Experimental Investigation on Unburned Methanol and Formaldehyde Emissions from a Direct-Injection Diesel / Methanol Dual-Fuel Engine

For large-bore marine methanol / diesel dual-fuel engines, this study investigates the formation characteristics of unregulated emissions through experimental methods and explores the mechanisms by which engine load and injection timing influence the emissions of unburned methanol and formaldehyde. The study was carried out on a supercharged intercooled inline six-cylinder engine, and Fourier Transform Infrared Spectroscopy (FTIR) was used to monitor the exhaust composition in real time. The study shows that methanol released in the exhaust is due to the incomplete combustion of the methanol fuel. In the combustion process of methanol fuel, formaldehyde mainly arises from two pathways, the first of which is the partial oxidation of methanol inside the cylinder; secondly, the unburned methanol in the exhaust gas oxidizes in the exhaust pipe to generate formaldehyde. As the load increased from 25% to 100%, the unburned methanol emissions decreased by 29%, and formaldehyde emissions decreased by 71%. This is mainly attributed to the enhanced oxidation reaction and reduced wall crevice effect due to the increased combustion temperature. Methanol injection timing optimization was effective in controlling unregulated emissions, with methanol emissions lower at -7° CA ATDC and formaldehyde emissions reaching larger values under this condition. Delaying the diesel injection to -16°CA ATDC led to a 38% increase in unburned methanol emissions, caused by fuel spray interactions and longer stagnation, whereas formaldehyde emissions showed minimal change.