This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Impedance Modeling and Aging Research of the Lithium-Ion Batteries Using the EIS Technique
Technical Paper
2019-01-0596
ISSN: 0148-7191, e-ISSN: 2688-3627
This content contains downloadable datasets
Annotation ability available
Sector:
Language:
English
Abstract
As the core component of electric vehicles (EVs), batteries attach increasingly general attention along with the rapid expansion of electric vehicle market. Battery performance effect directly the safety and reliability of the EVs, so its managing technologies are more and more crucial. Among them, the methods of estimating the state of health (SoH) and predicting remaining useful life become the focuses, which are essential to ensure their dependability and optimum performance over time. This paper mainly focuses on impedance modeling and aging research (aging diagnosis and life prediction) of lithium-ion batteries. Electrochemical impedance spectroscopy (EIS) technique is used to obtain impedance characteristic of batteries. On the one hand, equivalent circuit modeling (ECM) can be motivated by EIS, with the goal to fit measured impedance data using circuit elements. On the other hand, the aging research of batteries can be analyzed using the resistance information provided by EIS due to the correlation between battery resistance and lifetime. The possible causes of battery aging are analyzed based on changes in the impedance spectrum, which are obtained under different life conditions through an accelerated life experiment. According to the result and the corresponding electrode process, an improved Randels model is then established. Furthermore, a method to predict the battery life based on EIS is proposed. The battery life characterization parameters and calculation methods are defined according to related test manuals and standards. Then, the impedance amplitude of a certain frequency is selected as an estimation parameter. Finally, the first-order polynomial is selected as the fitting function comparing with the fitting results of various functions.
Recommended Content
Authors
Citation
Gao, Q., Dai, H., Wei, X., and Jiang, B., "Impedance Modeling and Aging Research of the Lithium-Ion Batteries Using the EIS Technique," SAE Technical Paper 2019-01-0596, 2019, https://doi.org/10.4271/2019-01-0596.Data Sets - Support Documents
Title | Description | Download |
---|---|---|
Unnamed Dataset 1 | ||
Unnamed Dataset 2 |
Also In
References
- Miller , P. Automotive Lithium-Ion Batteries State of the Art and Future Developments in Lithium-Ion Battery Packs for Passenger Car Applications Johnson Matthey Technology Review 59 1 4 13 2015
- Lu , L. , Han , X. , Hua , J. , and Ouyang , M. A Review on the Key Issues for Lithium-Ion Battery Management in Electric Vehicles Journal of Power Sources 226 3 272 288 2013
- Dai , H. , Zhou , Y. , Gu , W. , Wei , X. et al. Review on Life Studies of Traction Li-Ion Batteries in Electric Vehicles Chinese Journal of Power Sources 10 1952 1954 2014
- Cheng , S. , Zhang , J. , Liu , H. , Leng , Y. et al. Study on Cycling Deterioration of MH-Ni Battery by Electrochemical Impedance Spectroscopy (EIS) Chinese Journal of Power Sources 74 1 155 157 1999
- Sauvant-Moynot , V. , Bernard , J. , Mingant , R. , Delaille , A. et al. ALIDISSI, a Research Program to Evaluate Electrochemical Impedance Spectroscopy as a SOC and SOH Diagnosis Tool for Li-Ion Batteries Oil & Gas Science and Technology 65 1 79 89 2010
- Mingant , R. , Bernard , J. , Sauvant-Moynot , V. , Delaille , A. et al. EIS Measurements for Determining the SOC and SOH of Li-Ion Batteries ECS Transactions 33 39 41 53 2011
- Tröeltzsch , U. , Kanoun , O. , and Trankler , H. Characterizing Aging Effects of Lithium Ion Batteries by Impedance Spectroscopy Electrochim Acta 51 1664 1672 2006
- Eddahech , A. , Briat , O. , Henry , H. , Deletage , J.Y. et al. Ageing Monitoring of Lithium-Ion Cell during Power Cycling Tests Microelectron Reliab 51 2011 1968-1971
- Galeotti , M. , Cina , L. , Giammanco , C. et al. Performance Analysis and SOH (State of Health) Evaluation of Lithium Polymer Batteries through Electrochemical Impedance Spectroscopy Energy 89 678 686 2015
- Itagaki , M. , Kobari , N. , Yotsuda , S. , Watanabe , K. et al. LiCoO 2 Electrode/Electrolyte Interface of Li-Ion Rechargeable Batteries Investigated by In Situ Electrochemical Impedance Spectroscopy Journal of Power Sources 148 2 78 84 2005
