Browse Topic: Three-way catalysts

Items (811)
The gasoline particulate filter (GPF) represents a durable solution for particulate emissions control in light-duty gasoline-fueled vehicles. It is also seen as a viable technology in North America to meet the upcoming US EPA tailpipe emission regulation, the proposed “Multipollutant Rule for Model Year 2027”. The goal of this study was to track the evolution of tailpipe particulate emissions of a modern GTDI light duty vehicle under typical North American mileage accumulation; from a fresh state to 4000-mile, and finally to its full useful life of 150,000-miles. For this purpose, a production TWC + GPF after-treatment system was installed in place of the T3B85 TWC-only system. Chassis dyno emissions testing was performed at the pre-determined mileage points with on-road driving conducted for the necessary mileage accumulation. This report will show the outstanding filtration durability and enhanced particulate control and of the current GPF technology all the way to 150,000 miles for
Craig, AngusWarkins, JasonBeattie, JamesNipunage, SanketMoser, DavidDay, RyanBanker, Vonda
Decarbonization and a continuous reduction in exhaust emissions from combustion engines are key objectives in the further development of modern powertrains. In order to address both aspects, the DE4LoRa research project is developing an innovative hybrid powertrain that is characterized by the highly flexible combination of two electric motors with a monovalent compressed natural gas (CNG) engine. This approach enables highly efficient driving in purely electric, parallel and serial operating modes. The use of synthetic CNG alone leads to a significant reduction in CO2 emissions and thus in the climate impact of the drivetrain. With CNG-powered engines in particular, however, methane and other tailpipe emissions of climate gases and pollutants must also be minimized. This is possible in particular through efficient exhaust gas aftertreatment and an effective operating strategy of the powertrain. This publication presents measurement results that examine the critical aspect of cold
Noone, PatrickHerold, TimBeidl, Christian
The target of the upcoming automotive emission regulations is to promote a fast transition to near-zero emission vehicles. As such, the range of ambient and operating conditions tested in the homologation cycles is broadening. In this context, the proposed work aims to thoroughly investigate the potential of post-oxidation phenomena in reducing the light-off time of a conventional three-way catalyst. The study is carried out on a turbocharged four-cylinder gasoline engine by means of experimental and numerical activities. Post oxidation is achieved through the oxidation of unburned fuel in the exhaust line, exploiting a rich combustion and a secondary air injection dedicated strategy. The CFD methodology consists of two different approaches: the former relies on a full-engine mesh, the latter on a detailed analysis of the chemical reactions occurring in the exhaust line. The coupling between experimental data and simulation results provides a complete assessment of the investigated
Barillari, LorisPipolo, MarioDella Torre, AugustoMontenegro, GianlucaOnorati, AngeloVacca, AntoninoChiodi, MarcoKulzer, André
The impending emission regulations in both China (CN7) and the United States (Tier 4) are set to impose more stringent emission limits on hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx), and particulate matter (PM). CN7 places particular emphasis on reducing particulate number (PN) thresholds, while the forthcoming United States Tier 4 legislation is primarily concerned with reducing the allowable particulate matter (PM) to an assumed limit of 0.5 mg/mile. Given the more stringent constraints on both PN and PM emissions, the development of enhanced aftertreatment solutions becomes imperative to comply with these new regulatory demands. Coated Gasoline Particulate Filters (cGPFs) play a pivotal role as essential components for effective PN and PM abatement. These filters are typically deployed in one of two configurations: close-coupled to the turbocharger positioned downstream of a primary three-way catalyst (TWC) or located further downstream of the exhaust system in an
Schoenhaber, JanKawashima, ShotaGotthardt, MeikeSchühle, Johannes
Stoichiometric natural gas (CNG) engines are an attractive solution for heavy-duty vehicles considering their inherent advantage in emitting lower CO2 emissions compared to their Diesel counterparts. Additionally, their aftertreatment system can be simpler and less costly as NOx reduction is handled simultaneously with CO/HC oxidation by a Three-Way Catalyst (TWC). The conversion of methane over a TWC shows a complex behavior, significantly different than non-methane hydrocarbons in stoichiometric gasoline engines. Its performance is maximized in a narrow A/F window and is strongly affected by the lean/rich cycling frequency. Experimental and simulation results indicate that lean-mode efficiency is governed by the palladium’s oxidation state while rich conversion is governed by the gradual formation of carbonaceous compounds which temporarily deactivate the active materials. Lean/rich cycling around stoichiometry enables a higher CH4 oxidation as the oxygen storage seems to balance the
Karamitros, DimitriosIbraimova, AdjerKonstantinidis, KonstantinosKoltsakis, GrigoriosChoi, SungmuCho, Jiho
