This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Neat Oxymethylene Ethers: Combustion Performance and Emissions of OME 2 , OME 3 , OME 4 and OME 5 in a Single-Cylinder Diesel Engine
Technical Paper
2020-01-0805
ISSN: 0148-7191, e-ISSN: 2688-3627
This content contains downloadable datasets
Annotation ability available
Sector:
Language:
English
Abstract
Diesel engines are arguably the superior device in the ground transportation sector in terms of efficiency and reliability, but suffer from inferior emission performance due to the diffusive nature of diesel combustion. Great research efforts gradually reduced nitrogen oxide (NOX) and particulate matter (PM) emissions, but the PM-NOX trade-off remained to be a problem of major concern and was believed to be inevitable for a long time. In the process of engine development, the modification of fuel properties has lately gained great attention. In particular, the oxygenate fuel oxymethylene ether (OME) has proven potential to not only drastically reduce emissions, but possibly resolve the formerly inevitable trade-off completely. Although intensified investigations with OME were conducted within the past decade, little is known about the specific influence of fuel properties inherent to unimolecular, high chain-length OME on combustion characteristics, emission performance and particle size. The latter is of special concern, as studies on oxygenate fuels reported increased formation of nanoparticles, which are known to have adverse effects on human health.
In this paper, the authors present a detailed analysis of emissions, combustion characteristics, and particle size of neat oxymethylene ethers. A single-cylinder diesel engine was fueled with neat OME2, OME3, OME4 and OME5 to evaluate effects that directly correlate with chain length. In the process, hydrogenated vegetable oil (HVO) was used as diesel reference fuel. It was found that a high chain length beneficially affects NOX with little drawbacks on thermal efficiency for the operation without exhaust gas recirculation. This trade-off clearly evolves favorable with high chain lengths, as NOX emissions are reduced in greater extent than engine efficiency. Particle size is not adversely influenced by the additional, fuel-bound oxygen. In comparison to HVO, all OME display a significant efficiency advantage in lean combustion due to enhanced burnout speed.
Authors
Topic
Citation
Dworschak, P., Berger, V., Härtl, M., and Wachtmeister, G., "Neat Oxymethylene Ethers: Combustion Performance and Emissions of OME2, OME3, OME4 and OME5 in a Single-Cylinder Diesel Engine," SAE Technical Paper 2020-01-0805, 2020, https://doi.org/10.4271/2020-01-0805.Data Sets - Support Documents
Title | Description | Download |
---|---|---|
Unnamed Dataset 1 | ||
Unnamed Dataset 2 | ||
Unnamed Dataset 3 | ||
Unnamed Dataset 4 |
Also In
References
- European Parliament Official Journal of the European Union 2009
- European Parliament Official Journal of the European Union 2009
- Schubiger , R. , Bertola , A. , and Boulouchos , K. Influence of EGR on Combustion and Exhaust Emissions of Heavy Duty DI-Diesel Engines Equipped with Common-Rail Injection Systems SAE Technical Paper 2001-01-3497 2001 https://doi.org/10.4271/2001-01-3497
- Akihama , K. , Takatori , Y. , Inagaki , K. , Sasaki , S. et al. Mechanism of the Smokeless Rich Diesel Combustion by Reducing Temperature SAE Technical Paper 2001-01-0655 2001 https://doi.org/10.4271/2001-01-0655
