Identification and Quantification of PAHs in Gasoline Soot Using ASE-GC-MS/MS

In the present work, a novel method that combines accelerated solvent extraction (ASE) and gas chromatography coupled with triple quadrupole tandem mass spectrometry (GC-MS/MS) was proposed to identify and quantify polycyclic aromatic hydrocarbons (PAHs) in gasoline soot. The n-hexane was employed to extract the target analytes, and the optimal extraction conditions were identified (cycle times = 3, extraction time = 30 min, extraction temperature = 120°C, and extraction pressure = 100 MPa). The extraction efficiency of six analytes was measured to assess the ASE method; the formation mechanism of partial PAHs was discussed, and the 18 PAHs in gasoline soot were studied both qualitatively and quantitatively under the optimal conditions. It was found that our new method reached a high correlation coefficient (between 0.9987 and 0.9997); the limits of quantification (LOQs) (S/N = 6) for these PAHs were between 0.003 and 0.009 ng/mL with a relative standard deviation (RSD) of 2.9–10.6%. Our method demonstrated good performance in determining the target analytes in soot samples, such as gasoline soot, some materials soot, co-combustion soot, gasoline, and materials. The PAHs differences in soot samples containing gasoline and materials soot samples were significant enough to obtain the observed discrimination. The method is an accurate and sensitive quantitative method to identify gasoline residues in soot samples of arson fire.