Browse Topic: Electrolytes
The intention of this exploration is to evolve an optimization method for the Electrochemical Machining (ECM) process on Haste alloy material, taking into account various performance characteristics. The optimization relies on the amalgamation of the Taguchi method with an Adaptive Neuro-Fuzzy Inference System (ANFIS). Haste alloy is extensively utilized in the aerospace, nuclear, marine, and car sectors, specifically in situations that are prone to corrosion. The experimental trials are organized based on Taguchi's principles and involve three machining variables: feed rate, electrolyte flow rate, and electrolyte concentration. This examination examines performance indicators, including the pace at which material is removed and the roughness of the surface. It also includes geometric factors such as overcut, shape, and tolerance for orientation. The results suggest that the rate at which the feed is supplied is the most influential element affecting the necessary performance standards
The aspiration of this exploration is to evolve an optimization technique for the Electrochemical Drilling process on Haste alloy material, considering various performance factors. The Taguchi approach, along with Grey Relational Analysis (GRA), forms the basis for optimization. Haste alloy has a wider range of uses in industries such as aerospace, nuclear, and marine, especially in harsh environments. The experimental trials conducted in accordance with Taguchi's approach have utilized three machining variables: feed rate, electrolyte flow rate, and electrolyte concentration. When doing this examination, we analyze not only the rate at which material is removed and the roughness of the surface, but also other characteristics that indicate performance, such as overcut, shape, and orientation tolerance. The analytical findings indicate that the feed rate is the primary factor that directly impacts the required performance standards. Regression models are constructed to make predictions
The aim of this study is to create an Adaptive Neuro-Fuzzy Inference System (ANFIS) model for the Electrochemical Machining (ECM) process using Nimonic Alloy material, with a specific focus on several performance aspects. The optimization strategy utilizes the combination of the Taguchi method and ANFIS integration. Nimonic Alloy is widely employed in the aerospace, nuclear, marine, and car sectors, especially in situations that are susceptible to corrosion. The experimental trials are designed according to Taguchi's method and involve three machining variables: feed rate, electrolyte flow rate, and electrolyte concentration. This study investigates performance indicators, such as the rate at which material is removed, the roughness of the surface, and geometric characteristics, including overcut, shape, and tolerance for orientation. Based on the analysis, it has been determined that the feed rate is the main component that influences the intended performance criteria. In order to
The objective of this research is to develop an optimization strategy for the Electrochemical Drilling process on Nimonic alloy material, taking into account various performance factors. The optimization strategy relies on the integration of the Taguchi method with Grey Relational Analysis (GRA). Nimonic is extensively utilized in aerospace, nuclear, and marine industries, specifically in situations that are prone to corrosion. The experimental trials are structured based on Taguchi's principle and encompass three machining variables: feed rate, electrolyte flow rate, and electrolyte concentration. This inquiry examines performance indicators like the rate of material removal, surface roughness, as well as geometric parameters such as overcut, shape, and orientation tolerance. Based on the investigation, it is determined that the feed rate is the primary factor that directly affects the intended performance criteria. In order to enhance the accuracy of predictions, multiple regression
Existing commercial battery technologies, which use liquid electrolytes and carbonaceous anodes, have certain drawbacks such as safety concerns, limited lifespan, and inadequate power density particularly at high temperatures. This has prompted researchers to search for solid electrolytes that are safe and compatible with lithium metal anodes, which are known for their high theoretical specific power capacity.
Anode-free sodium metal batteries (AFSMBs) with initial zero sodium anodes are promising energy-storage devices to achieve high energy density and low cost. The morphology and reversibility of sodium controls the cycling lifespan of the AFSMBs, which is directly affected by the separator. Here, we compared the sodium deposition and corresponding electrochemical behaviors under the influence of three commercial separators, which were Celgard 2500, Al2O3-coated PP separator and glass fiber (denoting as 2500, C-PP and GF). Firstly, the reversibility of sodium plating/stripping was tested using half-cells, where coulombic efficiencies were stable at ~99.89% for C-PP and GF compare to 99.65% for 2500, indicating more dead sodium were formed for 2500. Then, the morphologies of deposited sodium were compared using optical microscopy. Compared to inhomogeneous sodium growth under 2500, C-PP obtained more flatter sodium layer with less height difference, attributing to the high mechanical
Dr. Park Jun-woo of the Korea Electrotechnology Research Institute (KERI) Next-Generation Battery Research Center and Sung Junghwan, student researcher at the UST KERI Campus, have successfully engineered a technology focused on the “size-controlled wet-chemical synthesis of solid-state electrolytes (sulfide superionic conductors).” It not only cuts the processing time and cost by over fifty percent but also doubles the resultant quality.
