Comparison of Ammonia Emission Characteristics Between Different Gasoline Vehicles Equipped with Three-Way Catalysts

In recent years, the tightening of vehicle emission regulations has led to a decreasing trend in regulated pollutants such as NOₓ and CO. However, the emission of ammonia (NH₃), which is unintentionally generated during the purification process in three-way catalyst of gasoline vehicles, has become a growing concern. NH₃ emissions from vehicles can serve as a precursor to PM2.5 and have been reported to cause local roadside pollution. Therefore, there is a growing need for on-road testing to identify conditions under which NH₃ is likely to be emitted. Furthermore, since engine control strategies vary among vehicle types, it is desirable to consider differences in emission behavior across different models. In this study, on-road NH₃ emissions were measured for multiple vehicle models with different powertrains, and the effects of engine behaviors and engine operating duration across vehicles on NH₃ emissions were investigated. To analyze differences in NH₃ emission behavior among vehicle types, conventional gasoline vehicles and series-type hybrid vehicles were employed. Additionally, vehicle control parameters were obtained via an OBD (On-Board Diagnostics) interface unit and utilized for analysis. The analysis revealed that, for the conventional gasoline vehicles, aggressive accelerator pedal control induced rapid fluctuations in engine speed, which in turn led to NH₃ emissions. In contrast, for the series-type hybrid vehicles, NH₃ emissions were primarily observed when the engine started under specific conditions, whereas differences in driver behavior had only a minor direct impact on NH₃ emissions. In addition, longer engine operating durations resulted in higher emission levels. A common characteristic observed across both vehicle types was that NH₃ emissions were elevated during periods corresponding to CO emissions, which serve as precursors to NH₃ formation.