Experimental and Computational Study on Combustion and Performance Characteristics of an Ammonia–Diesel Dual-Fuel Engine under Low Load Conditions

Ammonia is receiving heightened attention as a carbon-neutral and hydrogen energy carrier alternative fuel for compression ignition engines. However, replacing diesel with ammonia poses significant challenges due to its low reactivity and slow-burning nature, particularly at low-load conditions. This study investigated the effect of ammonia energy share (AES) on the combustion characteristics and performance of an ammonia–diesel dual-fuel (ADDF) compression ignition engine operating under low loads and at a constant speed of 1800 RPM. The experiments were conducted at three different loads: 6 Nm, 13.5 Nm, and 18 Nm, corresponding to 11%, 25%, and 33% of full load, respectively. At each load, the AES was incrementally increased, ranging from zero to its maximum limit, while maintaining the COV of IMEP below 3% to ensure stable combustion. Furthermore, CFD simulations were performed using a CONVERGE CFD model of the engine to analyze the in-cylinder thermal and chemical behavior, and the model was validated against the experimental data. The experimental results showed that the AES reached 40%, 58%, and 61% for engine loads of 6 Nm, 13.5 Nm, and 18 Nm, respectively. Increasing AES reduced the mean in-cylinder temperature and peak cylinder pressure, and shifted the peak pressure location toward the expansion stroke. Combustion phasing was delayed, and combustion duration increased with higher ammonia substitution. CFD analysis revealed weaker high-temperature and OH reaction zones, along with reduced OH and H radical activity, and increased persistence of NH₂ and HO₂ evolution at higher AES, indicating slower oxidation of the ammonia-containing mixture. The results highlight the challenges associated with high-ammonia operation at low loads and provide deeper insight into the combustion processes governing ADDF engine performance.