A team from Lawrence Berkeley National Laboratory (Berkeley Lab) and Florida State University has designed a new blueprint for solid-state batteries that are less dependent on specific chemical elements, particularly critical metals that are challenging to source due to supply chain issues. Their work could advance solid-state batteries that are efficient and affordable.
ABSTRACT Cornerstone Research Group (CRG) developed a lithium metal (Li-metal) battery cell for military applications. Utilizing a Li-metal anode, high energy density cathode, and an advanced low-temperature fluorinated electrolyte, the cell was designed and developed to provide high-power and low temperature capabilities. The 1.5 Ah Li-metal pouch cell had a specific energy of 247 Wh/kg and was able to discharge at ultra-low temperatures (-57 °C). Moreover, the Li-metal cell demonstrated extremely high-power by fully discharging at 10 C while maintaining over 70% its initial capacity. To demonstrate the Li-metal cell’s utility for military vehicle use, CRG modeled the cell into the 6T battery platform. A novel module housing was designed to evenly apply compression to the Li-metal cells to improve cell performance. Based on these projections, the Li-metal 6T battery could have a capacity of 163 Ah with a specific energy of 179 Wh/kg. Citation: J. Hondred, F. Zalar, P. Nikolaev, B
Development of all-solid-state batteries is crucial to achieve carbon neutrality. However, their high surface resistance causes these batteries to have low output, limiting their applications. To this end, researchers have employed a novel technique to investigate and modulate electric double layer dynamics at the solid/solid electrolyte interface. The researchers demonstrate unprecedented control of response speed by over two orders of magnitude, a major steppingstone towards realization of commercial all-solid-state batteries.
By the end of 2023 there will be 10 Chinese electric passenger vehicles using advanced semi-solid-state batteries (ASSB) - an industry-first application for EVs and a milestone for vehicle electrification, according to Paul Haelterman, North American VP at Autodatas, a vehicle benchmarking and research firm. It's “a huge step for the industry's production pursuit of all-solid-state batteries,” Haelterman told SAE Media ahead of his presentation on China's EV market at SAE's WCX 2023 conference in Detroit. A semi-solid-state battery can be one in which one electrode does not contain a liquid electrolyte and the other electrode does. Or it can be a battery in which the mass or volume of the solid electrolyte in the monomer accounts for half of the total mass or volume of the electrolyte in the monomer. Some battery experts view semi-solid-state as a compromise technology, offering a faster route to scale, but is heavy and requires more volume.
Start-up battery developer Factorial Energy's workforce of engineers, chemists and other technology specialists has topped 100 with recent hirings in the Asia-Pacific region. A pilot manufacturing plant for the firm's solid-state lithium-metal batteries is slated to launch later this year. And, Hyundai Motor Co., Stellantis and Mercedes-Benz have invested in the Woburn, Massachusetts-based company and its proprietary Factorial Electrolyte System Technology, trademarked FEST. CEO Siyu Huang recently spoke with SAE Media's Kami Buchholz. Condensed highlights of the interview:
Researchers have devised a tiny, nano-sized sensor capable of detecting protein biomarkers in a sample at single-molecule precision. Coined as hook and bait, a tiny protein binder fuses to a small hole created in the membrane of a cell — known as a nanopore — which allows ionic solution to flow through it.
Solid-state lithium-ion batteries that use a solid electrolyte may potentially operate at wide temperatures and provide satisfactory safety. Moreover, the use of a solid electrolyte, which blocks the formation of lithium dendrites, allows batteries to use metallic lithium for the anode, enabling the batteries gain an energy density significantly higher than that of traditional lithium-ion batteries. Solid electrolytes play a role of conducting lithium ions and are the core of solid-state lithium-ion batteries. However, the development of solid lithium electrolytes towards a high lithium ionic conductivity, good chemical and electrochemical stability and scalable manufacturing method has been challenging. We report a new material composed of nitrogen-doped lithium metaphosphate, denoted as NLiPO3. The material delivers a lithium ionic conductivity on the order of 10-4 S/cm at room temperature, which is about two orders of magnitude higher than that of conventional LiPON – the
Accelerating demand for renewable energy and electric vehicles is sparking a high demand for the batteries that store generated energy and power engines. But the batteries behind these sustainability solutions aren’t always sustainable themselves. In a paper published in the journal Matter, scientists created a zinc battery with a biodegradable electrolyte from an unexpected source — crab shells.
Lithium-ion (Li-ion) batteries are one of the most used batteries that support modern ITC society, including smartphones and EVs. These batteries are repeatedly charged and discharged by Li-ions passing back and forth between the positive and negative electrodes, with the Li-ion electrolyte acting as a passageway for the ions.
