Browse Topic: Fuel reformers
ABSTRACT Fuel Cell Systems offer high efficiency, quiet, clean, low signature power generation. To be useful for military applications they must use commonly available logistic fuels: JP8 is the primary fuel of choice. This paper reports the results of 1000 hour tests of innovative hardware to desulfurize and reform JP8. Results from early testing of a 6 kW fully integrated PEM fuel cell system operating on JP8 are also presented
In prior work, the EGR loop catalytic reforming strategy developed by ORNL has been shown to provide a relative brake engine efficiency increase of more than 6% by minimizing the thermodynamic expense of the reforming processes, and in some cases achieving thermochemical recuperation (TCR), a form of waste heat recovery where waste heat is converted to usable chemical energy. In doing so, the EGR dilution limit was extended beyond 35% under stoichiometric conditions. In this investigation, a Microlith®-based metal-supported reforming catalyst (developed by Precision Combustion, Inc. (PCI)) was used to reform the parent fuel in a thermodynamically efficient manner into products rich in H2 and CO. We were able to expand the speed and load ranges relative to previous investigations: from 1,500 to 2,500 rpm, and from 2 to 14 bar break mean effective pressure (BMEP). Experiments were conducted to determine the effects of the H/C ratio of the fuel on H2 production and on the engine
A fuel reforming technology using a low temperature oxidation was developed to improve a NOx reduction performance of HC-SCR (Hydrocarbons Selective Catalytic Reduction) system, which does not require urea. The low-temperature oxidization of a diesel fuel in gas phase produces NOx reduction agents with high NOx reduction ability such as aldehydes and ketones. A pre-evaporation-premixing-type reformer was adopted in order to generate a uniform temperature field and a uniform fuel/air premixed gas, and to promote the low temperature oxidation efficiently. As a fundamental study, elementary reaction analysis for n-hexadecane/air premixtures was carried out to investigate the suitable reformer temperature and fuel/air equivalence ratio for generation of oxygenated hydrocarbons. It was found that the reforming efficiency was highest at the reforming temperature around 623 to 673K, and aldehydes and ketones were produced. It was inferred that the NOx reduction performance by the reformed
As global climate change concerns lead the automotive industry to push towards manufacturing more sustainable automobiles, a number of technologies and powertrains have developed. Less common among these new powertrains are fuel cell systems due to their relatively high cost and requirement of an associated fuel reformation process. This reformer is needed if widely available hydrocarbon fuels are to be used. There are currently few initiatives combining fuel cell systems with internal combustion engines, but these initiatives are unable to mitigate the primary drawbacks of fuel cell systems. Current designs place the engine downstream of the fuel cells, resulting in the same need for prior fuel processing. In this work, a configuration is considered in which the engine is placed upstream of the fuel cell system, and its syngas-rich exhaust is fed directly into the fuel cell system for electricity production. Fuel-rich compression-ignition engine combustion can break down fuel into
Methanol is a promising fuel for future spark-ignition engines. Its properties enable increased engine efficiency. Moreover, the ease with which methanol can be reformed, using waste exhaust heat, potentially offers a pathway to even higher efficiencies. The primary objective of this study was to build and validate a model for a methanol fueled direct-injection spark-ignition engine with on-board fuel reforming for future investigation and optimization. The second objective was to understand the combustion characteristics, energy losses and engine efficiency. The base engine model was developed and calibrated before adding a reformed-exhaust gas recirculation system (R-EGR). A newly developed laminar burning velocity correlation with universal dilution term was implemented into the model to predict the laminar burning velocity with the presence of hydrogen in the reforming products. At the same EGR ratio, there is a small increase in the engine efficiency with fuel reforming compared