- Pierpont , D.A. , Montgomery , D.T. , and Reitz , R.D. Reducing Particulate and NOx Using Multiple Injections and EGR in a D.I. Diesel SAE Technical Paper 950217 2002 https://doi.org/10.4271/950217
- Uchida , N. , Daisho , Y. , Saito , T. , and Sugano , H. Combined Effects of EGR and Supercharging on Diesel Combustion and Emissions SAE Technical Paper 930601 1993 https://doi.org/10.4271/930601
- Yu , R.C. and Shahed , S.M. Effects of Injection Timing and Exhaust Gas Recirculation on Emissions from a D.I. Diesel Engine SAE Technical Paper 811234 1981 https://doi.org/10.4271/811234
- Mitchell , D.L. , Pinson , J.A. , and Litzinger , T.A. The Effects of Simulated EGR via Intake Air Dilution on Combustion in an Optically Accessible DI Diesel Engine SAE Technical Paper 932798 1993 https://doi.org/10.4271/932798
- Signer , M. , Heinze , P. , Mercogliano , R. , and Stein , H.J. European Programme on Emissions, Fuels and Engine Technologies (EPEFE)-Heavy Duty Diesel Study SAE Technical Paper 961074 1996 https://doi.org/10.4271/961074
- Barro , C. , Meyer , P. , and Boulouchos , K. Optical Investigations of Soot Reduction Mechanisms using Post-Injections in a Cylindrical Constant Volume Chamber (CCVC) SAE Technical Paper 2014-01-2839 2014 https://doi.org/10.4271/2014-01-2839
- Bertola , A. , Schubiger , R. , Kasper , A. , Matter , U. et al. Characterization of Diesel Particulate Emissions in Heavy-Duty DI-Diesel Engines with Common Rail Fuel Injection Influence of Injection Parameters and Fuel Composition SAE Technical Paper 2001-01-3573 2001 https://doi.org/10.4271/2001-01-3573
- Johnson , T.V. Review of Vehicular Emissions Trends SAE Int. J. Engines 8 3 1152 1167 2015 https://doi.org/10.4271/2015-01-0993
- Bagley , S.T. , Baumgard , K.J. , Gratz , L.D. , Johnson , J.H. et al. Characterization of Fuel and Aftertreatment Device Effects on Diesel Emissions Health Effects Institute Research Report 76 1996
- Su , D.S. , Müller , J.-O. , Jentoft , R.E. , Rothe , D. et al. Fullerene-Like Soot from EuroIV Diesel Engine: Consequences for Catalytic Automotive Pollution Control Topics in Catalysis 30/31 241 245 2004 10.1023/B:TOCA.0000029756.50941.02
- Härtl 2015
- Kunte , S. , Bertola , A. , Obrecht , P. , and Boulouchos , K. Temporal Soot Evolution and Diesel Engine Combustion: Influence of Fuel Composition, Injection Parameters, and Exhaust Gas Recirculation International Journal of Engine Research 7 6 459 470 2006 10.1243/14680874JER01006
- Mathis , U. , Mohr , M. , Kaegi , R. , Bertola , A. et al. Influence of Diesel Engine Combustion Parameters on Primary Soot Particle Diameter Environ. Sci. Technol. 39 6 1887 1892 2005 10.1021/es049578p
- Donaldson , K. , Li , X.Y. , and MacNee , W. Ultrafine (Nanometre) Particle Mediated Lung Injury Journal of Aerosol Science 29 5-6 553 560 1998 10.1016/S0021-8502(97)00464-3
- Seaton , A. , Godden , D. , MacNee , W. , and Donaldson , K. Particulate Air Pollution and Acute Health Effects The Lancet 345 8943 176 178 1995 10.1016/S0140-6736(95)90173-6
- Pope , C.A. , Schwartz , J. , and Ransom , M.R. Daily Mortality and PM10 Pollution in Utah Valley Archives of Environmental Health 47 3 211 217 1992 10.1080/00039896.1992.9938351
- Dockery , D.W. , Pope , C.A. , Xu , X. , Spengler , J.D. et al. An Association Between Air Pollution and Mortality in Six U.S. Cities The New England Journal of Medicine 329 24 1753 1759 1993 10.1056/NEJM199312093292401
