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Understanding the Challenges Associated with Soot-in-Oil from Diesel Engines: A Review Paper
Technical Paper
2021-01-0568
ISSN: 0148-7191, e-ISSN: 2688-3627
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SAE WCX Digital Summit
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English
Abstract
The major drivers in the development of the latest generation of engines are environmental. For diesel engines, mitigating the effects of soot contamination remains a significant factor in meeting these challenges. There is general consensus of soot impacting oil performance. Considerable efforts have been made towards a greater understanding of soot-lubricant interaction and its effects on engine performance. However, with evolution of engine designs resulting in changes to soot composition/ properties, the mechanisms of soot-lubricant interaction in the internal combustion engine continue to evolve. A variety of mechanisms have been proposed to explain soot-induced wear in engine components. Furthermore, wear is not the only topic among researchers. Studies have shown that soot contributes to oil degradation by increasing its viscosity leading to pumpability and lubricant breakdown issues. It has also been noted that soot affects friction, but conflicting results have been presented in the literature. This paper aims to critically review and discuss the current understanding of soot-induced mechanisms in heavy-duty diesel engines, as reported in the literature. Emphasis will be given to the aspects of wear, friction, and viscosity, critically highlighting the main pathways for future research. Different hypotheses on wear and the potential mechanisms behind the soot-lubricant interaction are also discussed, showing potential issues related to soot contamination as well as the strong relationship with oil formulation. Multiple factors are responsible for wear and its impact seems to depend on the boundary lubrication conditions achieved during the test. Moreover, different wear rates have been found among the studies, ranging from some 103μm3/Nm to 200 103μm3/Nm. Although the particulate matter is the cause of poorer lubrication performances in many investigations, lower viscosity reductions with temperatures have been found in presence of soot contamination. Finally, variations in the friction coefficient up to 144% suggest a significant impact of particulate matter on the frictional behaviour of a lubricant.
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Pacino, A., Haffner-Staton, E., La Rocca, A., Smith, J. et al., "Understanding the Challenges Associated with Soot-in-Oil from Diesel Engines: A Review Paper," SAE Technical Paper 2021-01-0568, 2021, https://doi.org/10.4271/2021-01-0568.Data Sets - Support Documents
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References
- Reşitoğlu , İ.A. , Altinişik , K. , and Keskin , A. The Pollutant Emissions from Diesel-Engine Vehicles and Exhaust After treatment Systems Clean Technologies and Environmental Policy 17 1 15 27 2015
- Zhao , H. Advanced Direct Injection Combustion Engine Technologies and Development: Diesel Engines Elsevier 2009 160 168
- Tanin , K. , Wickman , D. , Montgomery , D. , Das , S. , and Reitz , R.D. The Influence of Boost Pressure on Emissions and Fuel Consumption of a Heavy-Duty Single-Cylinder DI Diesel Engine SAE Transactions 1198 1219 1999
- Rouaud , C. , Marchi , A. , Cooper , B. Integrated Thermal Management for a Downsized Diesel Engine with Low CO2 Emissions Vehicle Thermal Management Systems Conference and Exhibition (VTMS10) 2011 Elsevier 375 387
- Idicheria , C.A. , and Pickett , L.M. Soot Formation in Diesel Combustion Under High-EGR Conditions SAE Technical Paper 2005-01-3834 2005 https://doi.org/10.4271/2005-01-3834