Ultra-Downsizing (UD) was introduced as an even higher level of downsizing for Internal Combustion Engines ICEs, see [2] SAE 2015-01-1252. The introduction of Ultra Downsizing (UD) aims to enhance the power, efficiency, and sustainability of ICEs while maintaining the thermal and mechanical strain within acceptable limits. The following approaches are utilized: 1 True Atkinson Cycles are implemented utilizing an asymmetrical crank mechanism called Variable Compression and Stroke Ratios (VCSR). This mechanism allows for extended expansion stroke and continuous adjustment of the Volumetric Compression Ratio (VCR). 2 Unrestricted two or more stage high-pressure turbocharging and intensive intercooling: This setup enables more complete filling of the cylinder and reduces the compression work on the piston, resulting in higher specific power and efficiency. 3 The new Load Control (LC) approach is based to continuous VCR adjustment. By adjusting the VCR without resorting to excessive
Gheorghiu, Victor
To satisfy the stringent regulations for exhaust gas emissions from gasoline-powered vehicles, large amounts of Rh and Pd have often been employed in three-way catalysts (TWCs) as the main active components. On the other hand, Pt-based TWCs are not often used in gasoline vehicles because Pt is readily sintered by its exhaust gases at approximately 1000 °C [1, 2]. In general, Pt-based TWCs must be located away from large thermal loads to maintain the active sites for gas purification. Based on this background, we previously reported that employing a small amount of CeO2 calcined at 1000 °C (cal-CeO2) in Pt-based TWCs was one of the most effective approaches for improving the catalytic activity without increasing the amount of Rh and Pd [3]. The effect of cal-CeO2 was attributed to the higher redox performance and Pt dispersion derived from the strong interactions between Ce and Pt. Therefore, the resulting Pt-based TWCs exhibited high catalytic performance, despite the low specific
Morita, ItaruTanaka, HirokiSaeki, ShoheiIsayama, AkihiroIwashina, KatsuyaNagao, YukiEndo, YoshinoriWakabayashi, TakashiHaneda, Masaaki
Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio. Through the detection of key performance parameters and
Di Maio, DarioGuido, ChiaraNapolitano, PierpaoloBeatrice, Carlo
The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover. Experimental data under fixed lambda conditions reveal that sulfur stored on the catalyst leads to
Kim, Mi-YoungDadi, Karthik VenkataGong, JianKamasamudram, Krishna
Emissions regulation continually drives the automotive industry to innovate and develop. This pushes to introduce mechanism to maintain negative crankcase pressure in gas engine to meet this changing regulation. The way a turbocharger is used, to meet engine performance, can impact the pressure balance over the compressor and turbine end seals. This pressure difference can allow oil to leak through turbocharger seals. In normal engine operating condition the pressure in the turbocharger end housings is higher than the bearing housing and oil/gas flows into the bearing housing, through the oil drain to the crankcase. Under certain operating conditions, such as low idle and motoring, this pressure difference can be reversed with a higher bearing housing pressure than the pressure behind the turbine wheel. Under this condition oil will flow out of the bearing housing to the recess behind the turbine wheel, will increase the exhaust tail pipe emission, high oil consumption and damages the
R, Mahesh Bharathi
The ever-tightening regulation norms across the world emphasize the magnitude of the air pollution problem. The decision to leapfrog from BS4 to BS6 – with further reduction in emission limits -showed India’s commitment to clean up its atmosphere. The overall cycle emissions were reduced significantly to meet BS6 targets [1]. However, the introduction of RDE norms in BS6.2 [1] demanded further reduction in emissions under real time operating conditions – start-stop, hard acceleration, idling, cold start – which was possible only through strategies that demanded a cost effective yet robust solutions. The first few seconds of the engine operation after start contribute significantly to the cycle gaseous emissions. This is because the thermal inertia of the catalytic converter restricts the rate at which temperature of the catalyst increases and achieves the desired “light-off” temperature. The challenge becomes more prominent in the turbocharged engines (where some part of exhaust heat
Kale, Vishal MarutiM, RavisankarHosur, ViswanathaSridhar, SBhimavarapu, AdityaLende, Nilesh AshokRose, DominikTao, Tinghong
Ethanol-gasoline blended fuels have been widely implemented in Indian markets followed by the Govt of India’s road map as ethanol reduces life-cycle greenhouse gas emissions and improves anti-knock performance. However, effects of Ethanol Blending on engine out emissions characteristics including particulates from gasoline direct injection (GDI) engine remains under development and investigation. In this study the effect of ethanol blended gasoline fuels with two blending rates 10% and 20% (v/v %) on catalyst conversion efficiencies and emissions on a 1.2 litre 3-cylinder turbo GDI engine is investigated. The addition of ethanol to gasoline fuel enhances the Octane rating (RON) of the blended fuels, oxygen content and changes Reid vapor pressure (RVP). The influence of lambda biasing, and lambda trim controller has been tested. The approach for calibration was adopted based on achieving the target pollutant conversion efficiencies. Test bench results indicated that with E10 blend all
