Open Access

Acid Neutralization Rates—Why Total Base Number Doesn’t Tell the Whole Story: Understanding How the Colloidal Structure of Overbased Detergents Influences Acid Neutralization Rates

Journal Article
04-14-01-0003
ISSN: 1946-3952, e-ISSN: 1946-3960
Published March 30, 2021 by SAE International in United States
Acid Neutralization Rates—Why Total Base Number Doesn’t Tell the Whole Story: Understanding How the Colloidal Structure of Overbased Detergents Influences Acid Neutralization Rates
Sector:
Citation: Growney, D., Trickett, K., Walker, G., and Robin, M., "Acid Neutralization Rates—Why Total Base Number Doesn’t Tell the Whole Story: Understanding How the Colloidal Structure of Overbased Detergents Influences Acid Neutralization Rates," SAE Int. J. Fuels Lubr. 14(1):27-40, 2021, https://doi.org/10.4271/04-14-01-0003.
Language: English

References

  1. Howard , K. , and Peal , S. Motor Oil Development for Passenger Cars with Low CO 2 Output Mineraloeltechnik 54 1 1 16 2009
  2. Howard , K. et al. Combining Durability and Fuel Economy in Heavy Duty Diesel Lubricants Runhuayou 25 5 6 13 2010
  3. Souza de Carvalho , M. , Judith et al. Lubricant Viscosity and Viscosity Improver Additive Effects on Diesel Fuel Economy Tribology International 43 2298 2302 2010
  4. Fletcher , K. , Dingwell , L. , Yang , K. , Lam , W. et al. Engine Oil Additive Impacts on Low Speed Pre-Ignition SAE Int. J. Fuels Lubr. 9 3 612 620 2016 https://doi.org/10.4271/2016-01-2277
  5. Mosier , P.E. , Dietz , J.G. , and Sammut , A. 2015
  6. Mosier , P.E. , Dietz , J.G. , and Sammut , A. 2016
  7. Mortier , R.M. and Orszulik , S.T. Chemistry and Technology of Lubricants Second Edition Blackie 1996 352
  8. Burk , W.M. , Domonkos , D. , Donnelly , K. , Duncan , D.A. et al. Are the Traditional Methods for Determining Depletion of Total Base Number Providing Adequate Engine Protection? J. Fuels Lubr. 116 4 850 859 2007 https://doi.org/10.4271/2007-01-4001
  9. Cartwright , S.J. and Carey , L.R. Control of Engine Oil Acidity SAE Technical Paper 801366 1980 https://doi.org/10.4271/801366
  10. Ellis , J.C. , and Edgar , J.A. Wear Prevention (in Auto Engines) by Alkaline Lubricating Oils SAE Trans. 61 244 252 1953 https://www.jstor.org/stable/44553248
  11. Bray , U.B. , Moore , C.C. , and Merrill , D.R. Improvements in Diesel-Engine Lubricating Oils SAE Trans 34 35 42 1939 https://www.jstor.org/stable/44467918
  12. Diggs , S.H. Effect of Sulfur in Gasoline in Wrist-Pin Corrosion in Automobiles Ind. Eng. Chem. 20 16 17 1928
  13. Besser , C. et al. Investigation of Long-Term Engine Oil Performance Using Lab-Based Artificial Ageing Illustrated by the Impact of Ethanol as Fuel Component Tribol. Int. 46 1 174 182 2012
  14. Besser , C. et al. Impact of Engine Oil Degradation on Wear and Corrosion Caused by Acetic Acid Evaluated by Chassis Dynamometer Bench Tests Wear 317 1-2 64 76 2014
  15. Sautermeister , F.A. , and Priest , M. Physical and Chemical Impact of Sulphuric Acid on Cylinder Lubrication for Large 2-Stroke Marine Diesel Engines Tribol. Lett. 47 2 261 271 2012
  16. Duan , Y. et al. Neutralisation of Acetic Acid by Automobile Motor Oil Tribol. Int. 98 94 99 2016
  17. Duan , Y. et al. Neutralisation Mechanism of Acetic Acid by Overbased Colloidal Nanoparticles Tribol. Lett. 64 1 1 11 2016
  18. Fu , J. et al. Acid Neutralisation by Marine Cylinder Lubricants inside a Heating Capillary: Strong/Weak-Stick Collision Mechanisms Ind. Eng. Chem. Res. 45 16 5619 5627 2006
  19. Fu , J. et al. Ostwald Ripening: A Decisive Cause of Cylinder Corrosive Wear Tribol. Lett. 27 1 21 24 2007
  20. Garcia-Bermudes , M. , Rausa , R. , and Papadopoulos , K.D. Formation of Colloidal Shells on Acidic Droplets Undergoing Neutralisation in Marine Diesel Engine Cylinder Oils Tribol. Lett. 51 1 85 92 2013
