Development of an Engine-Based Catalytic Converter Poisoning Test to Assess the Impact of Volatile ZDDP Decomposition Products from Passenger Car Engine Oils

An engine test has been developed to assess the impact of volatile phosphorus from passenger car engine oils on catalytic converter efficiency. The ten-day, steady-state, catalyst aging test was established to promote the production and consumption of volatile phosphorus species contained in crankcase vapors that are evacuated and combusted via the PCV system. A system for sampling, analyzing and identifying crankcase vapors led to a greater understanding of the phosphorus-based poisoning mechanism. Catalytic converter conversion efficiency was assessed through an engine-based system that swept catalyst inlet temperature from low to high while using a constant flow of controlled exhaust gas. The test results indicate correct ranking of field-tested oils that have catalyst poisoning data.