- McEnally , C.S. , Pfefferle , L.D. , Atakan , B. , and Kohse-Höinghaus , K. Studies of Aromatic Hydrocarbon Formation Mechanisms in Flames: Progress towards Closing the Fuel Gap Progress in Energy and Combustion Science 32 3 247 294 2006 10.1016/j.pecs.2005.11.003
- Burger , J. , Siegert , M. , Ströfer , E. , and Hasse , H. Poly(Oxymethylene) Dimethyl Ethers as Components of Tailored Diesel Fuel: Properties, Synthesis and Purification Concepts Fuel 89 11 3315 3319 2010 10.1016/j.fuel.2010.05.014
- Burger , J. , Ströfer , E. , and Hasse , H. Production Process for Diesel Fuel Components Poly(Oxymethylene) Dimethyl Ethers from Methane-Based Products by Hierarchical Optimization with Varying Model Depth Chemical Engineering Research and Design 91 12 2648 2662 2013 10.1016/j.cherd.2013.05.023
- Burger , J. and Hasse , H. Multi-Objective Optimization Using Reduced Models in Conceptual Design of a Fuel Additive Production Process Chemical Engineering Science 99 12 118 126 2013 10.1016/j.ces.2013.05.049
- Schmitz , N. , Burger , J. , Ströfer , E. , and Hasse , H. From Methanol to the Oxygenated Diesel Fuel Poly(Oxymethylene) Dimethyl Ether: An Assessment of the Production Costs Fuel 185 67 72 2016 10.1016/j.fuel.2016.07.085
- Held , M. , Tönges , Y. , Pélerin , D. , Härtl , M. et al. On the Energetic Efficiency of Producing Polyoxymethylene Dimethyl Ethers from CO2 Using Electrical Energy Energy Environ. Sci. 12 3 1019 1034 2019 10.1039/C8EE02849D
- BMWi and BMU 2010
- European Commission 2011 10.2833/10759
- Schemme , S. , Samsun , R.C. , Peters , R. , and Stolten , D. Power-to-Fuel as a Key to Sustainable Transport Systems - An Analysis of Diesel Fuels Produced from CO2 and Renewable Electricity Fuel 205 198 221 2017 10.1016/j.fuel.2017.05.061
- Burger , J. , Ströfer , E. , and Hasse , H. Chemical Equilibrium and Reaction Kinetics of the Heterogeneously Catalyzed Formation of Poly(Oxymethylene) Dimethyl Ethers from Methylal and Trioxane Ind. Eng. Chem. Res. 51 39 12751 12761 2012 10.1021/ie301490q
- Devaux , D. , Yano , H. , Uchida , H. , Dubois , J.-L. et al. Electro-Oxidation of Hydrolysed Poly-Oxymethylene-Dimethylether on PtRu Supported Catalysts Electrochimica Acta 56 3 1460 1465 2011 10.1016/j.electacta.2010.10.088
- Baranton , S. , Uchida , H. , Tryk , D.A. , Dubois , J.L. et al. Hydrolyzed Polyoxymethylenedimethylethers as Liquid Fuels for Direct Oxidation Fuel Cells Electrochimica Acta 108 350 355 2013 10.1016/j.electacta.2013.06.138
- Sirman , M.B. , Owens , E.C. , and Whitney , K.A. Emissions Comparison of Alternative Fuels in an Advanced Automotive Diesel Engine SAE Technical Paper 2000-01-2048 2000 https://doi.org/10.4271/2000-01-2048
- Kenney , T.E. , Gardner , T.P. , Low , S.S. , Eckstrom , J.C. et al. Overall Results: Phase I Ad Hoc Diesel Fuel Test Program SAE Technical Paper 2001-01-0151 2001 https://doi.org/10.4271/2001-01-0151
- Kocis , D. , Song , K. , Lee , H. , and Litzinger , T. Effects of Dimethoxymethane and Dimethylcarbonate on Soot Production in an Optically-accessible DI Diesel Engine SAE Technical Paper 2000-01-2795 2000 https://doi.org/10.4271/2000-01-2795
- Zhu , R. , Miao , H. , Wang , X. , and Huang , Z. Effects of Fuel Constituents and Injection Timing on Combustion and Emission Characteristics of a Compression-Ignition Engine Fueled with Diesel-DMM Blends Proceedings of the Combustion Institute 34 2 3013 3020 2013 10.1016/j.proci.2012.06.174
