g-C₃N₄, a metal-free semiconductor photocatalyst, demonstrates remarkable potential, but its practical application in pollutant degradation is significantly limited by the rapid recombination of photogenerated electron-hole pairs and low photocatalytic efficiency. To address this, a series of magnetic recyclable g-C₃N₄/CoFe₂O₄ composite photocatalysts with different CoFe₂O₄ doping ratios were innovatively designed and prepared via thermal polymerization, sol- gel, and combined with ultrasonic and heat treatment processes. The novelty of this composite design lies in the effective integration of magnetic CoFe₂O₄ with g-C₃N₄ through a heterojunction structure. It substantially boosts the absorption of visible light. Concurrently, it effectively fosters the separation and mobility of photo-induced charge carriers.
The composite materials were systematically characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, photoluminescence spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy. Using tetracycline hydrochloride as the target pollutant, the photocatalytic activity of the composites was evaluated under visible light irradiation, and the effects of initial concentration, catalyst dosage, and the influence of solution pH on degradation efficiency were also examined. The results indicated that the composite with a CoFe₂O₄ to g-C₃N₄ mass ratio of 1:3 (denoted as 3-CN/CFO) exhibited the optimal performance: a TCH degradation rate of 80.29 % within 105 minutes and a total organic carbon removal rate of 61.63 %. After five consecutive cycling experiments, the degradation efficiency remained above 70 %, demonstrating good reusability and stability. The performance improvement is attributed to the formation of heterojunctions in the composite, which effectively facilitates charge separation, inhibits carrier recombination, and enhances visible light absorption. Furthermore, the inherent magnetism of the composite permits efficient recovery, streamlining its integration into practical applications. Toward the purification of antibiotic-contaminated water, this research proposes a viable method for fabricating highly effective and recyclable photocatalysts.