Browse Topic: Microscopy
g-C₃N₄, a metal-free semiconductor photocatalyst, demonstrates remarkable potential, but its practical application in pollutant degradation is significantly limited by the rapid recombination of photogenerated electron-hole pairs and low photocatalytic efficiency. To address this, a series of magnetic recyclable g-C₃N₄/CoFe₂O₄ composite photocatalysts with different CoFe₂O₄ doping ratios were innovatively designed and prepared via thermal polymerization, sol- gel, and combined with ultrasonic and heat treatment processes. The novelty of this composite design lies in the effective integration of magnetic CoFe₂O₄ with g-C₃N₄ through a heterojunction structure. It substantially boosts the absorption of visible light. Concurrently, it effectively fosters the separation and mobility of photo-induced charge carriers. The composite materials were systematically characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, photoluminescence spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy. Using tetracycline hydrochloride as the target pollutant, the photocatalytic activity of the composites was evaluated under visible light irradiation, and the effects of initial concentration, catalyst dosage, and the influence of solution pH on degradation efficiency were also examined. The results indicated that the composite with a CoFe₂O₄ to g-C₃N₄ mass ratio of 1:3 (denoted as 3-CN/CFO) exhibited the optimal performance: a TCH degradation rate of 80.29 % within 105 minutes and a total organic carbon removal rate of 61.63 %. After five consecutive cycling experiments, the degradation efficiency remained above 70 %, demonstrating good reusability and stability. The performance improvement is attributed to the formation of heterojunctions in the composite, which effectively facilitates charge separation, inhibits carrier recombination, and enhances visible light absorption. Furthermore, the inherent magnetism of the composite permits efficient recovery, streamlining its integration into practical applications. Toward the purification of antibiotic-contaminated water, this research proposes a viable method for fabricating highly effective and recyclable photocatalysts.
Under a microscope, a bouquet of lollipop-like structures, each smaller than a grain of sand, waves gently in a petri dish of liquid. Suddenly, they snap together, like the jaws of a Venus flytrap, as a scientist waves a small magnet over the dish. What was previously an assemblage of tiny passive structures has transformed instantly into an active robotic gripper.
The Army requires rotorcraft drive systems to operate for 30 minutes following a loss of lubrication event to make an emergency landing. Coatings research has shown great promise for loss of lubrication, but coating repeatability and quality control is a primary hurdle. The Army partnered with Acree Technologies via a Small Business Innovation Research (SBIR) effort to develop an optimized gear coating for loss of lubrication. The research culminated in a system level transmission experiment that maintained flight relevant torque and speed through a helicopter gearbox without oil for three hours. The authors decided to shutdown the experiment for inspection after three hours of operation without oil because the temperature and vibration signals maintained steady state conditions without signs of failure. Teardown analysis showed the transmission gear surfaces did not scuff, scanning electron microscope analysis showed coating remained on the gear teeth, and cross-sectional SEM analysis showed a measurable coating thickness remaining on the gear teeth after three-hours of operation without oil.
Bench-level boundary-lubricated fretting experiments were conducted to compare the relative wear of all-steel and hybrid material pairs. Roller-on-raceway contacts were simulated using both AISI M50 steel and Si3N4 cylindrical rollers on flat AISI M50 steel disks. The rollers were 9 mm long with a 9 mm diameter. Tests were conducted with constant amplitude, oscillation frequency, and load. All tests were boundary-lubricated with 0.1 ml of DOD-PRF-85734, MIL-PRF-32538, MILPRF-23699, or unclassified ISO VG 68 aviation gear oil. Wear volume was calculated from 3D measurements on the roller and disk samples after each test. Wear tracks were inspected with light and scanning electron microscopy. It was concluded that hybrid pairs exhibited less wear than all-steel pairs when boundary-lubricated with three of the four aviation gear oils. Both hybrid and all-steel pairs exhibited similar wear when boundary-lubricated with MIL-PRF-23699 oil.
In a new study — the latest advance in the field of ptychography — researchers at CU Boulder have used doughnut-shaped beams of light to take detailed images of objects too tiny to view with traditional microscopes. The new technique could help scientists improve the inner workings of a range of “nanoelectronics,” including the miniature semiconductors in computer chips.