R, Navaneetha KannanS, Easwar RamS, Satish KumarKarthi, RamanathanRamakrishnan, Muthu
Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion. Reaction pathways responsible for its generation are analysed and the effects of changing the following engine operational and combustion parameters are explored: engine load
Bajwa, AbdullahShankar, VarunLeach, Felix
The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines. Modern spark ignition (SI) engines typically employ various in-cylinder emission reduction techniques along with a three
Sandhu, Navjot SinghLeblanc, SimonYu, XiaoReader, GrahamZheng, Ming
The objective of this experimental investigation was to analyze the effect of various exhaust gas aftertreatment technologies on particulate number emissions (PN) of an MPFI EU5 motorcycle. Specifically, three different aftertreatment strategies were compared, including a three-way-catalyst (TWC) with LS structure as the baseline, a hybrid catalyst with a wire mesh filter, and an optimized gasoline particulate filter (GPF) with three-way catalytic coating. Experimental investigations using the standard test cycle WMTC performed on a two-wheeler chassis dynamometer, while the inhouse particulate sampling system was utilized to gather information about size-dependent filtering efficiency, storage, and combustion of nanoparticles. The particulate sampling and measuring system consist of three condensation particle counters (CPCs) calibrated to three different size classes (SPN4, SPN10, SPN23). The study revealed that all three aftertreatment technologies were effective in reducing PN from
Schurl, SebastianBonifer, MarcusSchmidt, StephanBretterklieber, NikoJoshi, Pragati
Charge dilution in gasoline engines reduces NOx emissions and wall heat losses by the lower combustion temperature. Furthermore, under part load conditions de-throttling allows the reduction of pumping losses and thus higher engine efficiency. In contrast to lean burn, charge dilution by exhaust gas recirculation (EGR) under stoichiometric combustion conditions enables the use of an effective three-way catalyst. A pre-chamber spark plug with hot surface-assisted spark ignition (HSASI) was developed at the UAS Karlsruhe to overcome the drawbacks of charge dilution, especially under part load or cold start conditions, such as inhibited ignition and slow flame speed, and to even enable a further increase of the dilution rate. The influence of the HSASI pre-chamber spark plug on the heat release under EGR dilution and stoichiometric conditions was investigated on a single-cylinder gasoline engine. The performance of the HSASI spark plug was compared with a passive pre-chamber spark plug
Holzberger, SaschaKettner, MauriceKirchberger, Roland
In this study, we determined the detailed reaction mechanism of CO/NO/O2 for automotive three way catalysts. The N2O formation process obtained from measurements of the reaction properties and the formation process of adsorbed NCO species obtained from surface analysis of platinum group metals were added to a previous detailed surface reaction mechanism. The computational accuracy of the developed reaction mechanism was verified by the one-dimensional simulation software BOOST, and it was found to be sufficient for any combination of platinum group metals and gas concentrations
Matsumoto, YuheiShimokuri, DaisukeMiyoshi, AkiraHinokuma, SatoshiMurakami, HiroshiKawano, Michiharu
A multi-functional membrane filter was developed through deposition of agglomerated Three-Way Catalyst particles with a size of 1 ~ 2 microns on the conventional bare particulate filter. The filtration efficiency reaches almost 100 % from the beginning of soot trapping with a low pressure drop and both reductions of NO and CO emission were achieved
Hanamura, KatsunoriFujii, ShinpeiTeerapat, Suteerapongpun
Three-way catalysts are used in gasoline vehicles for simultaneous purifying nitrogen oxide, carbon monoxide, and hydrocarbon in recent years. However, the reduction of ammonia emission generated in the three-way catalyst is pressing issue. In EURO 7, ammonia will also be subject to the Real Driving Emissions regulation, and its emissions must be reduced. Previous studies have shown that ammonia emissions are higher under fuel-rich conditions, suggesting that differences in driving behavior have a significant impact on ammonia emissions in real-world driving, which includes various driving environments. In this study, driving tests were conducted on a direct- injection gasoline vehicle equipped with a three-way catalyst and Portable Emission Measurement System and Sensor-based Emission Measurement System to investigate the actual ammonia emissions on actual roads. Sensor-based Emission Measurement System includes the system that can measure ammonia and nitrogen monoxide concentrations
Sato, SusumuChen, JiaxinEang, ChanpayaTanaka, KotaroTange, Takeshi
