel cobalt aluminum oxide (NCA) is used as the cathode — for now anyway. The Swedish truck maker is continuously exploring other battery technologies.
Many research centers and companies in general aviation have been devoting efforts to the electrification of propulsive plants to reduce environmental impact and/or increase safety. Even if the final goal is the total elimination of fossil fuels, the limitations of today's battery in terms of energy and power densities suggest the adoption of hybrid-electric solutions. These systems combine the advantages of conventional and electric propulsive systems, namely reduced fuel consumption, high peak power, and increased safety deriving from redundancy. Today, lithium-ion batteries are the best commercial option for the electrification of all means of transportation. However, lithium batteries are a family of technologies that presents a variety of specifications in terms of gravimetric and volumetric energy density, discharge and charge currents, safety, and cost. This work presents a series/parallel hybrid electric powertrain derived from automotive applications (Honda i-MMD) tailored to
Donateo, TeresaSpada Chiodo, Ludovica
While Daimler Truck, Paccar and Accelera by Cummins are pursuing lithium iron phosphate (LFP) battery cells with technology partner EVE Energy (www.sae.org/news/2023/09/lfp-battery-cell-production-for-electric-commercial-vehicles), Volvo Trucks employs lithium-ion batteries in which lithium nickel cobalt aluminum oxide (NCA) is used as the cathode - for now anyway. The Swedish truck maker is continuously exploring other battery technologies. “If you look back at least three years, maybe five years, LFP was not really on the map. There has come some new evolvement on LFP which would make it better in many ways, [improved] things that were problematic with it before. It might very well be a solution in the future,” Peter Granqvist, senior vice president of Volvo Group Electromobility Technology, said at a media event at the company's headquarters in Gothenburg, Sweden, in late 2023. “Right now, we are not on that path, but I'm not excluding anything.” Granqvist said it's possible
Gehm, Ryan
There is an urgent need to decarbonize various industry sectors, including transportation; however, this is difficult to achieve when relying solely on today’s lithium-ion (Li-ion) battery technology. A lack of sufficient supply of critical materials—including lithium, nickel, and cobalt—is a major driving force behind the research, development, and commercialization of new battery chemistries that can support this energy transition. Many emerging chemistries do not face the same supply, safety, and often durability challenges associated with Li-ion technology, yet these solutions are still very immature and require significant development effort to be commercialized. This chapter identifies and evaluates various emerging battery chemistries suitable for deployment in the automotive industry and describes the advantages, disadvantages, and development challenges for each identified technology. Additionally, the chapter outlines development timelines, contending that, to benefit from
Kolodziejczyk, BartKozumplik, Brian
As companies continue to trumpet their next-gen EV battery tech, it seems like new chemistries face more momentum from the established champ, lithium-ion. There's no shortage of alternatives to lithium-ion EV batteries in development. From lithium-iron phosphate to sodium-ion to multiple solid-state chemistries, companies are racing to perfect these technologies and figure out how to manufacture them at scale. But to an outside observer, it can feel like breathless coverage of future battery technology is much ado about not much. Lithium-ion batteries seem to have all the momentum, seeing as they're the power supply of choice for most EV manufacturers. And if there's anything that's true in the automotive industry, it's how hard it is to buck momentum. Here are just a few of the big issues lithium-ion batteries have in their favor: Already built factories that manufacture batteries and face tremendous costs to retool for a different technology. An economy of scale that has driven down
Clonts, Chris
Lithium-ion batteries are the ubiquitous energy storage device of choice in portable electronics and more recently, in electric vehicles. However, there are numerous lithium-ion battery chemistries and in particular, several cathode materials that have been commercialized over the last two decades. In recent time several automakers have followed trend by announcing their own plans to move their EV production to LFP, due to its high intrinsic safety, fast charging, and long cycle life and cobalt free batteries as well as avoiding other supply chain constrained metals like nickel. Accurate estimation of the state-of-charge (SOC) is crucial for efficient and safe battery applications. However, existing SOC estimation methods (coulomb count, SOC-OCV methods) fail to provide accurate SOC estimation for LFP batteries that have a flat voltage-SOC relationship, and these present model-based methods can be ascribed to their inability to simultaneously accommodate the differences in voltage
Sandrabyna, MallikarjunaPatil, Akshata
