The effect of differential humidification and membrane thickness on PEMFC operation
2025-32-0039
To be published on 11/03/2025
- Event
- Content
- In the recent years, the urgency to decarbonize the mobility sector has highlighted the importance of the electrochemical hydrogen use in fuel cells to complement the battery-based electrification. Hydrogen is as an excellent energy carrier, and low-temperature Polymer Electrolyte Membrane Fuel Cells (PEMFCs) are part of an ever-evolving scenario, with particularly promising use in high energy demand mobility sectors. This paper presents a 3D-CFD study to analyse the behaviour of PEMFCs by examining the role of humidification conditions, covering fully humidified (anode and cathode), anode-only, cathode-only, and fully dry operations. This is simulated for several membrane thicknesses, reproducing a wide matrix of operating conditions and separator choices, and examining their respective effect on the cell’s resistance. In the first part of the paper, a part-specific mesh sensitivity analysis is conducted to establish general validity guidelines for the through-plane and in-plane grid resolution, which are here crucial in view of the high through-plane gradients of species concentration and electric potential. In the second part, the obtained results confirm that the fully dry operation results in a significant increase in cell’s internal resistance, as well as the opposite is verified for fully humidified operation. However, maintaining an external anode-only humidification and relying on the internal self-humidification can be a highly effective strategy, allowing to reduce the complexity of the balance of plant by simplifying the humidifiers sub-system. This is analysed in conjunction with the effect of the electrolyte thickness, which opens to the possibility to enhance or suppress self-humidification and water transport. Conclusions provide an overview of the design and operating choices to minimize the cell’s resistance at a minimum system complexity cost.
- Citation
- Scialpi, L., D'Adamo, A., and Marra, C., "The effect of differential humidification and membrane thickness on PEMFC operation," SAE Technical Paper 2025-32-0039, 2025, .