UV Absorbance Histories and Knock in a Spark Ignited Engine

Monochromatic ultraviolet (UV) absorbance, temperature, and pressure histories of unburned gas in a single cylinder CFR engine under motored, fired, and autoignition conditions were recorded on a multichannel magnetic tape recorder. Isooctane, cyclohexane, ethane, n-hexane, n-heptane, 75 octane number (ON), 50 ON, and 25 ON blends of primary reference fuels (PRF) were studied. Under knocking or autoignition conditions a critical absorbance at 2600 A was found, whose magnitude was independent of engine operating variables and dependent only on the knock resistance of the fuel. This absorbance increased rapidly when a certain temperature level was exceeded during the exothermic preflame reactions.