A high temperature and no oxygen atmosphere fuel reforming has been proposed for the purpose of exergy saving by theoretical analyzing the detailed exergy loss events of combustion process, the correctness and feasibility of this fuel reforming have been verified through experiments. The exergy behaviors of high temperature and no oxygen atmosphere fuel reforming have been extensively studied, and many benefits had been observed including: (1) simplifying the reforming device where catalysts are not necessary; (2) improving the total chemical exergy while effectively converting large moleculae to small moleculae; (3) improving the mixture’s ratio of specific heat that can promote work-extraction; and (4) lengthening the ignition delay that buys time for better mixing process. All of these benefits are conducive to a better organized HCCI combustion that may improve the engine second law efficiency
The Dual-Fuel (DF) combustion is a promising technology for efficient, low NOx and low exhaust particulate matter (PM) engine operation. To achieve equivalent performance to a DF engine with only the use of conventional liquid fuel, this study proposes the implementation of an on-board fuel reformation process by piston compression. For concept verification, DF combustion tests with representative reformed gas components were conducted. Based on the results, the controllability of the reformed gas composition by variations in the operating conditions of the reformer cylinder were discussed
Onboard reforming has been proposed as a strategy for improving spark-ignited (SI) engine efficiency through knock reduction, dilution limit extension, improved thermodynamic gas properties, and thermochemical exhaust enthalpy recuperation. One approach to onboard fuel reforming is to combust fuel in the engine cylinder under rich conditions, producing a hydrogen-rich reformate gas--which can subsequently be recirculated into the engine. Hydrogen is the preferred product in this process due to its high flame speed and knock resistance, compared with other reformate constituents. In this work, the effects of engine operation, fuel composition and water injection were evaluated for their effect on reformate gas composition produced under rich combustion conditions. Engine parameters, including intake pressure, intake temperature, combustion phasing, and valve timing all had no significant impact on hydrogen yield at a given equivalence ratio. Fuel effects on hydrogen yield were more
Powertrain simulations and catalyst studies showed the efficiency credits and feasibility of onboard reforming as a way to recover waste heat from heavy duty vehicles (HDVs) fueled by natural gas (NG). Onboard reforming involves 1) injecting NG into the exhaust gas recycle (EGR) loop of the HDV, 2) reforming NG on a catalyst in the EGR loop to hydrogen and carbon monoxide, and 3) combusting the reformed fuel in the engine. The reformed fuel has increased heating value (4-10% higher LHV) and flame speed over NG, allowing stable flames in spark ignition (SI) engines at EGR levels up to 25-30%. A sulfur-tolerant reforming catalyst was shown to reform a significant amount of NG (15-30% conversion) using amounts of precious metal near the current practice for HDV emissions control (10 g rhodium). Engine simulations showed that the high EGR levels enabled by onboard reforming are used most effectively to control engine load instead of waste-gating or throttling. This leads to 3% efficiency
In order to achieve high-efficiency and clean combustion in HCCI engines, combustion must be controlled reasonably. A great variety of species with various reactivities can be produced through low temperature oxidation of fuels, which offers possible solutions to the problem of controlling in-cylinder mixture reactivity to accommodate changes in the operating conditions. In this work, in-cylinder combustion characteristics with low temperature reforming (LTR) were investigated in an optical engine fueled with low octane number fuel. LTR was achieved through low temperature oxidation of fuels in a reformer (flow reactor), and then LTR products (oxidation products) were fed into the engine to alter the charge reactivity. Primary Reference Fuels (blended fuel of n-heptane and iso-octane, PRFs) are often used to investigate the effects of octane number on combustion characteristics in engines. Then PRF0 (n-heptane) and PRF50 (mixture of 50% n-heptane and 50% iso-octane by volume) were
Advancements in catalytic reforming have demonstrated the ability to generate syngas (a mixture of CO and hydrogen) from a single hydrocarbon stream. This syngas mixture can then be used to replace diesel fuel and enable dual-fuel combustion strategies. The role of port-fuel injected syngas, comprised of equal parts hydrogen and carbon monoxide by volume was investigated experimentally for soot reduction benefits under a transient load change at constant speed. The syngas used for the experiments was presumed to be formed via a partial oxidation on-board fuel reforming process and delivered through gaseous injectors using a custom gas rail supplied with bottle gas, mounted in the swirl runner of the intake manifold. Time-based ramping of the direct-injected fuel with constant syngas fuel mass delivery from 2 to 8 bar brake mean effective pressure was performed on a multi-cylinder, turbocharged, light-duty engine to determine the effects of syngas on transient soot emissions. A