  21. Wu , R.C. , Campbell , C.B. , and Papadopoulos , K.D. Acid-Neutralising of Marine Cylinder Lubricants: Effects of Nonionic Surfactants Ind. Eng. Chem. Res. 39 10 3926 3931 2000
  22. Wu , R.C. , Papadopoulos , K.D. , and Campbell , C.B. Visualization Test for Neutralisation of Acids by Marine Cylinder Lubricants AIChE J. 45 9 2011 2017 1999
  23. Agarwal , A.K. Biofuels (Alcohols and Biodiesel) Applications as Fuels for Internal Combustion Engines Prog. Energy Combust. Sci. 33 3 233 271 2007
  24. Baena , L.M. , Gomez , M. , and Calderon , J.A. Aggressiveness of a 20% Bioethanol-80% Gasoline Mixture on Autoparts: I Behavior of Metallic Materials and Evaluation of Their Electrochemical Properties Fuel 95 320 328 2012
  25. Galsworthy , J. , Hammond , S. , and Hone , D. Oil-Soluble Colloidal Additives Curr. Opin. Colloid Interface Sci. 5 5-6 274 279 2000
  26. Hone , D.C. et al. Colloidal Chemistry of Lubricating Oils Reactions and Synthesis in Surfactant Systems Surfactant Science Series New York Marcel Dekker, Cop. 2001 385 394
  27. Hudson , L.K. , Eastoe , J. , and Dowding , P.J. Nanotechnology in Action: Overbased Nanodetergents as Lubricant Oil Additives Adv. Colloid Interface Sci. 123-126 425 431 2006
  28. Lancon , D. and Doyen , V. 2012
  29. Wohltjen , H. et al. Solid State Microsensors for Lubricant Condition Monitoring: II. Total Base Number Lubr. Eng. 50 11 861 866 1994
  30. Papke , B.L. Neutralisation of Basic Oil-Soluble Calcium Sulfonates by Carboxylic Acids Tribol. Trans. 31 4 420 426 1988
  31. Hone , D.C. et al. Mechanism of Acid Neutralisation by Overbased Colloidal Additives in Hydrocarbon Media Langmuir 16 2 340 346 2000
  32. O'Sullivan , T.P. , Vickers , M.E. , and Heenan , R.K. The Characterization of Oil-Soluble Calcium Carbonate Dispersions Using Small-Angle x-Ray Scattering (SAXS) and Small-Angle Neutron Scattering (SANS) J. Appl. Crystallogr. 24 5 732 739 1991
  33. Ottewill , R.H. et al. Small-Angle Neutron-Scattering Studies on Nonaqueous Dispersions. Part 5: Magnesium Carbonate Dispersions in Hydrocarbon Media Colloid Polym. Sci. 270 6 602 608 1992
  34. Markovic , I. , and Ottewill , R.H. Small Angle Neutron Scattering Studies on Nonaqueous Dispersions of Calcium Carbonate. Part III. Concentrated Dispersions Colloid Polym. Sci. 264 5 454 462 1986
  35. Markovic , I. , and Ottewill , R.H. Small Angle Neutron Scattering Studies on Nonaqueous Dispersions of Calcium Carbonate. Part II. Determination of the Form Factor for Concentric Spheres Colloid Polym. Sci. 264 1 65 76 1986
  36. Griffiths , J.A. , and Heyes , D.M. Atomistic Simulation of Overbased Detergent Inverse Micelles Langmuir 12 10 2418 2424 1996
  37. Mansot , J.L. , Hallouis , M. , and Martin , J.M. Colloidal Antiwear Additives. 2. Tribological Behavior of Colloidal Additives in Mild Wear Regime Colloids Surf., A 75 25 31 1993
  38. Fabregas , J.L. , and Cucala , J. Influence of Microphysical Structure on In Vitro Activity of New Synthetic Antacids International Journal of Pharmaceutics 52 173 178 1989
  39. Meyer , T.A. , and Volk , G.W. Effect of Particle Size of Limestones on Soil Reaction, Exchangeable Cations, and Plant Growth Soil Science 73 37 52 1952
  40. Huang , J. , Fisher , P.R. , and Argo , W.R. Container Substrate-pH Response to Differing Limestone Type and Particle Size HortScience 42 1268 1273 2007
  41. Nave , S. et al. What Is So Special about Aerosol-OT? 2. Microemulsion Systems Langmuir 16 23 8741 8748 2000
  42. Eastoe , J. Surfactant Chemistry Wuhan W.U. Press 2003
  43. Tavacoli , J.W. et al. Effect of Water on Overbased Sulfonate Engine Oil Additives Langmuir 24 8 3807 3813 2008
  44. Heenan , R.K. 1989

Cited By