- Jungst , R.G. , Nagasubramanian , G. , Case , H.L. , Liaw , B.Y. et al. Accelerated Calendar and Pulse Life Analysis of Lithium-Ion Cells Journal of Power Sources 119 6 870 873 2003
- Chen , C.H. , Liu , J. , and Amine , K. Symmetric Cell Approach and Impedance Spectroscopy of High Power Lithium-Ion Batteries Journal of Power Sources 96 2 321 328 2001
- Nobili , F. , Tossici , R. , and Marassi , R. An AC Impedance Spectroscopy Study of LixCoO 2 at Different Temperatures Journal of Physical Chemistry 106 15 3909 3915 2002
- Zhuang , Q. , Xu , S. , and Qiu , X. Diagnosis of Electrochemical Impedance Spectroscopy in Lithium Ion Batteries Progress in Chemistry 22 6 1044 1057 2010
- Lv , D. and Li , W. Study on Electrochemical Impedance Spectroscopies of Insertion and Deinsertion of Lithium Ion in Spinel Lithium Manganese Oxide Acta Chimica Sinica 61 2 225 229 2003
- Levi , M.D. , Gamolsky , K. , Aurbach , D. , Heider , U. et al. On Electrochemical Impedance Measurements of Li x Co 0.2 Ni 0.8 O 2 and Li x NiO 2 Intercalation Electrodes Electrochimica Acta 45 11 1781 1789 2000
- Vetter , J. , Novák , P. , Wagner , M. , Veit , C. et al. Ageing Mechanisms in Lithium-Ion Batteries Journal of Power Sources 147 1 269 281 2005
- Li , J. , Murphy , E. , Winnick , J. , and Kohl , P.A. Studies on the Cycle Life of Commercial Lithium Ion Batteries during Rapid Charge-Discharge Cycling Journal of Power Sources 102 1 294 301 2001
- Ning , G. , Haran , B. , and Popov , B.N. Capacity Fade Study of Lithium-Ion Batteries Cycled at High Discharge Rates Journal of Power Sources 117 1 160 169 2003
- Sauer , D.U. , Karden , E. , Fricke , B. , Blanke , H. et al. Charging Performance of Automotive Batteries - An Underestimated Factor Influencing Lifetime and Reliable Battery Operation Journal of Power Sources 168 1 22 30 2007
- Lv , D. , Li , W. , Liu , X. , and Qiu , S. AC Impedance Models for Deinsertion and Insertion of Li+ Battery Bimonthly 5 326 327 2003
- Vetter , J. , Novak , P. , Wagner , M.R. , Veit , C. et al. Ageing Mechanisms in Lithium-Ion Batteries Journal of Power Sources 147 1 269 281 2005
- Arora , P. , White , R.E. , and Doyle , M. Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Journal of the Electrochemical Society 145 10 3647 3667 1998
- Wu , Y. , Jiang , X. , and Xie , J. The Reasons of Rapid Decline in Cycle Life of Li-Ion Battery Battery Bimonthly 39 4 206 207 2009
- Buqa , H. , Würsig , A. , Vetter , J. , Spahr , M. et al. SEI Film Formation on Highly Crystalline Graphitic Materials in Lithium-Ion Batteries Journal of Power Sources 153 2 385 390 2006
- Koltypin , M. , Aurbach , D. , Nazar , L. , and Ellis , B. More on the Performance of LiFePO 4 Electrodes - The Effect of Synthesis Route, Solution Composition, Aging, and Temperature Journal of Power Sources 174 2 1241 1250 2007
- Zhang , S. , Xu , K. , and Jow , T. Low-Temperature Performance of Li-Ion Cells with a LiBF 4 -Based Electrolyte Journal of Solid State Electrochemistry 7 3 147 151 2003
- Zhang , S. , Xu , K. , and Jow , T. The Low Temperature Performance of Li-Ion Batteries Journal of Power Sources 115 1 137 140 2003
- Liu , P. , Wang , J. , Hicks-Garner , J. , Sherman , E. et al. Aging Mechanisms of LiFePO4 Batteries Deduced by Electrochemical and Structural Analyses Journal of the Electrochemical Society 157 4 A499 A507 2010
- Amine , K. , Liu , J. , and Belharouak , I. High-Temperature Storage and Cycling of C-LiFePO/Graphite Li-Ion Cells Electrochemistry Communications 7 7 669 673 2005
- Zhu , J. , Zeng , K. , and Lu , L. Cycling Effects on Surface Morphology, Nanomechanical and Interfacial Reliability of LiMn 2 O 4 Cathode in Thin Film Lithium Ion Batteries Electrochimica Acta 68 5 52 59 2012
- Wohlfahrt-Mehrens , M. , Vogler , C. , and Garche , J. Aging Mechanisms of Lithium Cathode Materials Journal of Power Sources 127 1-2 58 64 2004
- Zhuang , Q. , Liu , W. , and Wu , S. Factors Affecting the Ion Conductivity of Organic Electrolyte for Li-Ion Batteries Chinese Battery Industry 5 47 49 2005
- Zhang , S.S. , Xu , K. , and Jow , T.R. EIS Study on the Formation of Solid Electrolyte Interface in Li-Ion Battery Electrochimica Acta 51 1636 1640 2002
- Padhi , A.K. , Nanjundaswamy , K.S. , and Goodenough , J.B. Phospho-Olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries Journal of the Electrochemical Society 144 4 1188 1194 1997