- Mehta , P.S. , and Das , S. A Correlation for Soot Concentration in Diesel Exhaust Based on Fuel-Air Mixing Parameters Fuel 71 6 689 692 1992
- Kalghatgi , G.T. The Outlook for Fuels for Internal Combustion Engines International Journal of Engine Research 15 4 383 398 2014
- Keskin , A. , Gürü , M. , and Altıparmak , D. Influence of Metallic Based Fuel Additives on Performance and Exhaust Emissions of Diesel Engine Energy Conversion and Management 52 1 60 65 2011
- Hasan , M. , and Rahman , M.M. Performance and Emission Characteristics of Biodiesel-Diesel Blend and Environmental and Economic Impacts of Biodiesel Production: A Review Renewable and Sustainable Energy Reviews 74 938 948 2017
- Hegab , A. , La Rocca , A. , and Shayler , P. Towards Keeping Diesel Fuel Supply and Demand in Balance: Dual-Fuelling of Diesel Engines with Natural Gas Renewable and Sustainable Energy Reviews 70 666 697 2017
- Carden , P. , Pisani , C. , Andersson , J. , Field , I. et al. The Effect of Low Viscosity Oil on the Wear, Friction and Fuel Consumption of a Heavy Duty Truck Engine SAE International Journal of Fuels and Lubricants 6 2 311 319 2013
- Knothe , G. , Sharp , C.A. , and Ryan , T.W. Exhaust Emissions of Biodiesel, Petrodiesel, Neat Methyl Esters, and Alkanes in a New Technology Engine Energy & Fuels 20 1 403 408 2006
- Mayer , A. , Czerwinski , J. , Wyser , M. , Mattrel , P. , and Heitzer , A. Impact of RME/Diesel Blends on Particle Formation, Particle Filtration and PAH Emissions SAE Technical Paper 2005-01-1728 2005 https://doi.org/10.4271/2005-01-1728
- Kim , S. , Fletcher , R. , and Zachariah , M. Understanding the Difference in Oxidative Properties Between Flame and Diesel Soot Nanoparticles: The Role of Metals Environmental Science & Technology 39 11 4021 4026 2005
- Anderson , B. Dowson , D. , Taylor , C.M. , and Godet , M. Company Perspectives in Vehicle Tribology-Volvo. Seventeenth Leeds-Lyon Symposium on Tribology Oxford Elsevier 1991
- Leong , D. , Shayler , P. , Pegg , I. , and Murphy , M. Characterizing the Effect of Viscosity on Friction in the Piston Assembly of Internal Combustion Engines Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 221 4 469 478 2007
- Taylor , R. , Mainwaring , R. , and Mortier , R. Engine Lubricant Trends Since 1990 Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 219 5 331 346 2005
- Dennis , A. , Garner , C.P. , and Taylor , D. The Effect of EGR on Diesel Engine Wear SAE Technical Paper 1999-01-0839 1999 https://doi.org/10.4271/1999-01-0839
- Li , S. , Csontos , A.A. , Gable , B.M. , Passut , C.A. , and Jao , T.-C. Wear in Cummins M-11/EGR test engines SAE Technical Paper 2002-01-1672 2002 https://doi.org/10.4271/2002-01-1672
- Maricq , M.M. Chemical Characterization of Particulate Emissions from Diesel Engines: A Review Journal of Aerosol Science 38 11 1079 1118 2007
- Green , D.A. , Lewis , R. , and Dwyer-Joyce , R. Wear of Valve Train Components due to Soot Contaminated Lubricant SAE Technical Paper 2006-01-1098 2006 https://doi.org/10.4271/2006-01-1098
- Hu , E. , Hu , X. , Liu , T. , Fang , L. et al. The Role of Soot Particles in the Tribological Behavior of Engine Lubricating Oils Wear 304 1-2 152 161 2013
- Welling , O. , Collings , N. , Williams , J. , and Moss , J. Impact of Lubricant Composition on Low-Speed Pre-Ignition SAE Technical Paper 2014-01-1213 2014 https://doi.org/10.4271/2014-01-1213
- Green , D. , and Lewis , R. Effect of Soot on Oil Properties and Wear of Engine Components Journal of Physics D: Applied Physics 40 18 5488 2007
- Joly-Pottuz , L. , Matsumoto , N. , Kinoshita , H. , Vacher , B. et al. Diamond-Derived Carbon Onions as Lubricant Additives Tribology International 41 2 69 78 2008
- Nagai , I. , Endo , H. , Nakamura , H. , and Yano , H. Soot and Valve Train Wear in Passenger Car Diesel Engines SAE Technical Paper 831757 1983 https://doi.org/10.4271/831757