The transportation sector, and commercial vehicles in particular, play an important role in global CO2 emissions. For this reason, the EU recently decided to reduce CO2 emissions from commercial vehicles by 30% until 2030. One alternative to conventional diesel propulsion is the usage of stoichiometric natural gas combustion. Due to the lowered C/H ratio and the cost effective exhaust after treatment (EAT) in form of a three way catalyst (TWC), less CO2 is emitted and it is possible to comply even with most stringent NOX legislations. However, the stoichiometric combustion of natural gas has also disadvantages. In particular, the throttling and retarded 50 % mass fuel burned (MFB50) positions due to knocking lead to efficiency losses. One way to minimize these is the usage of exhaust gas re-circulation (EGR), Miller cycle and water injection. The reduced knocking tendency allows the geometric compression ratio to be increased further, which leads to an additional efficiency advantage
Betz, MariusEilts, Peter
There is a growing need for low-emissions concepts due to stricter emission regulations, more stringent homologation cycles, and the possibility of a ban on new engines by 2035. Of particular concern are the conditions during a cold start, when the Three-Way Catalyst is not yet heated to its light-off temperature. During this period, the catalyst remains inactive, thereby failing to convert pollutants. Reducing the time needed to reach this temperature is crucial to comply with the more stringent emissions standards. The post oxidation by means of secondary air injection, illustrated in this work, is a possible solution to reduce the time needed to reach the above-mentioned temperature. The strategy consists of injecting air into the exhaust manifold via secondary air injectors to oxidize unburned fuel that comes from a rich combustion within the cylinder. This strategy can be implemented without major modifications to the engine's hardware or control system, making it an attractive
Pipolo, MarioKulzer, AndreChiodi, MarcoMoriyoshi, Yasuo
Given its ability to be combined with the three-way catalyst, the stoichiometric operation is significantly more attractive than the lean-burn process, when considering the increasingly severe NOx limit for cogeneration gas engines in Germany. However, the high temperature of the stoichiometric combustion results in increased wall heat losses, restricted combustion phasings (owing to knock tendency) and thus efficiency penalties. To lower the temperature of the stoichiometric combustion and thus improve the engine efficiency, exhaust gas recirculation (EGR) is one of the most effective means. Nevertheless, the dilution with EGR has much lower tolerance level than with excess air, which leads to a consequent drop in the thermal efficiency. In this regard, reducing the water vapor concentration in the recirculated exhaust gas and increasing the EGR reactivity are two potential measures that may extend the mixture dilution limit and result in engine efficiency benefits. Here, the reactive
Beltaifa, YoussefKettner, MauriceEilts, PeterRuchel, BosseFröstl, Sebastian
Future compliance to FAA 14 CFR Part 25 and EASA CS-25 Appendix O conditions has required icing wind tunnels to expand their cloud simulation envelope, and demonstrate accurate calibration of liquid water content and droplet particle size distributions under these conditions. This has led to a renewed community interest in the accuracy of these calibrations, and the potential inter-facility bias due to the choice of instrumentation and processing methods. This article provides a comparison of the response of various hot-wire liquid water content instruments under Appendix C and supercooled large droplet conditions, after an independent similar analysis at other wind tunnel facilities. The instruments are being used, or are under consideration for use, by facilities collaborating in the ICE GENESIS program. For droplet median volume diameters (MVDs) between about 15 and 250 μm, cylindrical hot wire LWC sensors were found to consistently and increasingly under-read measurements from
Esposito, Biagio M.Orchard, DavidLucke, JohannesNichman, LeonidBliankinshtein, NataliaLilie, LyleCatalano, PietroD'Aniello, FrancescoStrapp, J. Walter
Measurements in snow conditions performed in the past were rarely initiated and best suited for pure and extremely detailed quantification of microphysical properties of a series of microphysical parameters, needed for accretion modelling. Within the European ICE GENESIS project, a considerable effort of natural snow measurements has been made during winter 2020/21. Instrumental means, both in-situ and remote sensing were deployed on the ATR-42 aircraft, as well as on the ground (ground station at ‘Les Eplatures’ airport in the Swiss Jura Mountains with ATR-42 overflights). Snow clouds and precipitation in the atmospheric column were sampled with the aircraft, whereas ground based and airborne radar systems allowed extending the observations of snow properties beyond the flight level chosen for the in situ measurements. Overall, five flight missions have been performed at different numerous flight levels (related temperature range from -10°C to +2°C) beyond the ‘Les Eplatures’ airport
Jaffeux, LouisSchwarzenboeck, AlfonsCoutris, PierreFebvre, GuyDezitter, FabienAguilar, Borisbillault-Roux, Anne-claireGrazioli, JacopoBerne, AlexisKöbschall, KilianJorquera, SusanaDelanoe, Julien
