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Research on the High Frequency Resistance Behavior of a Proton Exchange Membrane Fuel Cell during Gas Purge
Technical Paper
2022-01-7009
ISSN: 0148-7191, e-ISSN: 2688-3627
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English
Abstract
Water management of proton exchange membrane fuel cell (PEMFC) is an important way to improve the performance and durability of fuel cell. The gas purge process of the PEMFC during shutdown can effectively remove the residual water in the fuel cell. At the same time, gas purge has been a common method to improve the low-temperature cold start possibility of PEMFC by minimizing residual water inside the fuel cell. In this paper, the gas purge process of the PEMFC is studied experimentally. As an important means to characterize the internal water content of the PEMFC, high frequency resistance (HFR) is used to represent the change of water content during gas purge. The effects of purge gas flow, purge time and cell temperature on purge performance were studied, and the purge methods are also compared. The results show that the longer the purge time is, the more water is taken away by gas purge. It can achieve better gas purge performance at higher cell temperature, because of the higher gas evaporation and saturated vapor pressure. The efficiency of gas purge can be significantly improved by increasing the purge gas flow rate both the anode and the cathode. In addition, changing the gas purge method, such as purge the anode or cathode side only, the HFR of fuel cell increases more rapidly than the method of simultaneous gas purge in both sides, and the effect of single anode purge is better than that of single cathode side purge, but the HFR will drop a lot at the end of purge.
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Ma, T., Wang, K., Du, B., Cong, M. et al., "Research on the High Frequency Resistance Behavior of a Proton Exchange Membrane Fuel Cell during Gas Purge," SAE Technical Paper 2022-01-7009, 2022, https://doi.org/10.4271/2022-01-7009.Also In
References
- Sopian , K. and Wan , R. Challenges and Future Developments in Proton Exchange Membrane Fuel Cells Renewable Energy 31 5 2006 719 727 https://doi.org/10.1016/j.renene.2005.09.003
- Shen , M. , Meuleman , W. , and Scott , K. The Characteristics of Power Generation of Static State Fuel Cells J Power Sources 115 2 2003 203 209 https://doi.org/10.1016/S0378-7753(02)00731-0
- Daud , W.R.W. et al. PEM Fuel Cell System Control: A Review Renewable Energy 113 2017 620 638 https://doi.org/10.1016/j.renene.2017.06.027
- Ma , T. , Lin , W. , Zhang , Z. , Kang , J. et al. Research on Electrochemical Impedance Spectroscope Behavior of Fuel Cell Stack under Different Reactant Relative Humidity Int J Hydrogen Energy 46 33 2021 17388 17396 https://doi.org/10.1016/j.ijhydene.2021.02.156
- Li , L. et al. Cold-Start Method for Proton-Exchange Membrane Fuel Cells Based on Locally Heating the Cathode Appl. Energy 254 113716 113716 https://doi.org/10.1016/j.apenergy.2019.113716
- Wu , J. , Xiao , Z. , Martin , J. et al. A Review of PEM Fuel Cell Durability: Degradation Mechanisms and Mitigation Strategies J Power Sources 184 1 2008 104 119 https://doi.org/10.1016/j.jpowsour.2008.06.006
- Ahluwalia , R.K. and Wang , X. Rapid Self-Start of Polymer Electrolyte Fuel Cell Stacks from Subfreezing Temperatures J Power Sources 162 1 2006 502 512 https://doi.org/10.1016/j.jpowsour.2006.06.071