- Ratoi , M. , Castle , R. , Bovington , C. , and Spikes , H. The Influence of Soot and Dispersant on ZDDP Film Thickness and Friction Lubrication Science 17 1 25 43 2004
- Ryason , P. , Chan , I. , and Gilmore , J. Polishing Wear by Soot Wear 137 1 15 24 1990
- Olomolehin , Y. , Kapadia , R. , and Spikes , H. Antagonistic Interaction of Antiwear Additives and Carbon black Tribology Letters. 37 1 49 2010
- Salehi , F.M. , Khaemba , D. , Morina , A. , and Neville , A. Corrosive-Abrasive Wear Induced by Soot in Boundary Lubrication Regime Tribology Letters. 63 2 19 2016
- Rounds , F.G. Carbon: Cause of Diesel Engine Wear? SAE Technical Paper 770829 1977 https://doi.org/10.4271/770829
- Rounds , F. Soots from Used Diesel Engine Oils - Their Effects on Wear as Measured in 4-Ball Wear Tests SAE Technical Paper 810499 1981 https://doi.org/10.4271/810499
- Keane , M. , Xing , S.-G. , Harrison , J. , Ong , T. , and Wallace , W. Genotoxicity of Diesel-Exhaust Particles Dispersed in Simulated Pulmonary Surfactant Mutation Research/Genetic Toxicology 260 3 233 238 1991
- George , S. , Balla , S. , Gautam , V. , and Gautam , M. Effect of Diesel Soot on Lubricant Oil Viscosity Tribology International 40 5 809 818 2007
- Antusch , S. , Dienwiebel , M. , Nold , E. , Albers , P. et al. On the Tribochemical Action of Engine Soot Wear 269 1-2 1 12 2010
- George , S. , Balla , S. , and Gautam , M. Effect of Diesel Soot Contaminated Oil on Engine Wear Wear 262 9-10 1113 1122 2007
- Guo , M.-f. , Z-b , C. , Z-c , Z. , and Zhu , M.-h. Characterization and Lubrication Performance of Diesel Soot Nanoparticles as Oil Lubricant Additives RSC Advances 5 123 101965 101974 2015
- Liu , C. , Nemoto , S. , and Ogano , S. Effect of Soot Properties in Diesel Engine Oils on Frictional Characteristics Tribology Transactions 46 1 12 18 2003
- John , H. Internal Combustion Engine Fundamentals McGraw-Hill Science 1988 631 645
- Bockhorn , H. Soot Formation in Combustion: Mechanisms and Models Springer Science & Business Media 2013
- Lahaye , J. Soot in Combustion Systems and Its Toxic Properties Springer Science & Business Media 2013
- Wagner , H.G. Soot Formation in Combustion Symposium (International) on Combustion 1979 Elsevier 3 19
- Homann , K. Carbon Formation in Premixed Flames Combustion and Flame 11 4 265 287 1967
- Clague , A. , Donnet , J. , Wang , T. , and Peng , J. A Comparison of Diesel Engine Soot with Carbon Black Carbon 37 10 1553 1565 1999
- Gaddam , C.K. , and Vander Wal , R.L. Physical and Chemical Characterization of SIDI Engine Particulates Combustion and Flame 160 11 2517 2528 2013
- Pfau , S.A. , La Rocca , A. , Haffner-Staton , E. , Rance , G.A. et al. Soot in the Lubricating Oil: An Overlooked Concern for the Gasoline Direct Injection Engine? SAE Technical Paper 2019-01-0301 2019 https://doi.org/10.4271/2019-01-0301
- Lapuerta , M. , Martos , F.J. , and Herreros , J.M. Effect of Engine Operating Conditions on the Size of Primary Particles Composing Diesel Soot Agglomerates Journal of Aerosol Science 38 4 455 466 2007
- La Rocca , A. , Di Liberto , G. , Shayler , P. , and Fay , M. The Nanostructure of Soot-in-Oil Particles and Agglomerates from an Automotive Diesel Engine Tribology International 61 80 87 2013
- Su , D.S. , Jentoft , R.E. , Müller , J.-O. , Rothe , D. et al. Microstructure and Oxidation Behaviour of Euro IV Diesel Engine Soot: A Comparative Study with Synthetic Model Soot Substances Catalysis Today 90 1-2 127 132 2004
- Lee , K.O. , Cole , R. , Sekar , R. , Choi , M.Y. et al. Morphological Investigation of the Microstructure, Dimensions, and Fractal Geometry of Diesel Particulates Proceedings of the Combustion Institute 29 1 647 653 2002