The tightening trend of regulations on the levels of admitted pollutant emissions has given a great spur to the research work in the field of combustion and after-treatment devices. Despite the improvements that can be applied to the development of the combustion process, pollutant emissions cannot be reduced to zero; for this reason, the aftertreatment system will become a key component in the path to achieving near-zero emission levels. This study focuses on the numerical analysis and optimization of different metallic substrates, specifically developed for three-way catalyst (TWC) and Diesel oxidation catalyst (DOC) applications, to improve their thermal efficiency by reducing radial thermal losses through the outer mantle. The optimization process relies on computational fluid dynamics (CFD) simulations supported by experimental measurements to validate the numerical models carried out under uncoated conditions, where chemical reactions do not occur. Full-scale three-dimensional
Sartirana, AndreaMontenegro, GianlucaDella Torre, AugustoOnorati, AngeloPace, LorenzoZaldua-Moreno, Naroa
In contrast to the currently primarily used liquid fuels (diesel and gasoline), methane (CH4) as a fuel offers a high potential for a significant reduction of greenhouse gas emissions (GHG). This advantage can only be used if tailpipe CH4 emissions are reduced to a minimum, since the GHG impact of CH4 in the atmosphere is higher than that of carbon dioxide (CO2). Three-way catalysts (TWC - stoichiometric combustion) and methane oxidation catalysts (MOC - lean combustion) can be used for post-engine CH4 oxidation. Both technologies allow for a nearly complete CH4 conversion to CO2 and water at sufficiently high exhaust temperatures (above the light-off temperature of the catalysts). However, CH4 combustion is facing a huge challenge with the planned introduction of Euro VII emissions standard, where stricter CH4 emission limits and a decrease of the cold start starting temperatures are discussed. The aim of the present study is to develop a reliable kinetic catalyst model for MOC
Leon de Syniawa, LarisaSiddareddy, Reddy BabuOder, JohannesFranken, TimGuenther, VivienRottengruber, HermannMauss, Fabian
For vehicles with internal combustion engines, tailpipe emissions heavily rely on the aftertreatment system, typically a catalytic converter. Modern three-way catalysts (TWC) can very effectively convert the unburnt hydrocarbons (HC), CO, and NOx into non-harmful gases such as H2O, CO2, and N2 when the catalyst brick reaches a relatively high temperature. However, before that catalyst light-off temperature is reached, the emissions conversion efficiency is low, leading to high tailpipe emissions. Due to this light-off temperature requirement of the catalytic converter, the emissions from the engine cold-start period contributes a significant portion of vehicle overall emissions. One of the major reasons for high emissions during cold start is low combustion chamber wall temperatures, lower than the initial boiling temperature of gasoline fuel. This results in fuel film formation, and significantly incomplete evaporation prior to combustion. In this study, an approach to increase the
Zhu, ShengrongHollowell, JeffreyHa, Kyoung-PyoFantin, NicholasShirley, Mark
Reaching near-zero cold start emissions in a wide range of ambient conditions is a challenging, yet necessary objective. Optimizing the combustion, although fundamental to lower specific engine-out emissions, is not sufficient, especially in high-performance engines. A very high after-treatment efficiency from engine start-up onwards is mandatory. Active heating technologies allow quick heating up of after-treatment devices like a three way catalyst above their light-off temperature, regardless of engine operation. In this work, the particular characteristics of a fuel burner were analyzed. The steps that led to the design of an exhaust system equipped with a fuel burner are reported. The fuel burner ability to efficiently heat up after-treatment devices was assessed by numerical simulations and then verified experimentally. Cumulative results were compared with a passive catalyst heating strategy. The fuel burner proved effective in reducing tailpipe emissions via pre-heating, i.e
Rossi, VincenzoBrocchi, LucaMedda, MassimoPaltrinieri, StefanoRulli, FedericoTonelli, Roberto
The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions. The experimental data indicate
Kim, Mi-YoungDadi, Rama KrishnaGong, JianKamasamudram, Krishna
To prevent global warming, many countries are making efforts to reduce CO2 emissions toward achieving 2050 carbon neutrality. In order to reduce CO2 concentration quickly, in addition to spread of renewable energy and expansion of BEV, it is also important to reduce CO2 emissions by improving thermal efficiency of ICE (internal combustion engine) and utilizing carbon neutral fuels such as synthetic fuels and biofuels. It is well known that lean burn is an effective technology to increase thermal efficiency of engine highly. However, since NOx emission from lean burn engine cannot be reduced with three-way catalyst, there have been issues such as complicated system configuration due to the addition of NOx reduction catalyst or limiting lean operation to narrow engine speed and load in order to meet emission regulation of each country. This paper introduces super lean burn engine with over lambda 2.5 that achieves both high thermal efficiency and significantly low NOx emission in order
Kimura, KoshiroSAKAI, HiroyukiOmura, TetsuoTakahashi, Daishi
