Diesel Soot Oxidation under Controlled Conditions

A quantitative relationship between diesel soot oxidation rate and oxidation temperature and oxygen partial pressure was investigated by burning the diesel exhaust soot particles in a controlled flat flame supplied with methane/air/oxygen/nitrogen mixtures. The oxidation temperature and the oxygen partial pressure were controlled in the ranges of 1530 to 1820 K and 0.01 to 0.05 atm (1atm = 1.01325 bar) respectively. Soot particle size distribution measurements were achieved with transmission electron microscopy (TEM) for particle samples that were collected on copper grids at different positions along the flame centerline. Oxidation periods were determined by means of laser Doppler anemometry (LDA). The experimental results showed that the experimental oxidation rates fall between the values predicted by the Nagle and Strickland-Constable formula and those by the Lee formula.