- Lu , T. , Cheung , C. , and Huang , Z. Effects of Engine Operating Conditions on the Size and Nanostructure of Diesel Particles Journal of Aerosol Science 47 27 38 2012
- Orhan , O. , Haffner-Staton , E. , La Rocca , A. , and Fay , M. Characterisation of Flame-Generated Soot and Soot-in-Oil Using Electron Tomography Volume Reconstructions and Comparison with Traditional 2D-TEM Measurements Tribology International 104 272 284 2016
- Fino , D. , Bensaid , S. , Piumetti , M. , and Russo , N. A Review on the Catalytic Combustion of Soot in Diesel Particulate Filters for Automotive Applications: From Powder Catalysts to Structured Reactors Applied Catalysis A: General 509 75 96 2016
- Siegmann , K. , and Siegmann , H. Molecular Precursor of Soot and Quantification of the Associated Health Risk. Current Problems in Condensed Matter Springer 1998 143 160
- Brown , E. Jr. Friction and Wear Testing with the Modern Four-Ball Apparatus Wear 17 5-6 381 388 1971
- Penchaliah , R. , Harvey , T. , Wood , R. , Nelson , K. , and Powrie , H. The Effects of Diesel Contaminants on Tribological Performance on Sliding Steel on Steel Contacts Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 225 8 779 797 2011
- Ramkumar , P. , Wang , L. , Harvey , T. , Wood , R. et al. The effect of diesel engine oil contamination on friction and wear World Tribology Congress 2005 537 538
- Peng , J.-F. , Shen , M.-X. , and Cai , Z.-B. Nano Diesel Soot Particles Reduce Wear and Friction Performance Using an Oil Additive on a Laser Textured Surface Coatings 8 3 89 2018
- Braun , D. , Greiner , C. , Schneider , J. , and Gumbsch , P. Efficiency of Laser Surface Texturing in the Reduction of Friction Under Mixed Lubrication Tribology International 77 142 147 2014
- Zhang , H. , Zhang , D. , Hua , M. , Dong , G. , and Chin , K. A Study on the Tribological Behavior of Surface Texturing on Babbitt Alloy Under Mixed or Starved Lubrication Tribology Letters 56 2 305 315 2014
- Green , D. , and Lewis , R. The Effects of Soot-Contaminated Engine Oil on Wear and Friction: A Review Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering 222 9 1669 1689 2008
- Medalia , A.I. , Rivin , D. , and Sanders , D.R. A Comparison of Carbon Black with Soot Science of the Total Environment 31 1 1 22 1983
- Müller , J.-O. , Su , D.S. , Wild , U. , and Schlögl , R. Bulk and Surface Structural Investigations of Diesel Engine Soot and Carbon Black Physical Chemistry Chemical Physics 9 30 4018 4025 2007
- Watson , A.Y. , and Valberg , P.A. Carbon Black and Soot: Two Different Substances AIHAJ-American Industrial Hygiene Association 62 2 218 228 2001
- Kontou , A. , Southby , M. , and Spikes , H. Effect of Steel Hardness on Soot Wear Wear 390 236 245 2017
- Pfau , S.A. , La Rocca , A. , Haffner-Staton , E. , Rance , G.A. et al. Comparative Nanostructure Analysis of Gasoline Turbocharged Direct Injection and Diesel Soot-in-Oil with Carbon Black Carbon 139 342 352 2018
- Wedlock , D.J. , Shuff , P. , Dare-Edwards , M. , Jia , X. , and Williams , R.A. SAE Technical Paper 1999-01-1516 1999 https://doi.org/10.4271/1999-01-1516
- Corso , S. , and Adamo , R. The Effect of Diesel Soot on Reactivity of Oil Additives and Valve Train Materials SAE Technical Paper 841369 1984 https://doi.org/10.4271/841369
- Hosonuma , K. , Yoshida , K. , and Matsunaga , A. The Decomposition Products of Zinc Dialkyldithiophosphate in an Engine and their Interaction with Diesel Soot Wear 103 4 297 309 1985
- Green , D. , and Lewis , R. Investigation of soot contaminated lubricant wear mechanisms SAE Technical Paper 2007-01-1964 2007 https://doi.org/10.4271/2007-01-1964
- Skurai , T. , and Yoshida , K. Tribological Behaviour of Dispersed Phase Systems International Tribology Conference 1987 Institution of Engineers Australia 110
