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The influence of PAH contamination of Lubricating Oil on Diesel Particulate PAH Emissions
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The influence of contamination of lubricating oil on the emissions of total particulate, particulate polycyclic aromatic hydrocarbons (PAH) and unburnt fuel and gaseous emissions have been investigated for a modified Perkins 4.236 D.I. diesel engine. The emissions during fuel firing and motoring in the absence of fuel are compared. The results showed that the exhaust particulate during both firing and motoring were not affected by lubricating oil contamination. Emission of PAH during fuel firing and motoring increase with oil contamination which in turn reflects the build up of PAH with oil age. Some of the particulate PAH are biologically active. The contribution of oil derived PAH increase with age. Comparison of the gaseous emissions during fuel firing and during motoring also showed an increase in UHC with age of lubricating oil.
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Williams, P., Abbass, M., Andrews, G., and Bartle, K., "The influence of PAH contamination of Lubricating Oil on Diesel Particulate PAH Emissions," SAE Technical Paper 890825, 1989, https://doi.org/10.4271/890825.Also In
References
- Braddock J.N. Bradow R.L. Emissions patterns of diesel powered passenger cars SAE Paper 750682 1975
- Braddock J.N. Gabele P.A. Emission patterns of diesel powered passenger cars Part II SAE Paper 770168 1977
- Black F. High L. Methodology for determining particulate and gaseous diesel hydrocarbon emissions SAE Paper 790422 1979
- Lepperhof G. Kroon G. Impact of particulate traps on the hydrocarbon fraction of diesel particulates SAE Paper 850013 1985
- Williams P.T. Abbass M.K. Tam L.P. Andrews G.E. Ng K.L. Bartle K.D. A comparison of exhaust pipe dilution tunnel and roadside diesel particulate SOF and gaseous hydrocarbon emissions SAE Paper 880351 1988
- EPA. Control of Air Pollution. Federal Register (50) 51 March 1985
- ECE Diesel Emissions Proposals from Class M1 European Passenger Cars. ECE R15-05 1987
- Perez J.M. Jass R.E. Leddy D.G. Coordinating Research Council. Chemical methods for the measurement of unregulated diesel emissions CRC-APRAC Project CAPI-1-64 1987
- Williams P.T. Andrews G.E. Bartle K.D. Diesel particulate emissions: the role of unburnt fuel in the organic fraction composition SAE Paper 870554 1987
- Williams P.T. Bartle K.D. Andrews G.E. The relation between polyaromatic compounds in diesel fuels and particulates. 65 1150 1158 1986
- MacDonald J.S. Barsic N.J. Gross G.P. Shahed S.P. Johnson J.H. Status of diesel particulate measurement methods SAE Paper 840345 1984
- Abbass M.K. Andrews G.E. Williams P.T. Bartle K.D. Davies I.L. Tanuii L.K. Diesel particulate emissions: Pyrosynthesis of PAH from hexadecane SAE Paper 880345 1988
- Henderson T.R. Sun J.D. Li A.P. Hanson R.L. Bechtold W.E. Harvey T.M. Shabanowitz J. Hunt D.F. GC/MS and MS/MS studies of diesel exhaust mutagenicity and emissions from chemically defined fuels Environ. Sci. Tech 18 428 434 1984
- Williams P.T. Andrews G.E. Bartle K.D. The role of lubricating oil in diesel particulate and particulate PAC emissions SAE Paper 872084 1987
- Mayer W.J. Lechman D.C. Hilden D.L. The contribution of engine oil to diesel exhaust particulate emissions SAE Paper 800256 1980
- Hilden D.L. Mayer M.J. The contribution of engine oil to particulate engine exhaust emissions from light duty diesel powered vehicles SAE Paper 841395 1984
- Cartillieri W. Tritthart P. Particulate analysis of light duty diesel engines (IDI & DI) with particular reference to the lube oil particulate fraction SAE Paper 840418 1984