A key challenge for the practical introduction of dual-fuel reactivity controlled compression ignition (RCCI) combustion modes in diesel engines is the requirement to store two fuels on-board. This work demonstrates that partially reforming diesel fuel into less reactive products is a promising method to allow RCCI to be implemented with a single stored fuel. Experiments were conducted using a thermally integrated reforming reactor in a reformed exhaust gas recirculation (R-EGR) configuration to achieve RCCI combustion using a light-duty diesel engine. The engine was operated at a low engine load and two reformed fuel percentages over ranges of exhaust gas recirculation (EGR) rate and main diesel fuel injection timing. Results show that RCCI-like emissions of NOx and soot were achieved load using the R-EGR configuration. It was also shown that complete fuel conversion in the reforming reactor is not necessary to achieve sufficiently low fuel reactivity for RCCI combustion. Overall
Improvement of thermal efficiency is an important problem for internal combustion engines. Fuel reforming with dehydrogenation reaction by exhaust heat is one of the measures to increase thermal efficiency using hydrogen mixed SI combustion. For this kind engine system, hydrous ethanol has a good potential. Furthermore, when the hydrous ethanol inject to combustion chamber directory, high compression combustion can be achieved by its large amount of latent heat. Therefore, fuel lubricity is an important check point for the hydrous ethanol reforming engine systems. In this study, effect of water concentrations within ethanol on the hydrous ethanol fuel lubricity has been evaluated using HFRR (High-Frequency Reciprocating Rig) test method. Wear scar diameter on 100 % of ethanol was around 700 μm which was a little better than gasoline lubricity. When the water concentration within ethanol was increased, the wear scar diameters were decreasing around 330 μm. Considering this phenomenon by
In-cylinder thermochemical fuel reforming (TFR), which involves running one cylinder rich of stoichiometric and routing its entire exhaust back into the intake manifold, is an attractive method for improving engine performances. Compared with other hydrocarbon fuels, the chemical structure of methane is more stable owing to much shorter carbon chain. As ethanol contains hydroxyl in chemical structure, it potentially generates OH radical during the combustion. Therefore, adding ethanol into natural gas (NG) might help the thermochemical reforming process in engine cylinder. This paper focused on researching the effects of ethanol-NG combined in-cylinder TFR on engine performances, before which the effect of NG in-cylinder TFR was examined in detail. Cylinder #4 (TFR cylinder) was running rich and its cooled exhaust was coupled to the intake manifold of a four-cylinder engine during the experiments. For NG in-cylinder TFR, a rapid decrease of brake specific fuel consumption was found
Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity. Additionally, a gasoline surrogate matching the broad molecular composition of RD587
Gasoline direct injection (GDI) engines have become very attractive in transportation due to several benefits over preceding engine technologies. However, GDI engines are associated with higher levels of particulate matter (PM) emissions, which is a major concern for human health. The aim of this work is to broaden the understanding of the effect of hydrogen combustion and the influence of the three way catalytic converter (TWC) on PM emission characteristics. The presence of hydrogen in GDI engines has been reported to reduce fuel consumption and improve the combustion process, making it possible to induce higher rates of EGR. A prototype exhaust fuel reformer build for on-board vehicle hydrogen-rich gas (reformate) production has been integrated within the engine operation and studied in this work. It is concluded that benefits on engine out soot emissions from the combustion of the reformate-gas are more noticeable in the engine operation conditions with a higher concentration of