- Maricq , M.M. , Chase , R.E. , Podsiadlik , D.H. , Siegl , W.O. et al. The Effect of Dimethoxy Methane Additive on Diesel Vehicle Particulate Emissions SAE Technical Paper 982572 1998 https://doi.org/10.4271/982572
- Vertin , K.D. , Ohi , J.M. , Naegeli , D.W. , Childress , K.H. et al. Methylal and Methylal-Diesel Blended Fuels for Use in Compression-Ignition Engines SAE Technical Paper 1999-01-1508 1999 https://doi.org/10.4271/1999-01-1508
- Ren , Y. , Huang , Z.H. , Jiang , D.M. , Liu , L.X. et al. Engine Performance and Emission Characteristics of a Compression Ignition Engine Fuelled with Diesel/Dimethoxymethane Blends Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering 219 7 905 914 2005 10.1243/095440705X28367
- Iannuzzi , S.E. , Barro , C. , Boulouchos , K. , and Burger , J. Combustion Behavior and Soot Formation/Oxidation of Oxygenated Fuels in a Cylindrical Constant Volume Chamber Fuel 167 49 59 2016 10.1016/j.fuel.2015.11.060
- Härtl , M. , Seidenspinner , P. , Jacob , E. , and Wachtmeister , G. Oxygenate Screening on a Heavy-Duty Diesel Engine and Emission Characteristics of Highly Oxygenated Oxymethylene Ether Fuel OME1 Fuel 153 328 335 2015 10.1016/j.fuel.2015.03.012
- Kitamura , T. , Ito , T. , Senda , J. , and Fujimoto , H. Mechanism of Smokeless Diesel Combustion with Oxygenated Fuels Based on the Dependence of the Equivalence Ration and Temperature on Soot Particle Formation International Journal of Engine Research 3 4 223 248 2002 10.1243/146808702762230923
- Härtl , M. , Pélerin , D. , Dworschak , P. , Maier , T. et al. Potential of the Sustainable C1-Fuels OME, DMC and MeFo for Particulate Free Combustion in DI and SI Engines Liebl , J. , Beidl , C. , and Maus , W. Internationaler Motorenkongress 2018, Proceedings Wiesbaden Springer Vieweg 2018 978-3-658-21014-4
- Pélerin , D. , Gaukel , K. , Härtl , M. , Jacob , E. et al. Potentials to Simplify the Engine System Using the Alternative Diesel Fuels Oxymethylene Ether OME1 and OME3−6 on a Heavy-Duty Engine Fuel 259 116231 2020 10.1016/j.fuel.2019.116231
- Tree , D.R. and Svensson , K.I. Soot Processes in Compression Ignition Engines Progress in Energy and Combustion Science 33 3 272 309 2007 10.1016/j.pecs.2006.03.002
- Curran , H.J. , Fisher , E.M. , Glaude , P.-A. , Marinov , N.M. et al. Detailed Chemical Kinetic Modeling of Diesel Combustion with Oxygenated Fuels SAE Technical Paper 2001-01-0653 2001 https://doi.org/10.4271/2001-01-0653
- Omari , A. , Heuser , B. , Pischinger , S. , and Rüdinger , C. Potential of Long-Chain Oxymethylene Ether and Oxymethylene Ether-Diesel Blends for Ultra-Low Emission Engines Applied Energy 239 1242 1249 2019 10.1016/j.apenergy.2019.02.035
- Valentino , G. and Iannuzzi , S. Effect of Different Fuels Properties on Emissions and Performance of a Light Duty Four-Cylinder Diesel Engine Under Premixed Combustion SAE Technical Paper 2014-01-2674 2014 https://doi.org/10.4271/2014-01-2674
- Liu , H. , Wang , Z. , Wang , J. , He , X. et al. Performance, Combustion and Emission Characteristics of a Diesel Engine Fueled with Polyoxymethylene Dimethyl Ethers (PODE3-4)/Desel Blends Energy 88 793 800 2015 10.1016/j.energy.2015.05.088
- Svensson , K.I. , Richards , M.J. , Mackrory , A.J. , and Tree , D.R. Fuel Composition and Molecular Structure Effects on Soot Formation in Direct-Injection Flames Under Diesel Engine Conditions SAE Technical Paper 2005-01-0381 2005 https://doi.org/10.4271/2005-01-0381
