Gravity heat pipes achieve efficient energy transfer through the evaporation and condensation of their internal working fluid, which steadily conducts underground heat to the surface and thereby provides a continuous and stable heat source for road pavements in winter. Considering the snow and ice melting demand of road surfaces in winter, this paper establishes an indoor environmental simulation experimental platform to systematically investigate the influence laws of different working fluids on the start-up temperature, start-up pressure, heat transfer power, and other key performance indicators of L-shaped gravity heat pipes. Through experimental research and analysis, it is revealed that heat pipes with R-134a and R245fa working fluids can operate stably at a shallow geothermal temperature of about 25 °C, while the acetone working fluid heat pipe operates unstably under this condition. The heat pipe filled with R-134a working fluid achieves the maximum heat transfer power under shallow geothermal conditions, followed by the heat pipe filled with R245fa. Although the heat transfer power of the acetone-filled heat pipe is generally relatively low, its heat transfer power increases most significantly with the rise of the evaporation section temperature. Under low-temperature conditions, the thermal conductivity of the evaporation section increases with the rise in the heating temperature of the evaporation section, while that of the condensation section decreases with the increase in the heating temperature of the evaporation section. Through experimental research and comparative analysis, this paper deeply explores the application potential of gravity heat pipe technology in green highway construction, and evaluates the feasibility and economic benefits of its engineering implementation, which provides a scientific basis and engineering guidance for the selection of green energy in future infrastructure construction.