Controlling thermal dissipation by operating components in car batteries requires a heat management design that is of utmost importance. As a proactive cooling method, the usage of PCM (Phase Change Materials) to regulate battery module temperature is suggested. Even at lower flow rates, liquid cooling has a heat transfer coefficient that is 1.5–3 times better. The rate of global cell production has increased today from 4,000 to 100,000 cells per day. Future-proof Li (metal) battery chemistry with a 3x increase in energy density. Ineffective thermal management of the battery is the root of the issue. In order to optimise battery modules, it is important to identify likely failure modes and causes. The medium used to carry heat from the battery over its passage duration at various operating temperatures is a variety of phase-change materials. The latent heat is significant, and many vegetable fats derived from fatty acids are more effective than salt hydrates and paraffin. Melting
Deepan Kumar, SadhasivamR, Vishnu Ramesh KumarDinesh Kumar, DevadossManojkumar, RA, TamilselvanM, BoopathiC, Lokesh
This paper proposes a novel reconfigurable battery balancing topology and reinforcement learning-based intelligent balancing management system. The different degradations cause a significant loss of battery pack available capacity, as the pack power output relies on the weakest cell due to the relevant physical requirements. To handle this capacity drop issue, a reconfigurable battery topology is adopted to improve the usability of the heterogeneous battery. There are some existing battery reconfigurable topologies in the literature. However, these studies rely on the limited options of topology designs, and there is a lack of study on the reconfigurability of these designs and other possible new designs. Also, it is rare to find an optimal management system for the reconfigurable battery topology. To fill these research gaps, this paper explores existing battery reconfigurable topology designs and proposes a new reconfigurable topology for battery balancing. Besides, the battery
Ye, YimingZhang, Jiangfeng
There's a mild irony in a battery company called ONE that believes the way to increase electric vehicle adoption actually relies on two. Two battery chemistries in one pack, that is, according to ONE founder and CEO Mujeeb Ijaz. We spoke with Ijaz about ONE's dual-chemistry pack in early 2022, but the company recently shared more details on how it plans to make EVs with a 600-mile range feasible in the coming years. Our Next Energy is working on two new battery types (the Aries and Gemini series), both of which start with a lithium iron phosphate (LFP) chemistry. The whiz-bang, 600-mile (966-km), dual-chemistry Gemini pack isn't due to go into production until 2025 or 2026, but ONE is currently testing its Aries II pack. The Aries II is a structural cell-to-pack singlechemistry battery based on the Aries I battery now available for class 3-6 commercial trucks, buses and utilities or in the Aries Grid energy storage system. ONE is working with partners Bollinger Motors, Motiv and the
Blanco, Sebastian
Mid-September of 2023 brought a United Auto Workers (UAW) strike against each of the Detroit Three automakers. Apart from the face-value issues of a strike, the UAW's extraordinary choice to hit all three automakers - at an unusually unsettled inflection point in the industry's technology progression - may have generational implications. By some accounts, there are more than a few untied shoelaces tangling the industry's march toward electrification. The cost of EVs (their batteries, specifically) is emerging as a persistent impediment to mainstream adoption in the U.S. and Europe. The situation is magnified by post-pandemic inflation that's pressuring consumers and hiking the cost of EV-related materials; battery prices aren't declining and manufacturers and battery developers are scrambling for options - less-expensive but lower-performing lithium-iron phosphate battery chemistry is emerging as one immediate alternative.
Visnic, Bill
NMC and LFP lithium-ion batteries find favor in different regions as OEMs move to electrify larger excavators and loaders. The success of electric vehicles in the construction industry will largely be determined by battery prices being low enough that the total cost of ownership is cheaper than diesel alternatives. IDTechEx's new report, “Electric Vehicles in Construction 2023-2043,” shows that there is a battery price tipping point, under which it will be cheaper over the vehicle lifetime to operate an EV. Selecting the right chemistry will be imperative for getting a low enough vehicle price. So why is a clear dichotomy seen between the batteries being deployed in China compared to Europe? Electric vehicles in construction are an emerging market. IDTechEx has built a database of more than 100 example makes and models across seven different construction-vehicle categories: mini excavators, excavators (>6 tonne), compact loaders, backhoe loaders, wheel loaders, telehandlers and mobile
Jeffs, James
Many owners of electric vehicles worry about how effective their battery will be in very cold weather. Now a new battery chemistry may have solved that problem.