- Lee , S.Y. , Kim , S.U. , Kim , H.J. et al. Water Removal Characteristics of Proton Exchange Membrane Fuel Cells Using a Dry Gas Purging Method J Power Sources 180 2 2008 784 790 https://doi.org/10.1016/j.jpowsour.2008.01.009
- Tajiri , K. , Wang , C.Y. , and Tabuchi , Y. Water Removal from a PEFC during Gas Purge Electrochim. Acta 53 22 2008 6337 6343 https://doi.org/10.1016/j.electacta.2008.04.035
- Xu , P. , Zhang , J. , Guo , X. , Gao , Y. et al. An Experimental Investigation into Gas Purge after Shutdown and Cold Start Performance of Proton Exchange Membrane Fuel Cell Journal of Tongji University (Natural Science) 045.0z1 2017 126 131 https://doi.org/10.11908/j.issn.0253-374x.2017.s1.022
- Wang , C. Gas Purge in a Polymer Electrolyte Fuel Cell J Electrochem. Soc. 2007 154 https://doi.org/10.1149/1.2776226
- Ito , H. , Maeda , T. , Kato , A. , et al. Gas Purge for Switching from Electrolysis to Fuel Cell Operation in Polymer Electrolyte Unitized Reversible Fuel Cells J Electrochem. Soc. 2010 157 7 1072 1080 https://doi.org/10.1149/1.3428709
- Ding , J. , Mu , Y. , Zhai , S. , and Tao , W. Numerical Study of Gas Purge in Polymer Electrolyte Membrane Fuel Cell Int J Heat Mass Transf. 103 2016 744 752 https://doi.org/10.1016/j.ijheatmasstransfer.2016.07.051
- Pasaogullari , U. and Wang , C. Two-Phase Modeling and Flooding Prediction of Polymer Electrolyte Fuel Cells J Electrochem. Soc. 152 2005 A380 https://doi.org/10.1149/1.1850339
- Wang , C. Two-phase Modeling of Gas Purge in a Polymer Electrolyte Fuel Cell J Power Sources 2008 183 609 18 https://doi.org/10.1016/j.jpowsour.2008.05.078
- Mu , Y.T. , He , P. , Ding , J. , and Tao , W. Modeling of the Operation Conditions on the Gas Purging Performance of Polymer Electrolyte Membrane Fuel Cells Int J Hydrogen Energy 42 2017 11788 11802 https://doi.org/10.1016/j.ijhydene.2017.02.108
- Tang , H.Y. , Santamaria , A.D. , Bachman , J. , and Park , J.W. Vacuum-Assisted Drying of Polymer Electrolyte Membrane Fuel Cell Appl. Energy 107 2013 264 270 https://doi.org/10.1016/j.apenergy.2013.01.053
- Luo , Y. and Jiao , K. Cold Start of Proton Exchange Membrane Fuel Cell Prog. Energy Combust. Sci. 64 2018 29 61 https://doi.org/10.1016/j.pecs.2017.10.003
- Kim , Y.S. , Kim , S.I. , Lee , N.W. , and Kim , M.S. Study on a Purge Method Using Pressure Reduction for Effective Water Removal in Polymer Electrolyte Membrane Fuel Cells Int J Hydrogen Energy 40 2015 9473 9484 https://doi.org/10.1016/j.ijhydene.2015.05.136
- Kim , S.I. , Lee , N.W. , Kim , Y.S. , and Kim , M.S. Effective Purge Method with Addition of Hydrogen on the Cathode Side for Cold Start in PEM Fuel Cell Int J Hydrogen Energy 38 2013 11357 11369 https://doi.org/10.1016/j.ijhydene.2013.06.101
- Tajiri , K. , Tabuchi , Y. , and Wang , C.Y. Isothermal Cold Start of Polymer Electrolyte Fuel Cells J Electrochem. Soc. 154 2007 B147 https://doi.org/10.1149/1.2402124
- Tajiri , K. , Tabuchi , Y. , Kagami , F. , Takahashi , S. et al. Effects of Operating and Design Parameters on PEFC Cold Start J Power Sources 165 2007 279 286 https://doi.org/10.1016/j.jpowsour.2006.12.017
- Pinton , E. , Fourneron , Y. , Rosini , S. et al. Experimental and Theoretical Investigations on a Proton Exchange Membrane Fuel Cell Starting Up at Subzero Temperatures J Power Sources 186 1 2009 80 88 https://doi.org/10.1016/j.jpowsour.2008.09.056
- Springer , T.E. Polymer Electrolyte Fuel Cell Model J Electrochem. Soc. 138 8 1991 2334 2342 https://doi.org/10.1149/1.2085971