Natural gas (NG) is a domestically abundant, low-cost fuel with the potential to displace gasoline and diesel fuel in commercial and off-road vehicles. NG engines typically produce lower engine-out pollutant emissions, such as NOx, CO and particulate matter, which could simplify emission control systems. Blending NG with hydrogen (H₂) can improve engine performance and increase combustion efficiency to further reduce engine-out emissions. Additionally, the presence of H2 in the exhaust stream may also facilitate the catalytic conversion of methane and other pollutants, resulting in cleaner tailpipe emissions.
This study evaluates the impact of H2 on the conversion of methane, CO, and NOx emissions on a commercial three-way catalyst (TWC) in a flow reactor using synthetic gas mixtures that simulate stoichiometric engine exhausts with NG or NG+H₂ combustion. The work examines whether, and how, the additional amount of H₂ in the exhaust stream affects the conversion efficiency of methane and other pollutants. Experiments were conducted with both degreened and aged catalysts under controlled conditions, systematically varying temperature, air-to-fuel ratio (λ), and λ modulation. Test conditions covered λ values from 0.996 to 1.000 to represent nominally stoichiometric engine operation with different λ modulation amplitudes, as well as a range of temperatures to inform control strategies for effective CH₄, CO, and NOₓ reduction. Overall, the results show that hydrogen addition significantly improves the conversion efficiency of CH₄ and NOₓ, particularly at temperatures below 450 ℃. More significantly, this study highlights that exhaust gas composition, operating temperature, λ management, and the oxygen storage capacity of the TWC all play major roles in affecting the tailpipe emissions from NG and NG+H₂ combustion.