The majority of powertrain types considered important contributors to achieving the CO2 targets in the transportation sector employ a battery as an energy storage device. The need for batteries is hence expected to grow drastically with increasing market share of CO2-optimized powertrain concepts. The resulting huge pressure on the development of future electrochemical energy storage systems necessitates the application of advanced methodologies enabling a fast and cost-efficient concept definition and optimization process. This paper presents a model-based methodology for the optimization of BEV thermal management concept layouts and operation strategies targeting minimized energy consumption. Starting at the vehicle level, the proposed methodology combines appropriate representations of all primary powertrain components with 1D cooling and refrigerant circuit models and focuses on their interaction with the battery chemistry. To this end, the battery cells are thermally modeled in 3D
Fandakov, AlexanderTourlonias, PaulHerzog, AlexanderÖzkan, EmreMehnert, Ronny KurtSens, Marc
One of the solutions for reducing greenhouse gas emissions in the transport sector is the electrification of mobility. The technology currently most widely used by car manufacturers is the Li-ion battery (LiB). Unfortunately, Li-ion batteries can suffer dramatic events with catastrophic consequences known as thermal runaway (TR). TR has many possible causes: excessive temperature, mechanical deformation, electrical overcharge, internal short circuit. Typically, TR causes violent combustion that is difficult or impossible to control, with the emission of potentially toxic gases and particles. TR is a major problem for manufacturers and can have serious consequences for users. Understanding TR is a key safety issue. This paper presents a new methodology to characterize the thermal runaway of Li-ion battery cells, combining gas analysis, thermodynamic measurements and high-speed imaging. The protocol was applied to characterize two commercial battery cell types with different positive
Richardet, Lucasde Persis, StéphanieBardi, MicheleLecompte, MatthieuBrocchetto, Vincent
Vehicle electrification is one of the most important emerging trends in the transportation sector and a necessary step towards the reduction of polluting substances and greenhouse gas (GHG) emissions. However, electric vehicles still present some environmental criticalities, such as indirect emissions related to the electricity used for charging the traction battery, which depends on the considered national electricity generation mix. The leading approach for quantifying the potential environmental impacts is the Life Cycle Assessment (LCA), a standardized methodology that takes into account the whole life cycle of a product, including production, use phase, and end-of-life. Among them, the use phase is the most controversial and heterogenic part of the battery LCA, being environmental impacts depending on different national electricity generation mixes and several factors difficult to estimate, such as charge-discharge power losses that provide significant contributions to the overall
Silvestri, LucaDe Santis, MicheleFalcucci, GiacomoSerao, PaolaBella, Gino
ABSTRACT Cornerstone Research Group (CRG) developed a lithium metal (Li-metal) battery cell for military applications. Utilizing a Li-metal anode, high energy density cathode, and an advanced low-temperature fluorinated electrolyte, the cell was designed and developed to provide high-power and low temperature capabilities. The 1.5 Ah Li-metal pouch cell had a specific energy of 247 Wh/kg and was able to discharge at ultra-low temperatures (-57 °C). Moreover, the Li-metal cell demonstrated extremely high-power by fully discharging at 10 C while maintaining over 70% its initial capacity. To demonstrate the Li-metal cell’s utility for military vehicle use, CRG modeled the cell into the 6T battery platform. A novel module housing was designed to evenly apply compression to the Li-metal cells to improve cell performance. Based on these projections, the Li-metal 6T battery could have a capacity of 163 Ah with a specific energy of 179 Wh/kg. Citation: J. Hondred, F. Zalar, P. Nikolaev, B
Hondred, JohnZalar, FrankNikolaev, PashaHenslee, Brian
ABSTRACT Low charge times are very desirable for battery electric vehicles. Lithium Nickel Cobalt Aluminum (NCA) chemistry is used in vehicles like the Tesla Model S for their energy density and also used in several consumer applications. Investigators used state of art NCA cells to conduct research into the tradeoffs between charge time, life and safety. Eight different charge profiles were compared. These included the standard CC-CV strategy and the state of the art Tesla Model S profile. Impact of temperature is also embedded in the selection of charge profiles. A non-dimensional charge metric is proposed as a composite of the impacts of charge time, effective charge stored, aging, overcharge sensitivity and lithium plating sensitivity. This metric is computed for all tested charge profiles and the best candidates are identified. Citation: Bapiraju Surampudi PhD, Ian Smith, Terry Alger PhD, “Some Insights in Fast Charge Methods for NCA Cells,” In Proceedings of the Ground Vehicle
Surampudi, BapirajuSmith, IanAlger, Terry
As the industry quickly shifts its focus from ICE to BEVs, there is a prime opportunity to rethink the basics of the vehicle/propulsion development, manufacturing, procurement and the customer-facing go-to market strategy. OEMs and suppliers are using the electrification shift to evaluate all aspects of their enterprises. As the ICE propulsion system dominated our industry structure for the past 120 years, we became accustomed to a slow-but-steady speed of ICE technology change and innovations. As virtually every traditional OEM - and scores of startups - focus on electrified propulsion, the speed of innovation and required flexibility will be a blur compared to the last couple of decades. It will be standard practice for all entities to use this transition as a level-setting event - to essentially rethink the enterprise. As such, industry players will need to innovate at a swifter pace and need to adopt partnerships to fill gaps and defray risk, while ensuring any investment has
By the end of 2023 there will be 10 Chinese electric passenger vehicles using advanced semi-solid-state batteries (ASSB) - an industry-first application for EVs and a milestone for vehicle electrification, according to Paul Haelterman, North American VP at Autodatas, a vehicle benchmarking and research firm. It's “a huge step for the industry's production pursuit of all-solid-state batteries,” Haelterman told SAE Media ahead of his presentation on China's EV market at SAE's WCX 2023 conference in Detroit. A semi-solid-state battery can be one in which one electrode does not contain a liquid electrolyte and the other electrode does. Or it can be a battery in which the mass or volume of the solid electrolyte in the monomer accounts for half of the total mass or volume of the electrolyte in the monomer. Some battery experts view semi-solid-state as a compromise technology, offering a faster route to scale, but is heavy and requires more volume.