- Kitagawa , H. , Murayama , T. , Tosaka , S. , and Fujiwara , Y. The Effect of Oxygenated Fuel Additive on the Reduction of Diesel Exhaust Particulates SAE Technical Paper 2001-01-2020 2001 https://doi.org/10.4271/2001-01-2020
- Pellegrini , L. , Marchionna , M. , Patrini , R. , Beatrice , C. et al. Combustion Behaviour and Emission Performance of Neat and Blended Polyoxymethylene Dimethyl Ethers in a Light-Duty Diesel Engine SAE Technical Paper 2012-01-1053 2012 https://doi.org/10.4271/2012-01-1053
- Pellegrini , L. , Marchionna , M. , Patrini , R. , and Florio , S. Emission Performance of Neat and Blended Polyoxymethylene Dimethyl Ethers in an Old Light-Duty Diesel Car SAE Technical Paper( 2013-01-1035 ) 2013 https://doi.org/10.4271/2013-01-1035
- Delfort , B. , Durand , I. , Jaecker-Voirol , A. , Lacôme , T. et al. Oxygenated Compounds and Diesel Engine Pollutant Emissions Performances of New Generation of Products SAE Technical Paper 2002-01-2852 2002 https://doi.org/10.4271/2002-01-2852
- Cheng , A.S. , Dibble , R.W. , and Buchholz , B.A. The Effect of Oxygenates on Diesel Engine Particulate Matter SAE Technical Paper 2002-01-1705 2002 https://doi.org/10.4271/2002-01-1705
- Gomez , A. , Sidebotham , G. , and Glassman , I. Sooting Behavior in Temperature-Controlled Laminar Diffusion Flames Combustion and Flame 58 1 45 57 1984 10.1016/0010-2180(84)90077-4
- Haynes , B.S. and Wagner , H.G. Soot Formation Progress in Energy and Combustion Science 7 4 229 273 1981 10.1016/0360-1285(81)90001-0
- Huang , Z.H. , Ren , Y. , Jiang , D.M. , Liu , L.X. et al. Combustion and Emission Characteristics of a Compression Ignition Engine Fuelled with Diesel-Dimethoxy Methane Blends Energy Conversion and Management 47 11-12 1402 1415 2006 10.1016/j.enconman.2005.08.020
- Ren , Y. , Huang , Z. , Miao , H. , Di , Y. et al. Combustion and Emissions of a DI Diesel Engine Fuelled with Diesel-Oxygenate Blends Fuel 87 12 2691 2697 2008 10.1016/j.fuel.2008.02.017
- Song , J. , Alam , M. , Boehman , A. , and Kim , U. Examination of the Oxidation Behavior of Biodiesel Soot Combustion and Flame 146 4 589 604 2006 10.1016/j.combustflame.2006.06.010
- Vander Wal , R.L. and Mueller , C.J. Initial Investigation of Effects of Fuel Oxygenation on Nanostructure of Soot from a Direct-Injection Diesel Engine Energy Fuels 20 2364 2369 2006 10.1021/ef060201+
- Lautenschütz , L. , Oestreich , D. , Seidenspinner , P. , Arnold , U. et al. Physico-Chemical Properties and Fuel Characteristics of Oxymethylene Dialkyl Ethers Fuel 173 129 137 2016 10.1016/j.fuel.2016.01.060
- Lautenschütz , L. , Oestreich , D. , Seidenspinner , P. , Arnold , U. et al. Corrigendum to “Physico-chemical properties and fuel characteristics of oxymethylene dialkyl ethers” [ Fuel 173 (2016) 129-137] Fuel 209 812 2017 10.1016/j.fuel.2017.07.083
- Pellegrini , L. , Patrini , R. , and Marchionna , M. Effect of POMDME Blend on PAH Emissions and Particulate Size Distribution from an In-Use Light-Duty Diesel Engine SAE Technical Paper 2014-01-1951 2014 https://doi.org/10.4271/2014-01-1951
- Wang , Z. , Liu , H. , Ma , X. , Wang , J. et al. Homogeneous Charge Compression Ignition (HCCI) Combustion of Polyoxymethylene Dimethyl Ethers (PODE) Fuel 183 206 213 2016 10.1016/j.fuel.2016.06.033
