4000 F Oxidation Resistant Thermal Protection Materials

Coated refractory metals, coated and alloyed graphites, hafnium-tantalum alloys, refractory borides, and stabilized zirconias are considered for the 3600–4000 F high-velocity air environment. Only refractory borides and stabilized zirconias are indicated as offering long duration and reuse capabilities for such high-temperature utilization. Iridium, as coatings on substrates of either graphites or refractory metals, appears attractive for shorter times (less than 1 hr). Environmental evaluation and the need for a theoretical framework to enable the prediction of performance data for such materials are indicated to be major problems facing users and suppliers.