This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Reduction of NO x in a Single Cylinder Diesel Engine Emissions Using Selective Non-Catalytic Reduction (SNCR) with In-Cylinder Injection of Aqueous Urea
Technical Paper
2019-24-0144
ISSN: 0148-7191, e-ISSN: 2688-3627
This content contains downloadable datasets
Annotation ability available
Sector:
Language:
English
Abstract
The subject of this study is the effect of in-cylinder selective non-catalytic reduction (SNCR) of NOx emissions in diesel exhaust gas by means of direct injection of aqueous urea ((NH2)2CO) into the combustion chamber. A single cylinder diesel test engine was modified to accept an electronically controlled secondary common rail injection system to deliver the aqueous urea directly into the cylinder during engine operation. Direct in-cylinder injection was chosen to ensure precise delivery of the aqueous urea without the risk of any premature reactions taking place. The injection strategy was four molar ratios, 4.0, 2.0, 1.0 and 0.5 with five varying injection timings of 60, 20, 10, 0, and -30 degrees after top dead center (ATDC). The main secondary injection fluid, aqueous urea, was mixed with glycerol (C3H8O3) in an 80-20 ratio, by mass, with the desire to function as a lubricant for the secondary injector. In addition to the base line and aqueous urea tests, neat water injection and an 80-20 ratio, by mass, water-glycerol solution tests were also conducted to compare the effects of said additives as well. The data collected from the engine tests showed that the aqueous urea-glycerol solution secondary had no effect on the reduction of NOx and even resulted in an increase of up to 5% in some tests. This was due to the low average in-cylinder temperature as well as increasing the required residence time, prohibiting the reduction reaction from taking place. The neat water and water-glycerol solution secondary injection was found to have a reduction effect of up to 59% on NOx production in the emissions due to the evaporative cooling effect and increased heat capacity of the water.
Recommended Content
Technical Paper | New Catalytic Solutions for Tightening Emission Standards |
Aerospace Standard | Procedure for the Analysis and Evaluation of Gaseous Emissions from Aircraft Engines |
Topic
Citation
Timpanaro, A. and Nuszkowski, J., "Reduction of NOx in a Single Cylinder Diesel Engine Emissions Using Selective Non-Catalytic Reduction (SNCR) with In-Cylinder Injection of Aqueous Urea," SAE Technical Paper 2019-24-0144, 2019, https://doi.org/10.4271/2019-24-0144.Data Sets - Support Documents
Title | Description | Download |
---|---|---|
Unnamed Dataset 1 | ||
Unnamed Dataset 2 | ||
Unnamed Dataset 3 |
Also In
References
- Baukal , C. Everything You Need to Know about NO x November 2005 http://www.johnzink.com/wp-content/uploads/everything-about-nox.pdf
- U.S. Energy Information Administration International Energy Outlook 2017 2017 https://www.eia.gov/outlooks/archive/ieo17/
- Miller , J.A. and Bowman , T.C. Mechanism and Modeling of Nitrogen Chemistry in Combustion 15 287 338 1989
- May , W.R. x 2012
- Pulkrabek , W.W. Engineering Fundamentals of the Internal Combustion Engine Upper Saddle River, New Jersey Prentice Hall
- Ishida , M. , Ueki , H. , and Sakaguchi , D. x 1997
- Bedford , F. , Rutland , C. , Dittrich , P. , Raab , A. , and Wirbeleit , F. 2000
- Mailboom , A. and Tauzia , X. NO x and PM Emissions Reduction on an Automotive HSDI Diesel Engine with Waterindiesel Emulsion and EGR: An Experimental Study 90 11 3179 3192 2011
- Li , D. , Zhen , H. , Xingcai , L. , Wu-Gao , Z. , and Jian-Guang , Y. Physico-Chemical Properties of Ethanol-Diesel Blend Fuel and its Effect on Performance and Emissions of Diesel Engines 30 967 976 2004
- Xing-Cai , L. , Jian-Guang , Y. , Wu-Gao , Z. , and Zhen , H. Effect of Cetane Number Improver on Heat Release Rate and Emissions of High Speed Diesel Engine Fueled with Ethanol-Diesel Blend Fuel 83 2013 2020 2004
- Thompson , G.J. and Nuszkowski , J. Neat Fuel Influence on Biodiesel Blend Emissions International Journal of Engine Research 11 61 77 Aug. 18, 2009
- Weaver , C.S. and Turner , S.H. 1994
- Stanglmaier , R.H. , Ryan , T.W. , and Souder , J.S. x 2001
