Sulfur Tolerance of Selective Partial Oxidation of NO to NO2 in a Plasma

Authors

• B. M. Penetrante - Lawrence Livermore National Laboratory
• R. M. Brusasco - Lawrence Livermore National Laboratory
• B. T. Merritt - Lawrence Livermore National Laboratory
• G. E. Vogtlin - Lawrence Livermore National Laboratory

Topic

• Selective catalytic reduction (SCR)
• Diesel exhaust emissions
• Particulate matter (PM)
• Nitrogen oxides
• Hydrocarbons
• Particulate filters
• Catalysts

Citation

Also In

References

1. Hamada, H. Kintaichi, Y. Sasaki, M. Ito, T. Tabata, M. “Selective Reduction of Nitrogen Monoxide with Propane over Alumina and HZSM-5 Zeolite - Effect of Oxygen and Nitrogen Dioxide Intermediate” Appl. Catal. 70 L15 1991
2. Petunchi, J.O. Hall, W.K. “On the Role of Nitrogen Dioxide in the Mechanism of the Selective Reduction of NO x over Cu-ZSM-5 Zeolite” Appl. Catal. B: Environmental 2 L17 1993
3. Shelef, M. Montreuil, C.N. Jen, H.W. “NO 2 Formation Over Cu-ZSM-5 and the Selective Catalytic Reduction of NO” Catal. Lett. 26 277 1994
4. Yokoyama, C. Misono, M. “Catalytic Reduction of Nitrogen Oxides by Propene in the Presence of Oxygen over Cerium Ion-Exchanged Zeolites: 2. Mechanistic Study of Roles of Oxygen and Doped Metals” J.Catal. 150 9 1994
5. Kung, M. Bethke, K. Alt, D. Yang, B. Kung, H. NO x Reduction ACS Symposium Series 1995
6. Hirao, Y. Yokoyama, C. Misono, M. “Enhancement by Water Vapour of Catalytic Reduction of NO by Propene Over Mechanically Mixed Mn 2 O 3 and Sn-ZSM-5” Chem. Comm. March 7 597 1996
7. Maunala, T. Kintaichi, Y. Inaba, M. Haneda, M. Sato, K Hamada, H. “Enhanced Activity of In and Ga-Supported Sol-Gel Alumina Catalysts for NO Reduction by Hydrocarbons in Lean Conditions” Appl. Catal. B: Environmental 15 291 1998
8. Iwamoto, M. Hernandez, A.M. Zengyo, T. “Oxidation- of NO to NO 2 on a Pt-MFI Zeolite and Subsequent Reduction of NO x by C 2 H 4 on an In-MFI Zeolite: a Novel De-NO x Strategy in Excess Oxygen” Chemical Communications Jan 7 1997 37
9. Iwamoto, M. Zengyo, T. “Highly Selective Reduction of NO in Excess Oxygen through the Intermediate- Addition of Reductant (IAR) Between Pt-and Zn-MFI Zeolites” Chem. Lett. 1283 1997
10. Shimokawabe, M. Ohi, A. Takezawa, N. “Catalytic Reduction of Nitrogen Dioxide with Propene in the Presence and Absence of Oxygen Over Various Metal Oxides” React. Kinet. Catal. Lett. 52 393 1994
11. Takahashi N. Shinjoh H. Iijima T. Suzuki T. et al. “The New Concept 3-Way Catalyst for Automotive Lean-Burn Engine - NO x Storage and Reduction Catalyst” Catalysis Today 27 1996 63
12. Brogan, M.S. Brisley, R.J. Moore, J.S. Clark, A.D. “Evaluation of NO x Adsorber Catalyst Systems to Reduce Emissions of Lean Running Gasoline Engines” SAE Paper 962045 1996
13. Mahzoul, H. Brilhac, J.F. Gilot, P. “Experimental and Mechanistic Study of NO x Adsorption over NO x Trap Catalysts” Appl. Catal. B: Environmental 20 47 1999
14. Cooper, B.J. Thoss, J.E. “Role of NO in Diesel Particulate Emission Control” SAE Paper 890404 1989
15. Yoshida, K. Makino, S. Sumiya, S. Muramatsu, G. Helferich, R. “Simultaneous Reduction of NO x and Particulate Emission from Diesel Engine Exhaust” SAE Paper 892046 1989
16. Penetrante, B.M. Brusasco, R.M. Merritt, B.T. Pitz, W.J. Vogtlin, G.E. Kung, M.C. Kung, H.H. Wan, C.Z. Voss, K.E. “Plasma-Assisted Catalytic Reduction of NO x ” SAE Paper 982508 1998
17. Penetrante, B.M. Hsiao, M.C. Merritt, B.T. Vogtlin, G.E. Wallman, P.H. Neiger, M. Wolf, O. Hammer, T. Broer, S. “Pulsed Corona and Dielectric-Barrier Discharge Processing of NO in N 2 ” Appl. Phys. Lett. 68 3719 1996
18. Penetrante, B.M. Hsiao, M.C. Merritt, B.T. Vogtlin, G.E. Wallman, P.H. Kuthi A. Burkhart, C.P. Bayless, J.R. “Electron-Impact Dissociation of Molecular Nitrogen in Atmospheric-Pressure Non-Thermal Plasma Reactors” Appl. Phys. Lett. 67 3096 1995
19. Penetrante, B.M. Hsiao, M.C. Merritt, B.T. Vogtlin, G.E. Wallman, P.H. “Comparison of Electrical Discharge Techniques for Non-Thermal Plasma Processing of NO in N 2 ” IEEE Trans. Plasma Sci. 23 679 1995
20. McLarnon, C.R. Penetrante, B.M. “Effect of Reactor Design on the Plasma Treatment of NO x ” SAE Paper 982434 1998
21. McLarnon, C.R. Penetrante, B.M. “Effect of Gas Composition on the NO x Conversion Chemistry in a Plasma” SAE Paper 982433 1998
22. Morgan W. L. Penetrante, B. M. “ELENDIF: A Time-Dependent Boltzmann Solver for Partially Ionized Plasmas” Comp. Phys. Comm. 58 127 152 1990
23. Kee, R. J. Rupley F. M. Miller, J. A. “Chemkin-II: A FORTRAN Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics,” Sandia National Laboratories Report No. SAND89-8009B UC-706 April 1992
24. Atkinson, R. Baulch, D.L. Cox, R.A. Hampson, R.F. Jr., Kerr, J.A. Troe, J. “Evaluated Kinetic, Photochemical and Heterogeneous Data for Atmospheric Chemistry” J. Phys. Chem. Ref. Data 26 521 1997
25. Wilk, R.D. Cernansky, N.P. Pitz, W.J. Westbrook, C.K. “Propene Oxidation at Low and Intermediate Temperatures - A Detailed Chemical Kinetic Study” Combust. Flame 77 145 1989
26. Koert, D.N. Pitz, W.J. Bozzelli, J.W. “Chemical Kinetic Modeling of High Pressure Propane Oxidation and Comparison to Experimental Results” Twenty-Sixth International Symposium on Combustion The Combustion Institute Pittsburgh, PA 1996 633 640
27. Pitz, W.J. Westbrook, C.K. Leppard, W.R. “Autoignition Chemistry of C4 Olefins Under Motored Engine Conditions: A Comparison of Experimental and Modeling Results” SAE Paper 912315 1991
28. Marinov, N.M. Castaldi, M.J. Melius, C.F. Tsang, W. “Aromatic and Polycyclic Aromatic Hydrocarbon Formation in a Premixed Propane Flame” Comb. Sci. Tech. 28 295 1997

Cited By