Hydrogenated nitrile butadiene rubbers (HNBR) and their derivatives have gained significant importance in automotive compressed natural gas (CNG) valve applications. In one of the four-wheelers, CNG valve application, HNBR elastomeric diaphragms are being used for their excellent sealing and pressure regulation properties. The HNBR elastomeric diaphragm was developed to sustain CNG higher pressure However, it was found permanently deformed under lower pressures. In this research work, number of experiments was carried out to find out the primary root cause of diaphragm permanent deformation and to prevent the failure for safe usage of the CNG gas. HNBR diaphragm deformation investigation was carried out using advanced qualitative and quantitative analysis methods such as Soxhlet Extraction Column, Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), Optical Microscopy (OM), Scanning Electron Microscopy (SEM), and Thermogravimetric Analysis (TGA). For this purpose, we have carried out experiments on OK (HNBR diaphragm with higher bar pressure) and field-failed diaphragms (HNBR diaphragm deformed after lower bar CNG pressure). We have found that OK and Field failed diaphragms have different filler concentrations and uneven dispersion and distribution. Also, the crosslinking density of the failed Field diaphragms was observed in declining order in comparison with the OK diaphragms. TGA and SEM analysis revealed the filler concentration and morphology of the diaphragms. The chemical nature and thermal properties have been analysed using FTIR and DSC analysis techniques. The Soxhlation extractions study helped to understand the crosslinking density of OK and field failure diaphragms. Preventive measures have been implemented to mitigate the HNBR diaphragm permanent deformation issue.
To meet the need for better 3D imaging that works during live surgery, researchers recently developed a new kind of surgical microscope called the Fourier light-field multiview stereoscope, known as FiLM-Scope.
Innovators at NASA Johnson Space Center have developed a handheld digital microscope to fill the critical microscopy needs of human space exploration by providing flight crews in situ hematological diagnostic and tracking ability to assess and monitor crew health in the absence of gravity. Although currently in use aboard the International Space Station (ISS) to work in conjunction with NASA’s handheld slide staining system, the microscope may have numerous applications here on Earth.
A novel sintering method of bridging the two mechanically polished and oriented single-crystals together face-to-face in a non- environmental controlled atmosphere to fabricate the bicrystal substrate of NaCl of macroscopic thickness, with a common zone axis and having planarity over large areas, has been developed. Epitaxial [001] bicrystalline thin face-centered cubic (fcc) metal film of surface-reactive metal-containing tilt grain boundary across the interface is first grown in high vacuum directly by flash deposition on initially fabricated [001] oriented bicrystalline substrate of NaCl. The [001] tilt boundary, thus produced, and is examined by electron microscopy to characterize grain boundary morphology and structure. The findings of some preliminary investigations are then presented. A distinct atomic structure is observed for 310 and 210 inclination. Both HAADF-STEM and Diffraction images reveal that such fabricated high-angle grain boundary accommodates minor deviations from the exact high coincidence density ∑=5 misorientation. The potential use of the present technique is extended to produce a wide variety of homophase bicrystals, containing grain boundaries at the midplane, normal to any crystallographic surface without the necessity of a separate bonding operation.
The solar-based hybrid automotive vehicle represents a trend marked by technological excellence, offering an efficient, cost-effective, and eco-friendly solution. Besides, the enhancement of solar absorption due to poor weather is influenced by poor solar power with reduced photocurrent density. This research focuses on enhancing the solar power and photocurrent density of conventional solar cells featuring aluminium-doped zinc oxide thin films (AZO) using the Mist Chemical Vapor Deposition (MIST CVD) process with a zinc acetate precursor solution processed at temperatures ranging from 200 to 400°C. To investigate the effect of AZO on the functional behaviour of solar cells, microstructural studies utilizing scanning electron microscopy and X-ray diffraction reveal the concentration of AZO and the alignment of Al/ZnO peaks as even. As a result, this research demonstrates a 21% increase in solar power output compared to conventional Cadmium Telluride (CdTe) cells, with an improvement in photocurrent density of 1.24 mA/cm2. This advanced solar cell technology is recommended for use in electric vehicle (EV) applications.
Fused deposition modeling (FDM) is a rapidly growing additive manufacturing method employed for printing fiber-reinforced polymer composites. Nonetheless, the performance of printed parts is often constrained by inherent defects. This study investigates how the varying annealing parameter affects the tribological properties of FDM-produced polypropylene carbon fiber composites. The composite pin specimens were created in a standard size of 35 mm height and 12 mm diameter, based on the specifications of the tribometer pin holder. The impact of high-temperature annealing process parameters are explored, specifically annealing temperature and duration, while maintaining a fixed cooling rate. Two set of printed samples were taken for post-annealing at temperature of 85°C for 60 and 90 min, respectively. The tribological properties were evaluated using a dry pin-on-disc setup and examined both pre- (as-built) and post-annealing at temperature of 85°C for 60 and 90 min printed samples. Tribological tests were conducted under varying normal loads (5, 10, 15, and 20 N) and sliding velocities (1 and 3 m/s), following the ASTM G99 standard test procedure. Significantly notable enhancements in wear and friction properties were consistently observed across all tribometer test conditions when the composites underwent annealing at 85°C for 60 min, surpassing the performance of other samples. These particular samples, subjected to the 85°C/60-min annealing process, exhibited elevated hardness, diminished wear rates, and reduced coefficients of friction (COF). A detailed examination using a scanning electron microscope revealed that the wear mechanism on the surface of the tribometer-tested samples exhibited milder wear when carbon fiber was added, followed by annealing at 85°C for 60 min, compared to the 90-min annealing. These promising results suggest that the proposed composites have potential applications in industries such as prosthetics, aerospace, and automobiles.