Buchholz, Kami
There is an urgent need to decarbonize various industry sectors, including transportation; however, this is difficult to achieve when relying solely on today’s lithium-ion (Li-ion) battery technology. A lack of sufficient supply of critical materials—including lithium, nickel, and cobalt—is a major driving force behind research, development, and commercialization of new battery chemistries that can support this energy transition. Many emerging chemistries do not face the same supply, safety, and often durability challenges associated with Li-ion technology, yet these solutions are still very immature and require significant development effort to be commercialized. Emerging Automotive Battery Chemistries: Hedging Market identifies and evaluates various chemistries suitable for deployment in the automotive industry and describes advantages, disadvantages, and development challenges for each identified technology. Additionally, it outlines development timelines, contending that, to
Kolodziejczyk, Bart
Overcharging lithium-ion batteries is a failure mode that is observed if the battery management system (BMS) or battery charger fails to stop the charging process as intended. Overcharging can easily lead to thermal runaway in a battery. In this paper, nickel manganese cobalt (NMC) battery modules from the Chevrolet Bolt, lithium manganese oxide (LMO) battery modules from the Chevrolet Volt, and lithium iron phosphate (LFP) battery modules from a hybrid transit bus were overcharged. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages, gaseous emissions, and feedback from volatile organic compound (VOC) sensors. Overcharging a battery can cause lithium plating and other exothermic reactions that will lead to thermal runaway. During the testing, VOC sensors were used to determine what, if any, amount of forewarning they may provide in the event the
Surampudi, BapirajuJones, KevinBanks, Zachary
The use of wireless power transfer systems, consisting of inductive electrical coils on the vehicle and the power source may be designed for dynamic operations where the vehicle will absorb energy at highway speeds from transmitting coils in the road. This has the potential to reduce the onboard energy storage requirements for vehicles while enabling significantly longer missions. This paper presents an approach to architecting a dynamic wireless power transfer corridor for heavy duty battery electric commercial freight vehicles. By considering the interplay of roadway power capacity, roadway and vehicle coil coverage, seasonal road traffic loading, freight vehicle class and weight, vehicle mobility energy requirements, on-board battery chemistry, non-electrified roadway vehicle range requirements, grid capacity, substation locations, and variations in electricity costs, we minimize the vehicle TCO by architecting the electrified roadway and the vehicle battery simultaneously. The idea
Sujan, Vivek AnandSiekmann, AdamTennille, SarahTsybina, Eve
This document aids in mitigating risk for the storage of lithium-ion cells, traction batteries, and battery systems intended for use in automotive-type propulsion systems and similar large format (e.g., stationary, industrial) applications. Nothing precludes other industries and applications from using these recommendations.
Battery Transportation and Storage Committee
The saying ‘Two steps forward, one step back’ describes the overall progress of CASE - Connected, Autonomous, Shared and Electrified vehicles and infrastructures. While electrification and connected technologies arguably have each taken a step forward, funding four industry-changing secular shifts in unison was always a lot to ask. The resulting investment head-winds are not surprising, given the added impacts of COVID, microchip and labor shortages, the Russia-Ukraine war, and inflation/higher interest rates dampening vehicle sales. Viewed from 30,000 feet, CASE's uneven takeoff trajectory has been governed by often unproven technologies being deployed within unrealistic timelines. OEMs and suppliers have devoted billions to the development and implementation of electrified propulsion in the major developed markets. Regulations have made the ‘E’ in CASE the highest priority. This includes battery-electric vehicle development and assembly, battery chemistry R&D, cell plants, strategic
Silicon-infused anodes, already widely considered one of the most promising candidate technologies for the next significant performance-improvement phase of electric-vehicle (EV) Lithium-ion (Li-ion) batteries, enjoyed a significant boost in September 2022, when GM and OneD Battery Sciences revealed a joint research and development agreement to study the potential to use OneD’s silicon nanotechnology in GM’s Ultium battery cells. General Motors and Volta Energy Technologies also invested in a $25-million Series C funding for OneD, a move interpreted by some as a vote of confidence that silicon-anode technology is poised to make a comparatively imminent impact on EV battery development.
