This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Oxygen Storage Capacity (OSC) Measurement of 3-Way Automotive Catalysts Using the CATAGEN OMEGA Test Reactor
Technical Paper
2021-24-0083
ISSN: 0148-7191, e-ISSN: 2688-3627
This content contains downloadable datasets
Annotation ability available
Sector:
Language:
English
Abstract
A Three-way automotive catalyst's ability to store oxygen is still a crucial performance metric for modern day catalyst applications. With more stringent emissions legalisation, the oxygen storage capacity (OSC) within the catalyst can assist with converting different exhaust gases such as CO, THC and NOx under transient operating conditions. OSC is currently the only onboard catalyst performance metric recorded during a vehicle's useful life. Catalyst performance is correlated to this OSC measurement.
Rhodium is a precious metal used in automotive catalysts to help with the conversion of NOx. The price of rhodium is increasing drastically, requiring original equipment manufacturers (OEMs) to look at cost-effective alternatives to maintain NOx conversion within the exhaust stream.
OSC in the catalyst is possible due to ceria in the washcoat. Stored oxygen can help promote other reactions in the catalyst bed to help with the conversion of NOx. For a catalyst's OSC to be fully understood by an OEM a reliable, repeatable and accurate OSC measurement is required. A reliable OSC measurement allows the user to understand how OSC degrades throughout the full useful life (FUL) of the catalyst, helping to understand the catalyst's performance.
CATAGEN has developed a new, unique measurement technique with precise control of gas composition and test parameters to provide a pure measurement of performance to measure the OSC of the catalyst.
Authors
Citation
Data Sets - Support Documents
Title | Description | Download |
---|---|---|
Unnamed Dataset 1 | ||
Unnamed Dataset 2 |
Also In
References
- Bartholomew , C.H. Fundamentals of Industrial Catalytic Processes Jon Wiley & Sons 2006
- Rood , S. Recent Advance in Gasoline Three-Way Catalyst Formulation: A Review Journal of Automobile Engineering 234 4 2020 936 949
- Argus Media www.argusmedia.com/en/news
- Guillén-Hurtado , N. Three-Way Catalysts: Past, Present and Future DYNA 79 175 2012 114 121
- Maloney , P. https://uk.mathworks.com
- Khossusi , T. Development and Validation of an Oxygen Storage Model for Three Way Catalyst SETC - SAE International 2003
- Duprez , D. Oxygen Storage and Mobility on Model Three-Way Catalysts Topics in Catalysis Vols 16 /17 2001 1 4
- Trovarelli , A. Catalysis by Ceria and Related Materials London Imperial College Press 2013
- Yao , H.C. Ceria in Automotive Exhaust Catalysts Dearborn Ford motor company 1983
- LaBarge , J. The Effects of Caalyts Volume and Ceria COntent on the Emissions Performance and Oxygen Storage of Automotive Catalysts SAE Fuels and Lubricants - Technical Paper Series Philadelphia 1993
- Zhou , Z. NOx reduction on Ceria: Impact of lean-rich cycling Applied Catalysis B: Environmental 240 2019 79 91
- Blades , L. Ageing Mechanisms in Automotive Catalysts Belfast Queens University 2015
- Irwin , K. Ageing Mechanisms and Procedures for Automotive Catalysts Belfast Queens University Belfast 2018
- Woods , A. Ageing and Characterisation of Automotive Catalysts Belfast Queens University Belfast 2007
- Bosch 2005
- Grane , L.M. Creation of OBD Limit Motorcycle Catalysts Using Different Ageing Methods SAE World Congress Detroit 2021