A classical way to image nanoscale structures in cells is with high-powered, expensive super-resolution microscopes. As an alternative, MIT researchers have developed a way to expand tissue before imaging it — a technique that allows them to achieve nanoscale resolution with a conventional light microscope.
The development of advanced high-strength steels has become essential in the production of lightweight, safe, and more economical vehicles within the context of the automotive industry. Among the advanced high-strength steels, complex phase steels stand out, characterized by their high formability and high energy absorption and deformation capacity. Laser welding is a technique that applies laser using high energy density as a heat source. It has the advantages that the high welding speed and low heat input compared to other welding methods cause a decrease in deformation, and the narrow width of the weld bead and heat-affected zone allows for the welding of complex parts that would be difficult for other welding methods. Based on a study of a complex phase steel, an analysis was made of the microstructures observed by optical microscopy, the grain boundaries and certain phases contained in this microstructure, as well as the microstructures of each area in the laser welding region observed by scanning electron microscopy. Presenting as results the microstructures of the welded region, such as martensite and bainite phases are the dark phases and retained austenite and ferrite phases are the light phases.
Lithium iron phosphate is one of the most important materials for batteries in electric cars, stationary energy storage systems, and tools. It has a long service life, is comparatively inexpensive and does not tend to spontaneously combust. Energy density is also making progress. However, experts are still puzzled as to why lithium iron phosphate batteries undercut their theoretical electricity storage capacity by up to 25 percent in practice. To utilize this dormant capacity reserve, it would be crucial to know exactly where and how lithium ions are stored in and released from the battery material during the charging and discharging cycles. Researchers at Graz University of Technology (TU Graz) have now taken a significant step in this direction. Using transmission electron microscopes, they were able to systematically track the lithium ions as they traveled through the battery material, map their arrangement in the crystal lattice of an iron phosphate cathode with unprecedented resolution, and precisely quantify their distribution in the crystal.
Anode-free sodium metal batteries (AFSMBs) with initial zero sodium anodes are promising energy-storage devices to achieve high energy density and low cost. The morphology and reversibility of sodium controls the cycling lifespan of the AFSMBs, which is directly affected by the separator. Here, we compared the sodium deposition and corresponding electrochemical behaviors under the influence of three commercial separators, which were Celgard 2500, Al2O3-coated PP separator and glass fiber (denoting as 2500, C-PP and GF). Firstly, the reversibility of sodium plating/stripping was tested using half-cells, where coulombic efficiencies were stable at ~99.89% for C-PP and GF compare to 99.65% for 2500, indicating more dead sodium were formed for 2500. Then, the morphologies of deposited sodium were compared using optical microscopy. Compared to inhomogeneous sodium growth under 2500, C-PP obtained more flatter sodium layer with less height difference, attributing to the high mechanical strength of Al2O3 layer. Differently, we discovered that sodium was grown into pores in GF to form sodium particles with large active surface, which contacts with sufficient electrolytes and could be reversibly stripped. The reversibility of the sodium in GF were further verified using in situ X-ray diffraction tests. Accordingly, cycling performance of AFSMBs were improved using C-PP and GF, where capacity retention after 120 cycles were 56.9%, 61.6% and 69.2% for 2500, C-PP and GF, respectively. Moreover, the AFSMB using 2 mAh cm-2 Na[Ni1/3Fe1/3Mn1/3]O2 as cathode with GF exhibiting excellent capacity of 117.61 mAh g-1 under high current density of 1 C. Subsequently, in situ EIS tests after/during charging/discharging process were further conducted to illustrate the enhancement of rate and cycling performance. This work demonstrates the effect of separators on the sodium deposition for higher irreversibility and stability, which could also offer insights for developing advanced separators to achieve high performance AFSMBs.
Researchers at the National Institute of Standards and Technology (NIST) and colleagues have developed standards and calibrations for optical microscopes that allow quantum dots to be aligned with the center of a photonic component to within an error of 10 to 20 nanometers (about one-thousandth the thickness of a sheet of paper). Such alignment is critical for chip-scale devices that employ the radiation emitted by quantum dots to store and transmit quantum information.
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