- West , B.H. and Sluder , C.S. x 2000
- Schenk , C. , McDonald , J. and Olson , B. x 2001
- Lyon , R.K. Aug 19, 1975
- Kimball-Linne , M.A. and Hanson , R.K. Combustion-Driven Flow Reactor Studies of Thermal DeNO x Reaction Kinetics 64 337 351 1986
- Bowman , C.T. and Hanson , R.K. Investigation of Selective Non-Catalytic Process for In-Situ Reduction of NOx and CO Emissions from Marine Gas Turbines and Diesel Engines Stanford, CA High Temperature Gas Dynamics Laboratory, Mechanical Engineering Department Stanford University 1997
- Lyon , R.K. Thermal DeNO x Environmental Science and Technology 21 3 231 238 1987
- Caton , J.A. and Siebers , D.L. Comparison of Nitric Oxide Removal by Cyanuric Acid and by Ammonia Combustion Science and Technology 65 277 293 1989
- Arand , J.K. , Verdes , R.P. , Muzio , J.L. , Niguel , L. , Sotter , J.G. , and Viejo , M. x June 17, 1980
- Caton , J.A. and Xai , Z. The Selective Non-Catalytic Removal (SNCR) of Nitric Oxides Froom Engine Exhaust Streams: Comparison of Three Processes ASME Journal of Engineering for Gas Turbines and Power 126 234 240 2004
- Yim , S.D. , Kim , S.J. , Baik , J.H. , Nam , I.-S. et al. Decomposition of Urea into NH3 for SCR Process Industrial Engineering Chemical Research 43 4856 4863 2004
- Xu , B. , Tian , H. , Yang , J. , Sun , D. , and Cai , S. A System of Selective Non-Catalytic Reduction of NO x for Diesel Engine Advanced Materials Research 201-203 643 646 2011
- Nakanishi , Y. , Yoshihara , Y. , Nishiwaki , K. , and Tanaka , T. Reduction of Nitric Oxide in Diesel Exhaust with the Addition of Methylamine JSME International Journal 46 1 2003
- Hui , Z. , Boyan , X. , and Chauncheng , W. Numerical Simulation to Reduce NO x of Diesel Engine Urea-SCR Sytem The Open Mechanical Engineering Journal 8 643 647 2014
- Hug , H.T. , Mayer , A. , and Hartanstein , A. 1993
- Xie , L. , Liu , F. , Ren , L. , Shi , X. et al. Excellent Performance of One-Pot Synthesized Cu-SSZ-13 Catalyst for the Selective Catalytic Reduction of NO x with NH3 Environmental Science & Technology 48 1 566 572 2014 10.1021/es4032002
- Nam , C.H. and Gibbs , B.M. SNCR Application to Diesel Engine DeNO x under Combustion-driven Flow Reactor Conditions Journal of Environmental Sciences 769 778 2012
- Nam , C.-M. , Kwon , G. , and Mok , Y. Diesel Engine NO x Reduction by SNCR Under Simulated Flow Reactor Conditions Environmental Engineering Research 11 3 149 155 2006
- Golovitchev , V.I. , Montorsi , L. , and Denbratt , I. Numerical Evaluation of a New Strategy of Emissions Reduction by Urea Injection For Heavy Duty Diesel Engines Engineering Applications of Computational Fluid Mechanics 1 3 189 206 2007
- Hossain , K.A. , Mohd-Jaafar , M.N. , Appalanidu , K.B. , Mustafa , A. , and Ani , F. N. Application of Urea Based SNCR System in the Combustion Effluent Containing Low Level of Baseline Nitric Oxide Environmental Technology 26 251 259 2005
- Miyamoto , N. , Ogawa , H. , Wang , J. , Shudo , T. , and Yamazaki , K. Diesel NO x Reduction with Ammonium Oxidizing Agents Directly Injected in to the Cylinder International Journal of Vehicle Design 16 1 71 79 1995
- Willand , J. , Teigeler , M. , Wirbeleit , F. , Enderle , C. et al. Selective Non-Catalytic NO x -Reduction in Diesel Engines Using Aqueous Urea SAE Technical Paper 982651 1998 10.4271/982651
- Kasuya , F. , Glarborg , P. , Johnsson , J. E. , and Dam-Johansen , K. The Thermal DeNO x Process; Influence of Partial Pressures and Temperature Chemical Engineering Science 50 9 1455 1466 1995
- Jeong , S.J. , Lee , S.-J. , and Kim , W.-S. Numerical Study on the Optimum Injection of Urea-Water Solution for SCR DeNO x Performance of a Heavy-Duty Diesel Engine to Improve DeNO x Performance and Reduce NH3 Slip Environmental Engineering Science 25 7 1017 1035 2008
- Maxpro Technologies, Inc.
- NTK x 2010
- ISO - International Organization of Standardization Diesel Engines - NO x Reduction Agent AUS 32 -- Part 4: Refilling Interface http://www.iso.org/iso/iso_catalogue/catalogue_tc/catalogue_detail.htm?csnumber=42941 2016
- 2017
- Kong , S. , Veltman , M. , and Gross , C. Performance of a Compression-Ignition Engine Using Direct-Injection of Liquid Ammonia/DME Mixture Proceeding of the Ammonia Fuel Conference 2011