Engineers at the University of California San Diego have developed lithium-ion batteries that perform well at freezing cold and scorching hot temperatures, while packing a lot of energy. The researchers accomplished this feat by developing an electrolyte that is not only versatile and robust throughout a wide temperature range, but also compatible with a high energy anode and cathode.
High energy and power density Lithium-ion batteries are used as energy storage devices for indispensable applications ranging from cell phones to hybrid electric vehicles, unmanned aerial vehicles and commercial passenger aircrafts. To monitor the health of the battery and its various performances, it is crucial to understand the electrochemical behavior of the battery. The Doyle-Fuller-Newman (DFN) model is a popular electro-chemistry-based model, which characterizes the solid and electrolyte diffusion dynamics in the battery and predicts current/voltage response. However, the DFN model requires many parameters that need to be estimated to obtain an accurate battery model. In this article, an electro-chemistry based cell model is developed using GT-AutoLion to simulate and validate the performance for two different commercially available Lithium Iron Phosphate (LiFePO4) and Nickel Cobalt Aluminum (NCA) cells. GT-AutoLion is a powerful tool for physics-based modeling to predict
Natarajan, NesamaniPanday, AishwaryaDuddu, SrinivasaSingh, Thongbam TKesavan, DeepaAnnabathula, Sateesh
Engineers at the University of California San Diego have developed lithium-ion batteries that perform well at freezing cold and scorching hot temperatures, while packing a lot of energy. The researchers accomplished this feat by developing an electrolyte that is not only versatile and robust throughout a wide temperature range, but also compatible with a high energy anode and cathode.
A team of researchers led by chemists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory has learned that an electrolyte additive allows stable high-voltage cycling of nickel-rich layered cathodes. Their work could lead to improvements in the energy density of lithium batteries that power electric vehicles.
ABSTRACT PPG formulates N-methyl pyrrolidone free (NMP−free) cathodes for Li−ion batteries capable of delivering sufficient power for automotive starting, lighting and ignition (SLI) as well as adequate charge capacity for powering auxiliary electronics. In this paper, NMP−free energy cathodes and power cathodes were formulated using developmental binders, and refinement of carbon/binder ratio and slurry mix procedure. Learnings from the energy and power cathode development were conceptually combined in the formulation of capacity enhanced power cathodes. These cathodes were evaluated electrochemically via power capability and rate capability testing in battery coin cells, as well as in 0.5 Ah multilayer pouch cells. Carbon content was found to be a critical factor in attaining high cold crank performance. This work represents significant steps toward potential commercialization of NMP−free cathode coated foil for Li−ion batteries. Citation: S. Esarey, A. Kizzie, C. Woodley, I. Matts
Esarey, Samuel L.Kizzie, AustinWoodley, ChristopherMatts, IanHellring, StuartZhou, ZhilianTerrago, Gina
Electric vehicle batteries typically require a tradeoff between safety and energy density. If the battery has high energy and power density — required for uphill driving or merging on the freeway — then there is a chance the battery can catch fire or explode in the wrong conditions. But materials that have low energy/power density, and therefore high safety, tend to have poor performance. There is no material that satisfies both.
Battery engineers targeting electric vehicles (EVs) continue to research designs with solid-state electrolyte because of the alluring twin promises of significantly higher energy densities – which lead to longer driving range – and greatly enhanced safety that comes with eliminating liquidous electrolytes. Additional presumed advantages for solid-state batteries are quicker recharging and longer lifespan – not to mention the potential to reduce the amount of critical, high-cost minerals required for lithium-ion battery chemistries.
Metal-air batteries can be used in a variety of applications ranging from range extenders for electric vehicles to emergency power systems. Metal-sea-water batteries are primarily used for underwater applications ranging from torpedoes to underwater unmanned vehicles. A team of researchers at the Department of Mechanical Engineering, MIT, has developed an oil displacement system to mitigate open-circuit corrosion in metal-air and metal-seawater batteries.
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