A Study on the Solid Ammonium SCR System for Control of Diesel NOx Emissions

One of most effective NOx control technology of modern diesel engines is SCR with ammonia. Current NOx reduction systems are designed to use a solution of urea dissolved in water as a source of ammonia. However, the liquid urea systems have technical difficulties, such as a freezing point below −11°C and solid deposit formation in the exhaust temperature below 200°C. The objective of this study is to investigate the possibility of a new ammonia generation system that uses low-cost solid ammonium salt, such as solid urea and ammonium carbonate. The result shows that ammonium carbonate is more suitable than solid urea because of low decomposition temperature and no change to the other ammonium salt during the decomposition process. This paper also shows the NOx reduction capability of the new ammonia delivery system that uses ammonium carbonate.