The recently concluded partnership for advancing combustion engines (PACE) was a US Department of Energy consortium involving multiple national laboratories focused on addressing key efficiency and emission barriers in light-duty engines. Generation of detailed experimental data and modeling capabilities to understand and predict cold-start behavior was a major pillar in this program. Cold-start, as defined by the time between first engine crank and three-way catalyst light-off, is responsible for a large percentage of NOx, unburned hydrocarbon, and particulate matter emissions in light-duty engines. Minimizing emissions during cold-start is a trade-off between achieving faster three-way catalyst light-off, and engine out emissions during that period. In this study, engine performance, emissions, and catalyst warmup potential were monitored while the engine was operated using a single direct injection (baseline case) as well as a two-way-equal-split direct injection strategy. These
Jatana, Gurneesh S.Dal Forno Chuahy, FlavioSzybist, James
Global focus on CO2 reduction and environmental protection is increasing. To comply with stricter exhaust gas regulations and reduce real world emissions, it is becoming increasingly important to improve the performance of three-way catalysts. Therefore, highly efficient conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) is required. In general, the more active the precious metals used, the better the conversion performance. However, precious metals have supply risks, such as price fluctuation and the uneven distribution of production areas. Therefore, it is necessary to lower emissions while also lowering the amount of precious metals used. This paper focuses on how catalysts are used and describes the development of a new three-way catalyst for the purpose of strengthening cold conversion and decreasing the usage of precious metals
Tojo, TakumiShirakawa, ShogoNakahigashi, SeijiHoshino, ShoOnozuka, TakashiNoguchi, TakahiroAikawa, Tomomasa
The model-based design is very much prominent in the vehicle level control system design and state estimation algorithms. It gives the edge to understand and interpret the dynamic systems. Three-way catalytic converter is a thermo-chemical device to convert the toxic oxides into carbon dioxide and water vapor, during this conversion reactions it generates the heat over the catalyst surface. Detailed chemical and thermal model of the catalyst will be able to predict the conversion efficiency, state of stored oxygen (SoX) and oxygen storage capacity (OSC). As the catalyst get aged, the reaction rates of conversion reactions deteriorate, in results the temperature dynamics also varies which wanes the exothermic heat. In this work, a novel perspective is presented to capture the behavior of SoX and health of the catalytic converter using thermal model analysis of TWC. An equivalent second order multi input single output (MISO) linear sub-space model is identified for the complex detailed
Mandloi, DeepakSahu, PrachiBagade, Monika JayprakashDas, Himadri
The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass. This investigation assessed different emitted particle reduction efficiency, highlighting distinct levels between no-load (low
Di Maio, DarioGuido, ChiaraNapolitano, PierpaoloBeatrice, CarloGolini, Stefano
This paper, written in collaboration with Ford, evaluates the effectiveness of higher cell density combined with higher porosity, lower thermal mass substrates for emission control capability on a customized, RDE (Real Driving Emissions)-type of test cycle run on a chassis dynamometer using a gasoline passenger car fitted with a three-way catalyst (TWC) system. Cold-start emissions contribute most of the emissions control challenge, especially in the case of a very rigorous cold-start. The majority of tailpipe emissions occur during the first 30 seconds of the drive cycle. For the early engine startup phase, higher porosity substrates are developed as one part of the solution. In addition, further emission improvement is expected by increasing the specific surface area (GSA) of the substrate. This test was designed specifically to stress the cold start performance of the catalyst by using a short, 5 second idle time preceding an aggressive, high exhaust mass flowrate drive cycle. The
Nakasumi, HayakiKawakami, AkifumiOhara, Etsujisugimoto, KentaroHibi, NoriyukiAsako, TsuyoshiKato, KyoheiAnoop, Reghunathan-NairAffan, SyedThanasiu, EvaLambert, Christine K.Hubbard, Carolyn
Brazilian Emissions Regulations are getting tighter in the coming years. With PROCONVE L7 in Jan-2023 and PROCONVE L8 in 2025, regulated emissions limits will significantly decrease, such as, the NMOG + NOx standard from 130 mg/km (PL6) to 50 mg/km (PL8). This challenge will necessitate better aftertreatment performance, with expected increases the catalytic converter PGM content, and consequently higher system cost. It is understood that approximately 75% of an engine’s gaseous pollutants occur during the first few seconds after a cold start, thus it is crucial to promote the emissions conversion performance during that period. One approach is to decrease the heat capacity of the catalytic system, which can be done by utilizing cordierite substrates with thinner walls or an increased material porosity. CORNING has developed an innovative technology to substantially raise the porosity of conventional ultra-thin wall substrates from 35% to 55%, while maintaining their strength. This