Redox flow batteries are stationary batteries in which the energy is located in the electrolyte, outside of the cell itself, as in a fuel cell. They are often marketed with the prefix “eco” since they open the possibility of storing excess energy from, for example, the Sun and wind. It appears that they can be recharged an unlimited number of times; however, redox flow batteries often contain vanadium, a scarce and expensive metal. The electrolyte in which energy is stored in a redox flow battery can be water-based, which makes the battery safe to use but results in a lower energy density.
Researchers at NASA’s Jet Propulsion Laboratory (JPL) are developing a novel microthruster that could provide easy-to-control propulsion during spaceflight. Using solid silver as the fuel source, this innovative microthruster provides thrust via electrospray without heating the fuel reservoir or transporting liquid metals. Instead of transporting a molten metal, this design transports metal ions via a solid electrolyte film.
Engineers at the University of California San Diego have developed lithium-ion batteries that perform well at freezing cold and scorching hot temperatures, while packing a lot of energy. The researchers accomplished this feat by developing an electrolyte that is not only versatile and robust throughout a wide temperature range, but also compatible with a high energy anode and cathode.
Researchers have developed new polymer electrolytes for redox flow batteries that are flexible, efficient, and environmentally friendly.
Engineers at the University of California San Diego have developed lithium-ion batteries that perform well at freezing cold and scorching hot temperatures, while packing a lot of energy. The researchers accomplished this feat by developing an electrolyte that is not only versatile and robust throughout a wide temperature range, but also compatible with a high energy anode and cathode.
A team of researchers led by chemists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory has learned that an electrolyte additive allows stable high-voltage cycling of nickel-rich layered cathodes. Their work could lead to improvements in the energy density of lithium batteries that power electric vehicles.
The element niobium (Nb), a transition metal, stands ready to improve the performance of one of the lithium-ion (Li-ion) battery’s confusing array of possible electrode chemistries — the LTO (lithium titanium oxide) anode, which after graphite is the second most-produced. During battery charging, lithium ions leave the positive cathode and move through the battery’s electrolyte to take up positions of higher energy in the anode. During discharge, this process reverses and drives electrons through an external circuit to power the load.
Currently the preferred technology to power electric vehicles, lithium-ion (Li-ion) batteries, has become too expensive for long-duration grid-scale energy storage systems — not to mention that lithium itself is becoming more and more elusive.
Researchers from the University of Waterloo, Canada, who are members of the Joint Center for Energy Storage Research (JCESR), headquartered at the U.S. Department of Energy's (DOE) Argonne National Laboratory, have discovered a new solid electrolyte that offers several important advantages.
Among the limitations of electric vehicles (EVs) is the lack of a long-lasting, high-energy-density battery that reduces the need to fuel up on long-haul trips. The same is true for houses during blackouts and power grid failures— small, efficient batteries able to power a home for more than one night without electricity don’t yet exist. A major issue is that while rechargeable lithium metal anodes play a key role in how well this new wave of lithium batteries functions, during battery operation, they are highly susceptible to the growth of dendrites — microstructures that can lead to dangerous short-circuiting, catching on fire, and even exploding.
Lithium-ion batteries now in widespread use for everything from mobile electronics to electric vehicles rely on a liquid electrolyte to carry ions back and forth between electrodes within the battery during charge and discharge cycles. The liquid uniformly coats the electrodes, allowing free movement of the ions.
As researchers push the boundaries of battery design, seeking to pack ever greater amounts of power and energy into a given amount of space or weight, one of the more promising technologies being studied is lithium-ion batteries that use a solid electrolyte material between the two electrodes, rather than the typical liquid. But such batteries have been plagued by a tendency for branch-like projections of metal called dendrites to form on one of the electrodes, eventually bridging the electrolyte and shorting out the battery cell.
Lithium-ion batteries are critical for modern life, powering laptops, cellphones, and other devices; however, there is a safety risk — the batteries can catch fire. Zinc-based aqueous batteries avoid the fire hazard by using a water-based electrolyte instead of the conventional chemical solvent. But uncontrolled dendrite growth limits their ability to provide the high performance and long life needed for practical applications.
Single-use diagnostic tests often aren’t practical for health professionals or patients in resource-limited areas, where cost and waste disposal are big concerns. So, researchers reporting in ACS Applied Materials & Interfaces have turned to a surprising material, Tootsie Roll® candy, to develop an inexpensive and low-waste device. The candy was used as an electrode, the part of the sensor that detects salt and electrolyte levels in saliva, to monitor ovulation status or kidney health.
Lithium-metal batteries hold almost twice the energy of their widely used lithium-ion counterparts and they’re lighter. That combination offers the prospect of an electric vehicle that would be lighter and go much farther on a single charge. But lithium-metal batteries in the laboratory have been plagued by premature death, lasting only a fraction of the time of today’s lithium-ion batteries.
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