With the advancement of computer vision technologies and the widespread deployment of video surveillance systems, traffic safety and the development of intelligent highways have been significantly enhanced. As a key component of the intelligent video analysis module in smart highways, person re-identification (re-ID) addresses critical challenges, including cross-segment tracking of pedestrians illegally using emergency lanes, multi-camera joint searches for lost persons in service areas, and trajectory tracing of individuals involved in traffic accidents. These functions directly support the core goals of "safety assurance and efficient service" for smart highways. However, due to the complexity of the application scene, its generalization to unseen environments remains a core challenge. This problem is formally studied under the setting of Single-Domain Generalizable Person Re-identification (SDG re-ID), which aims to train a model on a single source domain that can perform well on arbitrary unseen target domains. To handle this issue, this paper proposes a novel Disentangled Augmentation re-ID Framework (DisReID) that disentangles and augments both structure and style. Specifically, DisReID consists of two modules: Structure-aware Viewpoint Simulation (SVS), a novel pre-processing technique that simulates cross-camera perspective changes by perspective transformation, diversifying geometric structure without harming identity semantics; and Style-Dominant Frequency Perturbation (SFP), which selectively focuses on the style-dominant frequencies and applies perturbation to enable controllable style augmentation while preserving structure cues. Furthermore, to alleviate the BN-induced domain bias, we introduce a simple yet effective test-time adaptation strategy, termed Cluster Fine-tuning (CF), that performs unsupervised clustering on target-domain features to assign pseudo-labels and subsequently fine-tunes the model, enhancing adaptability to unseen domains. Extensive experimental results on four public datasets demonstrate that our DisReID achieves superior generalization performance compared to the state-of-the-art methods. This work provides key technical support for the large-scale application of re-ID in smart highways, advancing the goal of "full-domain perception and intelligent collaboration".