Petrini Fogaça, RômuloUrbani Amadei, GabrielL. Warkins, JasonA. Craig, Angus
Emissions development work for gasoline aftertreatment systems is often conducted in a laboratory on a chassis dynamometer. In this situation, extractive sample lines are frequently connected to the aftertreatment system before and after various components, such as a three-way catalyst, selective catalytic reduction substrate, and the like. This is done to measure the conversion efficiency of the aftertreatment system components as a function of time. The time series exhaust component concentration data, also referred to as continuous data, are combined with a measure of exhaust volumetric flowrate and used to calculate mass-based emissions. As gasoline powertrains become cleaner and produce lower levels of criteria emissions, the proximity (i.e., colocated or not colocated) of the volumetric flowrate and concentration measurements may affect the accuracy of the overall mass emission calculation. In this work, we investigate the effect of water condensation and evaporation on
Kempema, Nathan J.Lown, AnneKralik, LoraLoos, Mike
Cloud computing technologies are embodied with automotive sector copiously. It aids in using data and computing services to manage information, communication, and computing, through Internet-based apps and online digital services. A cloud computing-based framework is suitable for developing and deploying simulation models to study, analyse and optimise the vehicle performance. The framework proves functional in collecting vehicle data, processing and then using them for datadriven or model-based development to deliver a complete software solution. Server-less cloud computing technologies with storage and function triggers form the architecture. The paper outlines a data-driven model of a Three-Way Catalyst (TWC) to test the cloud framework as an end-to-end solution. The model estimates a metric to quantify the oxygen storage capacity of the TWC over the air. This metric is an online adaptive gain, estimated through system diagnosis using the Recursive Least Squares method. This is
Singh, ShwetanshuMandloi, DeepakDas, Himadri
The electrified internal combustion engine can contribute to further improving air quality and reducing impact on climate change. A previous publication looked into ultra-low initial cold-start emissions with the implementation of a state-of-the-art emission control system on a gasoline vehicle with market E10 gasoline. This paper reports additional investigations on different drop-in sustainable renewable fuels, including e-fuels. The gasoline demonstrator vehicle is equipped with a 48V mild-hybrid powertrain with a 1.5 L direct injection engine. The innovative emission control system consists of an electrically pre-heated catalyst (EHC) and first three-way catalyst (TWC) in close-coupled position, in combination with an underfloor catalysed gasoline particulate filter (cGPF), second TWC and ammonia slip catalyst (ASC). Pollutant emission tests are conducted on a challenging chassis dyno test for cold-start emissions at 23 °C and -10 °C. Tests that were done before on reference E10
Demuynck, JoachimMendoza Villafuerte, PabloBosteels, DirkKuhrt, AndreasBrauer, MaximilianSens, MarcWilliams, JohnChaillou, ChristopheGordillo, Victor
TWC exposure to extreme temperature could result in irreversible damage or thermal failure. Thus, a strategy embedded in the engine control unit (ECU) called catalyst overheating protection (COP) will be activated to prevent TWC overheating. When COP is activated, the command air-fuel ratio will be enriched to cool the catalyst monolith down. Fuel enrichment has been proven a main prerequisite for ammonia formation in hot TWCs as a by-product of NOx reduction. Hence, COP events could theoretically be a source of post-catalyst ammonia from petrol vehicles, but this theory is yet to be confirmed in published literature. This paper validated this hypothesis using a self-programmed chassis-level test. The speed of the test vehicle was set to constant while the TWC temperature was raised stepwise until a COP event was activated. It is observed that at both testing speeds, the ammonia spike identified by a Fourier-transformation infrared analyzer (FTIR) spectrometer accorded well with the
Wang, XinLi, RuonanThomas, DaisyWang, ChongyaoGe, YunshanLi, Hu
The exhaust gas composition of several potential greenhouse gas neutral C1-based synthetic fuels and gasoline/alkylate-blends are compared to each other and benchmarked against gasoline. The search for sustainable alternatives to conventional fossil fuels is still ongoing. Ideally, the exhaust gas of such an alternative should not deteriorate the environment’s air quality. The testing conducted here is focused on automotive application. However, promising fuel candidates could also be used elsewhere. The gasoline/alkylate blends investigated contain various percentages of dimethyl carbonate (DMC) or methyl formate (MeFo). Various methanol-MeFo mixtures as well as a 65 vol% DMC+ 35 vol% MeFo mixture are investigated as examples for a pure synthetic fuel. The tests are carried out on a single-cylinder spark ignition research engine. To analyze the gaseous emissions a state-of-the-art FTIR, equipped with a specifically tailored evaluation method, and conventional exhaust gas analyzers are
