In-Situ Raman Measurements of Fuel Dilution of Lubricant Films in a Direct-Injection Spark-Ignition Engine

To measure the fuel proportion within the lubricant film, an in-situ Raman spectroscopy technique was employed in a specially modified single-cylinder direct-injection spark-ignition engine. The engine block was engineered for optical access with a fused silica window, enabling a focused laser beam to probe the lubricant film on the engine liner under motoring conditions. The lubricant used was GTL8 base oil with ZDDP additive, and iso-octane was injected as a model fuel to study fuel-lubricant mixing. A calibration curve was established by recording Raman spectra of known mixtures of GTL8 oil and iso-octane. The Raman intensity ratio of the iso-octane peak to the oil peak was used as a quantitative indicator of fuel concentration. During engine operation, Raman spectra were acquired in real time, on a cycle-by-cycle basis, through the optical window. Upon iso-octane injection, its characteristic Raman peak appeared in the spectrum, and the intensity ratio was referenced against the calibration curve to estimate the fuel proportion within the lubricant film. Experimental results demonstrated that the iso-octane signal could be detected during and after injection and this allowed for real-time monitoring of fuel dilution dynamics. The main challenge encountered was high fluorescence from oil, which sometimes obscured the Raman peaks and complicated quantification. Despite this, the technique successfully demonstrated the feasibility of direct, in-situ, and real-time quantification of fuel dilution in engine lubricant films, providing a valuable tool for studying fuel-lubricant interactions under operating engine conditions.