- Cuthbertson R.D. Shore P.R. Sundstrom L. Heden P.O. Direct analysis of diesel particulate-bound hydrocarbons by gas chromatography with solid sample injection SAE Paper 870626 1987
- Lee M.L. Novotny M. Bartle K.D. ”Analytical chemistry of polycyclic aromatic hydrocarbons” Academic Press New York 1981
- Lee F.S.C. Schuetzle D. Bjorseth ”Handbook of polycyclic aromatic compounds” Marcel Dekker Inc. New York 1983
- Lewton J. “Toxicological effects of emissions from diesel engines” Elseveir New York 1982
- National Research Council ”Health effects of exposure to diesel exhaust” Washington D.C. 1981
- Abbass M.K. Williams P.T. Andrews G.E. Bartle K.D. The aging of lubricating oil, the influence of unburnt fuel and particulate SOF contamination SAE Paper 872085 1987
- Williams P.T. Andrews G.E. Bartle K.D. Bisop P. Watkins P. Analysis of the polycyclic aromatic compounds of diesel fuel by gas chromatography with ion-trap detection Biomedical and Environmental Mass Spectrometry 15 517 519 1988
- Greeves G. Wang C.H.T. Origins of hydrocarbon and carbon dioxide emissions from diesel engines 17th International Congress FISITA 779-804 1978
- Greeves G. Khan I.M. Wang C.H.T. Fenne I. Origins of hydrocarbon emissions from diesel engines SAE Trans. 86 1235 1251 1977
- Yu R.C. Wong V.W. Shahed S.M. Sources of hydrocarbon emissions from direct injection diesel engines SAE Trans. 89 324 335 1980
- Colmsjo A.L. Zebuhr Y.U. Ostman C.E. Analysis of poycyclic aromatic compounds in oil Proc. Conf. Heavy Oils and Residues Lyons, Technip, Paris 253 257 1984
- Ostman C.E. Colmsjo A.L. Zebuhr V.U. Polycyclic aromatic compounds in lubricating oil: a study of gasoline, gasoline/methanol, gas and diesel fuelled engines Cooke M. Dennis A.J. ”Polynuclear aromatic hydrocarbons: chemistry characterisation and carcinogenesis” Battelle Press Columbus OH 1986
- Grimmer G. Jacob J. Naujack K.W. Profile of the polycyclic aromatic hydrocarbons from lubricating oils inventory by GC/MS PAH in environmental materials Part 1 Fresenius Z Anal Chem 306 347 ( 1981
- Grimmer G. Jacob J. Naujack K.W. Dettbarn G. Profile of the polycyclic aromatic hydrocarbons from lubricating oils inventory by GC/MS PAH in environmental materials Part 2 Fresenius Z Anal Chem 309 13 1981
- Longwell J.P. ”Soot in combustion systems and its Toxic Properties” Lahaye J. Prado G. Plenum Press New York 1983
- Barfnecht T.R. Andon B.M. Thilly W.G. Hites R.A. Proc. 5th Int. Symp. on PAH Battelle Columbus OH 1980
- Williams R.L. Perez J.M. Griffing M.E. Areview of sampling conditioning effects on polynuclear aromatic hydrocarbons from heavy duty diesel engines SAE Paper 852081 1985
- Davies I.L. Bartle K.D. Andrews G.E. Williams P.T. Automated chemical class characterisation of kerosene and diesel fuels by on-line coupled microbore HPLC/capillary GC. J. Chromatog. Sci. March 1988
- Davies I.L. Raynor M.W. Williams P.T. Andrews G.E. Bartle K.D. Application of automated on-line microbore high performance liquid chromatography / capillary gas chromatography to diesel exhaust particulates. Anal. Chem 59 2579 2583 1987
- Davies I.L. Bartle K.D. Williams P.T Andrews G.E. On-line fractionation and identification of diesel fuel polycyclic aromatic compounds by two dimensional microbore high performance liquid chromatography/capillary gas chromatography. Anal. Chem 60 204 209 1988
- Vassilaros D.L. Kong R.C. Later D.W. Lee M.L. Linear retention index system for polycyclic aromatic compounds critical evaluation and additional indices. J. Chromatography 252 1 20 1982
- Halsall R. McMillan M.L. Schwartz B.J. An improved method for determining the hydrocarbon fraction of diesel particulates by vacuum oven sublimation SAE Paper 872136 1987