Kraus, ChristophFitz, PatrickFellner, FelixHärtl, MartinJaensch, Malte
The environmental impact of heavy-duty vehicles powered by natural gas is considered to be less harmful compared to Diesel vehicles. Consequently, the share of vehicles using either compressed natural gas (CNG) or liquified natural gas (LNG) is expected to increase in the coming years. Since most Euro VI compliant engines operate with stoichiometric air-fuel ratio, the aftertreatment system (ATS) requires efficient three-way catalyst. With ever increasing prices on platinum group metals (PGM) over the past few years, three-way catalysts products have been exposed to wild fluctuations in cost that have had great impact on their affordability. Given that stoichiometric operation is the most widely used calibration of heavy-duty natural gas engines, the trade-off between efficiency, calibration and PGM cost must be constantly reset. This study focuses on the evolution and transition from bimetallic palladium-rhodium (Pd:Rh) concepts to trimetallic platinum-palladium-rhodium (Pt:Pd:Rh
Sala, RafalKallinen, KaukoChernyshev, AlexanderWolff, ThomasMoreno, AndreinaDzida, JakubPfeifer, Mirko
Exhaust gas aftertreatment systems can, under certain conditions, create undesired chemical species as a result of their elimination reactions. A prime example of this is ammonia (NH3), which is not formed in the combustion reaction, but which can be formed within a three-way catalyst (TWC) when physicochemical conditions permit. The elimination of NOx in the TWC thus sometimes comes at the cost of significant emissions of NH3. Ammonia is a pollutant and a reactive nitrogen compound (RNC) and NH3 emissions should be analyzed in this context, alongside other RNC species. Examination of the literature on the subject published over the past two decades shows that ammonia, a species which is currently not subject to systematic emissions requirements for road vehicles in any market, is often identified as forming the majority of the RNC emissions under a range of operating conditions. It is expected that upcoming automotive emissions legislation (e.g. the European Union’s Euro 7/VII
Woodburn, JosephMerkisz, JerzyBielaczyc, Piotr
The development of future gasoline engines is dominated by the study of new technologies aimed at reducing the engine negative environmental impact and increase its thermal efficiency. One common trend is to develop smaller engines able to operate in stoichiometric conditions across the whole engine map for better efficiency, lower fuel consumption, and optimal conversion rate of the three-way catalyst (TWC). Water injection is one promising technique, as it significantly reduces the engine knock tendency and avoids fuel enrichment for exhaust temperature mitigation at high power operation. With the focus on reducing the carbon footprint of the automotive sector, another vital topic of research is the investigation of new alternative CO2-neutral fuels or so-called eFuels. Several studies have already shown how these new synthetic fuels can be produced by exploiting renewable energy sources and can significantly reduce engine emissions. This work is part of the FVV project number 1367
Rossi, EdoardoBargende, MichaelKulzer, André CasalChiodi, MarcoMassoud, EhabShrestha, KrishnaMauss, Fabian
An integrated electrically heated catalyst (EHC) in the three-way catalyst (TWC) of a gasoline internal combustion engine (ICE) is a promising technology to reduce engine cold-start pollutant emissions. Pre-heating the TWC ensures earlier catalyst light-off of a significant portion of the TWC. In such a case, the engine could readily be operated in a fuel-optimal manner since the engine cold-start emission is efficiently treated by the warmed-up EHC-equipped TWC. Pre-heating the EHC is an effective way to reduce cold-start emissions, among other possible EHC strategies. However, it might not always be possible to use pre-heating if the engine-start time is uncertain. In such a case, pre-heating can be started when the engine start is known with greater confidence and post-heating the catalyst could be followed. It would then be natural to turn off the EHC when the payoff for the electrical energy spent is no longer effective in engine cold-start emission reduction. The point in time at
Vilwanathan Velmurugan, DhineshMcKelvey, TomasOlsson, Jan-Ola
Catalytic converters have been effectively controlling the harmful exhaust gases to meet stringent emission norms. This article presents a new three-way catalyst developed using natural zeolite for effective emission reduction. The step-by-step preparation of the material for the developed catalyst is followed by its characterization using an energy dispersive X-ray (EDX), X-ray diffraction (XRD), and scanning electron microscope (SEM). The testing performed on a synthetic gas test bench (SGTB) shows substantial carbon monoxide (CO), hydrocarbon (HC), and nitric oxide (NO) reduction. Results show a 100% conversion for NO above 280°C, 54.8% for CO at 315°C, and 52% for HC at 500°C. The developed natural zeolite-based catalyst stands out from among current catalysts and can be endorsed for three-way conversions than the synthetic zeolite catalyst
Satpute, Sanjay T.Maske, Vidyasagar B.Kumbhar, Surajkumar G.Kumbhar, Sanjay R.Kurane, Rajanikant M.
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