Sampling System Investigation for the Determination of Semi-Volatile Organic Compounds (SVOC) Emissions From Engine Exhaust

Semi-volatile organic compounds (SVOC) are a group of compounds that may form during combustion and/or are present in the unburned portion of the fuel and lubricating oil which ultimately become part of the exhaust. Many of these compounds are considered toxic or carcinogenic. Since these compounds are present in very low concentrations in diesel engine exhaust, the methods for sampling, handling, and analyzing these compounds are critical to obtaining representative and repeatable results. Engine testing is typically performed using a dilution tunnel. With a dilution tunnel, the collection of a representative sample is important. Experiments were performed with a modified EPA Method TO-9A to determine the equilibration time and other sampling parameters required for the measurement of SVOC in dilute exhaust. The results show that representative results can be obtained with this method.