Characterization of Low Temperature Diesel Combustion with Various Dilution Gases

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO₂ + 64% Ar mixture which has a similar specific heat capacity as N₂ shows lower smoke emissions than with N₂. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation. Finally, smokeless and ultra-low NOx combustion with relatively high indicated thermal efficiency at 75% loads was realized by intake carbon dioxide enrichment.