- Liu , H. , Wang , Z. , Zhang , J. , Wang , J. et al. Study on Combustion and Emission Characteristics of Polyoxymethylene Dimethyl Ethers/Diesel Blends in Light-Duty and Heavy-Duty Diesel Engines Applied Energy 185 1393 1402 2017 10.1016/j.apenergy.2015.10.183
- Liu , J. , Wang , H. , Li , Y. , Zheng , Z. et al. Effects of Diesel/PODE (Polyoxymethylene Dimethyl Ethers) Blends on Combustion and Emission Characteristics in a Heavy Duty Diesel Engine Fuel 177 206 216 2016 10.1016/j.fuel.2016.03.019
- Hallgren , B.E. and Heywood , J.B. Effects of Oxygenated Fuels on DI Diesel Combustion and Emissions SAE Technical Paper 2001-01-0648 2001 https://doi.org/10.4271/2001-01-0648
- Hilden , D.L. , Eckstrom , J.C. , and Wolf , L.R. The Emissions Performance of Oxygenated Diesel Fuels in a Prototype DI Diesel Engine SAE Technical Paper 2001-01-0650 2001 https://doi.org/10.4271/2001-01-0650
- Brettschneider , J. Berechnung des Luftverhältnisses Lambda von Luft-Kraftstoff-Gemischen und des Einflusses von Messfehlern auf Lambda Bosch technische Berichte 6 4 177 186 1979
- Aatola , H. , Larmi , M. , Sarjovaara , T. , and Mikkonen , S. Hydrotreated Vegetable Oil (HVO) as a Renewable Diesel Fuel: Trade-off between NOx, Particulate Emission, and Fuel Consumption of a Heavy Duty Engine SAE Int. J. Engines 1 1 1251 1262 2009 https://doi.org/10.4271/2008-01-2500
- Pflaum , H. , Hofmann , P. , Geringer , B. , and Weissel , W. Potential of Hydrogenated Vegetable Oil (HVO) in a Modern Diesel Engine SAE Technical Paper 2010-32-0081 2010 https://doi.org/10.4271/2010-32-0081
- Zubel , M. , Bhardwaj , O.P. , Heuser , B. , Holderbaum , B. et al. Advanced Fuel Formulation Approach using Blends of Paraffinic and Oxygenated Biofuels: Analysis of Emission Reduction Potential in a High Efficiency Diesel Combustion System SAE Int. J. Fuels Lubr. 9 3 481 492 2016 https://doi.org/10.4271/2016-01-2179
- Kuronen , M. , Mikkonen , S. , Aakko , P. , and Murtonen , T. Hydrotreated Vegetable Oil as Fuel for Heavy Duty Diesel Engines SAE Technical Paper 2007-01-4031 2007 https://doi.org/10.4271/2007-01-4031
- Murtonen , T. , Aakko-Saksa , P. , Kuronen , M. , Mikkonen , S. et al. Emissions with Heavy-Duty Diesel Engines and Vehicles Using FAME, HVO and GTL Fuels with and without DOC+POC Aftertreatment SAE Int. J. Fuels Lubr. 2 2 147 166 2009 https://doi.org/10.4271/2009-01-2693
- Sugiyama , K. , Goto , I. , Kitano , K. , Mogi , K. et al. Effects of Hydrotreated Vegetable Oil (HVO) as Renewable Diesel Fuel on Combustion and Exhaust Emissions in Diesel Engine SAE Int. J. Fuels Lubr. 5 1 205 217 2012 https://doi.org/10.4271/2011-01-1954
- Boyd , R.H. Some Physical Properties of Polyoxymethylene Dimethyl Ethers J. Polym. Sci. 50 153 133 141 1961 10.1002/pol.1961.1205015316
- Zhu , J. , Lee , K.O. , Yozgatligil , A. , and Choi , M.Y. Effects of Engine Operating Conditions on Morphology, Microstructure, and Fractal Geometry of Light-Duty Diesel Engine Particulates Proceedings of the Combustion Institute 30 2 2781 2789 2005 10.1016/j.proci.2004.08.232
- Lee , K.O. , Cole , R. , Sekar , R. , Choi , M.Y. et al. Morphological Investigation of the Microstructure, Dimensions, and Fractal Geometry of Diesel Particulates Proceedings of the Combustion Institute 29 1 647 653 2002 10.1016/S1540-7489(02)80083-9
- Kittelson , D.B. Engines and Nanoparticles Journal of Aerosol Science 29 5-6 575 588 1998 10.1016/S0021-8502(97)10037-4