Study of Port Fuel Injection Engine Cold Start Unburned Hydrocarbons Reduction Using Computational Fluid Dynamics with a Reduced Iso-Octane Mechanism Considering Various Isomers and Thermal Decompositions

A modeling study was performed to find solutions to reduce the unburned hydrocarbons during cold start of a PFI (port fuel injection) SI (spark ignition) engine. Through modeling, the root cause for the high unburned hydrocarbons of the baseline engine during cold start was found. The slow combustion, which is due to the high amount of exhaust gas flowing back into the intake port and then becoming trapped inside the cylinder, is the root cause. A new valve lift, which can reduce the internal residual by 26%, was designed. Along with a fuel amount decrease of 35%, the UHC (unburned hydrocarbons) before the three-way catalyst can be reduced by 40%. The exhaust temperature using the new valve lift design increases by 400°C, which improves the performance of the three-way catalyst for further reducing UHC. In addition to the adoption of the new valve lift, an active SAI (secondary air injection) strategy was also investigated. Modeling results show that SAI can promote secondary combustion in the exhaust pipes to increase exhaust temperature and thus is beneficial for further oxidizing unburned hydrocarbons. The amount of active SAI mass flow rate should be controlled to less than 25% of the intake air flow rate to avoid the cooling effect dominating over the oxidation process. The duration of SAI should be from EVO (exhaust valve opening) to IVO (intake valve opening). For combustion modeling, a newly reduced iso-octane chemical kinetic mechanism was developed using carbon flux analysis to extract major reaction pathways for a wide range of practical engine temperature conditions. In the new reduced mechanism, a skeletal sub-mechanism for species starting from iso-octane to C₄ is coupled with a recently updated H₂/O₂/CO/C₁–C₄ detailed sub-mechanism. Including a reduced NOx (oxides of nitrogen) sub-mechanism, the final mechanism has 681 species and 3332 reactions. Before the new reduced iso-octane mechanism was used, it had been validated with available experimental data of ignition delay times, laminar flame speeds, and important species profiles in the literature. Both the investigation of PFI engine unburned hydrocarbons reduction under cold start operating conditions and the development of a reduced chemical mechanism are the objectives of this work.