- Gautam , M. , Durbha , M. , Chitoor , K. , Jaraiedi , M. et al. Contribution of Soot Contaminated Oils to Wear SAE Technical Paper 981406 1998 https://doi.org/10.4271/981406
- Sato , H. , Tokuoka , N. , Yamamoto , H. , and Sasaki , M. Study on Wear Mechanism by Soot Contaminated in Engine Oil (First Report: Relation Between Characteristics of Used Oil and Wear) SAE Technical Paper 1999-01-3573 1999 https://doi.org/10.4271/1999-01-3573
- Kuo , C.C. , Passut , C.A. , Jao , T.-C. , Csontos , A.A. , and Howe , J.M. Wear Mechanism in Cummins M-11 High Soot Diesel Test Engines SAE Technical Paper 981372 1998 https://doi.org/10.4271/981372
- Green , D. , Lewis , R. , and Dwyer-Joyce , R. Wear Effects and Mechanisms of Soot-Contaminated Automotive Lubricants Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 220 3 159 169 2006
- Archard , J. Contact and Rubbing of Flat Surfaces Journal of Applied Physics 24 8 981 988 1953
- Eaton , M. and Halling , J. 1975
- Prasad , M.G. , and Lakshminarayanan , P. Estimation of Oil Drain Life of Engine Oils in New Generation Diesel Engines in Tropical Conditions SAE International Journal of Fuels and Lubricants 5 2 576 592 2012
- Parsons , G. Dispersancy in Diesel Lubricants-A Study with Particular Reference to Oil Thickening Due to Insolubles Accumulation Journal of the Institute of Petroleum 55 544 1969
- Smith , I. , and Chowings , A. Lubricating Oil Contamination in Indirect Injection Diesel Engines SAE Technical Paper 760723 1976 https://doi.org/10.4271/760723
- Bauer , H. , Cypra , A. , Beer , A. , and Bauer , H. Bosch Automotive Handbook Warrendale, Penn SAE 1996
- Yasutomi , S. , Maeda , Y. , and Maeda , T. Kinetic Approach to Engine Oil. 3. Increase in Viscosity of Diesel Engine Oil Caused by Soot Contamination Industrial & Engineering Chemistry Product Research and Development 20 3 540 544 1981
- Bardasz , E.A. , Carrick , V.A. , Ebeling , V.L. , George , H.F. et al. Understanding Soot Mediated Oil Thickening Through Designed Experimentation Part 2: GM 6.5 L SAE Technical Paper 961915 1996 https://doi.org/10.4271/961915
- Ryason , P. , and Hansen , T. Voluminosity of Soot Aggregates: A Means of Characterizing Soot-Laden Oils SAE Technical Paper 912343 1991 https://doi.org/10.4271/912343
- Miyahara , M. , Watanabe , Y. , Naitoh , Y. , Hosonuma , K. , and Tamura , K. Investigation into Extending Diesel Engine Oil Drain Interval (Part 1) - Oil Drain Interval Extension by Increasing Efficiency of Filtering Soot in Lubricating Oil SAE Technical Paper 912339 1991 https://doi.org/10.4271/912339
- McGeehan , J.A. , Rutherford , J.A. , and Couch , M. Clean Diesel Exhaust but Sooty Engines: The Importance of the Crankcase Oil SAE Technical Paper 912342 1991 https://doi.org/10.4271/912342
- Walther , C. The Evaluation of Viscosity Data Erdol Teer 7 382 384 1931
- Batko , M.A. , Florkowski , D.W. , Devlin , M.T. , Li , S. et al. Low Temperature Rheological Properties of Aged Crankcase Oils SAE Technical Paper 2000-01-2943 2000 https://doi.org/10.4271/2000-01-2943
- Zeidan , M. , Jia , X. , Williams , R.A. , and Wedlock , D.J. Simulation of Aggregation with Applications to Soot Laden Lubricating Fluids Particle & Particle Systems Characterization: Measurement and Description of Particle Properties and Behavior in Powders and Other Disperse Systems 21 6 473 482 2004
- Covitch , M. , Humphrey , B. , and Ripple , D. Oil Thickening in the Mack T-7 Engine Test—Fuel Effects and the Influence of Lubricant Additives on Soot Aggregation SAE Technical Paper 852126 1985 https://doi.org/10.4271/852126
- Yoshida , K. Effects of Sliding Speed and Temperature on Tribological Behavior with Oils Containing a Polymer Additive or Soot Tribology Transactions 33 2 221 228 1990
- Chinas-Castillo , F. , and Spikes , H. The Behavior of Diluted Sooted Oils in Lubricated Contacts Tribology Letters 16 4 317 322 2004