A fuel reformer system that uses a steam reforming reaction in the exhaust gas recirculation (EGR) line with a catalyst was earlier proposed.(1) An analysis of engine test results revealed that not only hydrogen (H2) but also a H2 rich reformate additive in the air-fuel mixture was effective in suppressing knocking. To improve fuel economy via a high compression ratio, the knock limit is extended through the addition of H2 with its high octane number. In order to produce H2 on-board, we have proposed a fuel reformer for which the additions to the engine are an injector and a catalyst in the existing cooled EGR system. This method produces thicker H2 gas from gasoline by using heat and water vapor in the exhaust gas. The reformate mainly consists of H2, CO and CH4. The results of a previous study showed that hydrogen's high-speed flame had the effect of extending the EGR limit and that the reformate components besides hydrogen did not inhibit this effect.(1) Because the fuel has a
On-board hydrogen generation technology using a fuel reforming catalyst is an effective way to improve the fuel efficiency of automotive internal combustion engines. The main issue to be addressed in developing such a catalyst is to suppress catalyst deterioration caused by carbon deposition on the catalyst surface due to sulfur adsorption. Enhancing the hydrocarbon and water activation capabilities of the catalyst is important in improving catalyst durability. It was found that the use of a rare earth element is effective in improving the water activation capability of the catalyst. Controlling the hydrocarbon activation capability of the catalyst for a good balance with water activation was also found to be effective in improving catalyst durability
Negative valve overlap (NVO) is a viable control strategy that enables low-temperature gasoline combustion (LTGC) at low loads. Thermal effects of NVO fueling on main combustion are well understood, but fuel reforming chemistry during NVO has not been extensively studied. The objective of this work is to analyze the impact of global equivalence ratio and available oxidizer on NVO product concentrations. Experiments were performed in a LTGC single-cylinder engine under a sweep of NVO oxygen concentration and NVO fueling rates. Gas sampling at the start and end of the NVO period was performed via a custom dump-valve apparatus with detailed sample speciation by gas chromatography. Single-zone reactor models using detailed chemistry at relevant mixing and thermodynamic conditions were used in parallel to the experiments to evaluate expected yields of partially oxidized species under representative engine time scales. Modeling efforts help identify physical mechanisms that further describe
In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts
To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance. Fresh catalyst showed good performance in generating hydrogen, but an aged catalyst generated
To explore the exergy loss of engine combustion process, entropy generations were numerically analyzed through detailed chemical kinetics. It revealed that the reformed fuel with simpler molecular tended to produce lower combustion irreversibility. Furthermore, a promising high efficiency RM- HCCI (Reformed molecule HCCI) combustion principle was proposed. In a RM-HCCI engine, hydrocarbon fuels were reformed into small molecule fuels under high temperature and low/no oxygen atmosphere before injection into the cylinder when the exhaust gas enthalpy to a certain extent was recovered, further improving the engine efficiency. The second law efficiency (η2nd) of a RM-HCCI combustion with a CR of 10 can be increased from 36.78% to 45.47% by coordination of multiple control parameters, and to 67.79% by raising CR from 10 to 100. The RM-HCCI has many advantages: (1) less exergy losses during combustion processes, (2) longer ignition delays and shorter but controlled combustion durations, (3
Southwest Research Institute (SwRI) converted a 2012 Buick Regal GS to use an engine with Dedicated EGR™ (D-EGR™). D-EGR is an engine concept that uses fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency [1]. To accomplish reformation of the gasoline in a cost-effective, energy efficient manner, a dedicated cylinder is used for both the production of EGR and reformate. By operating the engine in this manner, many of the sources of losses from traditional reforming technology are eliminated and the engine can take full advantage of the benefits of reformate. The engine in the vehicle was modified to add the following components: the dedicated EGR loop, an additional injector for delivering extra fuel for reformation, a modified boost system that included a supercharger, high energy dual coil offset (DCO) ignition and other actuators used to enable the control of D-EGR combustion. In addition, the compression ratio of the
Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) and other forms of advanced combustion. When fuel is injected into O2-deficient NVO conditions, a portion of the fuel can be converted to products containing significant levels of H2 and CO. Additionally, other short chain hydrocarbons are produced by means of thermal cracking, water-gas shift, and partial oxidation reactions. The present study experimentally investigates the fuel reforming chemistry that occurs during NVO. To this end, two very different experimental facilities are utilized and their results are compared. One facility is located at Oak Ridge National Laboratory, which uses a custom research engine cycle developed to isolate the NVO event from main combustion, allowing a steady stream of NVO reformate to be exhausted from the engine and chemically analyzed. The other experimental facility, located at Sandia
The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity. The passive SCR significantly contributes to the total NOX conversion over a
Exhaust Gas Fuel Reforming has potential to be used for on-board generation of hydrogen rich gas, reformate, and to act as an energy recovery system allowing the capture of waste exhaust heat. High exhaust gas temperature drives endothermic reforming reactions that convert hydrocarbon fuel into gaseous fuel when combined with exhaust gas over a catalyst - the result is an increase in overall fuel energy that is proportional to waste energy capture. The paper demonstrates how the combustion of reformate in a direct injection gasoline (GDI) engine via Reformed Exhaust Gas Recirculation (REGR) can be beneficial to engine performance and emissions. Bottled reformate was inducted into a single cylinder GDI engine at a range of engine loads to compare REGR to conventional EGR. The reformate composition was selected to approximate reformate produced by exhaust gas fuel reforming at typical gasoline engine exhaust temperatures. The decision was guided by data from experimental work carried out
A study on the overall performance of an engine powered with hydrogen-enriched NG at stoichiometric condition, for different hydrogen shares have been described in this paper. The research has been carried on a General Motors Company X16SZR 4-cylinder, 4-stroke 1600 cm3 engine. Engine dynamometer tests were complemented with mathematical model calculations. Tested engine has been equipped with an aftermarket CNG feeding system where fuel is being injected into intake manifold simultaneously under low overpressure. Research program provided analysis for fuel blends with variable methane/hydrogen volume proportion (%): 100/0, 95/5, 90/10, 85/15, 80/20, 70/30, 60/40 and 50/50. Ignition timing and all other strategies, excluding EGR, remained unvaried. Testing procedure provided three different steady-state engine operation points for each of 8 different fuels: idle, high speed without load and full power at speeds in range of 1500-3500 rpm. The main aspect of the analysis was to identify
The nonroad Final Tier 4 US EPA emission standards require 88% reduction in NOx emission from the Interim Tier 4 standards. It is necessary to utilize aftertreatment technologies to achieve the required NOx reduction. The development of a fuel reformer, lean NOx trap (LNT) and optional selective catalytic reactor (SCR) on a John Deere 4045 nonroad engine is described in this paper. The paper discusses aftertreatment system performance, catalyst formulations and system controls of a fuel vaporizer, fuel reformer, LNT and SCR system designed to meet the nonroad Final Tier 4 emission standards. The 4045 John Deere engine was calibrated and integrated with the aftertreatment system. The system performance was characterized in an engine dynamometer performance test cell, durability test cell and on a vehicle. The catalyst performance was evaluated using aged catalysts and a detailed description of the LNT, DPF and SCR catalysts is provided. Test results show that the system performance met
This paper presents an analysis of combustion phasing in a controlled auto-ignition (CAI) engine fuelled with gasoline. Auto-ignition was achieved using an exhaust gas trapping method via negative valve overlap (NVO). Under slightly lean mixture conditions variable intake and exhaust valves timings were applied in order to analyze influence of amount of retained exhaust on auto-ignition timing and combustion duration. Combustion on-set was independent of exhaust valve closing event, which was responsible for amount of trapped residuals. However, it was found that auto-ignition timing was determined by intake valve timing. Combustion duration was affected by both exhaust and intake valve timings. Direct injection allowed for application of different mixture formation strategies including in-cylinder fuel reforming during the NVO phase. When fuel was injected in the late stage of NVO increase of air-fuel ratio (AFR) caused a retard of auto-ignition and reduction of heat release rate. In
Items per page:
50
1 – 50 of 161